Bulk characterization, nonlinear materials

While, in principle, the second-order response should have a higher strength than the third-order response, a strong geometrical condition (noncentrosymmetry at the atomic/molecular and at the bulk levels) limits the availability of second-order nonlinear materials. Experimentally, one has to ensure that a noncentrosymmetric configuration is used if one desires to measure the strength of the second-order nonlinear response, characterized by... [Pg.456]

The problem becomes more complex when studying solid phases because the microscopic NLO responses do not provide the full information about their macroscopic coimterparts, the second- and third-order nonlinear susceptibilities, and To make the transition between the microscopic and macroscopic, it is necessary to know the structure of the condensed phases as well as the nature and the effects of the intermolecular interactions in the bulk of the material. In both the Physics and Chemistry arena, several schemes have been proposed to characterize the NLO responses of solid phases. One of the authors has recently contributed to review these approaches [3] of which one of the extremes is occupied by the oriented gas approximation that consists in performing a tensor sum of the microscopic NLO properties to obtain the macroscopic responses of the crystal. The other extreme consists in performing a complete treatment of the solid by using the supermolecule method or by taking advantage of the spatial periodicity in crystal orbital calculations. In between these techniques, one finds the interaction schemes and the semi-empirical approaches. [Pg.82]

The tutorial begins with a description of the basic concepts of nonlinear optics and presents illustrations from simple models to account for the origin of the effects. The microscopic or molecular origin of these effects is then discussed in more detail. Following this, the relationship between molecular responses and the effects observed in bulk materials are presented and finally some of the experimental methods used to characterize these effects are described. [Pg.38]

This paper is a tutorial overview of the techniques used to characterize the nonlinear optical properties of bulk materials and molecules. Methods that are commonly used for characterization of second- and third-order nonlinear optical properties are covered. Several techniques are described briefly and then followed by a more detailed discussion of the determination of molecular hyperpolarizabilities using third harmonic generation. [Pg.73]

In this paper it has been attempted to provide an introductory overview of some of the various nonlinear optical characterization techniques that chemists are likely to encounter in studies of bulk materials and molecular structure-property relationships. It has also been attempted to provide a relatively more detailed coverage on one topic to provide some insight into the connection between the macroscopic quantities measured and the nonlinear polarization of molecules. It is hoped that chemists will find this tutorial useful in their efforts to conduct fruitful research on nonlinear optical materials. [Pg.93]

Kuzyk, M. G. Relationship between the Molecular and the Bulk Response, Chapter 3 in Characterization Technu ues and Tabulations for Organic Nonlinear Optical Materials, Edited by M. G. Kuzyk, C. W. Dirk, Marcel Dekker. New York, 1998. [Pg.304]

The synthesis and bulk and solution properties of block copolymers having nonlinear architectures are reviewed. These materials include star-block copolymers, graft copolymers, mik-toarm star copolymers, and complex architectures such as umbrella polymers and certain dendritic macromolecules. Emphasis is placed on the synthesis of well-defined, well-characterized materials. Such polymers serve as model materials for understanding the effects of architecture on block copolymer self-assembly, in bulk and in solution. [Pg.1]

Several of the third-order nonlinear effects described in section 4.1.3 can be used to characterize bulk materials. Degenerate four-wave mixing (DFWM) is used for measuring third-order properties of films and solutions [43-45], and though this experiment is complex to set up and interpret, it can give valuable information on the magnitude, sign and speed of the nlo process, as well as an indication of the nature of the excitation process. Results from DFWM can be found in section 4.3. Optical Kerr effect (OKE) [46] and electrical Kerr effect (EKE) [47] measurements have also been used to characterize third-order properties of nlo polymers. It is important to note that THG, DFWM, OKE and EKE all measure different parts of the third-order susceptibility, and... [Pg.144]

A wide variety of techniques have been employed for the characterization of thin film samples of nonlinear polymeric materials. Many of these are similar to techniques described in the previous section for bulk material characterization, and are employed with thin film samples both to assess differences in material properties in the two physical forms and because certain measurements such as absorption or electro-optic effects may be more easily made in thin film samples. Other techniques are specific to thin film samples in which light can be guided, for which parameters can be measured having no bulk equivalent, such as waveguide scatter or nonlinear mode coupling. [Pg.145]

In using nonlinear mechanical models, in addition to utilizing nonlinear elastic and shear thickening or thinning dashpot elements, a perturbation technique can also be used to incorporate nonlinear behavior. This is accomplished by adding small perturbation terms which are functions of the current level of elastic strain and strain rate to the elastic and viscous coefficients, respectively. This method was originally proposed by Davis (1964) and later applied by Renieri et al. (1976) in material characterization of bulk adhesives. [Pg.567]

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