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{{Short description|Inorganic compound}}
{{Short description|Inorganic compound}}
{{chembox
{{chembox
| Verifiedfields = changed
| Verifiedfields = changed
| Watchedfields = changed
| Watchedfields = changed
| verifiedrevid = 476995619
| verifiedrevid = 476995619
| Name = Cobalt(II) sulfate
| Name = Cobalt(II) sulfate
| ImageFile1 = Cobaltsulfat.JPG
| ImageFile1 = Cobalt(II) Sulfate.png
| ImageSize = 260 px
| ImageSize = 260 px
| ImageName = Cobalt(II) sulfate hydrate
| ImageName = Cobalt(II) sulfate hydrate
| ImageFile2 = Coaq6SO4.tif
| ImageFile2 = Coaq6SO4.tif
| ImageSize2 =
| ImageSize2 =
| ImageName2 = Cobalt(II) sulfate Xray
| ImageName2 = Cobalt(II) sulfate Xray
| IUPACName = Cobalt(II) sulfate
| IUPACName = Cobalt(II) sulfate
| OtherNames = Cobaltous sulfate
| OtherNames = Cobaltous sulfate
|Section1={{Chembox Identifiers
| Section1 = {{Chembox Identifiers
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 23338
| ChemSpiderID = 23338
| ChEBI_Ref = {{ebicite|correct|EBI}}
| ChEBI_Ref = {{ebicite|correct|EBI}}
| ChEBI = 53470
| ChEBI = 53470
⚫
| SMILES = [Co+2].[O-]S([O-])(=O)=O
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII = H7965X29HX
| UNII = H7965X29HX
Line 24: Line 23:
| UNII3 = Y8N698ZE0T
| UNII3 = Y8N698ZE0T
| UNII3_Comment = (heptahydrate)
| UNII3_Comment = (heptahydrate)
⚫
| SMILES = [Co+2].[O-]S([O-])(=O)=O

| SMILES_Comment = anhydrous
| SMILES1 = [OH2+][Co-4]([OH2+])([OH2+])([OH2+])([OH2+])[OH2+].[O-]S(=O)(=O)[O-]
| SMILES1_Comment = hexahydrate
| SMILES2 = [OH2+][Co-4]([OH2+])([OH2+])([OH2+])([OH2+])[OH2+].[O-]S(=O)(=O)[O-].O
| SMILES2_Comment = heptahydrate
| InChIKey = KTVIXTQDYHMGHF-NUQVWONBAJ
| InChIKey = KTVIXTQDYHMGHF-NUQVWONBAJ
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
Line 46: Line 50:
| KEGG3_Comment = (heptahydrate)
| KEGG3_Comment = (heptahydrate)
}}
}}
|Section2={{Chembox Properties
| Section2 = {{Chembox Properties
| Formula = CoSO<sub>4</sub>·(H<sub>2</sub>O)<sub>n</sub> (n=0,1,6,7)
| Formula = CoSO<sub>4</sub>·(H<sub>2</sub>O)<sub>n</sub> (n=0,1,6,7)
| MolarMass = 154.996 g/mol (anhydrous) <br> 173.01 g/mol (monohydrate) <br> 263.08 g/mol (hexahydrate) <br> 281.103 g/mol (heptahydrate)
| MolarMass = 154.996 g/mol (anhydrous) <br> 173.01 g/mol (monohydrate) <br> 263.08 g/mol (hexahydrate) <br> 281.103 g/mol (heptahydrate)
Line 60: Line 64:
| RefractIndex = 1.639 (monohydrate) <br> 1.540 (hexahydrate) <br> 1.483 (heptahydrate)
| RefractIndex = 1.639 (monohydrate) <br> 1.540 (hexahydrate) <br> 1.483 (heptahydrate)
| MagSus = +10,000·10<sup>−6</sup> cm<sup>3</sup>/mol}}
| MagSus = +10,000·10<sup>−6</sup> cm<sup>3</sup>/mol}}
|Section3={{Chembox Structure
| Section3 = {{Chembox Structure
| CrystalStruct = orthorhombic (anhydrous) <br> monoclinic (monohydrate, heptahydrate)}}
| CrystalStruct = orthorhombic (anhydrous) <br> monoclinic (monohydrate, heptahydrate)}}
|Section7={{Chembox Hazards
| Section7 = {{Chembox Hazards
| ExternalSDS = [http://hazard.com/msds/mf/baker/baker/files/c4972.htm JT Baker MSDS]
| ExternalSDS = [https://www.inchem.org/documents/icsc/icsc/eics1396.htm ICSC 1396] (heptahydrate)
| GHSPictograms = {{GHS07}}{{GHS08}}{{GHS09}}
| GHSPictograms = {{GHS07}}{{GHS08}}{{GHS09}}
| GHSSignalWord = Danger
| GHSSignalWord = Danger
| HPhrases = {{H-phrases|302|317|334|341|350|360|400|410}}
| HPhrases = {{H-phrases|302|317|334|341|350|360|410}}
| PPhrases = {{P-phrases|201|202|261|264|270|272|273|280|281|285|301+312|302+352|304+341|308+313|321|330|333+313|342+311|363|391|405|501}}
| PPhrases = {{P-phrases|201|202|261|264|270|272|273|280|281|285|301+312|302+352|304+341|308+313|321|330|333+313|342+311|363|391|405|501}}
| NFPA-H = 2
| NFPA-H = 2
Line 74: Line 78:
| FlashPt = Non-flammable
| FlashPt = Non-flammable
| LD50 = 424 mg/kg (oral, rat)
| LD50 = 424 mg/kg (oral, rat)
| PEL = }}}}
| PEL = }}
}}
[[File:Сульфат кобальта гептагидрат.jpg|alt=Cobalt(II) sulfate|thumb|Cobalt(II) sulfate heptahydrate]]

