Hydrocarbons atomic carbon

Now consider the alkynes, hydrocarbons with carbon-carbon triple bonds. The Lewis structure of the linear molecule ethyne (acetylene) is H—O C- H. To describe the bonding in a linear molecule, we need a hybridization scheme that produces two equivalent orbitals at 180° from each other this is sp hybridization. Each C atom has one electron in each of its two sp hybrid orbitals and one electron in each of its two perpendicular unhybridized 2p-orbitals (43). The electrons in the sp hybrid orbitals on the two carbon atoms pair and form a carbon—carbon tr-bond. The electrons in the remaining sp hybrid orbitals pair with hydrogen Ls-elec-trons to form two carbon—hydrogen o-bonds. The electrons in the two perpendicular sets of 2/z-orbitals pair with a side-by-side overlap, forming two ir-honds at 90° to each other. As in the N2 molecule, the electron density in the o-bonds forms a cylinder about the C—C bond axis. The resulting bonding pattern is shown in Fig. 3.23. [Pg.237]

In longer chained hydrocarbons, the carbon atoms have a zig-zag structure. Also, it is important to note that the atoms are free to rotate about any single bond. [Pg.42]

The reactions of ground state atomic carbon, C(3Pj), with unsaturated hydrocarbons are another important class of reactions characterized by multiple pathways. These reactions, besides being of fundamental interest, are of great relevance in the chemistry of the interstellar medium and also in combustion.12,93-95... [Pg.364]

A much more detailed and time-dependent study of complex hydrocarbon and carbon cluster formation has been prepared by Bettens and Herbst,83 84 who considered the detailed growth of unsaturated hydrocarbons and clusters via ion-molecule and neutral-neutral processes under the conditions of both dense and diffuse interstellar clouds. In order to include molecules up to 64 carbon atoms in size, these authors increased the size of their gas-phase model to include approximately 10,000reactions. The products of many of the unstudied reactions have been estimated via simplified statistical (RRKM) calculations coupled with ab initio and semiempirical energy calculations. The simplified RRKM approach posits a transition state between complex and products even when no obvious potential barrier... [Pg.33]

Thus, the 1,2-C pathway dominates when 84 is generated by the thermolysis of a tosylhydrazone salt, but a 1,2-H shift to cyclopropylethene is the major pathway when 84 is generated from either a hydrocarbon precursor or via the atomic carbon abstraction of oxygen from cyclopropylmethylketone at —196°C.U1... [Pg.97]

Scientists classify hydrocarbons as either aliphatic or aromatic. An aliphatic hydrocarbon contains carbon atoms that are bonded in one or more chains and rings. The carbon atoms have single, double, or triple bonds. Aliphatic hydrocarbons include straight chain and cyclic alkanes, alkenes, and alkynes. An aromatic hydrocarbon is a hydrocarbon based on the aromatic benzene group. You will encouter this group later in the section. Benzene is the simplest aromatic compound. Its bonding arrangement results in special molecular stability. [Pg.12]

Lead aerosol in the air is poisonous to breathe, especially for young children. Many people called for the abolition of lead in gasoline. In the 1970s, the photochemical smog in California was attributed to unburned hydrocarbons and carbon monoxide from automobile tailpipes, and the best solution was the catalytic converter which works with finely divided platinum particles deposited on alumina monoliths. When leaded gasoline is used, these platinum atoms would be quickly covered by a barrage of lead aerosols. This finally led to the abolishment of TEL as a gasoline additive. [Pg.16]

In aromatic hydrocarbons, the carbon atoms form a ring instead of being bonded together in a straight chain. The most common aromatic structure is the benzene ring, which consists of six carbon atoms bonded together in a hexagonal structure. Note that there are three double bonds. [Pg.29]

The most common procedure is that of semiempirical theory, which treats Hi as a parameter assumed reasonably constant for a given series of compounds. For example, in the case of aromatic hydrocarbons, each carbon atom is in a similar state and contributes one orbital (a 2orbital with its nodal plane corresponding to the molecular plane) to the above linear combination. Hiickel theory applied to these compounds assumes... [Pg.10]

Fig. 24. Inverse recombination probability of iodine atoms formed by photodissociation (at 485.8 nm) of iodine molecules in various hydrocarbon solvents, , carbon tetrachloride, A and hexachlorobuta-1,3-diene, v, as a graph against inverse viscosity. The temperature was 25 C and experimental errors are quoted to be 10% on the survival probability measurements. After Booth and Noyes [291] and Lampe and Noyes [292],...

