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High-performance liquid chromatography adsorbents

Selectivity of chromatographic separation is known to be varied by changing both the nonstationary phase composition and adsorbent nature. It is shown that the less are the values of the reached selectivity coefficient the higher are the requirements to column effectiveness. In this connection the choice of stationai y phase with high and predicted selectivity coefficient for the compounds being separated is still remains a topical problem of high-performance liquid chromatography. [Pg.138]

The value of for calcium hydroxyapatite can be defined by charge of Ca + and PO ions. From this point of view calcium hydroxyapatite can be used as high-selective adsorbents for high performance liquid chromatography because with increasing of will be rise a selectivity coefficient a. [Pg.138]

Nowack et al. [17] determined adsorbed iron III and nickel-EDTA species in soil by reverse phase ion-pair high-performance liquid chromatography. Iron III EDTA was found to be the main species present occuring at 30-... [Pg.287]

Spherical CaHAP panicles are synthesized by spray pyrolysis. The spherical particles are suitable for high-performance liquid chromatography (HPLC) adsorbents. The atomized solutions dissolving Ca(N03)2 and (NH4)2HP04 are evaporated into the hot part of a furnace, to be decomposed at 600°C (13). The CaHAP particles formed are hollow agglomerates of tine particles. [Pg.366]

The following table provides information on the properties and applications of some of the more specialized bonded, adsorbed, and polymeric phases used in modem high-performance liquid chromatography. In many cases, the phases are not commercially available refer to the appropriate literature citation for details on the synthesis. [Pg.138]

Kawasaki, T., Kobayashi, W., Ikeda, K., Takahashi, S., and Monma, H., High-performance liquid chromatography using spherical aggregates of hydroxyapatite micro-crystals as adsorbent, Eur. J. Biochem., 157, 291, 1986. [Pg.139]

The following table contains the common solvents used in thin-layer chromatography, with a measure of their strengths on silica gel and alumina. The solvent strength parameter, s°, is defined as the relative energy of adsorption per unit area of standard adsorbent.13 It is defined as zero on alumina when pentane is used as the solvent. This series is what was called the eluotropic series in the older literature. For convenience, the solvent viscosity is also provided. Note that the viscosity is tabulated in cP for the convenience of most users. This is equivalent to mPasec in the SI convention. Additional data on these solvents may be found in the tables on high-performance liquid chromatography. [Pg.184]

Zhou, Q., J. Xiao, and W. Wang. 2006. Using multi-walled carbon nanotubes as solid phase extraction adsorbents to determine dichlorodiphenyltrichloroethane and its metabolites at trace level in water samples by high performance liquid chromatography with UV detection. J. Chromatogr. A 1125 152-158. [Pg.471]

It was also shown that the adsorptive capacity of the mesoporous materials is in excess of an order of magnitude superior than that of conventional porous adsorbent materials thus, MCM-41 has the potential as a selective adsorbent in separation techniques, for example, high-performance liquid chromatography and supercritical fluid chromatography [122],... [Pg.319]

Nopper, B., Kohen, F., and Wilchek, M. (1989). A thiophilic adsorbent for the one-step high-performance liquid chromatography purification of monoclonal antibodies. Anal. Biochem. 180, 66-71. [Pg.628]

As discussed briefly earlier, the stationary phases commonly encountered in high performance liquid chromatography are either polar adsorbents (silica, alumina) or those which contain bonded phases (Yost et al. 1980, Braithwaite and Smith 1985). The latter are most likely to be silica coated with either polar (—NH2, —CN, or diol) or nonpolar (hydrocarbonaceous) ligands covalently attached via siloxane bonds. [Pg.552]

See other pages where High-performance liquid chromatography adsorbents is mentioned: [Pg.13]    [Pg.136]    [Pg.145]    [Pg.58]    [Pg.239]    [Pg.285]    [Pg.58]    [Pg.174]    [Pg.246]    [Pg.274]    [Pg.182]    [Pg.106]    [Pg.160]    [Pg.435]    [Pg.175]    [Pg.267]    [Pg.183]    [Pg.168]    [Pg.455]    [Pg.273]    [Pg.622]    [Pg.16]    [Pg.246]    [Pg.427]    [Pg.351]    [Pg.48]    [Pg.112]    [Pg.328]    [Pg.181]    [Pg.124]    [Pg.143]    [Pg.57]    [Pg.321]    [Pg.188]    [Pg.170]    [Pg.186]   
See also in sourсe #XX -- [ Pg.825 ]



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