Novel cyclic voltammetry behavior of 3-((benzothiazol-2- diazenylnaphthalene-2,7-diol and use it for spectrophotometric determination of copper (II )in honey sample

Authors

  • Fatma .A. Khazaal Chemistry Department / Faculty of Science /Kufa University, Iraq P.O Box(21)
  • Hussein. J. Mohammed
  • Muhammed . M.Radhi

DOI:

https://doi.org/10.24297/jac.v12i7.6123

Abstract

The azo reagent 3-((benzothiazol-2-diazenylnaphthalene-2,7-diol] was synthesized and characterized by FT-IR ,1H-NMR
and 13CNMR spectral techniques. The electrochemical behavior of the azo reagent and its complex with Cu (II) has been
studied at glassy carbon disk GCE electrode in different supporting electrolyte at concentration (1M) and scan rate
(100mv.s-1). Spectrophotometric determination of copper (II ) is based on the formation of a 2:1 complex with above
reagent. The complex has λmax at(588) nm and Ômax of( 1.436x104)L.mol-1.cm-1 .
A linear correlation (0.1 – 3.0 μg. ml-1) was found between absorbance at λmax and concentration . The effect of diverse
ions on the determination of copper (II) to investigate the selectivity of the method were also studied . The stability
constant of the product was (1.1x108 ) . The proposed method was successfully applied to the analysis of honey sample .

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References

1. 1-D.AJohnson,T.M.Florence,Anal.Chim.Acta,53,73,1971.
2. 2-A.S.Amin,A.S.AL-Attas,J.SaudiChem.Soc.,16,451, 1971.
3. 3-N.Menek,O.Cakir,H.Kocaokutgen,Mikrochim.Acta, 122,203,1996.
4. 4-N.Menek,Ph.D Thesis,, Ondokuz Mayis University,Samsun,Turkey(1994).
5. 5-T.Hihara,Y.Okada and Z.Morita.Dyes and pigments,73,141,2007.
6. 6- H. J Mohammed, A. Y .Muhi and H. al- meisslemaw E-Journal of Chemistry, 8(S1), S425-S433,2011.
7. 7- H. Khazal and H..J. Mohammed Inter. J. of Civil & Env Engin IJCEE-IJENS Vol: 14 No: 04,1,2014
8. 8-H.J.Mohammed , M. A.Awad , Sh.H.Mallah , Inter. J. of Basic & Appl Sci IJBAS-IJENS Vol:15 No:02 ,25 ,2015
9. 9- M.A. Awad and H.J.Mohammed,Chem. Sci. Transactions, 3(3) pp, 2014.
10. 10- N. k. Saeed&H.J.Mohammed, Inter. J. of Civil & Env. Eng. IJCEE-IJENS Vol: 14 No: 04 ,8 ,2014.
11. 11-W. Mohammed & H.J. Mohammed Inter. J. of Civil & Env. Eng. IJCEE-IJENS Vol:13 No:06 ,37, 2013
12. 12- A.A.Sayhood and H. J. Mohammed, Int. J. Chem. Sci.: 13(3), 1123-113, 2015.
13. 13- A.A.Sayhood and H. J. Mohammed, Der Pharma Chemica,Der Pharma Chemica, 7(8), 50-58, 2015.
14. 14-L.Zhang,Z.Li,X.Du,R.Li and X.Chang,Spectrochimica Acta partA: Molecular and Biomolecular
15. Spectroscopy, 86,443-448,2012
16. 15-H.Xie,X.D.Nie and Y.G.Tang;Chin.Chem.Lett,17(8),1077-1080,2006.
17. 16-M.Ghaedi,A.Shokrollahi and F.Ahmadi;J.Haz.Mater.,142,272-278,2007
18. 17-S.F.A.Ali,N.Imtiaz,S.U.Mehdi and M.Asif;InternationalConference on Chemical Engineering and
Pharmaceutical Sciences,(13-15),140-142.2012
19. 18- A. V .Pereira, , & O.Fatibello-Filho, ;. Anal. Chim. Acta, 366(1), 55-62. (1998).
20. 19-S.Lunvongsa,T.T suboi and S.Motomizu;Anal.Sci.,22,169-172,2006.
21. 20- G. W. Ewing, Instrumental Methods of Chemical Analysis, Mcgraw-Hill College, USA, 5th ed., 1985.
22. 21- W. C. Vosburgh and G. R. Cooper, J. Am. Chem. Soc., 63, 437–442,1941.
23. 22-B.R.Hsieh,D.Desilets,and P.M.Kazmaier, ,'Dyes and Pigments,.14,no.3,.165-189,1990.
24. 23-A.V.Zemskov,G.N.Rodionova,Y.G.Tuchin,and V.V.Karpov,"IR soectra and structure of some azo dyes-pazobenzene
derivatives-in various aggregate states,"Zhurnal Prikladnoi Spektroskopii,.49,no.4,.581-586,1988
25. 24-K.Ueno,"Polyazobenzenes.III.Infrared absorption spectra of some polyazobenzenes," J.Am. Chem.
Soc,.79,no.12,.3205-3208,1957.
26. 25- Tuzen M, Soylak M , and Elci.L,Anal chim Acta , ,584,101-108,2005.
27. 26-L.Dubenska,H.Levytska, and N.Poperechna,"Polarographic investigation of reduction process of some azo dyes and
their complexes with rare –earths" ,Talanta , .54,no 2..221-231,2001.
28. 27- G.W.Latimer, "Polargraphic behavior of metal chelates of o,o
̀̀ ̀̀
dihydroxyazo dyes ," Talanta , .15,no.1,.1-14,1968
29. 28- D.K.Gosser Jr., Cyclic Voltammetry : Simulation and Analysis of reaction Mechanisms ,VCH Publishers ,New York
,NY,USA,1993
30. 29-C.H.Bamford"Electrode kinetic princibles and methodology" .23, .17-21,1986.
31. 30-A.J.Bard and L.R.Faulkner,Electrochemical Methodes ,Fundamentals and Application,Wiley,NewYork.Ny,USA,2nd
edition,2001.
32. 31-R.N.Patel,n.Singh, D.K.Patel,and V.L.N.Gundla,"Synthesis,characterization and superoxide dismutase studies of
square pyramidal copper (II) complexes with bi and tri dentate polyamine ligands,"Indian Journal of chemistry
A.46,no.3,422-427,2007
32- G.D.Levitskaya,N.P.Poperechnaya , and L.O.Dubenskaya, Polarographic behavior of eriochrome red B and .33
its complexes with rare –earth ions,"Journal if Analytical Chemistry , .56,no 6,552-556,2001

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Published

2017-05-09

How to Cite

Khazaal, F. .A., Mohammed, H. J., & M.Radhi, M. . (2017). Novel cyclic voltammetry behavior of 3-((benzothiazol-2- diazenylnaphthalene-2,7-diol and use it for spectrophotometric determination of copper (II )in honey sample. JOURNAL OF ADVANCES IN CHEMISTRY, 12(7), 4243–4255. https://doi.org/10.24297/jac.v12i7.6123

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Vol. 12 No. 7 (2016)

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