Mercury and Sulphur Among The High Medieval Alchemists
Mercury and Sulphur Among The High Medieval Alchemists
Mercury and Sulphur Among The High Medieval Alchemists
William R. Newman
Indiana University, Bloomington, USA
This essay challenges the often expressed view that the principles of metals,
namely mercury and sulphur, were generally viewed by alchemists as being
of a metaphysical character that made them inaccessible to the tools and
operations of the laboratory. By examining a number of Arabo-Latin and
Latin alchemical texts in circulation before the end of the thirteenth century,
the author presents evidence that most alchemists of the period considered
mercury and sulphur to be materials subject to techniques of purification in
the same way that naturally occurring salts and minerals could be freed of
their impurities or dross. The article also points to the immense influence
of Avicenna and Albertus Magnus in formulating the theory that mercury
and sulphur were compounds of different materials, containing both fixed
and unfixed components. Finally, the author briefly examines the relationship
between this materialist approach to the principles and the chymical atomism
of early modern authors who were deeply aware of medieval alchemical
literature.
A well-known example of this old claim can be found in Robert Siegfried and Betty Jo Dobbs, Composition, A Neglected Aspect of the Chemical Revolution, Annals of Science 24 (1968): 27593; see especially on 292. More
recently, the claim has been adopted by Ursula Klein and Wolfgang Le Fevre, Materials in Eighteenth-Century
DOI 10.1179/1745823414Y.0000000004
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WILLIAM R. NEWMAN
Continued
Science (Cambridge, MA: MIT Press, 2007), who employ the term spiritual instead of metaphysical, but with
much the same meaning; see on 3940 et passim.
For a rather early example of this viewpoint, see Marie Boas [Hall], Robert Boyle and Seventeenth Century Chemistry (Cambridge: Cambridge University Press, 1958), 8386. A somewhat similar perspective underlies the otherwise
laudable book of Frederic L. Holmes, Eighteenth Century Chemistry as an Investigative Enterprise (Berkeley: Office
for History of Science and Technology, University of California at Berkeley, 1989). Holmes intended to extend
various features associated with the Chemical Revolution, such as operational interpretations of composition,
back to the French Academicians of the seventeenth century. See Holmes, Eighteenth Century Chemistry, 837. In
the case of earlier chymists such as Paracelsus, Holmes asserted that the principles were more spiritual than
material; see Holmes, Analysis by Fire and Solvent Extractions: The Metamorphosis of a Tradition, Isis 62
(1971): 12948, particularly on 132; and Holmes, Chemistry in the Acadmie Royale des Sciences, Historical
Studies in the Physical and Biological Sciences 34 (2003): 4168, especially on 4546.
Sbastien Moureau has pointed out to me in private communication that the purification approach does not fully
capture the complexity found in the Arabo-Latin De anima in arte alchemiae, which he is currently editing (there is
also an early modern imprint in the Artis chemicae principes, Avicenna atque Geber [Basel: Petrus Perna, 1572]). It is
not surprising that there would have been more than one approach to the alchemical principles in texts of Islamic
origin, given the wide dispersion of alchemical theory and practice there. I do not claim universality for the purification approach, only its widespread character.
Some alchemists even thought that the four elements themselves could be separated by the technology of the laboratory, especially by means of distillation. This is a central feature of the alchemical corpus ascribed to Jabir ibn
H ayyan, which is also found in the pseudo-Avicennian De anima in arte alchemiae. See Paul Kraus, Jabir ibn
329
based on the parallel refining of atraments, boraxes, and salts that one finds in
Arabic alchemy, and also on the refining of metals themselves. We do not normally
think of the metallic iron disguised under the form of powdery red rust, or the
copper lurking within verdigris, as metaphysical or spiritualwhy then should
we import those modes of expression into High Medieval alchemy when the original
actors did not employ them?
In the following discussion I will limit my analysis to texts that were composed
independently of the two great classics of medieval chrysopoetic alchemy, the
Summa perfectionis of Geber and the Testamentum traditionally attributed to the
Catalan philosopher Ramon Lull.5 Given the huge influence of the Geberian and
Lullian corpora on subsequent alchemists, one can easily fall into the trap of confusing the part for the whole by focusing on one or both of these traditions. In this
paper, I will consider a slightly earlier period, when alchemical traditions were
still in a state of flux and Arabo-Latin sources provided the most authoritative perspective on the aurific art. I will therefore focus on four textsthe Liber de congelatione et conglutinatione lapidum (also called De mineralibus) of Avicenna (Ibn
Sna, d. 1037 CE), which is a genuine translation from Arabic; the Liber secretorum
de voce Bubacaris, which is based on a genuine work by Abu Bakr Muh ammad ibn
Zakariyya al-Raz (d. 925 or 935 CE); the Liber mineralium or De mineralibus of
Albertus Magnus, which contains a careful sifting and analysis of mostly AraboLatin alchemical texts; and finally, the Breve breviarium attributed spuriously to
Roger Bacon: this final text was clearly dependent on Albertus Magnus despite
the authors apparent attempt to insert himself into the dispute between Bacon
and his opponents within the Franciscan order. These four works can be taken as
representative of four stages in the development of alchemy independent of the
Summa and the Testamentum, comprising translation, reworking, scholastic analysis, and full-blown employment of scholastic themes and techniques in crafting a
theory and practice of alchemy.