'''Cobalt(II) sulfate''' is any of the [[inorganic compound]]s with the formula CoSO<sub>4</sub>(H<sub>2</sub>O)<sub>x</sub>. Usually cobalt sulfate refers to the hexa- or heptahydrates CoSO<sub>4</sub><sup>.</sup>6H<sub>2</sub>O or CoSO<sub>4</sub><sup>.</sup>7H<sub>2</sub>O, respectively.<ref name=Ullmann/> The heptahydrate is a red solid that is soluble in water and [[methanol]]. Since cobalt(II) has an odd number of electrons, it salts are [[paramagnetic]].
'''Cobalt(II) sulfate''' is any of the [[inorganic compound]]s with the formula CoSO<sub>4</sub>(H<sub>2</sub>O)<sub>x</sub>. Usually cobalt sulfate refers to the hexa- or heptahydrates CoSO<sub>4</sub><sup>.</sup>6H<sub>2</sub>O or CoSO<sub>4</sub><sup>.</sup>7H<sub>2</sub>O, respectively.<ref name=Ullmann/> The heptahydrate is a red solid that is soluble in water and [[methanol]]. Since cobalt(II) has an odd number of electrons, its salts are [[paramagnetic]].


==Preparation, and structure==
==Preparation, and structure==
It forms by the reaction of metallic cobalt, its oxide, hydroxide, or carbonate with aqueous sulfuric acid:<ref name=Ullmann/>
It forms by the reaction of metallic cobalt, its oxide, hydroxide, or carbonate with aqueous sulfuric acid:<ref name=Ullmann/>
:{{chem2 | Co + H2SO4 + 7 H2O -> CoSO4(H2O)7 + H2 }}
:Co + H<sub>2</sub>SO<sub>4</sub> + 7 H<sub>2</sub>O → CoSO<sub>4</sub>(H<sub>2</sub>O)<sub>7</sub> + H<sub>2</sub>
:{{chem2 | CoO + H2SO4 + 6 H2O -> CoSO4(H2O)7 }}
:CoO + H<sub>2</sub>SO<sub>4</sub> + 6 H<sub>2</sub>O → CoSO<sub>4</sub>(H<sub>2</sub>O)<sub>7</sub>


