Context. Lightning has been suggested to play a role in triggering the occurrence of bio-ready chemical species. Future missions such as PLATO, ARIEL, HWO, and LIFE, as well as ground-based extremely large telescopes (ELTs), will carry out investigations of the atmospheres of potentially habitable exoplanets. Aims. We aim to study the effect of lightning on the atmospheric chemistry. We also consider how it affects false-positive and false-negative biosignatures and whether these effects would be observable on exo-Earth and TRAPPIST-1 planets. Methods. We utilised a combination of laboratory experiments and photochemical and radiative transfer modelling. We conducted spark discharge experiments in N2−CO2−H2 gas mixtures, representing a range of possible rocky-planet atmospheres. We investigated the production of potential lightning signatures (CO and NO), possible biosignature gases (N2O, NH3, and CH4), and important prebiotic precursors (HCN and urea). Using the measured CO and NO production rates, we conducted photochemical simulations for oxygen-rich and anoxic atmospheres for rocky planets orbiting in the habitable zones of the Sun and TRAPPIST-1 for a range of lightning flash rates. Synthetic spectra were calculated using SMART to study the atmosphere’s reflectance, along with the emission and transmission spectra. Results. Lightning enhances the spectral features of NO, NO2, and (in some cases) CO through direct production; whereas CH4 and C2H6 may be enhanced indirectly. Lightning at a flash rate slightly higher than on modern-day Earth is able to mask the ozone features of an oxygen-rich, biotic atmosphere, making it harder to detect the biosphere of such a planet. Similarly, lightning at a flash rate at least ten times higher than on modern-day Earth is also able to mask the presence of ozone in the anoxic, abiotic atmosphere of a planet orbiting a late M dwarf, reducing the potential for a false-positive life detection. Conclusions. The threshold lightning flash rates to eliminate oxygen (>0.1%) and ozone false positive biosignatures on planets orbiting ultra-cool dwarfs is up to ten times higher than the modern flash rate. This result indicates that lightning cannot always prevent these false-positive scenarios.

ABSTRACT We present ground-based optical transmission spectroscopy of the low-density hot Jupiter WASP-88b covering the wavelength range of 4413−8333  Å with the FOcal Reducer Spectrograph (FORS2) on the Very Large Telescope. The FORS2 white light curves exhibit a significant time-correlated noise that we model using a Gaussian process and remove as a wavelength-independent component from the spectroscopic light curves. We analyse complementary photometric observations from the Transiting Exoplanet Survey Satellite and refine the system properties and ephemeris. We find a featureless transmission spectrum with increased absorption towards shorter wavelengths. We perform an atmospheric retrieval analysis with the aura code, finding tentative evidence for haze in the upper atmospheric layers and a lower likelihood for a dense cloud deck. While our retrieval analysis results point towards clouds and hazes, further evidence is needed to definitively reject a clear-sky scenario.

Transmission spectroscopy has been a workhorse technique used over the past two decades to constrain the physical and chemical properties of exoplanet atmospheres1-5. One of its classical key assumptions is that the portion of the atmosphere it probes-the terminator region-is homogeneous. Several works from the past decade, however, have put this into question for highly irradiated, hot (Teq ≳ 1,000 K) gas giant exoplanets, both empirically6-10 and through three-dimensional modelling11-17. While models have predicted clear differences between the evening (day-to-night) and morning (night-to-day) terminators, direct morning and evening transmission spectra in a wide wavelength range have not been reported for an exoplanet so far. Under the assumption of precise and accurate orbital parameters for the exoplanet WASP-39 b, here we report the detection of inhomogeneous terminators on WASP-39 b, which has allowed us to retrieve its morning and evening transmission spectra in the near-infrared (2-5 μm) using the James Webb Space Telescope. We have observed larger transit depths in the evening, which are, on average, 405 ± 88 ppm larger than the morning ones, and also have qualitatively larger features than the morning spectrum. The spectra are best explained by models in which the evening terminator is hotter than the morning terminator by 17 7 - 57 + 65  K, with both terminators having C/O ratios consistent with solar. General circulation models predict temperature differences broadly consistent with the above value and point towards a cloudy morning terminator and a clearer evening terminator.