Continued
H ayyan: Contribution lhistoire des ides scientifiques dans lIslam (Cairo: Imprimerie de linstitut franais, 1942),
vol. 2, 418. As Sbastien Moureau has pointed out to me, this practice appears in dictio 7, Chapter 2 (40910) of the
1572 edition of the De anima in arte alchemiae.
See William R. Newman, The Summa perfectionis of pseudo-Geber (Leiden: Brill, 1991) and Michela Pereira and
Barbara Spaggiari, Il Testamentum alchemico attribuito a Raimondo Lullo (Firenza: Edizioni del Galluzzo, 1999).
In a useful recent article, Jean-Marc Mandosio and Carla di Martino argue that Avicennas text should actually be
referred to as De mineralibus, since the name De congelatione et conglutinatione lapidum properly refers only to the
first chapter of the translated text; see their La Mtorologie dAvicenne (Kitab al-Shifa V) et sa diffusion dans le
monde latin, in Wissen ber Grenzen: Arabisches Wissen und lateinisches Mittelalter, ed. Andreas Speer and Lydia
Wegener (New York: De Gruyter, 2006), 40623. For the present article, I have kept the name De congelatione et
conglutinatione lapidum, if only because this title has come to be widely recognized in the Anglo-Saxon world as
a result of Holmyard and Mandevilles 1927 edition.
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WILLIAM R. NEWMAN
influential section of Avicennas Kitab al-Shifa was translated into Latin at least
twice in the Middle Ages.7 The most important of the translations, done by
Alfred of Sareshel at some point in the second half of the twelfth century, often circulated with the translation of Aristotles Meteorology Book IV made by Henricus
Aristippus and sometimes with the newer translation of the Meteorology made by
William of Moerbeke in the thirteenth century.8 Because of its manuscript transmission, Avicennas text looked to contemporaries as though it was the conclusion
of Aristotles Meteorology IV; this fact lent the text considerable prestige and provided it with an authority that it might otherwise have lacked.9 Although Avicenna
famously attempts to rebut chrysopoeia in another passage of his De congelatione,
the text nonetheless accepts that metals are formed within the earth from mercury
and sulphur that differ in colour and purity.10 There are dirty and clean sulphurs
and mercuries, and these can vary in colour as well, according to Avicenna. Only
a very clean and pure mercury and sulphur will yield gold; the converse will
produce lead or iron.
What is of concern to us, however, is that Avicenna postulates that not only the
metals, but mercury and sulphur themselves, are compounded from more primitive
ingredients. As he puts it
The wateriness of the sulphurous [sulphureorum] is mixed with earth in a strong commixture with fervency of heat until they are made unctuous, and then they are coagulated by cold Quicksilver is as a water which is mixed with a very subtle,
sulphurous earth in a strong mixture until it does not rest on a flat surface, and this is
due to the great dryness which is in it, and therefore it does not adhere to anything touching it. And its whiteness is from the brightness of that water, and from the whiteness of
the subtle earth that is in it.11
According to this influential theory both sulphur and mercury are composed of an
earthy and a watery component. Clearly Avicenna is talking about ordinary sulphur
and mercury, since he refers to the unctuosity of the former when molten and to the
7
9
10
11
Mandosio and di Martino, La Mtorologie, 406. As the authors point out, the fifth part of Avicennas Kitab
al-Shifa, which contained his treatment of meteorology, was translated once in full; additionally, two partial translations were madeDe congelatione et conglutinatione lapidum, and De diluviis.
For the date of this translation, which is somewhat earlier than the traditionally accepted one, see Jean-Marc Mandosio, Humanisme ou barbarie? Fonnes de la latinit et mmoire de lAntiquit dans quelques traductions mdivales de textes philosophiques arabes, in critures latines de la mmoire de lAntiquit au XVI e sicle, ed. Hlne
Casanova-Robin et Perrine Galand (Paris: Classiques Garnier, 2010), 22763; see 24445. I thank Sbastien
Moureau for bringing this article to my attention.
See Mandosio and di Martino, La Mtorologie, especially on 41119.
Avicenna did not of course invent the sulphurmercury theory of the metals, which goes back at least as far as the
Book of the Secret of Creation (Kitab sirr al-Khalqa) attributed to the pseudonymous Balnu s. For a brief introduction to this obscure figure, see the entry by Martin Plessner, Balnu s, New Encyclopedia of Islam (Leiden: E. J. Brill,
1986), vol. 1, 99496. See also Ursula Weisser, Das Buch ber das Geheimnis der Schpfung von
pseudo-Apollonius von Tyana (Berlin: De Gruyter, 1980).
