Date: 4/4/2003

Reactor: quartz 300mm Power supply: Auto電氣

Exp. Cond. Reacting area: Silver coating 200 mm (= 6.0 I.D)
sus spring 4.0 mm O.D
Voltage 2.8 kV
Current 30.2 mA
Power(ave) 60 W
Frequency 20 KHz
Flowrate CH4 = 15 ml/min
CO2 = 15 ml/min
Reaction time 20 min
MFC set point CH4 = 12.6 sccm
CO2 = 13.2 sccm
Flowrate
29.97 ml/min
(Total Feed)
Flowrate
31.57 ml/min
(Product)

Input Exp. Data Exp. Results

Peak Area Volume Moles Conversion(%)
TCD 1.0000000E+00 CC
CH4(Feed) 2.47283E+05 4.878E-01 2.377E-05
CH4(product) 1.73474E+05 3.422E-01 1.668E-05 26.083
CO2(Feed) 7.37540E+04 4.597E-01 2.240E-05
CO2(product) 5.94920E+04 3.708E-01 1.807E-05 15.009
H2 2.10431E+05 1.315E-01 6.406E-06
CO 1.70780E+04 1.101E-01 5.366E-06
FID 5.00000E-01 CC
CH4(Feed) 4.04878E+03 5.637E-01 2.747E-05
CH4(product) 2.73787E+03 3.812E-01 1.858E-05 28.749
C2H2 3.10330E+00 2.201E-04 1.073E-08
C2H4 1.21203E+01 8.308E-04 4.049E-08
C2H6 2.58073E+02 1.698E-02 8.275E-07
C3H4 0.00000E+00 0.000E+00 0.000E+00
C3H6 0.00000E+00 0.000E+00 0.000E+00
C3H8 9.01763E+01 3.790E-03 1.847E-07
I-C4H10 1.12035E+01 3.333E-04 1.624E-08
n-C4H10 2.35737E+01 7.109E-04 3.464E-08
sum
Volume Factor 1.054

Calibration D.T. (2002.12) gas 1ml를 mol로 환산

TCD (1.00CC) Peak area Moles Area/mole retention time
CH4 5.06926E+05 0 1.0403E+10 7.496
CO2 1.60446E+05 0 3.2925E+09 29.339
H2 1.60073E+06 0 3.2848E+10 2.624
CO 1.55099E+05 0 3.1828E+09 14.435
FID (0.50CC) Peak area Moles Area/mole
CH4 7.18208E+03 0 7.3691E+07 2.620
C2H2 1.40970E+04 0 1.4464E+08 4.660
C2H4 1.45888E+04 0 1.4969E+08 4.870
C2H6 1.51984E+04 0 1.5594E+08 5.860
C3H4 2.11416E+04 0 2.1692E+08 16.770
C3H6 2.36119E+04 0 2.4227E+08 14.180
C3H8 2.3795E+04 0 2.4415E+08 15.620
I-C4H10 3.36115E+04 0 3.4487E+08 25.650
n-C4H10 3.31593E+04 0 3.4023E+08 27.610

Retention time 9.4 sec

반응존의 실제 부피: 5.6 cm3

spring 반지름: 2 mm
spring 평균반지름: 1.85 mm
사용된 촉매의 질량: 1g
들어간 촉매의 측정된 부피: 0.9 cm3
oscilloscope (1:10인 경우)
voltage(RMS) 2.424 kV
current(RMS) 44.61 mA
power(RMS) W
Frequency 20.00kHz

0.33 hr

selectivity(%) selectivity(%) yield(%)

(without f) (with facter)

70.588 54.431 14.6

59.124 55.450 12.2

0.236 0.222 0.02

0.892 0.837 0.09
18.235 17.102 1.89
0.000 0.000 0.00
0.000 0.000 0.00
6.105 5.725 0.42
0.716 0.671 0.04
1.527 1.432 0.08
27.711 25.989
Date: 4/4/2003
Reactor: quartz 300mm Power supply: Auto電氣
Exp. Cond. Reacting area: Silver coating 200 mm (= 6.0 I.D)
sus spring 4.0 mm O.D
Voltage 3 kV
Current 39.2 mA
Power(ave) 80 W
Frequency 20 KHz
Flowrate CH4 = 15 ml/min
CO2 = 15 ml/min
Reaction time 20 min
MFC set point CH4 = 12.6 sccm
CO2 = 13.2 sccm
Flowrate
29.97 ml/min
(Total Feed)
Flowrate
32.00 ml/min
(Product)

