Relaxation, atomic

Aiiger peaks also appear in XPS spectra. In this case, the x-ray ionized atom relaxes by emitting an electron with a specific kinetic energy E. One should bear in mind that in XPS the intensity is plotted against the bindmg energy, so one uses ( Bl.25.1) to convert to kinetic energy. [Pg.1859]

In this equation is the 6x6 matrix of second derivatives (elements Ide j), emd are the corresponding 3N x 6 and 6 x,3N mixed coordinate/strain matrices, is the 3iV X 3N second-derivative coordinate matrix and V is the unit cell volume. It is the second term in Equation (5.54) that accounts for internal atomic relaxations as the cell distorts. [Pg.311]

We designed less strained analogs of 61a-c by applying the lone pair effects (Sect. 2.1.4) [68]. Substitution of carbons with phosphorus atoms relaxes the strain (Scheme 28). Notably, substitution at the 3- and 4-positions in tricy-clo[2.1.0.0 ]pentane resulted in greater relaxation than substitution at the 2- and 5-positions. [Pg.282]

The addition of the methylmercuriacetylcarbene to cis- and //ms-butene was found to be completely stereospecific, suggesting that this carbene has a singlet ground state (with the heavy mercury atom, relaxation to the ground state should be rapid). [Pg.555]

When primary X-rays are directed on to a secondary target, i.e. the sample, a proportion of the incident rays will be absorbed. The absorption process involves the ejection of inner (K or L) electrons from the atoms of the sample. Subsequently the excited atoms relax to the ground state, and in doing so many will lose their excess energy in the form of secondary X-ray photons as electrons from the higher orbitals drop into the hole in the K or L shell. Typical transitions are summarized in Figures 8.35 and 8.36. The reemission of X-rays in this way is known as X-ray fluorescence and the associated analytical method as X-ray fluorescence spectrometry. The relation between the two principal techniques of X-ray emission spectrometry is summarized in Figure 8.37. [Pg.339]

The minimizations reveal dramatic atomic relaxations accompanying a large reduction in surface energy from that given by a perfect termination of the bulk structure. As Table 11.2 makes clear, interatomic distances in the outermost layers can change by over 50% relative to the bulk values ... [Pg.371]

We have tacitly assumed that the photoemission event occurs sufficiently slowly to ensure that the escaping electron feels the relaxation of the core-ionized atom. This is what we call the adiabatic limit. All relaxation effects on the energetic ground state of the core-ionized atom are accounted for in the kinetic energy of the photoelectron (but not the decay via Auger or fluorescence processes to a ground state ion, which occurs on a slower time scale). At the other extreme, the sudden limit , the photoelectron is emitted immediately after the absorption of the photon before the core-ionized atom relaxes. This is often accompanied by shake-up, shake-off and plasmon loss processes, which give additional peaks in the spectrum. [Pg.62]

We have already met the Auger process at the beginning of this chapter (Fig. 3.2) as a way in which photo-ionized atoms relax to ions of lower energy. However,... [Pg.83]

Obviously whenever binding energy data are fit to Eq. (9), the empirically determined values of k and l automatically take into account the atomic relaxation energy, ntr. Equation 9 gives very good correlations for molecules which have similar structures, presumably because of the automatic accounting for R>ntr and the fact that similar molecules have similar R>W values and that - w is therefore absorbed into the constant /. [Pg.165]

These results suggest that the most significant relaxation of the ZnS (110) surface is a downward displacement of the surface Zn atoms by approximately 0.02 nm. The surface S atoms relax out the surface by about 0.01 nm. The band structure and partial density of state (PDOS) of relaxed ZnS (110) surface are illustrated in Fig. 9.13. The atomic and bond overlap population analysis of ZnS (110) surface is listed in Table 9.6. It shows that the band gap of ZnS (110) surface is 1.5 eV, and it is smaller than that of bulk ZnS. The reason for band gap... [Pg.233]

Auger electron spectroscopy spect The energy analysis of Auger electrons produced when an excited atom relaxes by a radiationless process after ionization by a high-energy electron, ion, or x-ray beam. Abbreviated AES. o zha i lek.tran spek tras-ko pe ... [Pg.32]

Fluorescence excitation techniques provide a more sensitive detection system in which fluorescent X-ray photons (a fraction of the ionized absorbing atoms relax by emission of a fluorescent X-ray photon) are counted as the photon energy is scanned. The signal generated is proportional to the absorption coefficient, p, of the absorbing atom. [Pg.80]

We can avoid this symmetry-induced trap by deliberately breaking the symmetry of our atom s coordinates. One easy way to do this is to repeat our calculations after moving the H atom a small amount (say, 0.2 A) in some arbitrary direction that does not coincide with one of the symmetry directions on the surface. What we find, if we run calculations in which we start the H atom at a point about 0.2 A away from each of the high-symmetry sites mentioned above is that the H atom relaxes to the fourfold hollow site even if it is started quite near the top and bridge sites. This shows that the top and bridge sites are not minima for this system. [Pg.105]

FIGURE 4. Schematic diagram of the 248 nm laser photolysis of SO2 ground state S(3P) and S0(X3E") are produced by sequential two photon absorption by SOg. These species are further promoted to the electronically excited S (3p) and S0(b3e ) the S (3P) atoms relax (radiatively) to 3s then return to 3p by the emission of 182 nm light. From reference (215) with permission of the American Institute of Physics and the authors. [Pg.18]

From the final phase of the atomic relaxation the first-order rate coefficients for the / = 3 - 4 transition were determined at different argon pressures, to separate out the individual rate coefficients for the processes... [Pg.249]

It is conceivable that one may extract other evidence from photo-electron spectra of relevance for the physical significance of soft and hard behaviour. Thus, it is characteristic204 that the post-transitional atoms Cd(II), In(III) and Hg(II) show much smaller/ differences between fluorides and oxides than other elements in the oxidation state z where the order of magnitude of dl is z eV with the insoluble iodates occupying a position intermediate between fluorides and oxides. Noble gases205 embedded in metallic copper, silver or gold show inter-atomic relaxation effects171 amount-... [Pg.61]

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