9701 May June 2011 All Mark Schemes
9701 May June 2011 All Mark Schemes
9701 May June 2011 All Mark Schemes
com
UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
GCE Advanced Subsidiary Level and GCE Advanced Level
9701 CHEMISTRY
9701/11
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
Cambridge will not enter into discussions or correspondence in connection with these mark schemes.
Cambridge is publishing the mark schemes for the May/June 2011 question papers for most IGCSE,
GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
Page 2
www.maxpapers.com
Syllabus
9701
Question
Number
Key
Question
Number
Key
1
2
B
A
21
22
C
A
3
4
5
C
C
D
23
24
25
B
B
B
6
7
A
B
26
27
D
D
8
9
10
D
C
C
28
29
30
B
B
D
11
12
C
B
31
32
D
B
13
14
15
C
D
B
33
34
35
D
B
A
16
17
D
C
36
37
D
B
18
19
20
C
C
C
38
39
40
C
A
A
Paper
11
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UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
GCE Advanced Subsidiary Level and GCE Advanced Level
9701 CHEMISTRY
9701/12
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
Cambridge will not enter into discussions or correspondence in connection with these mark schemes.
Cambridge is publishing the mark schemes for the May/June 2011 question papers for most IGCSE,
GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
Page 2
www.maxpapers.com
Syllabus
9701
Question
Number
Key
Question
Number
Key
1
2
B
C
21
22
D
C
3
4
5
B
C
B
23
24
25
B
A
C
6
7
B
C
26
27
D
C
8
9
10
C
A
C
28
29
30
C
D
A
11
12
C
B
31
32
D
D
13
14
15
D
B
A
33
34
35
D
C
A
16
17
B
D
36
37
A
A
18
19
20
B
A
B
38
39
40
D
A
D
Paper
12
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UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
GCE Advanced Subsidiary Level and GCE Advanced Level
9701 CHEMISTRY
9701/13
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
Cambridge will not enter into discussions or correspondence in connection with these mark schemes.
Cambridge is publishing the mark schemes for the May/June 2011 question papers for most IGCSE,
GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
Page 2
www.maxpapers.com
Syllabus
9701
Question
Number
Key
Question
Number
Key
1
2
B
D
21
22
C
C
3
4
5
C
A
B
23
24
25
B
D
B
6
7
A
C
26
27
B
D
8
9
10
C
D
C
28
29
30
D
D
B
11
12
B
C
31
32
B
D
13
14
15
C
D
C
33
34
35
D
B
D
16
17
B
D
36
37
B
C
18
19
20
C
C
A
38
39
40
A
A
A
Paper
13
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UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
GCE Advanced Subsidiary Level and GCE Advanced Level
9701 CHEMISTRY
9701/21
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
Cambridge will not enter into discussions or correspondence in connection with these mark schemes.
Cambridge is publishing the mark schemes for the May/June 2011 question papers for most IGCSE,
GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
Page 2
1
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Syllabus
9701
(a) alkanes/paraffins
not hydrocarbon
Paper
21
(1)
[1]
(1)
[1]
(1)
(1)
(1)
= 275.3 t of CO2
(1)
[4]
(1)
(1)
[2]
(1)
(1)
[2]
[Total: 10]
Page 3
2
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Syllabus
9701
Paper
21
(1)
(1)
(1)
(1)
[4]
(1)
(1)
(1)
[1]
(1)
(1)
(1)
(1)
[6]
(1)
[1]
(1)
(1)
(1)
[3]
[Total: 15]
Page 4
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Syllabus
9701
Paper
21
3
dilute HCl
U(aq)
CaCl2
Ca(s)
H2O(l)
Na2CO3(aq)
(a)
U
V
W
X
Y
H2O(l)
X(s)
Ca(OH)2
dilute
H2SO4
Y(s)
CaCO3
roast in air
V (s)
CaO
dilute
HNO3
W(aq)
Ca(NO3)2
reaction 1
Z(s)
CaSO4
CaCl2
CaO
Ca(NO3)2
Ca(OH)2
CaCO3
(1)
(1)
(1)
(1)
(1)
[5]
(1)
[1]
(c) (i) Ca to U
Ca + 2HCl CaCl2 + H2
(1)
V to W
CaO + 2HNO3 Ca(NO3)2 + H2O
(1)
U to Y
CaCl2 + Na2CO3 CaCO3 + 2NaCl
(1)
(1)
[4]
(1)
[1]
Page 5
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Syllabus
9701
(e) (i) Ca to X
colourless gas formed/fizzing/effervescence/bubbles or
Ca dissolves or
white precipitate/suspension formed
(ii) strongly exothermic/vigorous reaction or
steam formed/steamy fumes or
surface crumbles
do not allow white ppt.
Paper
21
(1)
(1)
[2]
[Total: 13]
(1)
(1)
(1)
[3]
(1)
(1)
[2]
(1)
[1]
(CH3)2C
NH
NO2
H3C
C
H3C
[Total: 6]
Page 6
5
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Syllabus
9701
Paper
21
(1)
electrophilic
addition
elimination or dehydrohalogenation
(1)
(1)
(1)
(ii) reagent
NaOH/KOH/OH
conditions
in alcohol/ethanol
only allow conditions mark if reagent is correct
(1)
(1)
step 2
[5]
(1)
(1)
(1)
(1)
[1]
[4]
(1)
(1)
(1)
2(-394) -286
(1)
(1)
(1)
[6]
[Total: 16]
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UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
GCE Advanced Subsidiary Level and GCE Advanced Level
9701 CHEMISTRY
9701/22
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
Cambridge will not enter into discussions or correspondence in connection with these mark schemes.