Unfortunately, there is no critical edition of the De congelatione et conglutinatione available today. The Avicennae de
congelatione et conglutinatione lapidum compiled by E. J. Holmyard and D. C. Mandeville (Paris: Geuthner, 1927)
merely copies a single base manuscript and provides alternative readings in the apparatus with no attempt to emend
the obviously quite defective text. In the passage that I have translated here, I have followed the text provided in JeanJacques Manget, Bibliotheca chemica curiosa (Geneva: 1702), vol. 1, 63638. Needless to say, this uncontrolled text
should also be taken with a large grain of salt. For the Latin passage, see 637B.
331
fact that the latter rolls around on a flat surface when touched and does not stick to
the object or finger that is touching it. As the text continues, he also adds that
mercury is congealed by vapours from molten lead, presumably referring to the
formation of an amalgam, and by vapour of sulphur, an obvious reference to the
manufacture of artificial cinnabar.
Despite his affirmation of the sulphurmercury theory of metallic composition,
Avicenna of course rejects human attempts at replicating natures work on
metals with his famous dictum repeated throughout the subsequent history of
alchemySciant artifices alkimie species metallorum non posse transmutari
(Let the alchemists know that the species of metals cannot be transmuted). Hence,
we cannot expect Avicenna to provide us with techniques for refining mercury
and sulphur in order to remove their normally occurring defects and thereby
provide the means of transmuting metals. If we turn to Arabo-Latin alchemical
texts proper, however, such advice is readily forthcoming. An excellent example
can be found in the Liber secretorum de voce Bubacaris, a work that the historian
of Arabic alchemy Julius Ruska studied extensively in the 1930s. In a long article
published in 1936, Ruska argued that the Liber secretorum de voce Bubacaris
was a reworking (Bearbeitung) of Razs Kitab al-Asrar, which had already been
translated into Latin as the Liber Ebu baccar et Raisy (as found in the famous
Codex Speciale, Palermo Biblioteca Comunale 4QqA10). Although an exact
textual study of the relationship between the Liber secretorum de voce Bubacaris
and the Liber Ebu baccar et Raisy remains a desideratum, Ruskas work placed it
beyond doubt that the Liber secretorum descended from the genuine work of
Raz. In the absence of a close study of the two works, however, I will refer to the
reworking by its title, rather than assuming that all of its ideas go back to Raz.
The Liber secretorum de voce Bubacaris contains ideas about the nature and composition of sulphur and mercury that are similar to those of Avicenna, despite the
fact that the work is a practica rather than a treatise of natural philosophy.
Unlike Avicenna, however, Raz teaches the reader how to operate on mercury
and sulphur for chrysopoetic purposes:
The operation for quicksilver is washing, then to take away its humidity The operation of orpiment and sulphur is that they be whitened and freed from their burning
and from the fat that they have.12
As in the case of Avicenna, the Liber secretorum proceeds from the belief that
mercury contains an earthy component and a humidity: in order to prepare ones
quicksilver for alchemical purposes, it must therefore be refined by the washing
away of any dirtiness and the removal of its wetness. Similarly, the unctuosity of
sulphur and that of the closely related orpiment (arsenic sulphide) must be
removed; as the Liber secretorum reveals elsewhere in the text, this is the origin of
12
Liber secretorum de voce bubacaris, in MS Paris, BN lat. 6514, fol. 103ra: Operatio argenti vivi est lavatio deinde
levare eius humiditatem Operatio auripigmenti et sulphuris est ut dealbentur et liberentur ab ardore eorum et
pinguedine quam habent.
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WILLIAM R. NEWMAN
their combustibility. In order to drive home the point that the Liber secretorum is
talking about ordinary quicksilver, not some metaphysical analogue of mercury,
it is necessary to quote one more passage from the text:
There are two manners of sublimation of quicksilver, of which one is for the white [i.e.
for argyropoeia] and one for the red [i.e. for chrysopoeia proper]. But in each sublimation there are two secrets. One is that that the humidity be taken [recipiatur], the other
that you make it hard and dry and its humidity is thus removed.13
14
15
16
17
Liber secretorum de voce bubacaris, in MS Paris, BN lat. 6514, fol. 103ra103rb: Sublimationis argenti vivi due
sunt manieres quarum una est pro albedine et alia pro rubedine tamen in unaquaque sublimatione sunt duo
secreta ut unum est ut recipiatur humiditas aliud est ut facias illud durum et siccum et sic deperditur eius humiditas.
For the polyvalent meanings attached to the term quick or living (h ayy) in Arabic and Arabo-Latin alchemy, see
Sbastien Moureaus glossary in his forthcoming edition and study of the pseudo-Avicennian De anima in arte
alchemiae, which he has kindly shown me in draft form.
Julius Ruska, Al-Razs Buch Geheimnis der Geheimnisse, in Quellen und Studeint zur Geschichte der Naturwissenschaften unde der Medizin, vol. 6 (Berlin: Julius Springer, 1937). See especially on 10026, and 22025.
See Ernst Darmstaedter, Liber claritatis totius alkimicae artis, Archivio di Storia della Scienza 6 (1925): 31930; 7
(1926): 25765; 8 (1927): 95103; 8 (1927): 21429; 9 (1928): 6380; 9 (1928): 191208; and 9 (1928): 46282.
John A. Norris, The Mineral Exhalation Theory of Metallogenesis in Pre-Modern Mineral Science, Ambix 53
(2006): 4365.