The heptahydrate is only stable at humidity >70% at room temperature, otherwise it converts to the hexahydrate.<ref name=Redhammer/> The hexahydrate converts to the monohydrate and the anhydrous forms at 100 and 250&nbsp;°C, respectively.<ref name=Ullmann/>
The heptahydrate is only stable at humidity >70% at room temperature, otherwise it converts to the hexahydrate.<ref name=Redhammer/> The hexahydrate converts to the monohydrate and the anhydrous forms at 100 and 250&nbsp;°C, respectively.<ref name=Ullmann/>
:{{chem2 | CoSO4(H2O)7 -> CoSO4(H2O)6 + H2O }}
:CoSO<sub>4</sub>(H<sub>2</sub>O)<sub>7</sub> → CoSO<sub>4</sub>(H<sub>2</sub>O)<sub>6</sub> + H<sub>2</sub>O
:{{chem2 | CoSO4(H2O)6 -> CoSO4(H2O) + 5 H2O }}
:CoSO<sub>4</sub>(H<sub>2</sub>O)<sub>6</sub> → CoSO<sub>4</sub>(H<sub>2</sub>O) + 5{{nbsp}}H<sub>2</sub>O
:{{chem2 | CoSO4(H2O) -> CoSO4 + H2O }}
:CoSO<sub>4</sub>(H<sub>2</sub>O) → CoSO<sub>4</sub> + H<sub>2</sub>O


The hexahydrate is a [[metal aquo complex]] consisting of [[octahedral molecular geometry|octahedral]] [Co(H<sub>2</sub>O)<sub>6</sub>]<sup>2+</sup> ions associated with [[sulfate]] [[anions]] (see image in table).<ref>Elerman, Y. "Refinement of the Crystal Structure of CoSO<sub>4</sub> · 6H<sub>2</sub>O" Acta Crystallographica Section C 1988, volume 44, p599-p601. {{doi|10.1107/S0108270187012447}}</ref> The monoclinic heptahydrate has also been characterized by [[X-ray crystallography]]. It also features [Co(H<sub>2</sub>O)<sub>6</sub>]<sup>2+</sup> octahedra as well as one [[water of crystallization]].<ref name=Redhammer>{{cite journal |doi=10.2138/am.2007.2229|title=Co<sup>2+</sup>-Cu<sup>2+</sup> Substitution in Bieberite Solid-Solution Series, (Co<sub>1−x</sub>''Cu<sub>x</sub>'')SO<sub>4</sub> · 7H<sub>2</sub>O, 0.00 ≤ x ≤ 0.46: Synthesis, Single-Crystal Structure Analysis, and Optical Spectroscopy|year=2007|last1=Redhammer|first1=G. J.|last2=Koll|first2=L.|last3=Bernroider|first3=M.|last4=Tippelt|first4=G.|last5=Amthauer|first5=G.|last6=Roth|first6=G.|journal=American Mineralogist|volume=92|issue=4|pages=532–545|bibcode=2007AmMin..92..532R|s2cid=95885758}}</ref>
The hexahydrate is a [[metal aquo complex]] consisting of [[octahedral molecular geometry|octahedral]] [Co(H<sub>2</sub>O)<sub>6</sub>]<sup>2+</sup> ions associated with [[sulfate]] [[anions]] (see image in table).<ref>{{cite journal | doi = 10.1107/S0108270187012447| title = Refinement of the crystal structure of CoSO4.6H2O| date = 1988| last1 = Elerman| first1 = Y.| journal = Acta Crystallographica Section C Crystal Structure Communications| volume = 44| issue = 4| pages = 599–601| bibcode = 1988AcCrC..44..599E}}</ref> The monoclinic heptahydrate has also been characterized by [[X-ray crystallography]]. It also features [Co(H<sub>2</sub>O)<sub>6</sub>]<sup>2+</sup> octahedra as well as one [[water of crystallization]].<ref name=Redhammer>{{cite journal |doi=10.2138/am.2007.2229|title=Co<sup>2+</sup>-Cu<sup>2+</sup> Substitution in Bieberite Solid-Solution Series, (Co<sub>1−x</sub>''Cu<sub>x</sub>'')SO<sub>4</sub> · 7H<sub>2</sub>O, 0.00 ≤ x ≤ 0.46: Synthesis, Single-Crystal Structure Analysis, and Optical Spectroscopy|year=2007|last1=Redhammer|first1=G. J.|last2=Koll|first2=L.|last3=Bernroider|first3=M.|last4=Tippelt|first4=G.|last5=Amthauer|first5=G.|last6=Roth|first6=G.|journal=American Mineralogist|volume=92|issue=4|pages=532–545|bibcode=2007AmMin..92..532R|s2cid=95885758}}</ref>


