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Chelate effects

LEED See low energy electron dilTraction. lei See chelate effect, iepargylic acid See azeleic acid. [Pg.238]

Page, M. L., Jencks, W. P. Entropic contributions to rate accelerations in enzymic and intramolecular interactions and the chelate effect. Proc. Natl. Acad. Sci. USA 68 (1971) 1678-1683... [Pg.147]

The coordination of bidentate ligands is generally more efficient than expected on the basis of the binding affinity of monodentate analogues. This is referred to as the chelate effect. For reviews, see (a) Schwarzenbach, G. Helv. Chim. Acta, 1952, 35, 2344 (b) reference 75. [Pg.73]

The facile cyclopalladation of allylamine proceeds due to a chelating effect of the nitrogen. In MeOH, methoxypalladation take.s place to give the five-mem-bered chelating complex 507[460). The CO Insertion takes place readily in EtOH, giving ethyl 3-methoxy-4-dimethylaminobutyrate (508) in 50% yield[461). The insertion of alkenes also proceeds smoothly, giving the ami-noalkenes 509[462],... [Pg.95]

The carbopalladation of allylamine with malonate affords the chelating complex 510, which undergoes insertion of methyl vinyl ketone to form the amino enone 511[463]. The allylic sulfide 512 has the same chelating effect to give the five-membered complex 513 by carbopalladation[463.464]. [Pg.95]

The benzoic acid derivative 457 is formed by the carbonylation of iodoben-zene in aqueous DMF (1 1) without using a phosphine ligand at room temperature and 1 atm[311]. As optimum conditions for the technical synthesis of the anthranilic acid derivative 458, it has been found that A-acetyl protection, which has a chelating effect, is important[312]. Phase-transfer catalysis is combined with the Pd-catalyzed carbonylation of halides[3l3]. Carbonylation of 1,1-dibromoalkenes in the presence of a phase-transfer catalyst gives the gem-inal dicarboxylic acid 459. Use of a polar solvent is important[314]. Interestingly, addition of trimethylsilyl chloride (2 equiv.) increased yield of the lactone 460 remarkabiy[3l5]. Formate esters as a CO source and NaOR are used for the carbonylation of aryl iodides under a nitrogen atmosphere without using CO[316]. Chlorobenzene coordinated by Cr(CO)j is carbonylated with ethyl formate[3l7]. [Pg.190]

Some of these compounds could be considered as dietary additives, but various other terms, including pesticides, can also be used. They can have beneficial effects on the environment and this aspect will be discussed later. The ionophore monensin, which is an alicyclic polyether (Figure 1), is a secondary metabolite of Streptomyces and aids the prevention of coccidiosis in poultry. Monensin is used as a growth promoter in cattle and also to decrease methane production, but it is toxic to equine animals. " Its ability to act as an ionophore is dependent on its cyclic chelating effect on metal ions. ° The hormones bovine somatotropin (BST) and porcine somatotropin (PST), both of which are polypeptides, occur naturally in lactating cattle and pigs, respectively, but can also be produced synthetically using recombinant DNA methods and administered to such animals in order to increase milk yields and lean meat production. "... [Pg.87]

Examples were given above of stereocontrol due to substrate bias of a steric nature. Substrate bias can also result from coordinative or chelate effects. Some instances of coordinative (or chelate) substrate bias are shown retrosynthetically in Chart 18. [Pg.49]

On the basis of the values of AS° derived in this way it appears that the chelate effect is usually due to more favourable entropy changes associated with ring formation. However, the objection can be made that and /3l-l as just defined have different dimensions and so are not directly comparable. It has been suggested that to surmount this objection concentrations should be expressed in the dimensionless unit mole fraction instead of the more usual mol dm. Since the concentration of pure water at 25°C is approximately 55.5 moldm , the value of concentration expressed in mole fractions = cone in moldm /55.5 Thus, while is thereby increased by the factor (55.5), /3l-l is increased by the factor (55.5) so that the derived values of AG° and AS° will be quite different. The effect of this change in units is shown in Table 19.1 for the Cd complexes of L = methylamine and L-L = ethylenediamine. It appears that the entropy advantage of the chelate, and with it the chelate effect itself, virtually disappears when mole fractions replace moldm . ... [Pg.910]

Probably the most satisfactory model with which to explain the chelate effect is that proposed by G. Schwarzenbach If L and L-L are present in similar concentrations and are competing for two coordination sites on the metal, the probability of either of them coordinating to the first site may be taken as equal. However, once one end of L-L has become attached it is much more likely that the second site will be won by its other end than by L, simply because its other end must be held close to the second site and its effective concentration where it matters is therefore much... [Pg.911]

CC-1065 394 CeCl3-7H20 618 chelate effect 680 P-chelation-control 607 f. chelidonine 158... [Pg.791]

The term chelate effect refers to the fact that a chelated complex, i.e. one formed by a bidentate or a multidenate ligand, is more stable than the corresponding complex with monodentate ligands the greater the number of points of attachment of ligand to the metal ion, the greater the stability of... [Pg.54]

The formation of a single complex species rather than the stepwise production of such species will clearly simplify complexometric titrations and facilitate the detection of end points. Schwarzenbach2 realised that the acetate ion is able to form acetato complexes of low stability with nearly all polyvalent cations, and that if this property could be reinforced by the chelate effect, then much stronger complexes would be formed by most metal cations. He found that the aminopolycarboxylic acids are excellent complexing agents the most important of these is 1,2-diaminoethanetetra-aceticacid (ethylenediaminetetra-acetic acid). The formula (I) is preferred to (II), since it has been shown from measurements of the dissociation constants that two hydrogen atoms are probably held in the form of zwitterions. The values of pK are respectively pK, = 2.0, pK2 = 2.7,... [Pg.55]

