Experimento P(psia) V(ft^3/lb) V(ft^3/lbmol) Vr=V- RT/P Ai ∑Ai Φ

1 20 5.86 339.88 -8.845 -88.45 -88.45 0.9874

2 40 2.861 165.938 -8.4245 -172.695 -261.145 0.9632
3 60 1.86 107.88 -8.3616667 -167.86167 -429.00667 0.9403
4 100 1.06 61.48 -8.265 -332.53333 -761.54 0.8966
5 150 0.6557 38.0306 -8.4660667 -418.27667 -1179.8167 0.8444
6 200 0.4505 26.129 -8.7435 -430.23917 -1610.0558 0.7939
7 225 0.3794 22.0052 -8.9925778 -221.70097 -1831.7568 0.7690

Van der Waals

Experimento P(psia) V(ft^3/lb) V(ft^3/lbmol) Vr=V- RT/P Ai ∑Ai Φ

1 20 5.86 343.413879 -5.311121 -53.11121 -53.11121 0.9924138648
2 40 2.861 168.97649466 -5.3860053 -106.97126 -160.08247 0.9773088681
3 60 1.86 110.77613949 -5.4655272 -108.51533 -268.5978 0.9622207299
4 100 1.06 64.1040913416 -5.6409087 -222.12872 -490.72652 0.9320581256
5 150 0.6557 40.5973117059 -5.899355 -288.50659 -779.23311 0.894289244
6 200 0.4505 28.6519170236 -6.220583 -302.99845 -1082.2316 0.856269797
7 225 0.3794 24.5821842815 -6.4155935 -157.95221 -1240.1838 0.8370957067

Redlich Kwong

Experimento P(psia) V(ft^3/lb) V(ft^3/lbmol) Vr=V- RT/P Ai ∑Ai Φ

1 20 5.86 342.27954605 -6.4454539 -64.454539 -64.45454 0.9908011144
2 40 2.861 167.82589691 -6.5366031 -129.82057 -194.27511 0.9725293158
3 60 1.86 109.60751263 -6.634154 -131.70757 -325.98268 0.9543362381
4 100 1.06 62.8927206482 -6.8522794 -269.72867 -595.71135 0.9181332303
5 150 0.6557 39.3142263701 -7.1824403 -350.86799 -946.57934 0.8730870376
6 200 0.4505 27.2613623337 -7.6111377 -369.83945 -1316.4188 0.8279956263
7 225 0.3794 23.113354951 -7.8844228 -193.69451 -1510.1133 0.8053170571

Soave Redlich Kwong

Experimento P(psia) V(ft^3/lb) V(ft^3/lbmol) Vr=V- RT/P Ai ∑Ai Φ

1 20 5.86 342.06151007 -6.6634899 -66.634899 -66.6349 0.9904914196
2 40 2.861 167.59969198 -6.762808 -134.26298 -200.89788 0.9716062705
3 60 1.86 109.37220346 -6.8694632 -136.32271 -337.22059 0.9527997683
4 100 1.06 62.6355741689 -7.1094258 -279.57778 -616.79837 0.9153614965
5 150 0.6557 39.0195226866 -7.477144 -364.66425 -981.46262 0.8687311555
6 200 0.4505 26.9075368771 -7.9649631 -386.05268 -1367.5153 0.8219517402
7 225 0.3794 22.7137636178 -8.2840142 -203.11222 -1570.6275 0.7983599528
f=ΦP R T 250 f
19.75 10.73 650 P
38.53 10.73 650 200 f(VdW )
f(RK)
56.42 10.73 650 f(SRK)
f
89.66 10.73 650 150
126.66 10.73 650
158.77 10.73 650 100
173.03 10.73 650
50

0
0 50 100 150 200 250

�=𝑅𝑇/(𝑉−𝐵)−𝑎/𝑣^2
f=ΦP R T Pc Tc a b Vi=RT/P
19.8482773 10.73 650 529.097 734.58 49536.59313 1.86214517 348.725
39.0923547 10.73 650 529.097 734.58 49536.59313 1.86214517 174.3625
57.7332438 10.73 650 529.097 734.58 49536.59313 1.86214517 116.2416667
93.2058126 10.73 650 529.097 734.58 49536.59313 1.86214517 69.745
134.143387 10.73 650 529.097 734.58 49536.59313 1.86214517 46.49666667
171.253959 10.73 650 529.097 734.58 49536.59313 1.86214517 34.8725
188.346534 10.73 650 529.097 734.58 49536.59313 1.86214517 30.99777778

f=ΦP R T Pc Tc a b Vi=RT/P
19.8160223 10.73 650 529.097 734.58 1360402.858 1.29069006 348.725
38.9011726 10.73 650 529.097 734.58 1360402.858 1.29069006 174.3625
57.2601743 10.73 650 529.097 734.58 1360402.858 1.29069006 116.2416667
91.813323 10.73 650 529.097 734.58 1360402.858 1.29069006 69.745
130.963056 10.73 650 529.097 734.58 1360402.858 1.29069006 46.49666667
165.599125 10.73 650 529.097 734.58 1360402.858 1.29069006 34.8725
181.196338 10.73 650 529.097 734.58 1360402.858 1.29069006 30.99777778

f=ΦP R T Pc Tc a b Vi=RT/P
19.8098284 10.73 650 529.097 734.58 50194.73264 1.29069006 348.725
38.8642508 10.73 650 529.097 734.58 50194.73264 1.29069006 174.3625
57.1679861 10.73 650 529.097 734.58 50194.73264 1.29069006 116.2416667
91.5361496 10.73 650 529.097 734.58 50194.73264 1.29069006 69.745
130.309673 10.73 650 529.097 734.58 50194.73264 1.29069006 46.49666667
164.390348 10.73 650 529.097 734.58 50194.73264 1.29069006 34.8725
179.630989 10.73 650 529.097 734.58 50194.73264 1.29069006 30.99777778
 P
f(VdW )
f(RK)
f(SRK)
f

P
200 250

�=𝑅𝑇/(𝑉−𝐵)−𝑎/𝑣^2

8.615266E-10
3.587338E-07
7.03547E-07
-7.24728E-06
5.637101E-06
-2.60659E-05
7.481329E-06

2.215911E-08
6.270827E-07
-3.91206E-07
-2.80068E-06
-1.07444E-05
-2.97562E-06
-2.17195E-05

ω α Tr
0.181 1.0923176 0.884859375 2.568377E-08
0.181 1.0923176 0.884859375 6.676546E-07
0.181 1.0923176 0.884859375 -5.71351E-07
0.181 1.0923176 0.884859375 -7.5127E-06
0.181 1.0923176 0.884859375 -1.42202E-05
0.181 1.0923176 0.884859375 -1.08495E-05
0.181 1.0923176 0.884859375 1.01252E-05