==Uses and reactions==
==Uses and reactions==
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Hydrated cobalt(II) sulfate is used in the preparation of [[pigment]]s, as well as in the manufacture of other cobalt salts. Cobalt pigment is used in porcelains and glass. Cobalt(II) sulfate is used in storage [[Battery (electricity)|batteries]] and [[electroplating]] baths, [[sympathetic ink]]s, and as an additive to soils and animal feeds. For these purposes, the cobalt sulfate is produced by treating cobalt oxide with sulfuric acid.<ref name=Ullmann/>
Hydrated cobalt(II) sulfate is used in the preparation of [[pigment]]s, as well as in the manufacture of other cobalt salts. Cobalt pigment is used in porcelains and glass. Cobalt(II) sulfate is used in storage [[Battery (electricity)|batteries]] and [[electroplating]] baths, [[sympathetic ink]]s, and as an additive to soils and animal feeds. For these purposes, the cobalt sulfate is produced by treating cobalt oxide with sulfuric acid.<ref name=Ullmann/>


Being commonly available commercially, the heptahydrate is a routine source of cobalt in [[coordination chemistry]].<ref>{{cite journal |doi=10.1002/9780470132371.ch58|title=Resolution of the Tris(ethylenediamine)cobalt(III) Ion|journal=Inorganic Syntheses|year=1950|volume=6|last1=Broomhead|first1=J. A.|last2=Dwyer|first2=F. P.|last3=Hogarth|first3=J. W.|title=Inorganic Syntheses|pages=183–186|isbn=9780470132371}}</ref>
Being commonly available commercially, the heptahydrate is a routine source of cobalt in [[coordination chemistry]].<ref>{{cite book |doi=10.1002/9780470132371.ch58|title=Inorganic Syntheses|year=1950|volume=6|last1=Broomhead|first1=J. A.|last2=Dwyer|first2=F. P.|last3=Hogarth|first3=J. W.|chapter=Resolution of the Tris(ethylenediamine)cobalt(III) Ion |pages=183–186|isbn=9780470132371}}</ref>


==Natural occurrence==
==Natural occurrence==
Line 101: Line 106:


==Health issues==
==Health issues==
Cobalt is an essential mineral for mammals, but more than a few micrograms per day is harmful. Although poisonings have rarely resulted from cobalt compounds, their chronic ingestion has caused serious health problems at doses far less than the lethal dose. In 1965, the addition a cobalt compound to stabilize [[beer foam]] in Canada led to a peculiar form of toxin-induced [[cardiomyopathy]], which came to be known as ''beer drinker's cardiomyopathy''.<ref>{{cite journal |author= Morin Y |author2= Tětu A |author3= Mercier G|title=Quebec beer-drinkers' cardiomyopathy: Clinical and hemodynamic aspects |journal=Annals of the New York Academy of Sciences |volume=156 |issue= 1 |pages=566–576 |date=1969|pmid=5291148 |doi=10.1111/j.1749-6632.1969.tb16751.x|bibcode = 1969NYASA.156..566M |s2cid= 7422045 }}</ref><ref>{{cite journal|title = Cobalt|author = Barceloux, Donald G.|author2 = Barceloux, Donald|name-list-style = amp |doi = 10.1081/CLT-100102420|pmid = 10382556|journal = Clinical Toxicology|volume = 37|issue = 2|date = 1999| pages = 201–216}}</ref><ref>[https://pubchem.ncbi.nlm.nih.gov/compound/Cobalt_sulfate#section=Human-Toxicity-Excerpts 11.1.5 The unusual type of myocardiopathy recognized in 1965 and 1966 in Quebec (Canada), Minneapolis (Minnesota), Leuven (Belgium), and Omaha (Nebraska) was associated with episodes of acute heart failure (e/g/, 50 deaths among 112 beer drinkers).]</ref>
Cobalt is an essential mineral for mammals, but more than a few micrograms per day is harmful. Although poisonings have rarely resulted from cobalt compounds, their chronic ingestion has caused serious health problems at doses far less than the lethal dose. In 1965, the addition of a cobalt compound to stabilize [[beer foam]] in Canada led to a peculiar form of toxin-induced [[cardiomyopathy]], which came to be known as ''beer drinker's cardiomyopathy''.<ref>{{cite journal |author= Morin Y |author2= Tětu A |author3= Mercier G|title=Quebec beer-drinkers' cardiomyopathy: Clinical and hemodynamic aspects |journal=Annals of the New York Academy of Sciences |volume=156 |issue= 1 |pages=566–576 |date=1969|pmid=5291148 |doi=10.1111/j.1749-6632.1969.tb16751.x|bibcode = 1969NYASA.156..566M |s2cid= 7422045 }}</ref><ref>{{cite journal|title = Cobalt|author = Barceloux, Donald G.|author2 = Barceloux, Donald|name-list-style = amp |doi = 10.1081/CLT-100102420|pmid = 10382556|journal = Clinical Toxicology|volume = 37|issue = 2|date = 1999| pages = 201–216}}</ref><ref>[https://pubchem.ncbi.nlm.nih.gov/compound/Cobalt_sulfate#section=Human-Toxicity-Excerpts 11.1.5 The unusual type of myocardiopathy recognized in 1965 and 1966 in Quebec (Canada), Minneapolis (Minnesota), Leuven (Belgium), and Omaha (Nebraska) was associated with episodes of acute heart failure (e/g/, 50 deaths among 112 beer drinkers).]</ref>


Furthermore, cobalt(II) sulfate is suspected of causing [[cancer]] (i.e., possibly [[carcinogen]]ic, [[IARC Group 2B]]) as per the [[International Agency for Research on Cancer]] (IARC) Monographs.<ref>{{cite web | url = http://publications.iarc.fr/_publications/media/download/2705/29aacee6b89ff816188dcd990b61a16ad6486eec.pdf | work = IARC Monographs on the Evaluation of Carcinogenic Risks to Humans | volume = 86 | title = Cobalt in Hard Metals and Cobalt Sulfate, Gallium Arsenide, Indium Phosphide and Vanadium Pentoxide }}</ref>
Furthermore, cobalt(II) sulfate is suspected of causing [[cancer]] (i.e., possibly [[carcinogen]]ic, [[IARC Group 2B]]) as per the [[International Agency for Research on Cancer]] (IARC) Monographs.<ref>{{cite web | url = http://publications.iarc.fr/_publications/media/download/2705/29aacee6b89ff816188dcd990b61a16ad6486eec.pdf | work = IARC Monographs on the Evaluation of Carcinogenic Risks to Humans | volume = 86 | title = Cobalt in Hard Metals and Cobalt Sulfate, Gallium Arsenide, Indium Phosphide and Vanadium Pentoxide }}</ref>

==Related compounds==
* the [[Tutton salt]] K<sub>2</sub>Co(SO<sub>4</sub>)<sub>2</sub>{{hydrate|6|nolink=yes}}