The factors which influence the stability of metal ion complexes have been discussed in Section 2.23, but it is appropriate to emphasise here the significance of the chelate effect and to list the features of the ligand which affect chelate formation ... [Pg.164]

Chelate effect 54 Chelates 161, 169, 237 for gas chromatography, 237 Chelating resins 202, 212 Chelation 52... [Pg.859]

After 19 hours, no reaction between the zinc chelate 2 and benzaldehyde can be detected at 20 °C. However, 10 mol % of the zinc chelate effectively catalyzes theenantioselective addition of diethylzinc to aromatic aldehydes. The predominant formation of the S-configurated products, effected by this conformationally unambiguous catalyst, can be explained by a six-mem-bered cyclic transition state assembly17. The fact that the zinc chelate formed from ligand M is an equally effective catalyst clearly demonstrates that activation of the aldehyde moiety does not occur as a consequence of hydrogen bond formation between the ammonium proton of the pyrrolidine unit and the aldehydic oxygen. [Pg.172]

Certain types of oxygen scavenger have additional functions, such as pH neutralizing and metal chelating effects. [Pg.482]

An investigation of the chelate effect the binding of bidentate phosphine and arsine chelates in square-planar transition metal complexes. D. M. A. Minahan, W. E. Hill and C. A. McAuliffe, Coord. Chem. Rev., 1984, 55, 31-54 (153). [Pg.52]

Cone angle concepts, 2,1012-1028 chelate effects, 2,1012 definitions, 2,1015 models, 2,1015 phosphines chiral, 2,1014 polydentate, 2,1013 solubility effects, 2,1014 use, 2,1028... [Pg.112]

Metal hydroxides of first- and second-group elements can enhance ortho substitution, the degree of which depends on the strength of metal-chelating effects linking the phenolic oxygen with the formaldehyde as it approaches the ortho position. Transition metal ions of elements such as Fe, Cu, Cr, Ni, Co, Mn, and Zn as well as boric acid also direct ortho substitutions via chelating effects (Fig. 7.9). [Pg.380]

Spiroketals based upon such structures as l,7-dioxaspiro[5.5]undecane (18), occur frequently in natural products. Accordingly, an extensive amount of literature relates to the isolation and total synthesis of this type of compound. This literature was reviewed104 in 1989. The authors of Ref. 104 listed three factors that influence conformational preferences in these systems. They are (7) steric influences, (2) anomeric and related effects, and (3) intramolecular hydrogen bonding and other chelation effects. [Pg.224]

The Chelate Effect and Polydentate Ligands 147 Table 8-1. Stability constants for some nickel(ii) complexes of ammonia and 1,2-diaminoethane. [Pg.147]

Ligand-Field Stabilization Energies 8.2.3 Contributions to the Chelate Effect - The Entropy... [Pg.149]

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Aldol reaction chelation effects

Arylation chelation effects

Chain Chelate effect

Chelate Effects and Preorganization Entropy Factors

Chelate effect Chelating agents

Chelate effect coordination

Chelate effect kinetic effects

Chelate effect kinetics

Chelate effect stereochemistry

Chelate effect thermodynamic effects

Chelate effect with fluoride ions

Chelate effect, definition

Chelate effect, mechanism

Chelate effect, mechanism Thermodynamics

Chelate effect, polydentate ligands

Chelate ring size effects

Chelate rings and Jahn-Teller effect

Chelates chelate effect

Chelates chelate effect

Chelates heavy atom effect

Chelating agents effect

Chelating centers, effect

Chelating effect

Chelating effect

Chelation Effects in the Mizoroki-Heck Reaction

Chelation anti-chelate effect

Chelation chelate effect

Chelation chelate effect

Chelation control also group effects

Chelation effects

Chelation effects

Chelation effects Mukaiyama aldol reaction

Chelation effects aldol addition reactions

Chelation effects enolate alkylation

Chelation effects enolate formation

Chelation effects ester enolates

Chelation steric effects

Chelation therapy effectiveness

Chelation therapy side effects

Chelation-enhanced fluorescence effect

Chlorophyll chelate effect

Complexes chelate effect

Cooperativity and the Chelate Effect

Coordination chemistry chelate effect

Coordination compounds chelate effect

Diphosphine ligands, chelating, effect

Dissociation kinetic chelate effect

Donor Group Orientation and Chelate Ring Size Effects

Effect of Chelation

Effect of chelating agent

Effects of chelators

Enhanced Coordination by Preorganization. Surface Chelate Effect and Signaling

Enolates chelation effects

Entropy and the chelate effect

Entropy-related chelate effect

Equilibrium chelate effect

Esters chelation effects

Kinetic chelate effect

Macrocycles chelate effect

Metal-binding proteins, chelate effect

Metathesis, chelation effects

Peptide ligands chelating effects

Porphyrin chelate effect

Proteins chelate effect

Reverse chelate effect

Ring chelation effect

Siderophore chelate effect

Silicon chelates effect

Stability of Chelates Chelate and Macrocyclic Effects

Statistical and chelate effects

Surface Chelation Effects

Surface chelate effect

The Chelate Effect

The Kinetic Chelate Effect

Thermodynamic Origins of the Chelate Effect

Thermodynamic stability chelate effects

Thermodynamics, and chelate effect

Toxicity and Adverse Effects of Clinically Used Chelating Agents

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