Acetona Agua

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y,fracción

mol en Cp Mezcla a Temperatur


X, Fracción mol equil. De ΔHs 17.2 °C a vapor- PM de la
de acetona en acetona en (KJ/Kmol (KJ/Kg sol líquido °C , Mezcla (liq)
el líquido vapor sol) a 15 °C °C) solución Kg/Kmol
0 0 0 4.187 100 18.015
0.01 0.253 -89.242 4.179 91.7 18.41565
0.02 0.425 -188.4 4.162 86.6 18.8163
0.05 0.624 -447.3 4.124 75.7 20.01825
0.1 0.755 -668.7 4.02 66.6 22.0215
0.15 0.798 -770 3.839 63.4 24.02475
0.2 0.815 -786 3.81 62.2 26.028
0.3 0.83 -719 3.559 61 30.0345
0.4 0.839 -509 3.35 60.4 34.041
0.5 0.849 -350.1 3.14 60 38.0475
0.6 0.859 -252.6 2.931 59.5 42.054
0.7 0.874 -189.45 2.763 58.9 46.0605
0.8 0.898 -126.3 2.554 58.2 50.067
0.9 0.935 -63.15 2.387 57.5 54.0735
0.95 0.963 -31.575 2.303 57 56.07675
1 1 0 2.214 56.5 58.08

PM ACETONA PM DEL AGUA


58.08 KG/KMOL 18.015 KG/KMOL

t,°C 20 37.8 65.6 93.3 100


Cp acetona
KJ/Kg °C 2.22 2.26 2.34 2.43
Calor lat. De
evapo. KJ/Kg 1013 976 917 863 850

t,°C 20 37.8 65.6 93.3 100


Cp agua KJ/Kg
°C 4.187 4.184 4.19 4.215 4.223
Calor lat. De
evapo. KJ/Kg 2453.245 2412.224 2345.469 2276.0959 2258.41

Cp acetona KJ/Kg °C
2.45
f(x) = 9.2774194451378E-06 x² + 0.001827459391912 x + 2.17908491062433
2.4 R² = 0.999853412481328

2.35

2.3

2.25

2.2

2.15
R² = 0.999853412481328

2.35

2.3

2.25

2.2

2.15

2.1
10 20 30 40 50 60 70 80 90 100

Calor lat. de evpa. acetona


1050

1000 f(x) = − 2.03912995425042 x + 1052.95849130222


R² = 0.99967322891518
950

900

850

800

750
10 20 30 40 50 60 70 80 90 100 110
PM de la Hliq
Mezcla (vap) Hliq (KJ/Kg) (KJ/Kmol) Hvap(KJ/Km Hvap (KJ/Kg) Cp acetona Calor lat. De Cp agua
Kg/Kmol Mezcla Mezcla ol) Mezcla Mezcla KJ/Kg °C evapo. KJ/Kg KJ/Kg °C
18.015 355.895 6411.44843 47155.8298 2617.587 2.4491 849.09 4.2102
28.151445 315.683313 5813.5134 50471.4261 1792.85383 2.41984001 866.01453 4.2017589
35.042625 287.986605 5418.84235 52738.4589 1504.98026 2.40247604 876.41394 4.1972556
43.01556 227.982189 4563.80446 55205.7196 1283.38954 2.36693441 898.64013 4.1893749
48.264075 177.066221 3899.26379 56797.6628 1176.81035 2.33890004 917.19594 4.1846156
49.98687 153.757319 3693.98114 57322.5424 1146.75199 2.32939604 923.72106 4.1833356
50.667975 149.633752 3894.6673 57533.1269 1135.49292 2.32587956 926.16798 4.1829084
51.26895 139.774863 4198.06813 57715.9616 1125.74885 2.322389 928.6149 4.18251
51.629535 137.137443 4668.29569 57829.0374 1120.07667 2.32065344 929.83836 4.1823216
52.030185 132.098344 5026.01175 57961.5673 1113.99887 2.3195 930.654 4.1822
52.430835 124.422937 5232.48219 58091.7354 1107.96892 2.31806225 931.67355 4.1820525
53.03181 117.182631 5397.49059 58290.9549 1099.16963 2.31634289 932.89701 4.1818821
53.99337 107.81018 5397.7323 58616.4945 1085.62393 2.31434516 934.32438 4.1816924
55.475775 100.279645 5422.47139 59128.1187 1065.83673 2.31235625 935.75175 4.1815125
56.597595 96.1629324 5392.50472 59516.3919 1051.57104 2.310941 936.7713 4.18139
58.08 91.881 5336.44848 60033.5995 1033.63636 2.30953025 937.79085 4.1812725