Cambridge is publishing the mark schemes for the May/June 2011 question papers for most IGCSE,
GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
Page 2
(a) Kc =
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Syllabus
9701
[CH3CH2R][H20]
[CH3CH2H][ROH]
no units
Paper
22
(1)
(1)
(1)
(1)
(1)
(1)
(1)
(1)
[2]
[4]
(1)
[3]
(1)
[1]
(1)
(1)
[2]
[Total: 12]
Page 3
2
(a)
CH2=CH2 + HF
bonds
4 C-H
broken 1 C=C
/kJ mol 1 1 H-F
1640
610
562
2812
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Syllabus
9701
Paper
22
CH3CH2F
bonds
made
/kJ mol 1
5 C-H
2050
1 C-C
350
1 C-F
E
(2400 + E)
(1)
(1)
(1)
(1)
[4]
(1 + 1)
(c) in CCl2F2
C-Cl bond energy is 340 kJ mol 1 and is weaker than C-F or C-H bonds
C-Cl bond is broken by uvl or
Cl. free radicals are formed
[2]
(1)
(1)
[2]
(1)
[3]
(1)
[1]
(d) (i) the trapping of reflected heat from the Earth in the lower atmosphere
producing global warming
(ii) CO2/carbon dioxide
(e) octahedral
[Total: 12]
Page 4
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Syllabus
9701
Paper
22
3
Ba(s)
heat gently
R(s)
BaO
in oxygen
H2O(l)
S(aq)
BaCl2
dilute HCl
T(aq)
Ba(OH)2
Na2CO3(aq)
dilute H2SO4
U(s)
BaSO4
dilute HNO3
reaction 1
V(s)
BaCO3
(a) R
S
T
U
V
W
W(aq)
Ba(NO3)2
BaO
BaCl2
Ba(OH)2
BaSO4
BaCO3
Ba(NO3)2
(1)
(1)
(1)
(1)
(1)
(1)
(b) (i) T to W
Ba(OH)2 + 2HNO3 Ba(NO3)2 + 2H2O
heat on V
BaCO3 BaO + CO2
[6]
(1)
(1)
(ii) T to V
CO2
Ba(OH)2 + CO2 BaCO3 + H2O
(1)
(1)
[4]
(1)
[1]
Page 5
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Syllabus
9701
Paper
22
(1)
= 0.59 : 1.18
=1:2
gives BaO2
(1)
(ii) BaSO4
(1)
(1)
[4]
[Total: 15]
4
(a) (i)
Cl2(g)
brine
H2(g)
NaCl(aq)
diaphragm
steel cathode
titanium/graphite
anode
NaOH(aq)
(1)
(1)
(1)
(1)
[4]
(1)
(1)
[2]
(1)
[1]
[Total: 7]
Page 6
5
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Syllabus
9701
Paper
22
(a) CH2OCO(CH2)16CH3
CHOCO(CH2)16CH3
CH2OCO(CH2)16CH3
all three alcohol groups must be esterified
(b) dilute HCl or dilute H2SO4 or dilute mineral acid
or NaOH(aq) followed by dilute acid
(c)
[1]
(1)
[1]
(1)
[1]
CH3(CH2)7
C
C
(CH2)7CO2H
(d) (i) fatty acid that contains more than one C=C bond
(ii) hydrogen
nickel/Raney nickel/platinum/palladium
(e) (i) CH3(CH2)7CHO
OHC(CH2)7CX
(f)
(1)
(1)
(1)
(1)
[3]
(1)
(1)
(ii) 2,4-dinitrophenylhydrazine
yellow/orange/red precipitate
(1)
(1)
(1)
or
or
Fehlings/Benedict's solution
brick red ppt.
(1)
(i) two
(1)
(ii) ester
(1)
[6]
[2]
[Total: 14]
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UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
GCE Advanced Subsidiary Level and GCE Advanced Level
9701 CHEMISTRY
9701/23
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
Cambridge will not enter into discussions or correspondence in connection with these mark schemes.
Cambridge is publishing the mark schemes for the May/June 2011 question papers for most IGCSE,
GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
Page 2
1
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Syllabus
9701
Paper
23
Throughout this question, deduct one mark only for sig. fig. error.
(a) (i) the volume of solution A present in one typical ant is
7.5 x 10 6 x 1000 = 7.5 x 10 3 cm3
(1)
(1)
(1)
[3]
(1)
(1)
(1)
[3]
(1)
(1)
(1)
[3]
[Total: 9]
Page 3
2
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Syllabus
9701
(a) there are no inter-molecular forces present between ideal gas molecules
ideal gas molecules have no volume
collisions between ideal gas molecules are perfectly elastic
ideal gas molecules behave as rigid spheres
Paper
23
(any 2)
[2]
(1)
(1)
[2]
(1)
(1)
(1)
[3]
(1)
(1)
[2]
(e) 18
(1)
[1]
(f)
(1)
(1)
[2]
[Total: 12]
Page 4
3
(a)
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Syllabus
9701
Paper
23
atomic
radius of
element
Na
Mg
Al
Si
Cl
(1)
(1)
(1)
[3]
(1)
(1)
(1)
(1)
[4]
(b)
melting
point of
element
Na
Mg
Al
Si
Cl
Page 5
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Syllabus
9701
Paper
23
(c)
electrical
conductivity
of element
Na
Mg
Al
Si
Cl
ionic
covalent
van der Waals forces/induced dipoles
(1)
(1)
(1)
(1)
[4]
(1)
(1)
(1)
(1)
[4]
[Total: 15]
Page 6
4
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Syllabus
9701
Paper
23
(a) C9H16O2
(1)
(1)
(1)
(1)
(ii) Br2/bromine
decolourised
allow
KMnO4/H+
decolourised
(1)
(1)
[1]
[5]
(1)
(1)
(ii) CH3(CH2)4CH(Cl)CH=CHCHO
(1)
(iii) CH3(CH2)4CH(OH)CH=CHCH2OH
(1)
[4]
[Total: 10]
Page 7
5
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Syllabus
9701
Paper
23
(1)
(ii) one
(1)
[2]
(1)
(1)
(1)
(1)
(1)
(1)
[6]
(1)
(1)
(1)
[3]
(1)
(1)
(1)
[3]
(c) none
alcohol is tertiary
cannot be oxidised
(d)
C*
H
H
O
C
O
C
H
H
correct structure
fully displayed
CO2C2H5 group (allow ecf on wrong esters)
correct chiral C atom (allow ecf on wrong esters)
[Total: 14]
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UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
GCE Advanced Subsidiary Level and GCE Advanced Level
9701 CHEMISTRY
9701/31
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
Cambridge will not enter into discussions or correspondence in connection with these mark schemes.
