Hydroxyl groups structure

Reaction occurs differently since there are two types of hydroxyl groups (as noted earlier), the two ring hydroxyls and the methylene hydroxyl. In the typical formation of esters, such as cellulose acetate, the ring hydroxyl groups are acetylated initially (structure 9.8) prior to the C-6 exocyclic hydroxyl. Under appropriate reaction conditions, reaction continues to almost completion with the esterification of all three hydroxyl groups (structure 9.9). In triacetate products, only small amounts (on the order of 1%) of the hydroxyls remain free, and of these generally about 80% are C-6 hydroxyl. [Pg.269]

While some phenol is produced by the nucleophilic substitution of chlorine in chlorobenzene by the hydroxyl group (structure 17.17), most is produced by the acidic decomposition of cumene hydroperoxide (structure 17.18) that also gives acetone along with the phenol. Some of the new processes for synthesizing phenol are the dehydrogenation of cyclohexanol, the decarboxylation of benzoic acid, and the hydrogen peroxide hydroxylation of benzene. [Pg.534]

Alkaloid (C22H35NO3 mp 190-19 ) was also isolated in small amounts from D. bicolor (100, 101). It was shown to contain an N-ethyl, a tertiary methyl, a methoxyl, and four hydroxyl groups. Structure 84 was assigned to alkaloid on the basis of comparisons of the 13C chemical shifts for alkaloids A and and their hydrochloride salts with those of deoxylycoctonine and isotalatizidine. Recently, the 13C chemical shift assignments for alkaloid have been revised (102). Because alkaloids A and are closely related and the structure of alkaloid A was revised to 85 with the C-6 a-acetyl group, perhaps the C-6 hydroxyl group in alkaloid is also present in the a-configuration. [Pg.30]

Acid hydrolysis of serratamic acid gave a nitrogen-free acid, C10H20O3J and a water soluble component identical with L-serine. The acid, m.p. 47°C, [ajo —19° (chloroform), was identified as 3(d)-hydroxydecanoic acid. As serratamic acid exhibits amide bands in its infrared spectrum (1649, 1632, 1549 cm" ) and contains a primary hydroxyl group, structure (1), N-(3D-hydroxydecanoyl)-L-serine, was proposed (6) (Scheme 1). This structure was confirmed by synthesis from 3d-hydroxydecanoic acid and L-serine methyl ester (7). [Pg.3]

A commonplace variation on the general pattern seen m carbohydrate structure is the replacement of one or more of the hydroxyl substituents by some other atom or group In deoxy sugars the hydroxyl group is replaced by hydrogen Two examples of deoxy sugars are 2 deoxy d nbose and l rhamnose... [Pg.1042]

Another structural variation is the replacement of a hydroxyl group m a carbohydrate by an ammo group to give an ammo sugar The most abundant ammo sugar is one of the oldest and most abundant organic compounds on earth N Acetyl d glucosamine is the... [Pg.1042]

The free anomeric hydroxyl group IS the one shown at the far right of the preced ing structural formula The symbol is used to represent a bond of variable stereochemistry... [Pg.1047]

Sucralose has the structure most similar to su crose Galactose replaces the glucose unit of sucrose and chlorines replace three of the hydroxyl groups Sucralose is the newest artificial sweetener having been approved by the U S Food and Drug Adminis tration in 1998 The three chlorine substituents do not dimmish sweetness but do interfere with the ability of the body to metabolize sucralose It there fore has no food value and IS noncaloric... [Pg.1051]

Anomeric effect (Section 25 8) The preference for an elec tronegative substituent especially a hydroxyl group to oc cupy an axial orientation when bonded to the anomeric carbon m the pyranose form of a carbohydrate Anti (Section 3 1) Term describing relative position of two substituents on adjacent atoms when the angle between their bonds is on the order of 180° Atoms X and Y m the structure shown are anti to each other... [Pg.1276]

In Table 5.3, is compared with the total hydroxyl concentration (Ni, + N ) of the corresponding fully hydroxylated, sample. The results clearly demonstrate that the physical adsorption is determined by the total hydroxyl content of the surface, showing the adsorption to be localized. It is useful to note that the BET monolayer capacity n JH2O) (= N ) of the water calculated from the water isotherm by the BET procedure corresponds to approximately 1 molecule of water per hydroxyl group, and so provides a convenient means of estimating the hydroxyl concentration on the surface. Since the adsorption is localized, n.(H20) does not, of course, denote a close-packed layer of water molecules. Indeed, the area occupied per molecule of water is determined by the structure of the silica, and is uJH2O) 20A ... [Pg.274]

Structure Modification. Several types of stmctural defects or variants can occur which figure in adsorption and catalysis (/) surface defects due to termination of the crystal surface and hydrolysis of surface cations (2) stmctural defects due to imperfect stacking of the secondary units, which may result in blocked channels (J) ionic species, eg, OH , AIO 2, Na", SiO , may be left stranded in the stmcture during synthesis (4) the cation form, acting as the salt of a weak acid, hydrolyzes in aqueous suspension to produce free hydroxide and cations in solution and (5) hydroxyl groups in place of metal cations may be introduced by ammonium ion exchange, followed by thermal deammoniation. [Pg.447]

Poly(vinyl acetate) is an atactic material and is amorphous. Whilst the structure of polyfvinyl alcohol) is also atactic the polymer exhibits crystallinity and has essentially the same crystal lattice as polyethylene. This is because the hydroxyl groups are small enough to fit into the lattice without disrupting it. [Pg.390]

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