Input Exp. Data Exp. Results

Peak Area Volume Moles Conversion(%)
TCD 1.0000000E+00 CC
CH4(Feed) 2.47283E+05 4.878E-01 2.377E-05
CH4(product) 1.46360E+05 2.887E-01 1.407E-05 36.797
CO2(Feed) 7.37540E+04 4.597E-01 2.240E-05
CO2(product) 5.52520E+04 3.444E-01 1.678E-05 20.003
H2 2.79687E+05 1.747E-01 8.514E-06
CO 2.27480E+04 1.467E-01 7.147E-06
FID 5.00000E-01 CC
CH4(Feed) 4.04878E+03 5.637E-01 2.747E-05
CH4(product) 2.27940E+03 3.174E-01 1.547E-05 39.882
C2H2 4.64250E+00 3.293E-04 1.605E-08
C2H4 1.36099E+01 9.329E-04 4.546E-08
C2H6 3.14475E+02 2.069E-02 1.008E-06
C3H4 0.00000E+00 0.000E+00 0.000E+00
C3H6 4.63510E+00 1.963E-04 9.566E-09
C3H8 1.38079E+02 5.803E-03 2.828E-07
I-C4H10 2.43259E+01 7.237E-04 3.527E-08
n-C4H10 3.48201E+01 1.050E-03 5.117E-08
sum
Volume Factor 1.068

Calibration D.T. (2002.12) gas 1ml를 mol로 환산

TCD (1.00CC) Peak area Moles Area/mole retention time
CH4 5.06926E+05 0 1.0403E+10 7.496
CO2 1.60446E+05 0 3.2925E+09 29.339
H2 1.60073E+06 0 3.2848E+10 2.624
CO 1.55099E+05 0 3.1828E+09 14.435
FID (0.50CC) Peak area Moles Area/mole
CH4 7.18208E+03 0 7.3691E+07 2.620
C2H2 1.40970E+04 0 1.4464E+08 4.660
C2H4 1.45888E+04 0 1.4969E+08 4.870
C2H6 1.51984E+04 0 1.5594E+08 5.860
C3H4 2.11416E+04 0 2.1692E+08 16.770
C3H6 2.36119E+04 0 2.4227E+08 14.180
C3H8 2.3795E+04 0 2.4415E+08 15.620
I-C4H10 3.36115E+04 0 3.4487E+08 25.650
n-C4H10 3.31593E+04 0 3.4023E+08 27.610

Retention time 9.4 sec

반응존의 실제 부피: 5.6 cm3

spring 반지름: 2 mm
spring 평균반지름: 1.85 mm
사용된 촉매의 질량: 1g
들어간 촉매의 측정된 부피: 0.9 cm3
oscilloscope (1:10인 경우)
voltage(RMS) 2.617 kV
current(RMS) 51.11 mA
power(RMS) W
Frequency 20.00kHz

0.33 hr

selectivity(%) selectivity(%) yield(%)

(without f) (with facter)

68.735 51.973 19.7

57.698 54.667 16.5

0.259 0.245 0.04

0.734 0.695 0.11
16.280 15.425 2.33
0.000 0.000 0.00
0.232 0.220 0.02
6.848 6.489 0.65
1.139 1.079 0.08
1.652 1.566 0.12
27.144 25.718
Date: 4/4/2003
Reactor: quartz 300mm Power supply: Auto電氣
Exp. Cond. Reacting area: Silver coating 200 mm (= 6.0 I.D)
sus spring 4.0 mm O.D
Voltage 3.5 kV
Current 47.3 mA
Power(ave) 100 W
Frequency 20 KHz
Flowrate CH4 = 15 ml/min
CO2 = 15 ml/min
Reaction time 20 min
MFC set point CH4 = 12.6 sccm
CO2 = 13.2 sccm
Flowrate
29.97 ml/min
(Total Feed)
Flowrate
32.26 ml/min
(Product)