Cambridge is publishing the mark schemes for the May/June 2011 question papers for most IGCSE,
GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
Page 2
www.maxpapers.com
Syllabus
9701
Paper
31
Question
Sections
Indicative material
Mark
PDO Layout
MMO
Collection
II
PDO
Recording
III
IV
(a)
V, VI and VII
Award V, VI and VII for a difference from Supervisor
within 0.20 cm3
Award V and VI for a difference of > 0.20 0.40 cm3
Award V for a difference of > 0.40 0.60 cm3
If the best titres are 0.60 cm3 apart cancel one of
the Q marks.
[7]
Page 3
(b)
ACE
Interpretation
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Syllabus
9701
Paper
31
ACE
Interpretation
PDO Display
[1]
1
1
[4]
[Total: 12]
Page 4
(a)
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Syllabus
9701
Paper
31
MMO Collection
PDO Recording
II
ACE
Interpretation
PDO Display
[5]
[2]
Page 5
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Syllabus
9701
Paper
31
Examiner to calculate 20% and 40% of supervisors T and convert to nearest 0.5oC.
(b)
(c)
ACE
Interpretation
MMO Quality
1
[3]
ACE
Interpretation
PDO Display
ACE
Conclusions
ACE
Improvements
[3]
[1]
[Total: 14]
Page 6
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Syllabus
9701
Paper
31
FA 7 is Zn(NO3)2(s); FA 8 is CuSO4(s)
3
(iii) ACE
Conclusions
(iv) MMO
Decisions
MMO
Collection
(v) MMO
Decisions
ACE
Conclusions
(b) (i)
MMO
Collection
[9]
(ii) ACE
Conclusions
1
[5]
[Total: 14]
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UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
GCE Advanced Subsidiary Level and GCE Advanced Level
9701 CHEMISTRY
9701/32
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
Cambridge will not enter into discussions or correspondence in connection with these mark schemes.
Cambridge is publishing the mark schemes for the May/June 2011 question papers for most IGCSE,
GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
Page 2
www.maxpapers.com
Syllabus
9701
Paper
32
Question
Sections
Indicative material
Mark
PDO Layout
MMO
Collection
II
PDO
Recording
III
MMO
Decisions
(a)
Supervisor mass
to 2 decimal places
candidate mass
Calculate difference in Supervisor and candidate scaled values and award quality
marks as below.
MMO Quality
V, VI and VII
Award V, VI and VII if 0.25 cm3
[7]
Page 3
(b)
ACE
Interpretation
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Syllabus
9701
Paper
32
ACE
Interpretation
[1]
1
(d)
ACE
Interpretation
1
[6]
1
[1]
[Total: 15]
Page 4
(a)
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Syllabus
9701
PDO Layout
PDO Recording
II
2
[5]
1
II
(ii)
(iii)
ACE
Conclusions
(c)
Paper
32
ACE
Improvements
[4]
[1]
[Total: 10]
Page 5
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Syllabus
9701
Paper
32
MMO
Collection
II
[4]
II
[4]
Page 6
(b) (i)
MMO
Collection
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Syllabus
9701
Paper
32
(ii)
(iii)
(+)2 to (+)3.
ACE
Conclusions
[5]
[2]
[Total: 15]
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UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
GCE Advanced Subsidiary Level and GCE Advanced Level
9701 CHEMISTRY
9701/33
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
Cambridge will not enter into discussions or correspondence in connection with these mark schemes.
Cambridge is publishing the mark schemes for the May/June 2011 question papers for most IGCSE,
GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
Page 2
www.maxpapers.com
Syllabus
9701
Paper
33
Question
Sections
Indicative material
Mark
PDO Layout
PDO
Recording
II
PDO
Recording
III
MMO Decision
IV
(a)
Examiner rounds any burette readings to the nearest 0.05 cm3, checks subtractions
and then selects the best titre using the hierarchy:
two identical; titres within 0.05 cm3; titres within 0.1 cm3; etc
to calculate mean (ignore any labelled rough).
Examiner compares [corrected mean titre/corrected mass of FA 1] with Supervisor
result. Calculate the ratios to 2 dp.
MMO Quality
1
1
1
[7]
Page 3
(b)
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9701
Paper
33
MMO Decision
PDO Display
ACE
Interpretation
PDO Display
(d)
ACE
Interpretation
[2]
II
ans to (i) 5
and
ans to (ii) 10
with no additional steps
III
IV
(i)
[5]
1
[2]
[Total: 16]
Page 4
(a)
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Syllabus
9701
Paper
33
PDO Display
PDO Recording
II
MMO Decision
(c)
ACE
Interpretation
ACE
Improvements
1
1
[5]
[2]
[1]
[Total: 8]
Page 5
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Syllabus
9701
Paper
33
(a)
(b)
MMO
Collection
MMO
Decisions
PDO Layout
MMO
Collection
FA 6 cation: ammonium/NH4+
from some evidence and no CON obs
FA 6 anion: bromide/Br
No ecf but can award Br from any mention of cream
but ppt must be present or off-white ppt insoluble or
partially soluble in NH3.
Fizzing/effervescence/bubbling (occurs)
(not gas is produced)
If limewater test used here give second mark in (a).
ACE
Conclusion
(c)
MMO
Collection
ACE
Conclusion
(d)
MMO
Collection
[2]
[6]
[3]
[2]
Page 6
(e)
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9701
Paper
33
MMO Decision
ACE
Conclusion
FA 7 anion: sulfate/SO42
Allow from minimum evidence of white ppt with
Ba2+(aq)
1
[3]
[Total: 16]
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UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
GCE Advanced Subsidiary Level and GCE Advanced Level
9701 CHEMISTRY
9701/34
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
Cambridge will not enter into discussions or correspondence in connection with these mark schemes.