333
You should know that the mineral bodies are vapours which are thickened and coagulated according to the working of nature over a long time. What is first coagulated in
them is quicksilver and sulphur. And these two are the origins of the mineral. And
they are the water and the oil. A temperate concoction has remained with them
with heat and humidity until they are congealed, and from them the [mineral] bodies
are generated. Then they are gradually mutated until they become silver and gold in a
thousand years.18
In both of the partial editions of the De aluminibus et salibus that are currently
available, Pseudo-Razs description of metallogenesis from the two principles
immediately follows a succession of recipes for purifying and congealing ordinary
mercury. These recipes range from the sublimation of quicksilver with salt and atrament to the manufacture of vermilion and amalgamation: in short, they belong to
the traditional corpus of mercurial alchemy conspicuous in the work of the
genuine Raz. There can be no doubt whatsoever that the mercury and sulphur of
the De aluminibus et salibus consist of the ordinary materials that we know by
those terms today, although the text views these principles as subjects that require
purification and refining. Since the case is the same for the other Arabo-Latin
texts that I have briefly surveyed here, we may now pass to the Liber mineralium
of Albertus Magnus, a work that drew upon these sources and tried to bring
them into conformity with the scholastic natural philosophy of the mid-thirteenth
century.
19
Although there are two modern printings of De aluminibus et salibus, there is no fully adequate edition of the text at
present. The text is found in Robert Steele, Practical Chemistry in the Twelfth Century: Rasis de aluminibus et
salibus, Isis 12 (1929): 1046, and in Julius Ruska, Das Buch der Alaune und Salze (Berlin: Verlag Chemie,
1935). Steeles text is based on the copy of De aluminibus et salibus found in MS Paris, BN lat. 6514, to which he
has compared London, British Library MS Arundel 164 and the extracts in printed versions of Vincent of Beauvaiss
Specula. Ruskas text is based on a version of the De aluminibus et salibus found in a sixteenth-century imprint
John of Garlands De mineralibus liber (Basel, 1560) which Ruska compares to Steeles edition. I have translated
the text of Ruska here, incorporating the suggestions that he makes in the notes to his own German translation.
See Ruska, 62, 95. The passage is found in Steele on 27. For the Hebrew tradition of the De aluminibus et
salibus, see Gabriele Ferrario, Origin and Transmission of the Liber de aluminibus et salibus, in Chymists and
Chymistry: Studies in the History of Alchemy and Early Modern Chymistry, ed. Lawrence M. Principe (Sagamore
Beach: Science History Publications, 2006), 13748.
Robert Halleux, Albert le grand et lalchimie, Revue des sciences philosophiques et thologiques 66 (1982): 5780.
334
WILLIAM R. NEWMAN
the simple mineral exhalation theory described above. In his chapter on the matter
out of which metals are made, Albert argues that the two principles, like many other
things, contain a twofold unctuosity or oiliness. What Albert has in mind, for the
moment, is sulphur, which he views as a compound. The standard text of the
Liber mineralium found in volume five of Auguste Borgnets Opera omnia is defective at this crucial point, so I will correct it with the addition of a few words found in
two medieval manuscripts, Vaticanus palatinus latinus 978 and Marburg Universittsbibliothek B20 (MS 26), in my own translation. I have placed the added words in
pointed brackets; otherwise the translated passage comes from Borgnet:
The unctuosity in many things is double, one of which is as it were extrinsic <with an
intermixed, adust, feculent earthiness, and this is highly combustible and flammable.
But the other is intrinsic,> quite subtle, having nothing feculent or combustible mixed
in, and this is not flammable, but intrinsic to the thing, retained in its roots so that it
cannot be torn out and drained out by fire. And we have given as an example the
liquor that is refined out of wine, in which [wine] there is a supernatant, flammable unctuosity, accidental, as it were, and bound on. The other [unctuosity] is commixed to the
whole substance of the liquor itself, not separable from the liquors substance, except
with loss of the substance; and this is not combustible.20
The concept of a double unctuosity is taken almost verbatim by Albert from the
little-studied Quaestiones Nicolai Peripatetici, a work that also circulated under the
title De vaporibus and was sometimes attributed to Averroes.21 The concept of a
double humidity, one of which is flammable, is clearly based on the distillation of
ethanol from wine, a fact already noted by Alberts translator Dorothy
Wyckoff.22 Just as wine contains a highly volatile, combustible material that can
be distilled off (ethanol), and a less volatile component that is not combustible, so
too does the metallic principle sulphur. Albert therefore continues to say that
normal sulphur contains a burning unctuosity that blackens and burns metals
when it is fused and dropped on them. For this reason, Albert adds, alchemists
20
21
22
Albertus Magnus, Liber mineralium, in B. Alberti Magni ratisbonensis episcopi, ordinis praedicatorum, opera
omnia, ed. Auguste Borgnet (Paris: Ludovicus Vivs, 1890), vol. 5, 61. I reproduce the text of Borgnet corrected
against MSS Vat. Palat. 978, fol. 8rb, lines 2023, and Marburg Universittsbibliothek B20 (MS 26), fol. 140v
(9v), lines 1011. I have placed the added lines in pointed brackets, retaining the medieval spellings. The only difference between the two manuscripts as far as the addition goes is that Marburg B20 (MS 26) lacks the autem before
est intrinseca: duplex est unctuositas in multis rebus: quarum una est quasi extrinseca, subtilis valde, nihil faetulentum vel cremabile habens admixtum: et haec non est inflammabilis, et intrinseca rei retenta in radicibus rei, ne per
ignem possit evelli et epotari: et nos dedimus de hoc exemplum in liquore, qui eliquatur ex vino, in quo una est unctuositas supernatans inflammabilis, et facile astringibilis et quasi accidentalis. Altera commixta toti substantiae
liquoris ipsius, non separabilis ex ipsa substantia liquoris, nisi per defectionem substantiae: et haec non est
cremabilis.
