Crystal structure and Hirshfeld surface analysis of (1 H-imidazole-κ N3)[ N-(2-oxido-benzyl-idene)tyrosinato-κ3O, N, O']copper(II)

Acta Crystallogr E Crystallogr Commun. 2023 Jun 2;79(Pt 7):596-599. doi: 10.1107/S2056989023004735. eCollection 2023 Jun 1.

Abstract

The title copper(II) complex, [Cu(C16H13NO4)(C3H4N2)], consists of a tridentate ligand synthesized from l-tyrosine and salicyl-aldehyde. One imidazole mol-ecule is additionally coordinating to the copper(II) ion. The crystal structure features N-H⋯O, O-H⋯O and C-H⋯O hydrogen bonds. The Hirshfeld surface analysis indicates that the most important contributions to the packing are from H⋯H (37.9%), C⋯H (28.2%) and O⋯H/H⋯O (21.2%) contacts.

Keywords: Hirshfeld analysis; Schiff base complex; amino acid; copper; crystal structure.

Grants and funding

This work was supported by a Grant-in-Aid for Scientific Research (A) KAKENHI (20H00336).