Cambridge is publishing the mark schemes for the May/June 2011 question papers for most IGCSE,
GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
Page 2
Question
1
(a)
www.maxpapers.com
Syllabus
9701
Indicative material
Paper
34
Mark
PDO Layout
MMO Collection
II
PDO Recording
III
MMO Decisions
Page 3
Question
MMO Quality
(c)
ACE
Interpretation
ACE
Interpretation
0.60 cm3
[7]
1
III
IV
V
(iii)
(iv)
(v)
(vi)
ACE
Interpretation
1
1
1
(i)
(ii)
(d)
Paper
34
Mark
V, VI and VII
Award V, VI and VII for a difference from Supervisor
within 0.20 cm3
Award V and VI only for 0.20 < 0.40 cm3
Award V only for 0.4 < 0.6 cm3
II
PDO Display
Syllabus
9701
Indicative material
www.maxpapers.com
[1]
1
1
1
1
1
[6]
1
[1]
[Total: 15]
Page 4
Question
2
(a)
PDO Recording
Syllabus
9701
Indicative material
I
II
MMO Decisions
www.maxpapers.com
III
Paper
34
Mark
1
1
or
between 3035 and 1015 with corresponding
volumes of water.
Examiner corrects any fractional times to the nearest second for 45 cm3 and 20 cm3 of
FB 6 and calculates t20/t45 to 2 dp
MMO Quality
(b)
(c)
(d)
(e)
ACE Conclusions
ACE Conclusions
ACE Interpretation
ACE Improvements
1
1
[5]
[1]
[1]
[1]
[1]
[Total: 9]
Page 5
Question
www.maxpapers.com
Syllabus
9701
Indicative material
Paper
34
Mark
(a)
PDO Layout
MMO Decisions
MMO Collection
(b)
ACE Conclusions
1
1
1
1
[5]
1
1
1
[3]
Page 6
Question
(c)
(d)
MMO Collection
ACE Conclusions
www.maxpapers.com
Syllabus
9701
Paper
34
Indicative material
Mark
1
1
1
1
[5]
1
1
[3]
[Total: 16]
www.maxpapers.com
UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
GCE Advanced Subsidiary Level and GCE Advanced Level
9701 CHEMISTRY
9701/35
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
Cambridge will not enter into discussions or correspondence in connection with these mark schemes.
Cambridge is publishing the mark schemes for the May/June 2011 question papers for most IGCSE,
GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
Page 2
Question
1
(a)
www.maxpapers.com
Syllabus
9701
Indicative material
Paper
35
Mark
PDO layout
MMO collection
II
MMO decisions
III
PDO recording
Examiner to check and correct (if necessary) subtractions in the titre table.
Examiner then selects the best titre using the hierarchy:
two identical; titres within 0.05 cm3, titres within 0.10 cm3, etc., (ignore rough titre)
For candidates and Supervisor scale titre for 45.00 cm3 FA 2 diluted.
Calculate titre 45.00/volume of FA 2 diluted to 2 dp
Calculate difference in Supervisor and candidate scaled values and award quality
marks as below.
MMO quality
0.60 cm3
1
1
1
[7]
Page 3
(b)
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Syllabus
9701
Paper
35
1
ACE interpretation
II
Correctly uses
titre from (b)
/1000 ans to (i) in (ii)
and ans to (ii) in (iii)
III
IV Uses (38.10
PDO display
(d)
ACE interpretation
[1]
ans to (iv))
1
1
Correctly evaluates:
/25 100 or 0.24 %
and
0.10
/titre in (b) 100
Answers must be given to at least 2 significant
figures and correctly rounded for the significant
figures shown.
0.06
[6]
[1]
[Total: 15]
Page 4
(a)
www.maxpapers.com
Syllabus
9701
PDO layout
PDO recording
II
III
(c)
(d)
(e)
Paper
35
1
[4]
Examiner to calculate (corrected) T1/m1 and T2/m2 for Supervisor and candidate.
Compare candidate value with the same value from the Supervisor report.
Award Q marks on the closer value.
1
MMO
quality
MMO collection
PDO layout
II
ACE interpretation
ACE
improvements
0.10 Cg
0.30 Cg
1
1
[2]
[2]
[1]
[1]
[Total: 10]
Page 5
www.maxpapers.com
Syllabus
9701
Paper
35
(a)
(b)
(c)
MMO decisions
MMO collection
MMO decisions
MMO collection
II
III
ACE conclusion
[2]
[3]
1
[1]
Page 6
(d)
(e)
(f)
www.maxpapers.com
Syllabus
9701
Paper
35
PDO recording
MMO collection
II
III
II
II
ACE conclusion
MMO collection
ACE conclusion
[3]
[2]
[4]
[Total: 15]
www.maxpapers.com
UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
GCE Advanced Level
9701 CHEMISTRY
9701/41
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
Cambridge will not enter into discussions or correspondence in connection with these mark schemes.
Cambridge is publishing the mark schemes for the May/June 2011 question papers for most IGCSE,
GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
Page 2
1
Syllabus
9701
www.maxpapers.com
Paper
41
[1]
[1]
(ii) advantage:
[1]
[1]
(ii) amide
[1]
[1]
[1]
[Total: 12]
Page 3
2
www.maxpapers.com
Syllabus
9701
Paper
41
[1]
(ii) both forward & reverse reactions are going on at the same time, but the concentrations
of all species do not change (owtte)
or rate of forward = rate of backward reaction
[1]
(b) (i) Kc = [H+][OH ]/[H2O]
[1]
(ii) Kw = [H+][OH ]
rearrangement of equation in (i) gives Kc[H2O] = [H+][OH ] & Kw = Kc[H2O] (owtte)
or the [H2O] is contained within Kw
[1]
[1]
14
)/ 5 10
= 2 1013
[1]
(correct ans = [2]) ecf [1]
14
)/ 9.49 10
[1]
[1]
(correct ans = [2]) [1]
= 1.05 1011(mol dm 3)
(iv) pH = 11.0
ecf [1]
ecf [1]
[Total: 12 max 11]
[1]
[1]
[1]
[1]
[1]
[1]
[1]
(ii)
Cl
Cl
P
Cl
[1]
P
Cl
[1]
ecf from structure in (ii) [1]
[Total: 10]
University of Cambridge International Examinations 2011
Page 4
4
www.maxpapers.com
Syllabus
9701
Paper
41
[1]
(b) (i) catalytic converter and passing the exhaust gases over a catalyst/Pt/Rh
[1]
[1]
(c) No, it wouldnt be reduced. Because the reaction in (a) does not presuppose a particular fuel
(owtte)
[1]
Allow formed from N2 and O2 in air during combustion
(d) (i) SO3 produces acid rain
[1]
(ii) NO + O2 NO2
[1]
[1]
[1]
[1]
[1]
[1]
[Total: 11]
(a)
transformation
reagent + conditions
C2H4 C2H5Cl
C2H5OH C2H5Cl
C2H6 C2H5Cl
Cl2 + light
C2H4 C2H4Cl2
CH3CO2H CH3COCl
H 3C
H 3C
CH3
Cl
CH2Cl
Cl2 + AlCl3
Cl2 + light or heat
[6]
Page 5
Syllabus
9701
NO2
www.maxpapers.com
Paper
41
[1]
NO2
curly arrow from ring to NO2+ and from C-H bond to ring
correct intermediate, including charge in the right place
Note charge area must be more than half ring
[1]
[1]
(ii) C is C6H5CO2H
[1]
[1]
[1]
(If C is given as 3-bromotoluene, then allow the last [2] marks if steps 1 and 2 are
reversed.)
