Scatter matrix

For themial unimolecular reactions with bimolecular collisional activation steps and for bimolecular reactions, more specifically one takes the limit of tire time evolution operator for - co and t —> + co to describe isolated binary collision events. The corresponding matrix representation of f)is called the scattering matrix or S-matrix with matrix elements... [Pg.773]

The physical interpretation of the scattering matrix elements is best understood in tenns of its square modulus... [Pg.773]

A completely difierent approach to scattering involves writing down an expression that can be used to obtain S directly from the wavefunction, and which is stationary with respect to small errors in die waveftmction. In this case one can obtain the scattering matrix element by variational theory. A recent review of this topic has been given by Miller [32]. There are many different expressions that give S as a ftmctional of the wavefunction and, therefore, there are many different variational theories. This section describes the Kohn variational theory, which has proven particularly useftil in many applications in chemical reaction dynamics. To keep the derivation as simple as possible, we restrict our consideration to potentials of die type plotted in figure A3.11.1(c) where the waveftmcfton vanishes in the limit of v -oo, and where the Smatrix is a scalar property so we can drop the matrix notation. [Pg.968]

S is the scattering matrix, analogous to that defined earlier. As before, the probabilities for transitions between states V and v are... [Pg.972]

Propagation then proceeds from R Oto large R, then the scattering matrix is easily connected to Y at large R. [Pg.988]

Note that the sums are restricted to the portion of the frill S matrix that describes reaction (or the specific reactive process that is of interest). It is clear from this definition that the CRP is a highly averaged property where there is no infomiation about individual quantum states, so it is of interest to develop methods that detemiine this probability directly from the Scln-ddinger equation rather than indirectly from the scattering matrix. In this section we first show how the CRP is related to the physically measurable rate constant, and then we discuss some rigorous and approximate methods for directly detennining the CRP. Much of this discussion is adapted from Miller and coworkers [44, 45]. [Pg.990]

The cross section a -is related to the partial wave reactive scattering matrix , tln-ough the partial wave sum... [Pg.991]

In this section, we insert explicitly. The sum has the following meaning for each pair of points x and a draw a path j (t) that starts at x (j (t = 0) = a ) and ends at x" (j (t = r) = a ). This path need not be a classical patii (see figure B3.4.15). Each such path contributes c where S is the action of the path. S (iimelated to the scattering matrix) is calculated very simply as... [Pg.2314]

We have found that display of nuclear trajectories and the simultaneous evolution of charge distributions to yield insightful details of complicated processes. Such descriptions also map more readily to the actual experimental conditions than do the more conventional time-independent scattering matrix descriptions. [Pg.237]

By virtue of the asymptotic condition, the scattering matrix can also be written in the form... [Pg.710]

As discussed by Miller and co-workers [52,53], it is worthwhile to develop theories that enable us to evaluate thermal reaction rate constants directly and not to rely on the calculations of the most detailed scattering matrix or the state-to-state reaction probabihty. Here, our formulation of the nonadiabatic transition state theory is briefly described for the simplest case in which the transition state is created by potential surface crossing [27]. [Pg.112]

In terms of the Stokes constant U, the reduced scattering matrix can be quantum mechanically exactly given by... [Pg.198]

The reduced scattering matrix in terms of the Stokes constant U is given quantum mechanically exactly as... [Pg.202]

The amount of information, which can be extracted from a spectrum, depends essentially on the attainable spectral or time resolution and on the detection sensitivity that can be achieved. Derivative spectra can be used to enhance differences among spectra, to resolve overlapping bands in qualitative analysis and, most importantly, to reduce the effects of interference from scattering, matrix, or other absorbing compounds in quantitative analysis. Chemometric techniques make powerful tools for processing the vast amounts of information produced by spectroscopic techniques, as a result of which the performance is significantly... [Pg.302]

In this section we will discuss perturbation methods suitable for high-energy electron diffraction. For simplicity, in this section we will be concerned with only periodic structures and a transmission diffraction geometry. In the context of electron diffraction theory, the perturbation method has been extensively used and developed. Applications have been made to take into account the effects of weak beams [44, 45] inelastic scattering [46] higher-order Laue zone diffraction [47] crystal structure determination [48] and crystal structure factors refinement [38, 49]. A formal mathematical expression for the first order partial derivatives of the scattering matrix has been derived by Speer et al. [50], and a formal second order perturbation theory has been developed by Peng [22,34],... [Pg.166]

Speer, S., Spence, J.C.H. and Ihrig, E. (1990) On differentiation of the scattering matrix in dynamical transmission electron diffraction, Acta Cryst. A, 46, 763-772. [Pg.179]

With the stationary solution ipfE, one can use asymptotic boundary conditions to extract the scattering matrix. However, for the total reaction... [Pg.420]

Sautet P, Joachim C (1988) Electronic transmission coefficient for the single-impurity problem in the scattering-matrix approach. Phys Rev B 38 12238... [Pg.264]

Ami S, Joachim C (2002) Intramolecular circuits connected to N electrodes using a scattering matrix approach. Phys Rev B 65 155419... [Pg.264]

Consider a v = 3 vertex out of which a bond of length p emerges and waves can imping on the vertex from two lines and be either transmitted or reflected. The vertex scattering matrix in this case is 2 x 2 and it reads... [Pg.38]

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