==References==
==References==

Latest revision as of 20:16, 10 September 2024

Cobalt(II) sulfate
Cobalt(II) sulfate Xray
Names
IUPAC name
Cobalt(II) sulfate
Other names
Cobaltous sulfate
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.030.291 Edit this at Wikidata
EC Number
  • 233-334-2
KEGG
RTECS number
  • GG3100000 (anhydrous)
    GG3200000 (heptahydrate)
UNII
  • InChI=1S/Co.H2O4S/c;1-5(2,3)4/h;(H2,1,2,3,4)/q+2;/p-2 checkY
    Key: KTVIXTQDYHMGHF-UHFFFAOYSA-L checkY
  • InChI=1/Co.H2O4S/c;1-5(2,3)4/h;(H2,1,2,3,4)/q+2;/p-2
    Key: KTVIXTQDYHMGHF-NUQVWONBAJ
  • anhydrous: [Co+2].[O-]S([O-])(=O)=O
  • hexahydrate: [OH2+][Co-4]([OH2+])([OH2+])([OH2+])([OH2+])[OH2+].[O-]S(=O)(=O)[O-]
  • heptahydrate: [OH2+][Co-4]([OH2+])([OH2+])([OH2+])([OH2+])[OH2+].[O-]S(=O)(=O)[O-].O
Properties
CoSO4·(H2O)n (n=0,1,6,7)
Molar mass 154.996 g/mol (anhydrous)
173.01 g/mol (monohydrate)
263.08 g/mol (hexahydrate)
281.103 g/mol (heptahydrate)
Appearance reddish crystalline (anhydrous, monohydrate)
pink salt (hexahydrate)
Odor odorless (heptahydrate)
Density 3.71 g/cm3 (anhydrous)
3.075 g/cm3 (monohydrate)
2.019 g/cm3 (hexahydrate)
1.948 g/cm3 (heptahydrate)
Melting point 735 °C (1,355 °F; 1,008 K)
anhydrous:
36.2 g/100 mL (20 °C)
38.3 g/100 mL (25 °C)
84 g/100 mL (100 °C)
heptahydrate:
60.4 g/100 mL (3 °C)
67 g/100 mL (70 °C)
Solubility anhydrous:
1.04 g/100 mL (methanol, 18 °C)
insoluble in ammonia
heptahydrate:
54.5 g/100 mL (methanol, 18 °C)
+10,000·10−6 cm3/mol
1.639 (monohydrate)
1.540 (hexahydrate)
1.483 (heptahydrate)
Structure
orthorhombic (anhydrous)
monoclinic (monohydrate, heptahydrate)
Hazards
GHS labelling:
GHS07: Exclamation markGHS08: Health hazardGHS09: Environmental hazard
Danger
H302, H317, H334, H341, H350, H360, H410
P201, P202, P261, P264, P270, P272, P273, P280, P281, P285, P301+P312, P302+P352, P304+P341, P308+P313, P321, P330, P333+P313, P342+P311, P363, P391, P405, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroformFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
2
0
0
Flash point Non-flammable
Lethal dose or concentration (LD, LC):
424 mg/kg (oral, rat)
Safety data sheet (SDS) ICSC 1396 (heptahydrate)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)
Cobalt(II) sulfate
Cobalt(II) sulfate heptahydrate

Cobalt(II) sulfate is any of the inorganic compounds with the formula CoSO4(H2O)x. Usually cobalt sulfate refers to the hexa- or heptahydrates CoSO4.6H2O or CoSO4.7H2O, respectively.[1] The heptahydrate is a red solid that is soluble in water and methanol. Since cobalt(II) has an odd number of electrons, its salts are paramagnetic.

Preparation, and structure

[edit]

It forms by the reaction of metallic cobalt, its oxide, hydroxide, or carbonate with aqueous sulfuric acid:[1]

Co + H2SO4 + 7 H2O → CoSO4(H2O)7 + H2
CoO + H2SO4 + 6 H2O → CoSO4(H2O)7

The heptahydrate is only stable at humidity >70% at room temperature, otherwise it converts to the hexahydrate.[2] The hexahydrate converts to the monohydrate and the anhydrous forms at 100 and 250 °C, respectively.[1]

CoSO4(H2O)7 → CoSO4(H2O)6 + H2O
CoSO4(H2O)6 → CoSO4(H2O) + 5 H2O
CoSO4(H2O) → CoSO4 + H2O

The hexahydrate is a metal aquo complex consisting of octahedral [Co(H2O)6]2+ ions associated with sulfate anions (see image in table).[3] The monoclinic heptahydrate has also been characterized by X-ray crystallography. It also features [Co(H2O)6]2+ octahedra as well as one water of crystallization.[2]

Uses and reactions

[edit]

Cobalt sulfates are important intermediates in the extraction of cobalt from its ores. Thus, crushed, partially refined ores are treated with sulfuric acid to give red-colored solutions containing cobalt sulfate.[1]