[Total: 12]
6
[1]
[1]
[1]
(iv)
compound
result
CH3OH
CH3CH2OH
CH3CHO
CH3CO2H
CHO
COCH3
[3]
Page 6
www.maxpapers.com
Syllabus
9701
Paper
41
CHO
CO2H
O
CO2H )
for D allow
CHO
(D + E + F): 3 [1]
(c) (allow displayed, skeletal and structural formulae)
Must be consistent with F
OH
G
allow for G
CO2H
CO2H
CO2H
CO2H
H
(only allow mark for H
if G is the 3-OH acid)
CO2H
OH
(G + H + J + K): 4 [1]
[1]
[Total: 14]
Page 7
7
www.maxpapers.com
Syllabus
9701
Paper
41
Enzyme + substrate
Enzyme-substrate complex
Enzyme + products
3 [1]
(c) a competitive inhibitor combines with the enzymes active site (so preventing the substrate
from binding)
[1]
non-competitive inhibitor bonds with the enzyme away from the active site/at an allosteric site
[1]
this changes the shape of the active site
[1]
Line must be of similar shape to original but level out below original line
[1]
(ii) Inhibitor reduces the number of enzymes with working active sites (owtte)
[1]
[Total: 10]
Page 8
8
www.maxpapers.com
Syllabus
9701
Paper
41
(a) partition separation due to the different solubilities of compounds in two solvents/phases
[1]
adsorption separation due to the different attractions between the compounds and the
stationary phase, relative to their solubility in the solvent
[1]
Note, if candidates do not refer to different solubilities and different attractions
max 1
(b)
X - sample
Ring:
A + B:
[1]
[1]
M
100 9
M + 1 1.1 n
Hence n
100
0.3
100 0.3
1.1 9
[1]
1.1 n
3.03
p = 3
(answer + working) [1]
(If the mass peak is at 122 and the compound contains Br and 3 C atoms then
Q = (122 79 36)) thus Q = 7
ecf from (ii) [1]
(The compound is C3H7Br)
(iii) (R is at m/e 43), hence C3H7+
(d) Any two from H2, H2O, CO, C2H4, C2H2, CH4
[1]
2 [1]
[Total: 10]
Page 9
9
www.maxpapers.com
Syllabus
9701
Paper
41
[1]
[1]
2 [1]
[1]
(ii)
O
O
CH2
CH2 O
[1]
[1]
[1]
(d) Monomers in Terylene have to alternate in order to condense out water (owtte)
[1]
Alkenes can link in any order (and still form a polyalkene) (or diagram showing this)
[1]
[Total: 10]
www.maxpapers.com
UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
GCE Advanced Level
9701 CHEMISTRY
9701/42
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
Cambridge will not enter into discussions or correspondence in connection with these mark schemes.
Cambridge is publishing the mark schemes for the May/June 2011 question papers for most IGCSE,
GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
Page 2
1
www.maxpapers.com
Syllabus
9701
Paper
42
[1]
[1]
[2]
acid-base/proton transfer/neutralisation/exothermic/reversible/
[1]
(ii)
H
H
[1]
[1]
[1]
3 x [1]
[1]
[1]
[1]
[1]
[1]
(iii) deep blue colour would change to light blue [NOT intensity of colour decreases]
hexaquocopper(II) ion or [Cu(H2O)6]2+ or [Cu(H2O)n(NH3)a n]2+, where a = 4 or 6
or ligand exchange (of NH3) by H2O
[1]
[1]
[4]
[1]
[1]
[1]
(Allow n=1 up to n=6. Also allow [CuCln]2 n as product. Examples from many possible are:
[Cu(H2O)6]2+ + 2Cl [Cu(H2O)4Cl2] + 2H2O
[Cu(H2O)6]2+ + 4Cl [CuCl4]2 + 6H2O
equation could include HCl on the LHS, for example:
[3]
[Cu(H2O)6]2+ + 4HCl H2CuCl4 + 2H+ + 6H2O or CuCl42 + 4H+ + 6H2O
[Total: 18 max 17]
Page 3
Syllabus
9701
Paper
42
(a) (i)
high
e ectr ca conduct v ty
high
medium
me t ng po nt
www.maxpapers.com
low
Si
Ge
Sn
Pb
medium
or
low
Si
Ge
Sn
Pb
[2] + [2]
(ii) m. pt. trend: (from) giant/macro molecular/covalent to metallic bonding
(or implied from at least two specific examples, e.g. diamond and tin)
(mention of simple covalent anywhere negates this mark)
[1]
[1]
[1]
[1]
[1]
[1]
[1]
[1]
[1]
[1]
or SnCl2(aq) will turn Cu2+(aq) from blue to colourless or give a pink/brown/coppercoloured ppt.
[1]
Sn2+ + Cu2+ Sn4+ + Cu
[1]
Other possible oxidants (Eo must be > +0.2V) include: S2O82 , H2O2, Cl2, Br2, I2 and Ag+.
No observations with the first three of these, but this should be stated explicitly, e.g. no
colour change.