For the double humidity in Albert and in Nicolaus Peripateticus, see Newman, Summa perfectionis of pseudoGeber, 21819. For more recent work on Nicolaus Peripateticus, see Sbastien Moureau, Les sources alchimiques
de Vincent de Beauvais, Spicae, Cahiers de latelier Vincent de Beauvais 2 (2012): 5118; consult especially 3435.
A critical edition is found in Stanisaw Wielgus, Quaestiones Nicolai Peripatetici, Mediaevalia Philosophica Polonorum 17 (1973): 57155.
Dorothy Wyckoff, trans., Albertus Magnus: Book of Minerals (Oxford: Clarendon Press, 1967), 157,
n. 8. Unfortunately Wyckoffs translation of this passage reproduced here is defective, as she has used Borgnets
text without consulting the manuscript tradition of the Liber mineralium. Hence I have retranslated the passage
for the present article.
335
advise that sulphur be washed in acid solutions and sublimed until its unctuosity is
removed and the sulphur can withstand fire without burning. As for quicksilver,
Albert first paraphrases Avicennas claim that it contains a liquid component
along with a subtle earth. In conformity with his theory of a twofold unctuosity,
however, Albert describes the moist component of mercury as a subtle, unctuous,
humidity (humidum subtile unctuosum), rather than a water.
Alberts theory therefore postulates that mercury and sulphur each contain a volatile component and a fixed one. Since the metals are themselves composed of the two
principles, it should follow that each metal should itself contain a fixed and a volatile
component, though the degree of fixity and volatility will vary with the particular
metal. A particularly instructive example can be found later in Alberts text, when
he discusses the causes of burning in metals. Here the Universal Doctor has taken
the interesting step of dividing the metals principles into three rather than two unctuosities. I quote this important passage from Dorothy Wyckoffs translation of the
Liber mineralium:
We know, therefore, that the ability of metals to be burnt is [due to] the Sulphur, and not
to the Quicksilver by itself. Furthermore, we also know that in anything that contains
very unctuous moisture mixed with earthiness, the moisture is of three kinds. One of
these is extremely airy and fiery, adhering to the surface, as a consequence of the
[upward] motion of those elements [Fire and Air], so that they always rise to the
surface of things in which they are mixed and combined. The second, close beneath
this, contains more wateriness floating about among the parts of the thing. The third
has its moisture firmly rooted and immersed in the parts and bounded in the combination; and therefore this is the only one that is not easily separated from the combination, unless the thing is totally destroyed. And therefore this must be the nature of
Sulphur.23
Here we can see that Albert has divided the extrinsic moisture into two types while
retaining the unitary character of the third, intrinsic humidity. His goal in making
this new bifurcation probably lay in the desire to have both a flammable and a
non-flammable type of unfixed humidity. Thus, the first extrinsic moisture is fiery
and airy, hence combustible, while the second is not, being composed of wateriness. Albert then repeats his earlier observation that alchemists cleanse sulphur
by means of penetrating solutions such as vinegar, and sour milk, and goats
whey, and water of chickpeas and boys urine and that they employ operations
such as boiling and sublimation. Now he tells us that this treatment removes the
first moisture, which is combustible, as well as the second, which merely evaporates
in the fire.24 Similar considerations emerge immediately after this passage when
Albert turns to quicksilver, although here Albert does not divide the extrinsic humidity into combustible and merely evaporative types. Instead, following Avicenna, he
speaks of quicksilver as being composed of a watery moisture united with a subtle
23
24
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WILLIAM R. NEWMAN
earth. Perhaps because Avicenna had described this inherent earth within mercury as
being sulphurous, Albert argues that there is an impure form of quicksilver that
can burn metals if it is too dirty or present in too great a quantity in a given metal.25
The passages from Alberts Liber mineralium that we have examined so far focus
on his theory of extrinsic and intrinsic humidities and how these pertain to mercury
and sulphur. In order to see how his theory of three humidities plays out in the composition of individual metals, we need to look at a final passage. The fourth book of
the Liber mineralium treats each of the then-known metals independently, while the
chapter on silver presents the theory of three humidities quite clearly:
And we know from what has been said that both Sulphur and Quicksilver and anything else at all which, because of its constitution [complexione], is moist and liquefiable
by Fire contains three [kinds of] moisture, just like living things, plants and animals.