Input Exp. Data Exp. Results

Peak Area Volume Moles Conversion(%)
TCD 1.0000000E+00 CC
CH4(Feed) 2.47283E+05 4.878E-01 2.377E-05
CH4(product) 1.27930E+05 2.524E-01 1.230E-05 44.310
CO2(Feed) 7.37540E+04 4.597E-01 2.240E-05
CO2(product) 5.23750E+04 3.264E-01 1.591E-05 23.557
H2 3.25210E+05 2.032E-01 9.900E-06
CO 2.64090E+04 1.703E-01 8.298E-06
FID 5.00000E-01 CC
CH4(Feed) 4.04878E+03 5.637E-01 2.747E-05
CH4(product) 1.98507E+03 2.764E-01 1.347E-05 47.222
C2H2 1.39118E+01 9.869E-04 4.809E-08
C2H4 1.67215E+01 1.146E-03 5.586E-08
C2H6 3.32171E+02 2.186E-02 1.065E-06
C3H4 0.00000E+00 0.000E+00 0.000E+00
C3H6 6.59320E+00 2.792E-04 1.361E-08
C3H8 1.55766E+02 6.546E-03 3.190E-07
I-C4H10 3.31393E+01 9.860E-04 4.805E-08
n-C4H10 4.15839E+01 1.254E-03 6.111E-08
sum
Volume Factor 1.076

Calibration D.T. (2002.12) gas 1ml를 mol로 환산

TCD (1.00CC) Peak area Moles Area/mole retention time
CH4 5.06926E+05 0 1.0403E+10 7.496
CO2 1.60446E+05 0 3.2925E+09 29.339
H2 1.60073E+06 0 3.2848E+10 2.624
CO 1.55099E+05 0 3.1828E+09 14.435
FID (0.50CC) Peak area Moles Area/mole
CH4 7.18208E+03 0 7.3691E+07 2.620
C2H2 1.40970E+04 0 1.4464E+08 4.660
C2H4 1.45888E+04 0 1.4969E+08 4.870
C2H6 1.51984E+04 0 1.5594E+08 5.860
C3H4 2.11416E+04 0 2.1692E+08 16.770
C3H6 2.36119E+04 0 2.4227E+08 14.180
C3H8 2.3795E+04 0 2.4415E+08 15.620
I-C4H10 3.36115E+04 0 3.4487E+08 25.650
n-C4H10 3.31593E+04 0 3.4023E+08 27.610

Retention time 9.4 sec

반응존의 실제 부피: 5.6 cm3

spring 반지름: 2 mm
spring 평균반지름: 1.85 mm
사용된 촉매의 질량: 1g
들어간 촉매의 측정된 부피: 0.9 cm3
oscilloscope (1:10인 경우)
voltage(RMS) 2.812 kV
current(RMS) 56.44 mA
power(RMS) W
Frequency 20.00kHz

0.33 hr

selectivity(%) selectivity(%) yield(%)

(without f) (with facter)

67.410 50.590 23.1

56.497 54.126 19.3

0.655 0.627 0.11

0.761 0.729 0.13
14.504 13.895 2.48
0.000 0.000 0.00
0.278 0.266 0.03
6.516 6.243 0.74
1.309 1.254 0.11
1.664 1.595 0.14
25.686 24.608
Date: 4/4/2003
Reactor: quartz 300mm Power supply: Auto電氣
Exp. Cond. Reacting area: Silver coating 200 mm (= 6.0 I.D)
sus spring 4.0 mm O.D
Voltage 3.9 kV
Current 61.4 mA
Power(ave) 129 W
Frequency 20 KHz
Flowrate CH4 = 15 ml/min
CO2 = 15 ml/min
Reaction time 20 min
MFC set point CH4 = 12.6 sccm
CO2 = 13.2 sccm
Flowrate
29.97 ml/min
(Total Feed)
Flowrate
32.73 ml/min
(Product)

Input Exp. Data Exp. Results

Peak Area Volume Moles Conversion(%)
TCD 1.0000000E+00 CC
CH4(Feed) 2.47283E+05 4.878E-01 2.377E-05
CH4(product) 1.06951E+05 2.110E-01 1.028E-05 52.755
CO2(Feed) 7.37540E+04 4.597E-01 2.240E-05
CO2(product) 4.88980E+04 3.048E-01 1.485E-05 27.579
H2 3.87328E+05 2.420E-01 1.179E-05
CO 3.10350E+04 2.001E-01 9.751E-06
FID 5.00000E-01 CC
CH4(Feed) 4.04878E+03 5.637E-01 2.747E-05
CH4(product) 1.62703E+03 2.265E-01 1.104E-05 56.103
C2H2 2.39571E+01 1.699E-03 8.282E-08
C2H4 2.09108E+01 1.433E-03 6.985E-08
C2H6 3.37095E+02 2.218E-02 1.081E-06
C3H4 0.00000E+00 0.000E+00 0.000E+00
C3H6 9.83190E+00 4.164E-04 2.029E-08
C3H8 1.74508E+02 7.334E-03 3.574E-07
I-C4H10 4.30177E+01 1.280E-03 6.237E-08
n-C4H10 5.18447E+01 1.564E-03 7.619E-08
sum
Volume Factor 1.092