[5]
[Total: 11 max 10]
Page 4
3
www.maxpapers.com
Syllabus
9701
(a) L = F/e or F = Le
Paper
42
[1]
[1]
(b) (i)
+
P .S .
a no d e
c a tho d e
C uS O 4 (a q )
to represent
[1]
[1]
[1]
[1]
[1]
ecf [1]
[1]
ecf [1]
(values in italics are if candidate has used Ar = 64, not 63.5. No last mark if not 3 s.f.:
correct ans = [5])
[9]
(c)
compound
product at anode
product at cathode
AgF
O2
Ag
FeSO4
O2
H2
MgBr2
Br2
H2
6 correct [5]
5 correct [4] etc.
Names can be used instead of symbols. If the atomic symbol (e.g. Br or H or O) is used
instead of the molecular formula (e.g. Br2 etc.) then deduct [1] mark only for the whole table.
[5]
[Total: 15]
University of Cambridge International Examinations 2011
Page 5
4
www.maxpapers.com
Syllabus
9701
Paper
42
OCOCH3
chain
repeat unit
[1]
[1]
[1]
[1]
ecf [1]
ecf [1]
[6]
O
O
[1]
(ii) ester
[1]
[1]
[1]
(v) they have the same molecular formula or C4H6O2 (do NOT allow empirical formula) or
same no. and type of atoms or same functional group or both are esters or they are
isomers
[1]
[5]
Page 6
www.maxpapers.com
Syllabus
9701
Paper
42
[1]
(ii)
CO2H
CO2H
(letters may be reversed)(allow ecf from E, also allow ecf for G from F)
cis-trans or geometrical isomerism
[1] + [1]
[1]
[4]
[Total: 15]
Page 7
5
www.maxpapers.com
Syllabus
9701
Paper
42
OH
ONa
+ Na
OH
ONa
nothing special
+ NaOH
OH
[1]
H2
H2O
[1]
nothing special
NO REACTION
+ CH3CO2H
must be (aq)
OH
[1]
OH
[1]
Br
Br
[1]
+ Br2
Br
[5]
(c) H is
OH
NO2
[1]
[1]
[1]
[1]
[4]
[Total: 13]
Page 8
6
www.maxpapers.com
Syllabus
9701
Paper
42
[1]
[1]
[1]
trypsin
amylase
activity
10
pH
[1]
[1]
[1]
[3]
[Total: 10]
Page 9
7
www.maxpapers.com
Syllabus
9701
Paper
42
(a)
Number
Process
Correct sequence
(numbers)
Extract DNA
mark as follows:
[1] mark
[1] mark
[1] mark
[3]
[1]
(ii) Phosphate groups are present in DNA or it makes the DNA fragments/bands etc. visible
or locates their position or identifies them on a photographic plate etc.
[1]
(NOT because its radioactive or makes the bands coloured)
[2]
(c) (i) Yes, all 4 children share one/some band (or match/gene/fragment/part/DNA/
amino acid) with the mothers (DNA) (NOT the general statement matches the
mothers DNA)
[1]
(ii) Child 2, since he/she shares none of the bands of fathers DNA/fingerprint or their
fingerprint/DNA does not match the fathers DNA (the general match is OK here)
[1]
[2]
(d) (i) Compare DNA fingerprint for each fragment (can be read into use of the word
same below)
Match the DNA patterns to determine which came from which skin
[1]
[1]
(ii) A named example of biological origin (N.B. a material, not a whole organism)
[1]
e.g. leather (= bull skin), pollen, fish scales, leaves, seeds, feathers, hair, blood, textiles
(or a named one like wool or silk or cotton or linen/flax), wood.
(N.B. NOT human or goat skin, also not metal, pottery or stone. If more than one
material is given, mark the first one)
[3]
[Total: 10]
Page 10
8
www.maxpapers.com
Syllabus
9701
Paper
42
[1]
[1]
[2]
(b) Forms of the same element (or of carbon, since carbon is the context of the question)
[1]
with different structures/arrangements of atoms
[1]
allow different molecular structure, but not structural formula. Any mention of compound
negates the mark.
[2]
(c) Nanoparticles are smaller than (animal) cells or they can pass through the cell membrane
or pass into/between cells
[1]
Drugs can be bound to/enclosed by the nanoparticle
[1]
[2]
(d) (i) Reduction/redox
[1]
63.5 100
= 34.6%
183.5
(if Ar(Cu) = 64 is used, ans = 34.8%. allow 3435%)
Hence percentage of copper present =
[1]
(iii) If the ore contains 2% of chalcopyrite by mass, calculate how much copper is produced
from each tonne of ore.
1 tonne = 1000 kg
1 tonne of chalcopyrite would produce 346 kg of copper
1 tonne of 2 % ore would produce 346 0.02 or 6.9 kg of copper ecf from (d)(ii)
[1]
(accept 7.0 or 7 kg)
answer may be given as 7000 g or 7 10 3 tonnes. If no units are given, assume they
are tonnes, and mark accordingly)
(iv) By displacement with a metal (the following specified metals higher than Cu in the ECS
may be used: Fe, Zn, Sn, Pb, Al, Mg. (NOT Ca, Li, Na. K etc.) or with a suitable nonmetallic reducing agent, e.g. SO2 or Sn2+, but not something that wouldnt react, like H2
or By electrolysis (with carefully controlled voltage)
[1]
[4]
[Total: 10]
www.maxpapers.com
UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
GCE Advanced Level
9701 CHEMISTRY
9701/43
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
Cambridge will not enter into discussions or correspondence in connection with these mark schemes.