Hydrated cobalt(II) sulfate is used in the preparation of pigments, as well as in the manufacture of other cobalt salts. Cobalt pigment is used in porcelains and glass. Cobalt(II) sulfate is used in storage batteries and electroplating baths, sympathetic inks, and as an additive to soils and animal feeds. For these purposes, the cobalt sulfate is produced by treating cobalt oxide with sulfuric acid.[1]

Being commonly available commercially, the heptahydrate is a routine source of cobalt in coordination chemistry.[4]

Natural occurrence

[edit]

Rarely, cobalt(II) sulfate is found in form of few crystallohydrate minerals, occurring among oxidation zones containing primary Co minerals (like skutterudite or cobaltite). These minerals are: biebierite (heptahydrate), moorhouseite (Co,Ni,Mn)SO4.6H2O,[5][6] aplowite (Co,Mn,Ni)SO4.4H2O and cobaltkieserite (monohydrate).[7][8][6]

Health issues

[edit]

Cobalt is an essential mineral for mammals, but more than a few micrograms per day is harmful. Although poisonings have rarely resulted from cobalt compounds, their chronic ingestion has caused serious health problems at doses far less than the lethal dose. In 1965, the addition of a cobalt compound to stabilize beer foam in Canada led to a peculiar form of toxin-induced cardiomyopathy, which came to be known as beer drinker's cardiomyopathy.[9][10][11]

Furthermore, cobalt(II) sulfate is suspected of causing cancer (i.e., possibly carcinogenic, IARC Group 2B) as per the International Agency for Research on Cancer (IARC) Monographs.[12]

[edit]

References

[edit]
  1. ^ a b c d e Donaldson, John Dallas; Beyersmann, Detmar (2005). "Cobalt and Cobalt Compounds". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a07_281.pub2. ISBN 3527306730.
  2. ^ a b Redhammer, G. J.; Koll, L.; Bernroider, M.; Tippelt, G.; Amthauer, G.; Roth, G. (2007). "Co2+-Cu2+ Substitution in Bieberite Solid-Solution Series, (Co1−xCux)SO4 · 7H2O, 0.00 ≤ x ≤ 0.46: Synthesis, Single-Crystal Structure Analysis, and Optical Spectroscopy". American Mineralogist. 92 (4): 532–545. Bibcode:2007AmMin..92..532R. doi:10.2138/am.2007.2229. S2CID 95885758.
  3. ^ Elerman, Y. (1988). "Refinement of the crystal structure of CoSO4.6H2O". Acta Crystallographica Section C Crystal Structure Communications. 44 (4): 599–601. Bibcode:1988AcCrC..44..599E. doi:10.1107/S0108270187012447.
  4. ^ Broomhead, J. A.; Dwyer, F. P.; Hogarth, J. W. (1950). "Resolution of the Tris(ethylenediamine)cobalt(III) Ion". Inorganic Syntheses. Vol. 6. pp. 183–186. doi:10.1002/9780470132371.ch58. ISBN 9780470132371.
  5. ^ "Moorhouseite".
  6. ^ a b "List of Minerals". 21 March 2011.
  7. ^ "Cobaltkieserite".
  8. ^ "Bieberite".
  9. ^ Morin Y; Tětu A; Mercier G (1969). "Quebec beer-drinkers' cardiomyopathy: Clinical and hemodynamic aspects". Annals of the New York Academy of Sciences. 156 (1): 566–576. Bibcode:1969NYASA.156..566M. doi:10.1111/j.1749-6632.1969.tb16751.x. PMID 5291148. S2CID 7422045.
  10. ^ Barceloux, Donald G. & Barceloux, Donald (1999). "Cobalt". Clinical Toxicology. 37 (2): 201–216. doi:10.1081/CLT-100102420. PMID 10382556.
  11. ^ 11.1.5 The unusual type of myocardiopathy recognized in 1965 and 1966 in Quebec (Canada), Minneapolis (Minnesota), Leuven (Belgium), and Omaha (Nebraska) was associated with episodes of acute heart failure (e/g/, 50 deaths among 112 beer drinkers).
  12. ^ "Cobalt in Hard Metals and Cobalt Sulfate, Gallium Arsenide, Indium Phosphide and Vanadium Pentoxide" (PDF). IARC Monographs on the Evaluation of Carcinogenic Risks to Humans.
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