0

He a lt h

Fire

Re a c t iv it y

P e rs o n a l
P ro t e c t io n

Material Safety Data Sheet

Zinc oxide MSDS
Section 1: Chemical Product and Company Identification
Product Name: Zinc oxide

Contact Information:

Catalog Codes: SLZ1009, SLZ1114, SLZ1222, SLZ1057

CAS#: 1314-13-2

Sciencelab.com, Inc.
14025 Smith Rd.
Houston, Texas 77396
US Sales: 1-800-901-7247
International Sales: 1-281-441-4400

RTECS: ZH4810000
TSCA: TSCA 8(b) inventory: Zinc oxide

Order Online: ScienceLab.com

CI#: Not available.

Synonym: Calamine; Zinc white

CHEMTREC (24HR Emergency Telephone), call:

1-800-424-9300

Chemical Name: Zinc Oxide

International CHEMTREC, call: 1-703-527-3887

Chemical Formula: ZnO

For non-emergency assistance, call: 1-281-441-4400

Section 2: Composition and Information on Ingredients

Composition:
Name

CAS #

% by Weight

Zinc oxide

1314-13-2

100

Toxicological Data on Ingredients: Zinc oxide: ORAL (LD50): Acute: 7950 mg/kg [Mouse].

Section 3: Hazards Identification

Potential Acute Health Effects:
Hazardous in case of inhalation. Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic for
bacteria and/or yeast. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. Repeated or
prolonged exposure is not known to aggravate medical condition.

Section 4: First Aid Measures

Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Get medical attention if irritation occurs.
p. 1

Skin Contact: Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops.
Serious Skin Contact: Not available.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.
Serious Inhalation: Not available.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear.
Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Non-flammable.
Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: Not available.
Fire Hazards in Presence of Various Substances: Not applicable.
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in
presence of static discharge: Not available.
Fire Fighting Media and Instructions: Not applicable.
Special Remarks on Fire Hazards: Slow addition of zinc oxide to cover linseed oil varnish causes generation of heat and
ignition.
Special Remarks on Explosion Hazards:
May explode when mixed with chlorinated rubber. Zinc Oxide and Magnesium can react explosively when heated.

Section 6: Accidental Release Measures

Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on
the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill:
Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the
contaminated surface and allow to evacuate through the sanitary system. Be careful that the product is not present at a
concentration level above TLV. Check TLV on the MSDS and with local authorities.

Section 7: Handling and Storage

Precautions:
Keep locked up.. Do not ingest. Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear
suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Keep away
from incompatibles such as acids.
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Do not store above 25C (77F).

p. 2

Section 8: Exposure Controls/Personal Protection

Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection: Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits:
TWA: 5 STEL: 10 (mg/m3) from ACGIH (TLV) [United States] Inhalation TWA: 15 (mg/m3) from OSHA (PEL) [United States]
Inhalation Total. TWA: 5 STEL: 10 CEIL: 25 (mg/m3) from NIOSH Inhalation TWA: 5 STEL: 10 (mg/m3) from OSHA (PEL)
[United States] Inhalation Respirable.Consult local authorities for acceptable exposure limits.

Section 9: Physical and Chemical Properties

Physical state and appearance: Solid. (Powdered solid.)
Odor: Odorless.
Taste: Bitter.
Molecular Weight: 81.38 g/mole
Color: White to yellowish-white
pH (1% soln/water): Not applicable.
Boiling Point: Not available.
Melting Point: 1975C (3587F)
Critical Temperature: Not available.
Specific Gravity: 5.607 (Water = 1)
Vapor Pressure: Not applicable.
Vapor Density: Not available.
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: Is not dispersed in cold water, hot water.
Solubility:
Insoluble in cold water, hot water Soluble in dilute acetic acid, or mineral acids, ammonia, ammonium carbonate, fixed alkali
hydroxide solution..

Section 10: Stability and Reactivity Data

Stability: The product is stable.
Instability Temperature: Not available.
p. 3

Conditions of Instability: Not available.

Incompatibility with various substances: Not available.
Corrosivity: Non-corrosive in presence of glass.
Special Remarks on Reactivity:
Reacts violently with magnesium, linseed oil. Reacts with hydrochloric acid to produce zinc chloride. Reacts with sulfuric
acid to produce zinc sulfate. Reacts with hydrogen fluoride to produce zinc fluoride tetrahydrate. Gradually absorbs CO2 on
exposure to air. Sublimes at normal pressure. Zinc Oxide reacts with Carbon Monoxide or hydrogen to produce elemental
zinc.
Special Remarks on Corrosivity: Not available.
Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Dermal contact. Inhalation. Ingestion.
Toxicity to Animals: Acute oral toxicity (LD50): 7950 mg/kg [Mouse].
Chronic Effects on Humans: MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic for bacteria and/
or yeast.
Other Toxic Effects on Humans:
Hazardous in case of inhalation. Slightly hazardous in case of skin contact (irritant), of ingestion.
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans:
May cause adverse reproductive effects based on animal data. No human data found at this time. May affect genetic material
(mutagenic).
Special Remarks on other Toxic Effects on Humans:
Acute Potential Health Effects: May cause mild skin irritation. Eyes: May cause mechanical eye irritation and conjunctivitis.
Inhalation: May cause mechanical irritation of the respiratory tract. A few sources claim that finely divided zinc oxide dust
can cause "metal fume fever." Zinc oxide dust is generally considered a nuisance dust; adverse effects are unlikely when
exposures are kept under reasonable control. Inhalation of high concentrations of Zinc Oxide fume or dust may cause "Metal
Fume Fever." Symptoms of metal fume fever may include a flu-like condition involving headache, chills, fever, sweats, nausea,
vomiting, cough, muscle aches and pains, and difficulty breathing, ;ulmonary edema. May also affect the liver. Ingestion: May
cause digestive tract irritation although Zinc oxide has a low toxicity by oral exposure route. Chronic Potential Health Effects:
Ingestion: Prolonged or repeated ingestion of zinc oxide may affect blood, metabolism, and the thyroid.

Section 12: Ecological Information

Ecotoxicity: Not available.
BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.
Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:
p. 4

Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

DOT Classification: Not a DOT controlled material (United States).
Identification: Not applicable.
Special Provisions for Transport: Not applicable.

Section 15: Other Regulatory Information

Federal and State Regulations:
Illinois toxic substances disclosure to employee act: Zinc oxide Rhode Island RTK hazardous substances: Zinc oxide
Pennsylvania RTK: Zinc oxide Minnesota: Zinc oxide Massachusetts RTK: Zinc oxide New Jersey: Zinc oxide California
Director's List of Hazardous Substances: Zinc oxide TSCA 8(b) inventory: Zinc oxide
Other Regulations: EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.
Other Classifications:
WHMIS (Canada): Not controlled under WHMIS (Canada).
DSCL (EEC):
R40- Possible risks of irreversible effects. S2- Keep out of the reach of children. S36/37- Wear suitable protective clothing and
gloves.
HMIS (U.S.A.):
Health Hazard: 2
Fire Hazard: 0
Reactivity: 0
Personal Protection: E
National Fire Protection Association (U.S.A.):
Health: 1
Flammability: 0
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Safety glasses.

Section 16: Other Information

References: Not available.
Other Special Considerations: Not available.
Created: 10/10/2005 08:34 PM
Last Updated: 05/21/2013 12:00 PM
The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
p. 5

their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.

p. 6