Cambridge is publishing the mark schemes for the May/June 2011 question papers for most IGCSE,
GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
Page 2
1
www.maxpapers.com
Syllabus
9701
Paper
43
[1]
[1]
[2]
acid-base/proton transfer/neutralisation/exothermic/reversible/
[1]
(ii)
H
H
[1]
[1]
[1]
3 x [1]
[1]
[1]
[1]
[1]
[1]
(iii) deep blue colour would change to light blue [NOT intensity of colour decreases]
hexaquocopper(II) ion or [Cu(H2O)6]2+ or [Cu(H2O)n(NH3)a n]2+, where a = 4 or 6
or ligand exchange (of NH3) by H2O
[1]
[1]
[4]
[1]
[1]
[1]
(Allow n=1 up to n=6. Also allow [CuCln]2 n as product. Examples from many possible are:
[Cu(H2O)6]2+ + 2Cl [Cu(H2O)4Cl2] + 2H2O
[Cu(H2O)6]2+ + 4Cl [CuCl4]2 + 6H2O
equation could include HCl on the LHS, for example:
[3]
[Cu(H2O)6]2+ + 4HCl H2CuCl4 + 2H+ + 6H2O or CuCl42 + 4H+ + 6H2O
[Total: 18 max 17]
Page 3
Syllabus
9701
Paper
43
(a) (i)
high
e ectr ca conduct v ty
high
medium
me t ng po nt
www.maxpapers.com
low
Si
Ge
Sn
Pb
medium
or
low
Si
Ge
Sn
Pb
[2] + [2]
(ii) m. pt. trend: (from) giant/macro molecular/covalent to metallic bonding
(or implied from at least two specific examples, e.g. diamond and tin)
(mention of simple covalent anywhere negates this mark)
[1]
[1]
[1]
[1]
[1]
[1]
[1]
[1]
[1]
[1]
or SnCl2(aq) will turn Cu2+(aq) from blue to colourless or give a pink/brown/coppercoloured ppt.
[1]
Sn2+ + Cu2+ Sn4+ + Cu
[1]
Other possible oxidants (Eo must be > +0.2V) include: S2O82 , H2O2, Cl2, Br2, I2 and Ag+.
No observations with the first three of these, but this should be stated explicitly, e.g. no
colour change.
[5]
[Total: 11 max 10]
Page 4
3
www.maxpapers.com
Syllabus
9701
(a) L = F/e or F = Le
Paper
43
[1]
[1]
(b) (i)
+
P .S .
a no d e
c a tho d e
C uS O 4 (a q )
to represent
[1]
[1]
[1]
[1]
[1]
ecf [1]
[1]
ecf [1]
(values in italics are if candidate has used Ar = 64, not 63.5. No last mark if not 3 s.f.:
correct ans = [5])
[9]
(c)
compound
product at anode
product at cathode
AgF
O2
Ag
FeSO4
O2
H2
MgBr2
Br2
H2
6 correct [5]
5 correct [4] etc.
Names can be used instead of symbols. If the atomic symbol (e.g. Br or H or O) is used
instead of the molecular formula (e.g. Br2 etc.) then deduct [1] mark only for the whole table.
[5]
[Total: 15]
University of Cambridge International Examinations 2011
Page 5
4
www.maxpapers.com
Syllabus
9701
Paper
43
OCOCH3
chain
repeat unit
[1]
[1]
[1]
[1]
ecf [1]
ecf [1]
[6]
O
O
[1]
(ii) ester
[1]
[1]
[1]
(v) they have the same molecular formula or C4H6O2 (do NOT allow empirical formula) or
same no. and type of atoms or same functional group or both are esters or they are
isomers
[1]
[5]
Page 6
www.maxpapers.com
Syllabus
9701
Paper
43
[1]
(ii)
CO2H
CO2H
(letters may be reversed)(allow ecf from E, also allow ecf for G from F)
cis-trans or geometrical isomerism
[1] + [1]
[1]
[4]
[Total: 15]
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9701
Paper
43
OH
ONa
+ Na
OH
ONa
nothing special
+ NaOH
OH
[1]
H2
H2O
[1]
nothing special
NO REACTION
+ CH3CO2H
must be (aq)
OH
[1]
OH
[1]
Br
Br
[1]
+ Br2
Br
[5]
(c) H is
OH
NO2
[1]
[1]
[1]
[1]
[4]
[Total: 13]
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9701
Paper
43
[1]
[1]
[1]
trypsin
amylase
activity
10
pH
[1]
[1]
[1]
[3]
[Total: 10]
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9701
Paper
43
(a)
Number
Process
Correct sequence
(numbers)
Extract DNA
mark as follows:
[1] mark
[1] mark
[1] mark
[3]
[1]
(ii) Phosphate groups are present in DNA or it makes the DNA fragments/bands etc. visible
or locates their position or identifies them on a photographic plate etc.
[1]
(NOT because its radioactive or makes the bands coloured)
[2]
(c) (i) Yes, all 4 children share one/some band (or match/gene/fragment/part/DNA/
amino acid) with the mothers (DNA) (NOT the general statement matches the
mothers DNA)
[1]
(ii) Child 2, since he/she shares none of the bands of fathers DNA/fingerprint or their
fingerprint/DNA does not match the fathers DNA (the general match is OK here)
[1]
[2]
(d) (i) Compare DNA fingerprint for each fragment (can be read into use of the word
same below)
Match the DNA patterns to determine which came from which skin
[1]
[1]
(ii) A named example of biological origin (N.B. a material, not a whole organism)
[1]
e.g. leather (= bull skin), pollen, fish scales, leaves, seeds, feathers, hair, blood, textiles
(or a named one like wool or silk or cotton or linen/flax), wood.
(N.B. NOT human or goat skin, also not metal, pottery or stone. If more than one
material is given, mark the first one)
[3]
[Total: 10]
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9701
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43
[1]
[1]
[2]
(b) Forms of the same element (or of carbon, since carbon is the context of the question)
[1]
with different structures/arrangements of atoms
[1]
allow different molecular structure, but not structural formula. Any mention of compound
negates the mark.
[2]
(c) Nanoparticles are smaller than (animal) cells or they can pass through the cell membrane
or pass into/between cells
[1]
Drugs can be bound to/enclosed by the nanoparticle
[1]
[2]
(d) (i) Reduction/redox
[1]
63.5 100
= 34.6%
183.5
(if Ar(Cu) = 64 is used, ans = 34.8%. allow 3435%)
Hence percentage of copper present =
[1]
(iii) If the ore contains 2% of chalcopyrite by mass, calculate how much copper is produced
from each tonne of ore.
