Tci Pci(kpa) Ai Bi Ci b=bi*yi bi*yi d=di*yi di*yi

0.043834 2.25563
C1 190.56 4599 4.934 8 1.5 0.021207 0.82107
C2 305.41 4800 4.934 8.3 0 0.004587 0.29713
C3 369.77 4240 4.934 8.82 0 0.003143 0.21337
iC4 407.82 3640 4.934 9.3 0 0.002423 0.15347
nC4 425.1 3784 4.934 9.35 0 0.00162 0.11041
iC5 460.35 3381 4.934 9.4 0 0.000982 0.06352
nC5 469.65 3365 4.934 9.5 0 0.001006 0.06588
nC6 506.4 3030 4.934 10 0 0.001205 0.07594
nC7 539.2 2740 4.934 10.5 0 0.001419 0.08588
nC8 568.4 2490 4.934 11 0 0.001646 0.09565
nC9 594.7 2280 4.934 11.2 0 0.00188 0.10386
nC10 617.7 2100 4.934 11.6 0 0.00212 0.11247
CO2 304.11 7374 3.5 6.8 0 0.000297 0.01870
H2S 373.37 8963 4.26 6.5 0 0.0003 0.03827
Total 0.043834 2.25563

Calculate Z follow Redlich Kwong Barxuk Equation

Z^3-Z^2-(m^2+m-d*m)Z-dm^2=0
b=bi*yi m=Pb/R/T
d=di*yi
bi=0,0867RTc/Pc
di=Ai+Bi(Tc/T-1)+Ci(Tc/T-1)^2
Note: F(Z)=0
PAGE 18 & 26 CNCBKTNVKDM

Solution is obtained by Goal Seek(see under Tools dropdown menu) by setting the value of the cell P2 at zer

369944076.xls
 m R P(kpa) T(k) yi f(Z) Z MWi
0.02636 8.3145 2000.000 400.0000 0.000052 0.968261
8.3145 400.0000 0.71 16.043
8.3145 400.0000 0.1 30.07
8.3145 400.0000 0.05 44.097
8.3145 400.0000 0.03 58.123
8.3145 400.0000 0.02 58.123
8.3145 400.0000 0.01 72.15
8.3145 400.0000 0.01 72.15
8.3145 400.0000 0.01 86.117
8.3145 400.0000 0.01 100.204
8.3145 400.0000 0.01 114.132
8.3145 400.0000 0.01 128.258
8.3145 400.0000 0.01 142.258
8.3145 400.0000 0.01 44.01
8.3145 400.0000 0.01 34.082
1

the value of the cell P2 at zero while changing cell Q2

369944076.xls
Mwi*yi Mw kg/m3 v (m3/kg)V=RZT/P Pci*yi Tci*yi Pc Tc
27.44214 17.04353 0.058673 1.610121 4499.4 249.4025
11.39053 3265.29 135.2976
3.007 480 30.541
2.20485 212 18.4885
1.74369 109.2 12.2346
1.16246 75.68 8.502
0.7215 33.81 4.6035
0.7215 33.65 4.6965
0.86117 30.3 5.064
1.00204 27.4 5.392
1.14132 24.9 5.684
1.28258 22.8 5.947
1.42258 21 6.177
0.4401 73.74 3.0411
0.34082 89.63 3.7337
27.44214 4499.4 249.4025

369944076.xls
 vci vci*yi vc
0.005669
0.00617 0.004381
0.00489 0.000489
0.00454 0.000227
0.00446 0.000134
0.00439 0.000088
0.00427 0.000043
0.00434 0.000043
0.00429 0.000043
0.00426 0.000043
0.0042 0.000042
0.00433 0.000043
0.00439 0.000044
0.00214 0.000021
0.00288 0.000029
0.005669

369944076.xls