TEMP DE REF.
15 °C

Cp agua KJ/Kg °C
4.23

4.22 f(x) = 1.08900805821042E-05 x² − 0.000860336369887 x + 4.20019812336364


R² = 0.999084415260641
4.21

4.2

4.19

4.18

4.17
R² = 0.999084415260641
4.21

4.2

4.19

4.18

4.17

4.16
10 20 30 40 50 60 70 80 90 100 110

Calor lat. De evapo. KJ/Kg


2500

2450
f(x) = − 2.43775904860306 x + 2503.49643813852
R² = 0.999707944682731
2400

2350

2300

2250

2200

2150
10 20 30 40 50 60 70 80 90 100 110
y,fracción
X, Fracción peso en
peso de equil. De
Calor lat. De acetona en acetona en
evapo. KJ/Kg el líquido vapor
2259.72 0 0
2279.95374 0.03153839 0.52197107 CURVA DE EQUILIBRIO, FRACC. PESO
2292.38652 0.06173371 0.70439929 1.2
2318.95854 0.14506763 0.84253047
2341.14252 0.26374225 0.90855155 1
2348.94348 0.36262604 0.92720028
2351.86884 0.44628861 0.93422324 0.8

2354.7942 0.58013285 0.94026501


0.6

Y
2356.25688 0.68247114 0.94382256
2357.232 0.76325646 0.94771756 0.4
2358.4509 0.82864888 0.95155303
2359.91358 0.88266519 0.95719758 0.2
2361.62004 0.92803643 0.96596749
2363.3265 0.96668424 0.97889214 0
0 0.2 0.4 0.6 0
2364.5454 0.98393719 0.98822291
X
2365.7643 1 1

6000

5000

4000
HL, HV KJ/KMOL

3000

2000

1000

0
0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

X,Y FRACC. MOL

2000
1800
1600
1400
1200
HL,HV KJ/KG

1000
800
600
2000
1800
1600
1400
1200

HL,HV KJ/KG
1000
800
600
400
200
0
0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 1.1
X,Y FRACC. PESO
ILIBRIO, FRACC. PESO DEL ACETONA

0.4 0.6 0.8 1 1.2


X

FRACCIÓN MOL DE ACETO


1.05
1
0.95
0.9
0.85
0.8
0.75
Y, fracción mol de acetona en el vapor.

0.7
0.65
0.6
0.55
0.5
0.45
0.4
0.35
0.3
0.25
0.2
0.15
0.1
0.05
0
0 0.05 0.1 0.15 0.2 0.25 0.3 0.35 0.4 0.45
0.3

Y
0.25
0.2
0.15
0.1
0.05
0
0 0.05 0.1 0.15 0.2 0.25 0.3 0.35 0.4 0.45

X fracción mo
ACCIÓN MOL DE ACETONA EN EL EQUILIBRIO -H20

25 0.3 0.35 0.4 0.45 0.5 0.55 0.6 0.65 0.7 0.75 0.8 0.85 0.9 0.95 1 1.05
25 0.3 0.35 0.4 0.45 0.5 0.55 0.6 0.65 0.7 0.75 0.8 0.85 0.9 0.95 1 1.05

X fracción mol de acetona en el líquido

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