1 tonne = 1000 kg
1 tonne of chalcopyrite would produce 346 kg of copper
1 tonne of 2 % ore would produce 346 0.02 or 6.9 kg of copper ecf from (d)(ii)
[1]
(accept 7.0 or 7 kg)
answer may be given as 7000 g or 7 10 3 tonnes. If no units are given, assume they
are tonnes, and mark accordingly)
(iv) By displacement with a metal (the following specified metals higher than Cu in the ECS
may be used: Fe, Zn, Sn, Pb, Al, Mg. (NOT Ca, Li, Na. K etc.) or with a suitable nonmetallic reducing agent, e.g. SO2 or Sn2+, but not something that wouldnt react, like H2
or By electrolysis (with carefully controlled voltage)
[1]
[4]
[Total: 10]
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UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
GCE Advanced Level
9701 CHEMISTRY
9701/51
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
Cambridge will not enter into discussions or correspondence in connection with these mark schemes.
Cambridge is publishing the mark schemes for the May/June 2011 question papers for most IGCSE,
GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
Page 2
Question
1
(a)
Sections
PLAN
Problem
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Syllabus
9701
Paper
51
Indicative material
Mark
[1]
[1]
Any graph showing a decreasing rate (not time) with Mr (bar chart
or any line). Axes must be labelled (accept group II carbonate).
Ignore units.
[1]
PLAN
Problem
(i)
(d)
PLAN
Methods
PLAN
Methods
(i)
[1]
(ii)
[1]
(i)
[1]
(ii)
[1]
[1]
(e)
[1]
[1]
[1]
[1]
[1]
Page 3
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Syllabus
9701
Paper
51
(f)
PLAN
Methods
[2]
(g)
ACE
Evaluation
[1]
Total
[16]
Page 4
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Syllabus
9701
Paper
51
Question
Sections
Indicative material
Mark
(a)
ACE
Data
Both Mrs calculated correctly 85, 69, ignore units. May be seen
in table.
[1]
(b)
ACE
Data
[1]
All data correct and to 2 sig figs ECF incorrect Mr. Allow 2
arithmetic or sig fig errors. No ECF of incorrect formula.
[1]
(d)
ACE
Data
ACE
Evaluation
[1]
[1]
[1]
Give one mark if the two anomalous points furthest from the line
(one on each side) are identified. Allow only one anomaly if there
is only one or all the anomalies are on the same side. Allow extra
anomalies due to misplotting. For credit, the anomalies must
include the most anomalous. In plotting the points, it is possible
that some points will be a little way from the correctly drawn line.
These in many cases are likely not to be ringed. Examiner
judgement will be required in determining whether or not a point
should be ringed. If 5 or more points are ringed do not award
this mark but allow any subsequent correct discussion.
[1]
[1]
[1]
One mark for two correct reasons not related to the points.
(e)
(f)
ACE
Data
Construction lines on graph. If line into origin and 0,0 used only
1 line necessary.
[1]
ACE
Conclusions
[1]
[1]
For stating that the slope supports the equation. ECF applies
from incorrect gradient.
[1]
For using the slope (1) and deducing a ratio (1:1). The mole
relationship must be present. ECF incorrect ratio provided
related to the above gradient.
[1]
ACE
Conclusions
Total
[14]
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UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
GCE Advanced Level
9701 CHEMISTRY
9701/52
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
Cambridge will not enter into discussions or correspondence in connection with these mark schemes.
Cambridge is publishing the mark schemes for the May/June 2011 question papers for most IGCSE,
GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
Page 2
www.maxpapers.com
Syllabus
9701
Paper
52
Question
Sections
Indicative material
Mark
PLAN
Problem
[1]
[1]
[1]
(a)
(c)
(d)
PLAN
Problem
PLAN
Methods
PLAN
Methods
(i)
[1]
[1]
(i)
[1]
(ii)
[1]
(i)
[1]
[1]
[1]
[1]
(ii)
Page 3
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Syllabus
9701
Paper
52
[1]
PLAN
Methods
[1]
Ignore spillages
(f)
PLAN
Methods
[2]
[15]
Page 4
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Syllabus
9701
Question
Sections
Indicative material
ACE
Data
(a)
Paper
52
Mark
[1]
[1]
[1]
ACE
Data
[1]
[1]
[1]
Line of best fit (the correct graph is a curve, hence straight lines
gain zero. If however a wrong set of results genuinely produces a
straight-line, award the mark for a straight-line) (ignore
extrapolation at temperatures lower than 20 oC)
[1]
ACE
Evaluation
[1]
[1]
[1]
[1]
Page 5
(d)
(e)
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Syllabus
9701
Paper
52
ACE Data
[1]
ACE
Conclusions
[1]
ACE
Conclusions
[1]
[1]
[15]
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UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
GCE Advanced Level
9701 CHEMISTRY
9701/53
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
Cambridge will not enter into discussions or correspondence in connection with these mark schemes.
Cambridge is publishing the mark schemes for the May/June 2011 question papers for most IGCSE,
GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
Page 2
www.maxpapers.com
Syllabus
9701
Paper
53
Question
Sections
Indicative material
Mark
PLAN
Problem
[1]
[1]
[1]
(a)
(c)
(d)
PLAN
Problem
PLAN
Methods
PLAN
Methods
(i)
[1]
[1]
(i)
[1]
(ii)
[1]
(i)
[1]
[1]
[1]
[1]
(ii)
Page 3
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Syllabus
9701
Paper
53
[1]
PLAN
Methods
[1]
Ignore spillages
(f)
PLAN
Methods
[2]
[15]
Page 4
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Syllabus
9701
Question
Sections
Indicative material
ACE
Data
(a)
Paper
53
Mark
[1]
[1]
[1]
ACE
Data
[1]
[1]
[1]
Line of best fit (the correct graph is a curve, hence straight lines
gain zero. If however a wrong set of results genuinely produces a
straight-line, award the mark for a straight-line) (ignore
extrapolation at temperatures lower than 20 oC)
[1]
ACE
Evaluation
[1]
[1]
[1]
[1]
Page 5
(d)
(e)
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Syllabus
9701
Paper
53
ACE Data
[1]
ACE
Conclusions
[1]
ACE
Conclusions
[1]
[1]
[15]