Acetic acid, potassium salt
- Formula: C2H3KO2
- Molecular weight: 98.1423
- IUPAC Standard InChIKey: SCVFZCLFOSHCOH-UHFFFAOYSA-M
- CAS Registry Number: 127-08-2
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Species with the same structure:
- Other names: Potassium acetate
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Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
S°solid,1 bar | 150.82 | J/mol*K | N/A | Ngeyi, Malik, et al., 1990 |
Constant pressure heat capacity of solid
Cp,solid (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
109.38 | 298.15 | Ngeyi, Malik, et al., 1990 | T = 4 to 585 K. |
Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tfus | 582. | K | N/A | Ngeyi, Malik, et al., 1990 | Crystal phase 1 phase; Uncertainty assigned by TRC = 2. K; TRC |
Tfus | 578.7 | K | N/A | Ferloni, Sanesi, et al., 1975 | Crystal phase 1 phase; Uncertainty assigned by TRC = 0.2 K; TRC |
Temperature of phase transition
Ttrs (K) | Initial Phase | Final Phase | Reference | Comment |
---|---|---|---|---|
332. | crystaline, III | crystaline, II | House and Kemper, 1990 | DH |
Enthalpy of phase transition
ΔHtrs (kJ/mol) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
---|---|---|---|---|---|
0.2454 | 429.5 | crystaline, II | crystaline, I | House and Kemper, 1990 | DH |
0.34671 | 411. | crystaline, IIIb | crystaline, IIIa | Ngeyi, Malik, et al., 1990 | DH |
0.18957 | 425. | crystaline, IIIa | crystaline, II | Ngeyi, Malik, et al., 1990 | DH |
1.613 | 474. | crystaline, II | crystaline, I | Ngeyi, Malik, et al., 1990 | DH |
7.649 | 582. | crystaline, I | liquid | Ngeyi, Malik, et al., 1990 | Crystal to isotropic liquid.; DH |
0.420 | 423. | crystaline, II | crystaline, I | Ferloni, Sanesi, et al., 1975, 2 | DH |
15.230 | 578.7 | crystaline, I | liquid | Ferloni, Sanesi, et al., 1975, 2 | DH |
Entropy of phase transition
ΔStrs (J/mol*K) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
---|---|---|---|---|---|
0.577 | 429.5 | crystaline, II | crystaline, I | House and Kemper, 1990 | DH |
0.8065 | 411. | crystaline, IIIb | crystaline, IIIa | Ngeyi, Malik, et al., 1990 | DH |
0.4157 | 425. | crystaline, IIIa | crystaline, II | Ngeyi, Malik, et al., 1990 | DH |
3.3840 | 474. | crystaline, II | crystaline, I | Ngeyi, Malik, et al., 1990 | DH |
13.137 | 582. | crystaline, I | liquid | Ngeyi, Malik, et al., 1990 | Crystal; DH |
1.0 | 423. | crystaline, II | crystaline, I | Ferloni, Sanesi, et al., 1975, 2 | DH |
26.3 | 578.7 | crystaline, I | liquid | Ferloni, Sanesi, et al., 1975, 2 | DH |
Mass spectrum (electron ionization)
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | E. White V, SmithKline Corp. |
NIST MS number | 353309 |
References
Go To: Top, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), NIST Free Links, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Ngeyi, Malik, et al., 1990
Ngeyi, S.P.; Malik, I.; Westrum,
E.F., Thermodyanamics of alkali alkanoates VII. Heat capacity and thermodynamic functions of potassium acetate from 4 to 585 K,
J. Chem. Thermodynam., 1990, 22, 91-98. [all data]
Ferloni, Sanesi, et al., 1975
Ferloni, P.; Sanesi, M.; Franzosini, P.,
Phase transitions in the alkali C1-n.C4 alkanoates,
Z. Naturforsch., A: Phys., Phys. Chem., Kosmophys., 1975, 30, 1447-57. [all data]
House and Kemper, 1990
House, J.H.; Kemper, K.A.,
Phase transitions and their thermal hysteresis in anhydrous potassium acetate,
Thermochim. Acta, 1990, 162(2), 325-331. [all data]
Ferloni, Sanesi, et al., 1975, 2
Ferloni, P.; Sanesi, M.; Franzosini, P.; C4 alkanoates, Phase transitions in the alkali C1-n.,
Z. Naturforsch. 30a, 1975, 1447-1454. [all data]
Notes
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- Symbols used in this document:
Cp,solid Constant pressure heat capacity of solid S°solid,1 bar Entropy of solid at standard conditions (1 bar) Tfus Fusion (melting) point Ttrs Temperature of phase transition ΔHtrs Enthalpy of phase transition ΔStrs Entropy of phase transition - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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