Germanide nitrides or nitride germanides are compounds containing anions composed of nitride (N3−) and germanide (Ge4−). They can be considered as mixed anion compounds or intermetallic compounds, as germanium could be considered as a metal. Related compounds include the nitride silicides, phosphide silicides, germanide phosphides, germanide arsenides, germanide antimonides, germanide bismuthides[1] and nitride carbides.
List
edit| formula | system | space group | unit cell Å | volume | density | comment | ref |
|---|---|---|---|---|---|---|---|
| Cr3GeN | tetragonal | P421m | a=5.375 c=4.012 | [2][3] | |||
| Mn3Cu1−xGexN | Pm3m | x=0 to 0.5 | [4] | ||||
| triclinic | P1 | ||||||
| monoclinic | P21 |
References
edit- ^ Cheung, Yan Yin Janice; Svitlyk, Volodymyr; Mozharivskyj, Yurij (1 October 2012). "Gd 4 Ge 3– x Pn x ( Pn = P, Sb, Bi, x = 0.5–3): Stabilizing the Nonexisting Gd 4 Ge 3 Binary through Valence Electron Concentration. Electronic and Magnetic Properties of Gd 4 Ge 3– x Pn x". Inorganic Chemistry. 51 (19): 10169–10175. doi:10.1021/ic300817j.
- ^ Boller, H. (1969). "Die Kristallstruktur von Cr3GeN". Monatshefte für Chemie (in German). 100 (5): 1471–1476. doi:10.1007/BF00900160. ISSN 0026-9247.
- ^ Lin, S.; Tong, P.; Wang, B.S.; Huang, Y.N.; Song, W.H.; Sun, Y.P. (January 2014). "Synthesis and characterization of Ge–Cr-based intermetallic compounds: GeCr3, GeCCr3, and GeNCr3". Journal of Alloys and Compounds. 584: 308–314. doi:10.1016/j.jallcom.2013.09.086.
- ^ Iikubo, S.; Kodama, K.; Takenaka, K.; Takagi, H.; Shamoto, S. (2008-01-24). "Magnetovolume effect in Mn 3 Cu 1 − x Ge x N related to the magnetic structure: Neutron powder diffraction measurements". Physical Review B. 77 (2): 020409. doi:10.1103/PhysRevB.77.020409. ISSN 1098-0121.