Neodymium(III) nitride is a chemical compound of neodymium and nitrogen with the formula NdN in which neodymium exhibits the +3 oxidation state and nitrogen exhibits the -3 oxidation state. It is ferromagnetic, like gadolinium(III) nitride, terbium(III) nitride and dysprosium(III) nitride.[3] Neodymium(III) nitride is not usually stoichiometric, and it is very hard to create pure stoichiometric neodymium nitride.[4]
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| Other names
Neodymium mononitride, azanylidyneneodymium
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| Identifiers | |
3D model (JSmol)
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| ChemSpider | |
| ECHA InfoCard | 100.042.937 |
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PubChem CID
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CompTox Dashboard (EPA)
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| Properties | |
| NdN | |
| Molar mass | 158.25 g/mol[1] |
| Structure[2] | |
| Rock Salt (cubic) | |
| Fm3m (No. 225) | |
a = 512.4 pm
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Formula units (Z)
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4 |
| Hazards | |
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Other anions
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Neodymium(III) arsenide Neodymium(III) phosphide Neodymium(III) antimonide Neodymium(III) bismuthide Neodymium(III) oxide |
Other cations
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PrN |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Preparation
editNeodymium(III) nitride can be prepared via an exothermic metathesis reaction between lithium nitride and anhydrous neodymium(III) chloride. Lithium chloride formed in the reaction can be removed by THF, a chemical in which lithium chloride dissolves.[5]
- NdCl3 + Li3N → NdN + 3 LiCl
It can also be prepared directly when neodymium reacts directly with nitrogen:
- 2 Nd + N2 → 2 NdN
It can be prepared when decomposing neodymium amide:
- Nd(NH2)3 → NdN + N2 + 3H2
It can also be produced when neodymium is ignited in air (which contains nitrogen),[6] but this also produces other compounds, such as neodymium oxide.
See also
editReferences
edit- ^ a b c "Neodymium nitride (NDN)".
- ^ Adachi, Jun; Katayama, Masahito; Kurosaki, Ken; et al. (2008). "Thermal properties of polycrystalline NdN bulk samples with various porosities". Journal of Nuclear Materials. 376 (1). Elsevier BV: 83–87. doi:10.1016/j.jnucmat.2007.12.009. ISSN 0022-3115.
- ^ Temmerman, W. M. (2009). "Chapter 241: The Dual, Localized or Band‐Like, Character of the 4f‐States". In Gschneider Jr., K. A. (ed.). Handbook on the Physics and Chemistry of Rare Earths vol 39. Elsevier. pp. 100–110. ISBN 978-0-444-53221-3.
- ^ Nasirpouri, Farzad and Nogaret, Alain (eds.) (2011) Nanomagnetism and Spintronics: Fabrication, Materials, Characterization and Applications. World Scientific. ISBN 9789814273053
- ^ Fitzmaurice, J.C.; Hector, A.; Rowley, A.T.; Parkin, I.P. (1994). "Rapid, low energy synthesis of lanthanide nitrides". Polyhedron. 13 (2). Elsevier BV: 235–240. doi:10.1016/s0277-5387(00)86597-3. ISSN 0277-5387.
- ^ Cotton, Simon (2006). Lanthanide and Actinide Chemistry. John Wiley & Sons Ltd.