One [kind of] moisture is thick and undigested [crassus et indigestus], rising to the
surface like grease, fat, or oil; and it is this that makes things inflammable. And
the second is like the phlegmatic humour [phlegmaticus humectans] that moistens the
parts of things, but does not contribute to generation or growth. And the third is the
radical [radicalis] moisture saturating the essential parts of a thing; and because of
this moisture the parts [of things] are firm, and grow, and are nourished. We have
found that silver is hard and dry. And therefore it must have been thoroughly cleansed
of the two superfluous [kinds of] moisture, and the subtlety of the third is responsible for
its excellent mixture.26
The upshot of this passage is that silver, during its generation beneath the earth,
has been purged of the two extrinsic humidities that would cause excessive combustibility and evaporation. In the same chapter, Albert explains that silvers mercury is
well digested and purified and mixed with extremely subtle material. The two
extrinsic humidities of its sulphur, moreover, have been largely removed by the
skill of nature.27 Nonetheless, when silver is strongly heated, it has a foul, sulphurous odour, revealing the presence of some remaining sulphur.
To summarize Alberts position, then, each of the metals is composed of the two
principles, sulphur and mercury. But because sulphur and mercury contain their own
extrinsic, unfixed components, and also intrinsic, fixed ones, it follows that the
metals are also fixed or unfixed in varying degree. Moreover, a clever metallurgist
or alchemist can determine the presence or absence of the principles by examining
the characteristics of the given metal when subjected to an intense fire, as in the
case of heated silvers sulphurous stench. And as we saw above, Albert thinks that
alchemists can remove the extrinsic components of sulphur, at least, by operations
involving sharp waters, boiling, and sublimation. Alberts claim that quicksilver
25
26
27
337
and sulphur have their own extrinsic and intrinsic components, and also his observation that these can be detected by heating the metal, would exercise considerable
influence in subsequent alchemy, above all in the Summa perfectionis of Geber and
the tradition stemming from it.28 But since the Summa is outside the limits of the
present paper, I will focus instead on an alchemical treatise that I believe to have
been composed independently of the Summa. Despite the fact that this text presents
itself as a work by Roger Bacon, all the evidence convinces one that it is actually an
attempt by a pseudonymous author to implement the theories of Albertus Magnus in
the realm of alchemical practice.29
30
31
338
WILLIAM R. NEWMAN
The Breve breviarium begins this passage with a recapitulation of the Avicennian
theory that quicksilver contains a subtle, sulphurous earth mixed together with a
watery material. The same claim is found in Alberts Liber mineralium, so it is no
surprise that pseudo-Roger then passes directly into an exposition of Alberts
theory that sulphur is composed of three humidities. If there is any doubt that the
Breve breviarium is deriving this theory from Albert, it should quickly be dispelled
by the close terminological relation between the two authors and the ordering of the
three humidities. Both pseudo-Roger and Albert call the first humidity unctuous
(unctuousa or unctuosum) and say that it burns (cremat); both authors speak of
the second humidity as phlegmatic (phlegmatica or phlegmaticus) and evaporative (evaporans or evanida), and most telling of all, both authors use the term
radical (radicalis) for the third type of humidity. But the two authors differ in
one crucial respectAlberts Liber mineralium is a descriptive study of geological
32
33
I have described these arguments in William R. Newman, Promethean Ambitions: Alchemy and the Quest to Perfect
Nature (Chicago: University of Chicago Press, 2004), 6768.
[Pseudo-] Roger Bacon, Breve breviarium, in Sanioris medicinae magistri D. Rogeri Baconis (Frankfurt: Joannes
Theobaldus Schnvvetterus, 1603), 10913.
339
34
35
36
[Pseudo-] Roger Bacon, Breve breviarium, 19098. See page 190 for the quoted passageSubstantia autem sua
terrea purganda est a grossa terrestreitate sulphurea. Aquea vero substantia ab humiditate duplici superflua.
For the terms vas artificiale and vas naturale, see [pseudo-] Roger Bacon, Breve breviarium, 191. These terms
also betray the influence of Albert the Great, who argues that skillful alchemists imitate nature when making their
vessels. See Wyckoff, Albertus Magnus, 18485.
[Pseudo-] Roger Bacon, Breve breviarium, 165.
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WILLIAM R. NEWMAN
digests and fixes the principle beneath the earth. This is done by now grinding the
sulphur with sal ammoniac and distilled vinegar, dissolving the mixture in the
heat of horse dung, evaporating the excess moisture, and congealing the prepared
sulphur. At this point, the sulphur will have been freed of its combustibility and volatility, so that it can now be used to correct defective metals.
