Sphalerite-chalcopyrite (Golden Hawk Mine, Picher, Oklahoma, USA) 3

Sphalerite-chalcopyrite from Oklahoma, USA.

A mineral is a naturally-occurring, solid, inorganic, crystalline substance having a fairly definite chemical composition and having fairly definite physical properties. At its simplest, a mineral is a naturally-occurring solid chemical. Currently, there are over 6000 named and described minerals - about 200 of them are common and about 20 of them are very common. Mineral classification is based on anion chemistry. Major categories of minerals are: elements, sulfides, oxides, halides, carbonates, sulfates, phosphates, and silicates.

The sulfide minerals contain one or more sulfide anions (S-2). The sulfides are usually considered together with the arsenide minerals, the sulfarsenide minerals, and the telluride minerals. Many sulfides are economically significant, as they occur commonly in ores. The metals that combine with S-2 are mainly Fe, Cu, Ni, Ag, etc. Most sulfides have a metallic luster, are moderately soft, and are noticeably heavy for their size. These minerals will not form in the presence of free oxygen. Under an oxygen-rich atmosphere, sulfide minerals tend to chemically weather to various oxide and hydroxide minerals.

Sphalerite is a somewhat common zinc sulfide mineral (ZnS). It has a metallic to submetallic to resinous to adamantine luster. Many metals can substitute for the zinc, such as iron, cadmium, and manganese. Sphalerite almost always has some iron in it, so a better chemical formula would be (Zn,Fe)S. Sphalerite has a wide color range, depending principally on iron content. Pure to almost pure sphalerite is whitish to greenish. With increasing iron content, sphalerite becomes yellowish to brownish to blackish. One variety of sphalerite has a strikingly intense dark red color (ruby sphalerite). Its streak color also varies with iron content from whitish to pale yellowish to brownish. Sphalerite is also distinctive in being moderately heavy for its size and having six different planes of cleavage.

Sphalerite is the most important zinc ore mineral. Zinc produced from sphalerite is used for many purposes, including mixing with copper to produce brass, rust protection of iron & steel, and for making modern American pennies (although the cost of making each zinc penny is more than 1¢).

In this Oklahoma zinc ore specimen, the blackish material is the sphalerite. The brassy gold-colored specks are chalcopyrite (CuFeS2, copper iron sulfide). Miners give blackish-colored sphalerite the nickname "Black Jack". The sample comes from the Golden Hawk Mine in the Picher Field, which is part of the Tri-State Mining District of Missouri-Kansas-Oklahoma.

Locality: Golden Hawk Mine, Picher, Tri-State Mining District, northeastern Oklahoma, USA
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Locality info. at:
www.mindat.org/loc-195950.html
and
www.mindat.org/loc-12395.html
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Photo gallery of sphalerite:
www.mindat.org/gallery.php?min=3727

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Taken on: April 26, 2021

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Sets appears in: • Tri-State Mining District (Kansas-Oklahoma-Missouri, USA) • Oklahoma Rocks & Fossils more » • Minerals - Sulfides (Sphalerite) « less

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