Optimized loading and sustained release of hydrophilic proteins from internally nanostructured particles

Langmuir. 2012 Dec 11;28(49):16788-97. doi: 10.1021/la303373q. Epub 2012 Nov 16.

Abstract

In this study, we demonstrate that emulsified microemulsions and micellar cubosomes are suitable as sustained delivery vehicles for water-soluble proteins. Through structural modifications, the loading efficiency of two model proteins, namely bovine serum albumin (BSA) and cytochrome c could be remarkably increased. A procedure for preparing these particles loaded with optimized amounts of sensitive substances is presented. Loading and dispersion at low temperatures is performed in two successive steps. First, a water-in-oil microemulsion is loaded with the proteins. Subsequently, this phase is dispersed in water resulting in particles with microemulsion and micellar cubic internal structure and a size of approximately 620 nm. This two-step method ensures optimal loading of the particles with the proteins. These nanostructured particles are able to sustain the release of the water-soluble BSA and cytochrome c. Within one day, less than 10% of BSA and 15% of cytochrome c are released. The release rate of cytochrome c is influenced by the nanostructure of the particles.

MeSH terms

  • Animals
  • Cattle
  • Chromatography, Reverse-Phase
  • Cytochromes c / chemistry*
  • Delayed-Action Preparations / chemistry*
  • Drug Compounding / methods*
  • Emulsions
  • Horses
  • Hydrophobic and Hydrophilic Interactions
  • Kinetics
  • Micelles
  • Mineral Oil / chemistry
  • Nanoparticles / chemistry*
  • Particle Size
  • Scattering, Small Angle
  • Serum Albumin, Bovine / chemistry*
  • Solubility
  • Temperature
  • Water / chemistry
  • X-Ray Diffraction

Substances

  • Delayed-Action Preparations
  • Emulsions
  • Micelles
  • Water
  • Serum Albumin, Bovine
  • Mineral Oil
  • Cytochromes c