Synthesis of bulk materials

Jim s work in preparation fundamentals culminated in his (along with coauthors Cristian Contescu and Adriana Contescu) 1995 review, Methods for Preparation of Catalytic Materials (Chem. Rev. 1995, 95, 477). The synthesis of bulk materials was described in an initial section on three-dimensional chemistry followed by a section on two-dimensional chemistry which reviewed the various aqueous, organic, vapor, and solid phase methods to apply catalyst precursors to support surfaces. [Pg.482]

Thus the first section to follow pertains to the synthesis of bulk materials including amorphous and mesoporous oxide supports (chapters 1 ), heteropolyacids (chapter 5), and colloidal metals (chapter 6). The second section covers the synthesis of heterogeneous materials, and has been divided into syntheses in nanoscale domains (chapters 7-10) and those based on two-dimensional metal complex-substrate interactions (chapters 11-14), or a clever way around noninteracting precursors via viscous drying (chapter 15). Effects of drying (chapter 16) and pretreatment (chapter 17) comprise the third section of the book. [Pg.482]

Synthesis of novel materials with desired and tunable physical and chemical properties continues to draw wide interest. Nanomaterials with a variety of shapes and sizes have been synthesized as they offer numerous possibilities to study size and shape-dependent variations of electronic, optical, and chemical properties. Nanomaterials of a particular element show drastic differences in physical and chemical properties when compared with the bulk state. For example, bulk gold, a metal that is insoluble in water can be made dispersible when it is in the nanoparticle form. There are drastic changes in the optical properties as well. Bulk gold appears yellow in color, but when it is in the nanoparticle form with an average core diameter of 16 nm, it appears wine red. Likewise, the chemistry of gold, such as catalysis, also shows a drastic change when the constituent units are in the nanometer range. [Pg.334]

Apart from development of new catalysts with enhanced activity, few processes with innovative chemistry are currently developed for C-H transformation in aromatics. Though new processes using cheaper raw materials or reducing the number of reaction steps may seem attractive at first glance, efforts for process development including research, scale-up, pilot plant, and timeline must be considered. Especially for large scale-synthesis of bulk chemicals process economics... [Pg.24]

The complexity of designing such catalysts arises because the C-H transformation function wanted is not the property of a bulk solid or a well-defined surface but of defects in phases. Such catalysts resemble their biological counterparts, the enzymes that consist also of a complex matrix holding the active site in place and in suitable electronic isolation. The ability to mimic this principle in heterogeneous catalysis with the concept of single site catalysts [45-47] has led to first academic success but is still far away from practical realization, because of the lack of suitable procedures for synthesis of bulk quantities of highly active material. [Pg.596]

Since the last review by Venuto in 1968,[1] there has been a continuous interest in the application of microporous and mesoporous materials as catalysts in the synthesis of bulk and fine chemicals.[211 Indeed, their acidic and basic properties can be combined with their structural properties in order to take advantage of their adsorption and shape selectivity properties, the latter being an advantageous feature of zeolites compared with other heterogeneous catalysts. Another important aspect... [Pg.141]

As for other recyclable heterogeneous catalysts, zeolites and related materials can also contribute to the development of environmentally friendly processes in the synthesis of bulk and fine chemicals. The concept of a biomass refinery, capable of separating, modifying and exploiting the numerous constituents of renewable resources, is gaining worldwide acceptance today with a very broad outlook. This chapter has attempted to show that this particular area of carbohydrate chemistry is in itself very rich, both in already acquired knowledge and potential future developments. [Pg.154]

The use of industrial enzymes for the synthesis of bulk and fine chemicals represents a somewhat specialized application for biocatalysts relative to their broader uses, as outlined above. Industrial biocatalysis is, however, becoming increasingly relevant within the chemical industry for the production of a wide range of materials (see Table 31.3).1,2,4-8 Broadly defined, a biocatalytic process involves the acceleration of a chemical reaction by a biologically derived catalyst. In practice, the biocatalysts concerned are invariably enzymes and are used in a variety of forms. These include whole cell preparations, crude protein extracts, enzyme mixtures, and highly purified enzymes, both soluble and immobilized. [Pg.1385]

Cram [49a] elaborated further on this concept by enclosing space in his carcerands and hemicarcerands (See Scheme 1) to form a new inner phase which he has referred to as a new phase of matter . In contrast to the hollow space found inside clathrates and zeolites for instance, the cages of these molecules are independent of the form and physical state. For example, hemicarcerands and related supramolecular systems (i.e. hemicarceplexes) prevail in the solid, liquid, or gas phase. This characteristic-hollow space, the inside surface — is maintained across all phase transitions. The inner surfaces and spaces of these systems are not manifested as bulk properties. An extensive review on the synthesis of these materials has been published recently [205]. [Pg.210]

Synthesis, Structure, and Physical Properties of Bulk Material... [Pg.1366]

Clearly, a fundamental understanding of the key strac-ture/property relationships, particularly membrane morphology and conductivity as a function of polymer electrolyte architecture and water content - both in the bulk hydrated membrane and at the various interfaces within the membrane electrode assembly (MEA), can provide guidance in the synthesis of novel materials or MEA manufacturing techniques that lead to the improvement in the efficiency and/or operating range of PEMFCs. [Pg.135]

Even if the problems of poor crystal intergrowth due to local exhaustion of reactants in the autoclave and synthesis of zeolite material in the bulk of the solution were solved, an important problem remains, related to the fact that several batch synthesis cycles (with their associated heating and cooling processes) are often required to achieve a zeolite membrane of good quality. Thus, a synthesis procedure in which reactants are continuously supplied to the synthesis vessel while this is maintained at a constant temperature would clearly be desirable not only for performance but also for the feasibility of the scale-up. This type of approaches has already been tested for inner MFI and NaA zeolite membranes [33-35], and the results obtained indicate that the formation of concomitant phases and the amount of crystals forming in the liquid phase are greatly reduced. Similarly, the continuous seeding of tubular supports by cross-flow filtration of aqueous suspensions [36-37] has been carried out for zeolite NaA membrane preparation. [Pg.278]

Synthesis of Giant Zeolite Crystals by a BMD (Bulk Material Dissolution) Technique In 2001, Shimizu et al.[120] developed a BMD (bulk materials dissolution) technique for the synthesis of giant zeolite crystals based on others work. A piece of bulk material,... [Pg.234]

Fiufiffal as Starting Material for the Synthesis of Bulk Chemicals. 100... [Pg.80]

Recent work on mullite synthesis has focused on variations of sol-gel methods, which allow control of the local distribution and homogeneity of the precursor chemistry. The microstructure of a sol-gel derived mullite is shown in Fig. 5. Along with an understanding of kinetics, sol-gel methods look promising for use in the manufacture of bulk materials, thin films, or fibers of mullite with almost any specified phase purity, phase distribution, and grain morphology. [Pg.35]

Liquid crystals combine properties of both liquids (fluidity) and crystals (long range order in one, two, or three dimensions). Examples of liquid crystalline templates formed by amphiphiles are lyotropic mesophases, block copolymer mesophases, and polyelectrolyte-suxfactant complexes. Their morphological complexity enables the template synthesis of particles as well as of bulk materials with isotropic or anisotropic morphologies, depending on whether the polymerization is performed in a continuous or a discontinuous phase. As the templating of thermotropic liquid crystals is already described in other reviews [47] the focus here is the template synthesis of organic materials in lyotropic mesophases. [Pg.213]

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