Natural Vibrations and Group Frequencies

The aim of molecular spectrum analysis is to reduce the vibrations observed in the infra-red, visible and ultra-violet band spectrum as well as in the Raman spectrum to a definite model locating exactly the individual atomic centers of mass on the one hand, and specifying quantitatively the forces between the constituent atoms on the other. The former object is relatively easy to attain from data on inter-nuclear distances and valence angles, while the latter is a difficult problem as yet unsolved. In interpreting band spectra, we have assumed that, among all the atoms of a molecule, including even those not directly united, forces interact which depend only upon the distances separating the atoms. [Pg.45]

This central force system, which has been used, for example, by D. M. Dennison and in which the potential energy of the molecule retains a [Pg.45]

Generally, greater forces are required to stretch a primary valence lengthwise than to deflect it from its normal direction. Preliminary information has already been reported in Table 10 and in the text on page 18 regarding the energy relationships the natural vibrations allow the presentation of more definite evidence. [Pg.46]

Kohlrausch and R. Mecke, who have sought to establish a clear relationship between the natural vibrations of a molecule and the valence forces, start out from the simplest case of a diatomic structure which undergoes harmonic oscillations of frequency v. In this case the mean force / required to pull the molecules apart—termed by KohlrauscI the spring force— is connected with the reduced mass ix and the frequency by the relation [Pg.46]

Another measure for the elasticity of a linkage under tensile stress has been introduced by R. Mecke in the so-called bond constant k this indicates the amount of work required to double the distance between th( atomic nuclei in the molecule, assuming the validity of Hookers law ovei the whole region. The bond constant is defined by the equation [Pg.46]

The mid-IR spectrum (4000-400 cm ) can be divided into four main regions, and the nature of a group frequency may generally be determined by the region in which it is located. In Table 16.2, the fundamental vibrations of some common chemical bonds in the mid region are presented and the wavelength and region for each vibration are included. [Pg.340]

Such characteristic and reliable frequencies provide a powerful means for identification of molecular subunits. By definition, they are largely insensitive to mechanical (vibrational) interactions and electronic effects from different adjacent atoms or groups. However, these perturbations can produce consistent shifts that are not so great as to destroy the characteristic nature of the group frequency, so that they provide information on the nature of the immediate chemical environment. [Pg.1039]

The frequencies of absorption bands present gives diagnostic information on the nature of functional groups in materials as well as information from any observed frequency shifts on aspects such as hydrogen bonding and crystallinity. In many cases, spectra can be recorded non-destructively using either reflection or transmission procedures. IR spectra of small samples can also be obtained through microscopes (IR microspectrometry). Chalmers and Dent [8] discuss the theory and practice of IR spectroscopy in their book on industrial analysis with vibrational spectroscopy. Standard spectra of additives for polymeric materials include the major collection by Hummel and Scholl [9]. [Pg.568]

The enzymatic reaction was performed at 30 °C for 2 hours in a volume of 1 ml of 250 mM phosphate buffer (pH 6.5) containing 50 mM of KOH, 32 U/ml of the enzyme, and [1- C]-substrate. The product was isolated as the methyl ester. When the (S)-enantiomer was employed as the substrate, C remained completely in the product, as confirmed by C NMR and HRMS. In addition, spin-spin coupling between and was observed in the product, and the frequency of the C-O bond-stretching vibration was down-shifted to 1690 cm" (cf. 1740 cm for C-O). On the contrary, reaction of the (R)-enantiomer resulted in the formation of (R)-monoacid containing C only within natural abundance. These results clearly indicate that the pro-R carboxyl group of malonic acid is ehminated to form (R)-phenylpropionate with inversion of configuration [28]. This is in sharp contrast to the known decarboxylation reaction by malonyl CoA decarboxylase [1] and serine hydroxymethyl transferase [2], which proceeds with retention of configuration. [Pg.22]

IR spectroscopy, one of the few surface analytical techniques not requiring a vacuum, provides a large amount of molecular information. The absorption versus frequency characteristics are obtained when a beam of IR radiation is transmitted through a specimen. IR is absorbed when a dipole vibrates naturally at the same frequency as the absorber, and the pattern of vibration is unique for a given molecule. Therefore, the components or groups of atoms that are absorbed into the IR at specific frequencies can be determined, allowing identification of the molecular structure. [Pg.18]

Such normal vibration analyses have been applied to the spectra of macromolecules to only a limited extent. In the first place, the only structure which has been analyzed in detail is that of the planar zig-zag chain of CHg groups, i.e., polyethylene. Neither substituted planar zig-zag chains nor the helical chain structures characteristic of many polymers [Bunn and Holmes (28)] have been submitted to such a theoretical analysis. In the second place, even for the case of polyethylene the answers are not in all instances unambiguous. Different assumptions as to the nature of the force field, and lack of knowledge of some of the force constants, has led to varying predictions of band positions in the observed spectrum. For the identification of certain modes, viz., those which retain the characteristics of separable group frequencies, such an analysis is not of primary importance, but for knowledge of skeletal frequencies and of interactions... [Pg.87]

It remains to be seen whether further work will establish other means of identifying the nature of trifluoroacetate groups from their vibrational spectra. A possibility that does not appear to have been explored fully in this respect is the relative intensity of the antisymmetric and symmetric CO2 stretching frequencies, for both infrared and Raman spectra. [Pg.33]

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