To conclude this section two compound specific reactions are worthy of mention. Firstly, the interaction of atomic carbon with benzene has been found to provide 1 albeit in 11% yield and as one of eleven hydrocarbon products46. Secondly, 4,5,7-tri-t-butylisobenzofuran has been reported to undergo furan-cyclopropenylaldehyde photorearrangement rather than An electrocyclization to the Dewar furan47. Steric factors undoubtedly dominate in yielding 2,3,5-tri-/-butylcyclopropabenzene-l-carbaldehyde the product was obtained in solution and characterized by H NMR only. [Pg.715]

The process consists of heating the fully machined part in an aimosphere rich in carbon monoxide or hydrocarbon gases at a temperature in the range I650-I800°F (899-982=C). Reactions at the surface of the rnetal liberate atomic carbon which is readily dissolved by the steel and diffuses inward from the surface. In a typical carburized case a depth of penetration of 0 05 inch (0.13 centimeter) was obtained in 4 hours at l701fF (927 C), The maximum carbon content at the surface was 1.10%. Shallow eases under 0 02 inch (0.05 centimeter) are useful for many purposes and very deep cases over 0.10 inch (0.25 centimeter) thick are required for gears lor heavy machinery and for armor plate. [Pg.295]

Petroleum, the raw material of the petrochemical industry, consists mostly of members of the simplest family of organic compounds, the hydrocarbons, compounds containing only carbon and hydrogen. There is an enormous number of hydrocarbons because carbon can form an amazing variety of chains, rings, and networks of atoms, and can do so by forming single, double, and triple bonds. [Pg.984]

Reactions of atomic carbon, produced by nuclear reactions, with a number of hydrocarbons have been studied by Wolfgang and his collaborators (69). To minimize radiation induced secondary reactions which occur when use is made of C14, a technique has been developed using short-lived C11 produced by a neutron exchange reaction between a platinum foil and a C12 ion beam from a heavy ion accelerator. Part of the scattered Cu atoms has been allowed to penetrate through the thin brass foil wall of a brass vessel and come in contact with the compound wrhose reaction is studied. Products have been analyzed by gas chromatography using a technique of simultaneous mass and radioactivity determination. [Pg.175]

The aromatic hydrocarbons 1,2-7,8-dibenzocoronene (79) and 1,12-2,3-4,5-6,7-8,9-10,11-hexabenzocoronene (80) have been studied, using partial three-dimensional data, by Robertson and Trotter (1961a, b) as part of a series of investigations into polynuclear aromatic hydrocarbons. The carbon skeletons of dibenzocoronene and hexabenzo-coronene are planar to within 0-038 and 0-065 A respectively. The r.m.s. deviations of the atoms from the appropriate mean molecular planes are 0-016 and 0-024 A, compared with the average estimated standard deviations in atomic position of 0-012 and 0-020 A respectively. There are, however, some indications from the electron density maps... [Pg.262]

In the above hydrocarbon syntheses, many of the important reactions have been studied in the laboratory, albeit mainly at room temperature. Important exceptions are reactions involving atomic carbon which, as we will see in our discussion on detailed results of models, appear to play a significant quantitative role in the syntheses of hydrocarbons and other organic molecules. The extension of ion-molecule syntheses to even larger hydrocarbons than shown above will require additional studies in the laboratory to determine relevant rates and products for both the insertion and condensation pathways. [Pg.151]

In a conjugated hydrocarbon, each carbon atom provides one it electron. Thus, for neutral systems, the number of atoms and the number of it electrons are identical. [Pg.55]

Alkanes can be either straight-chain or branched-chain. In straight-chain hydrocarbons, the carbon atoms on the end of the chain bond to only a single carbon atom and carbon atoms in the middle of the chain bond to only two carbon atoms, one on each side. In branched-chain hydrocarbons, the central carbon atoms bond to additional carbon atoms. [Pg.472]

The general formula for alkenes implies that at least two carbon atoms in any alkene compound have fewer than four bonded atoms. As a result, chemists refer to alkenes as unsaturated compounds. Unlike saturated compounds, unsaturated hydrocarbons contain carbon atoms that can potentially bond to additional atoms. [Pg.553]

In alkanes or saturated hydrocarbons, each carbon atom forms four covalent bonds. These bonds are C —C and C — H sigma bonds. Sigma bonds are very strong, so for this reason, alkanes are also known as paraffins which means "inert". [Pg.20]

In the elementary reactions of the pyrolysis, the atomic carbon is formed first. Then it transforms into the final product, whether it be soot, graphite, carbon nanofibers, or so forth. Why does the presence of catalysts make it possible to grow carbon nanofibers or nanotubes instead of soot In many cases, this is the so called carbide cycle that is characteristic of the catalytic process of hydrocarbon pyrolysis that is responsible for the growth of the elongated structures but not soot particles. The primary car bon atoms produced by pyrolytic decomposition of the hydrocarbon molecules are dissolved in the metal particle of the active catalyst compo nent to form a nonstoichiometric carbide (the carbon solution in the... [Pg.289]

Figure 5.2 A schematic of the mechanism of the nanofilaments growth at catalytic pyrolysis of hydrocarbons. Hydrocarbon decomposition on the metal nanoparticle (the dark area) surface produces chemisorbed atomic carbon Cg species with a high chemical potential. In the (pseudo)fluidized catalyst particle, the atomic carbon is capable of diffusing through the metal nanoparticles toward the interphase boundary between the active component and the growing face of the carbon nanofiber (the light areas).

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