I will not follow pseudo-Roger into the complicated techniques that he now
employs in order to accomplish his chrysopoetic goals with prepared mercury and
sulphur. It is enough to see how he has put the Albertine theory of three humidities
to work in his alchemical practice by employing technologies to free the two principles of their extrinsic humidities. There can be no doubt that pseudo-Roger sees
these humidities as material components intermixed with the radical, necessary
material of the sulphur and mercury. There is no essential difference in his mind
between these refining processes and subsequent ones found in the Breve breviarium
for purifying a host of other materials, including the metals themselves, as well as sal
ammoniac, sal alkali, saltpetre (sal petrae), soda (sal nitri), common salt (sal communis), rocksalt (sal gemmae), green and black atrament, various alums (e.g. glaciale
and plumosum), boraxes, and so forth. To give but one example of these purifying
processes, let us briefly consider pseudo-Rogers treatment of silver:
Silver [Luna] is prepared thus. First let it be purged by cupellation with lead [purgetur
cum plumbo & cinere]. Once fused it should be cast onto little branches and ignited
until red hot ten times, and each time it should be extinguished in pigs blood. After
each time let it be rent into thin pieces [lanietur tenuiter] and fused with a little borax
covering the sheets and then let it be cast again on the little branches and extinguished
ten times as before Then you should know for certain that you have very lovely
[dulcissimam], purged silver.37
The first part of this refining process is strightforward: pseudo-Roger advises that
the impure silver be cupelled with lead, as any medieval metallurgist would do. But
he is not satisfied with this. The molten silver then must be heated red hot and
thrown onto branches, then extinguished in pigs blood. Presumably, the use of
these organic materials would result in the further reduction of silver from its compounds. The process may be an adaptation from the technique of poling, during
which saplings were thrust into molten copper as part of its refining from ore.
Albert refers rather vaguely to the operation of poling in his Liber mineralium,
though it seems likely that pseudo-Roger is following other sources here as well.38
The technology need not detain us further, however. The lesson to learn here is
that silver, and indeed the other metals as well, must be purged and refined of
their impurities before they can enter into a process of transmutation, just as
mercury and sulphur must also undergo their refining.
37
38
341
Conclusion
We have now surveyed a variety of Arabo-Latin and original Latin works composed
before the Geberian Summa perfectionis and the Lullian Testmentum would exercise
their huge and lasting influence on Latin and vernacular Western alchemy. As we
have seen, in this formative period the principles of sulphur and mercury were
widely considered to be material components of metals that could be treated by
analytical methods: the imputation that they were somehow inaccessible to physical
manipulation, at least in the High Middle Ages, has proven hollow. If we were to
continue this paper to include the Latin Geber, moreover, we would see much the
same development of Albertine ideas and practices that we have encountered in
the Breve breviarium, for the Universal Doctor exercised a similar influence on
the Summa perfectionis. The principles were neither metaphysical nor spiritual
if by those terms one means immaterial. If, on the other hand, one means such
terms to suggest that ordinary quicksilver and sulphur were believed to contain a
pure portion disguised beneath various adulterations, that view would be closer
to the mark. But given that quicksilver and sulphur were subject to refining just
like other minerals and ores, it would seem at best gratuitous to use metaphysical
or other terms that imply the inability of the principles to be isolated or observed,
even if some historians have taken precisely that approach.
We have seen, then, that the once commonplace belief among historians of chemistry that alchemists universally viewed their mercury and sulphur to be metaphysical, spiritual, or ideal is severely challenged by the alchemy of the High
Middle Ages. At best, this historiographical fallacy falls victim to the error of synecdocheconfusing the part (certain chymical traditions directly before the eighteenth
century) for the whole (the sulphur-mercury theory over the longue dure). But
someone could object that I have committed the mirror-image of this mistake by
juxtaposing medieval alchemy to scholarship that was really only meant to illuminate the early modern period. What relation do the alchemy of the High Middle
Ages and chymistry in the century before Lavoisier really have towards one
another? In fact, the lines of affiliation between the Geberian tradition of alchemy
and the work of early modern chymists such as Andreas Libavius, Daniel Sennert,
and Robert Boyle have been exposed elsewhere: in a word, these authors were all
deeply cognizant of the literature of medieval alchemy, as were most of the chymists
of the sixteenth and seventeenth centuries.39 But how did the chymical atomism of
these authors relate to the works described in the present article?
The most basic feature of chymical atomism lay in the empirical realization that
the materials operated upon in the laboratory could and often did retain their identity even after having lost their previously sensible characteristics.40 By the same
39
40
William R. Newman, Atoms and Alchemy: Chymistry and the Experimental Origins of the Scientific Revolution
(Chicago: University of Chicago Press, 2006).