Calibration D.T. (2002.12) gas 1ml를 mol로 환산

TCD (1.00CC) Peak area Moles Area/mole retention time
CH4 5.06926E+05 0 1.0403E+10 7.496
CO2 1.60446E+05 0 3.2925E+09 29.339
H2 1.60073E+06 0 3.2848E+10 2.624
CO 1.55099E+05 0 3.1828E+09 14.435
FID (0.50CC) Peak area Moles Area/mole
CH4 7.18208E+03 0 7.3691E+07 2.620
C2H2 1.40970E+04 0 1.4464E+08 4.660
C2H4 1.45888E+04 0 1.4969E+08 4.870
C2H6 1.51984E+04 0 1.5594E+08 5.860
C3H4 2.11416E+04 0 2.1692E+08 16.770
C3H6 2.36119E+04 0 2.4227E+08 14.180
C3H8 2.3795E+04 0 2.4415E+08 15.620
I-C4H10 3.36115E+04 0 3.4487E+08 25.650
n-C4H10 3.31593E+04 0 3.4023E+08 27.610

Retention time 9.4 sec

반응존의 실제 부피: 5.6 cm3

spring 반지름: 2 mm
spring 평균반지름: 1.85 mm
사용된 촉매의 질량: 1g
들어간 촉매의 측정된 부피: 0.9 cm3
oscilloscope (1:10인 경우)
voltage(RMS) 3.199 kV
current(RMS) 67.97 mA
power(RMS) W
Frequency 20.00kHz

0.33 hr

selectivity(%) selectivity(%) yield(%)

(without f) (with facter)

68.810 51.354 27.9

56.903 54.583 23.1

0.967 0.927 0.20

0.815 0.782 0.17
12.615 12.100 2.56
0.000 0.000 0.00
0.355 0.341 0.05
6.257 6.001 0.85
1.456 1.396 0.15
1.778 1.706 0.18
24.243 23.254
 Selectivity(%)
Conversion(%) H2/CO
TCD FID
CH4 CO2 ratio H2 C2H2 C2H4 C2H6 C3H4 C3H6 C3H8
CO
60W 26.08 15.01 54.43 59.12 0.24 0.89 18.24 0.00 0.00 6.10
80W 36.80 20.00 51.97 57.70 0.26 0.73 16.28 0.00 0.23 6.85
100W 44.31 23.56 50.59 56.50 0.65 0.76 14.50 0.00 0.28 6.52
129W 52.76 27.58 51.35 56.90 0.97 0.82 12.61 0.00 0.36 6.26

Conversion ratio selectivity

CH4 CO2 H2/CO CO C2H2 C2H4 C2H6 C3H4 C3H6 C3H8 C4H10
60W 26.08 15.01 1.19 59.12 0.24 0.89 18.24 0.00 0.00 6.10 2.24
yield(%) 12.24 0.02 0.09 1.89 0.00 0.00 0.42 0.12
80W 36.80 20.00 1.19 57.70 0.26 0.73 16.28 0.00 0.23 6.85 2.79
yield(%) 16.53 0.04 0.11 2.33 0.00 0.02 0.65 0.20
100W 44.31 23.56 1.19 56.50 0.65 0.76 14.50 0.00 0.28 6.52 2.97
yield(%) 19.35 0.11 0.13 2.48 0.00 0.03 0.74 0.25
129W 52.76 27.58 1.21 56.90 0.97 0.82 12.61 0.00 0.36 6.26 3.23
yield(%) 23.07 0.20 0.17 2.56 0.00 0.05 0.85 0.33

C2 C3
19.36 6.10
2.01 0.42
17.27 7.08
2.47 0.68
15.92 6.79
2.73 0.78
14.40 6.61
2.92 0.89
 Sum
C4H10
2.24 86.84
2.79 84.84
2.97 82.18
3.23 81.15

carbon H2
sum
86.84 70.59
14.62
84.84 68.73
19.69
82.18 67.41
23.08
81.15 68.81
27.90