The site-selective formation of carbonrcarbon bonds through direct functionalizations of
otherwise unreactive carbonrhydrogen bonds constitutes an economically attractive strategy …

Fluorinated organic compounds increasingly gain importance in numerous areas of
chemistry and everyday life. Building blocks which contain fluorinated entities are of high …

Alkanes constitute the cheapest and most abundant feedstock for organic chemicals.
However, the redistribution of CsC and CsH bonds in hydrocarbons into more sophisticated …

The field of organometallic catalysis has attracted considerable interest from both academia
and industry due to its broad applications in synthetic transformations. Pd, Ni, Rh, and Ir …

Partially fluorinated alkanes, arenes, and alkenes can be transformed by a variety of
transition metal and lanthanide systems. Although the C–H bond is weaker than the C–F …

Understanding the mechanisms of chemical reactions, especially catalysis, has been an
important and active area of computational organic chemistry, and close collaborations …

Bindungsaktivierung in Aktion: Eine neuartige rutheniumkatalysierte oxidative Anellierung
von Alkinen durch die Spaltung von C‐H‐Bindungen eröffnet einen effizienten und breit …

In this Account, we describe the transition metal-mediated cleavage of C− F and C− H bonds
in fluoroaromatic and fluoroheteroaromatic molecules. The simplest reactions of …

Catalytic C–H functionalizations are increasingly viable tools for sustainable syntheses. In
recent years, inexpensive cobalt complexes were identified as powerful catalysts for C–H …

The activation of ubiquitous C–H bonds has great significance in the field of organic
synthesis given that it represents an ideal method for directly producing valuable chemicals …