For the term chymical atomism, see William R. Newman, The Significance of Chymical Atomism, Early
Science and Medicine 14 (2009): 24864. There were other significant features of chymical atomism of course,
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WILLIAM R. NEWMAN
token, seemingly homogeneous materials such as metals, blood, and wine could
consist of invisibly small particles of different types whose heterogeneity normally
eluded the senses and could only be revealed by analysis. This position, which
seems so natural and obvious to the modern mind, ran directly contrary to the theories of mixture upheld by Thomas Aquinas, Duns Scotus, and their many followers
in the medieval and early modern universities. Building primarily on Aristotles De
generatione et corruptione, but also employing his Metaphysics and Physics, the
Thomists and Scotists typically claimed that the ingredients going into a perfect
mixture lost their identity in the process of being mixed.41 Hence, the persistence
of metallic ingredients such as sulphur and mercury in a fully formed metal, not
to mention the four elements out of which the sulphur and mercury were supposed
to be made, would have violated the notion that the metals were perfect mixts. As a
result there was often an underlying, and sometimes explicit tension between Latin
alchemists and the mixture theorists of the Thomist and Scotist persuasions. This is
not to say that the main traditions of medieval alchemy were anti-Aristotelian in any
sense; as I have argued elsewhere, numerous Latin alchemists with scholastic training built on Book IV of Aristotles Meteorology to develop a corpuscular matter
theory that allowed for the persistence of robust sulphurous and mercurial particles
within the fully formed metals.42
In the course of the Middle Ages, alchemists built on their understanding of the
persistence of ingredients during laboratory analysis and synthesis in a way that
led, eventually, to demonstrative proofs of atomism, as in the reductions to the
pristine state (usually analysis after synthesis) popularized by the seventeenthcentury Wittenberg physician Daniel Sennert. The robust persistence of quicksilver
within compounds such as cinnabar, corrosive sublimate, and red precipitate led
Sennert to stress that it could always be reduced to its metallic character despite
being polytropos and polymorphos.43 The same phenomenon led Robert Boyle
to speak of mercury compounds as wearing disguises or masks the ordinary laboratory processes known to vulgar, unskilled chymists did not alter the
fundamental nature of the metal hidden behind its new illusory appearance.44
40
41
42
43
44
Continued
such as the alchemists frequent emphasis on laboratory analysis as a means of arriving at the constituents of mixed
bodies and the nascent acceptance of the negative-empirical principle, for which see the article cited.
For the diverse spectrum of medieval mixture theories, see Anneliese Maier, An Der Grenze Von Scholastik Und Naturwissenschaft (Roma: Edizioni di Storia e Letteratura, 1952, 2. Auflage).
The development and influence of this theory is the subject of Newman, Atoms and Alchemy.
Daniel Sennert, De chymicorum cum Aristotelicis et Galenicis consensu ac dissensu (Wittenberg: Schrer, 1629),
41819.
Robert Boyle, Essay of the Holy Scriptures, in The Works of Robert Boyle, ed. Michael Hunter and Edward
B. Davis (London: Pickering & Chatto, 19992000), vol. 13, 205: But all this is Nothing to the numerous Disguizes
that Proteus, Mercury will suffer himselfe to be maskd in, without devesting his Nature. For tho Chymists have
found wayes to disguise Quicksilver into almost as many formes as the Peripatetickes have ascribd to their
Materia Prima, & seeme to have soe perfectly changd it into Oyles, Salts, Fumes, Butters, Plasters, Powders, &
what not that they oftentimes believe themselves, when they boast those Appearing for Radicall Transformations;
yet doth that Inscrutable Prodigie of Nature, (what ever Chymists are pleasd to thinke to the Contrary) still
remayne Reall & untransmuted Mercury; & but too often manifests himselfe to be so, to their Cost who fondly
thinke, that for having forcd him from his outward Scheme, they have robbd him of his almost inaccessible Nature.
343
45
46
47
48
49
It is an irony of history that among the very mercury compounds derided by Boyle one would probably find corrosive
sublimate, which the medieval alchemists examined in this article viewed as a purer form of the material than running
quicksilver. This of course represents the natural progress by which chemical products considered great magisteries
and secrets in the thirteenth century and before came eventually to be viewed as vulgar and commonplace. Despite
their differing views of mercury compounds, however, Boyle and the alchemists examined here agreed on one fundamental pointthat the mercury had not been transmuted: it had either been purified of undesirable components (in
High Medieval alchemy) or it had been compounded (Boyle).
I do not mean simply modern chemical compounds here, of course. As we have seen, it was typical of the alchemists
surveyed in this article to view even materials that we now consider elemental, such as the metals, to be compounds.
One should note that the Latin noun for compound (compositio) implied a juxtaposition of substances in actu, not
a purely homogeneous mixture. For discussion of this, see Newman, Atoms and Alchemy, 2744.
In addition to the sources surveyed in this article, excellent examples of such techniques for removing or adding
mercury and sulphur can be found in Book 3 of the Summa perfectionis of Geber, the classic work of transmutational
alchemy in the High Middle Ages. See Newman, Summa perfectionis of pseudo-Geber, 74049.
For an overview of these genres, see William Eamon, Science and the Secrets of Nature: Books of Secrets in Medieval
and Early Modern Culture (Princeton: Princeton University Press, 1994). See also the still useful Ernst Darmstaedter,
Berg-, Probir- und Kunstbchlein, Mnchener Beitrge zur Geschichte und Literatur der Naturwissenschaften und
Medizin 2/3 (1926): 101206.
One should add that the atomistic demonstrations of Sennert, Boyle, and their chymical peers received a major boost
from their use of the mineral acids, which were of course largely or wholly unavailable in the thirteenth century.
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WILLIAM R. NEWMAN
Acknowledgements
I thank Sbastien Moureau and the other anonymous referee of this article for their
helpful comments and suggestions throughout.
Notes on contributor