Industrial & Consumer Specialties

Exactly your paint additive.

Functional Additives for Pigment Preparations, Coating Formulations, and Emulsion Polymers

Regulatory constraints, environmental considerations, and changing customer preferences require constant reformulations. At Clariant, we work closely with our customers to select the right additives to address your economical and ecological concerns and to help boost the performance of your paints, coatings or pigment preparations. Under the brand names DISPERSOGEN, EMULSOGEN, GENAPOL, NIPACIDE and D-FOAMR Clariant offers a broad range of wetting and dispersing agents, compatabilizers, synergists, emulsifiers, biocides and foam control agents.

Dispersing Agents
Trade name Dipsersogen 4387 Chemical composition Anionic surfactant, electrosteric stabilization Application and Properties APE-free, high performance wetting and dispersing of organic and inorganic pigments, reduces viscosity of pigment dispersions, prevents agglomeration APE-free, suitable for organic pigments and carbon blacks, acid form, non neutralized APE-free, zero VOC dispersing agent for most organic pigments APE-free, zero VOC wetting, dispersing and stabilizing agent for organic and inorganic pigments, prevents sedimentation and aglomeration APE-free, low VOC, synergist for regular and micronized inorganic pigments, reduces viscosity and allows higher pigment concentrations Dosage, % 4 30 (organic) 4 10 (inorganic)

Dispersogen LFH Emulsogen TS 200 Dipsersogen UDN

Polymeric dispersing agent with aromatic anchoring groups, anionic Tristyrylphenol ethoxylate Blend of polymeric surfactants, steric stabilization Blend of anionic and cationic components

4 30 5 10

59 13

Dispersogen PSM

Specialty dispersing agents for pigment dispersion

Dispersogen AN 100 Dispersogen PCE Mixture of nonionic and anionic surfactants and humectants Polymeric dispersing agent, anionic APE-free dispersing agent for organic and inorganic pigments in universal colorants APE-free dispersing agent for inorganic pigments including nano-scaled pigments, dosage depends on average particle size of the pigment APE- free, low foaming dispersant for organic pigments and carbon blacks Dispersing agent for organic pigments and carbon blacks in universal colorants APE-free dispersing agent for organic and inorganic pigments in universal colorants, alternative to Hostapal BV conc. Dispersing agent for organic and inorganic pigments in universal colorants 10 30

1 20 6 40 25 - 75 20 - 50 5 40

Dispersogen PSL 100 Comb-shaped polymeric dispersing agent Dispersogen 1728 Dispersogen ECS Hostapal BV conc. Polymeric dispersing agent, anionic Surfactant-based dispersing agent, anionic Tributyl phenol ether sulfate, anionic

continued on next page

Supplementary dispersing agents

Genapol X 1005 Emulsogen EPN 118 Dispersogen SNW Alkyl ethoxylate, 50% active in water Alkyl ethoxylate, 80% active in water Diakyl sulfosuccinate APE-free dispersing agent for organic pigments, prevents thixotropy for critical pigments, e.g. PR 122 APE-free dispersing agent for organic and inorganic pigments Compatibilizes water based pigment dispersion with solvent based coatings, increases dispersion of organic and inorganic pigments in solvent and water based coatings 15 25 20 50 varies based on formulation

Specialty Additives for Paints

Trade name Hostaphat Series Genapol UD 079 Genapol EP 1024 Genapol PN 30 Properties Various phosphate esters based surfactants APE-free rapid wetting agent for waterborne coatings, low dynamic surface tension, 90% active in water APE-free low foaming wetting agent for coatings and pigment preparations, 100% active Low foaming wetting agent and tint strength enhancer for organic pigments and carbon black in aqueous coatings, prevents the flocculation of organic pigments Dosage (% on formula) varies 15 13 0.1 0.3

Humectants and Special Solvents

Trade name Genapol G 260 Polyglykol 400 Polyglykol G Series Dipropylene glycol DME Tetraglyme, Butyldiglyme Chemical composition Glycerol ethoxylate Polyethylene glycol Properties Waterborne pigment preparations with low VOC contents, replacement of ethylene glycol, propylene glycol and low molecular weight glycol ethers, 5-20% on preparation Alternative to ethylene glycol, propylene glycol and low molecular weight glycol ethers Glycerin based ethoxlylate NMP replacement, inert, non-toxic NMP replacement, inert, non-toxic, low VOC

Biocides
Product Nipacide BIT Series Nipacide BIT 10 W Nipacide BK Nipacide TBX Nipacide CMX Nipacide JLP10 Active ingredients 1,2-benzisothiazolin-3-one (BIT) 1,2-benzisothiazolin-3-one (BIT) Hexahydro-1,3,5-tris (2-hydroxyethyl)s-triazine BIT and triazine p-chloro-m-xylenol Silver chloride on titanium dioxide Supply Form Solution, various solvent systems and concentrations Solution in water Solution Solution Solid 20 and 40% Solutions Liquid dispersion, low VOC pH Stability 2 12 2 12 6 10 7 12 4 12 49 3-12 n Bactericide n n n n n n n n n n n Fungicide n n Algaecide

Nipacide IPBC Series 3-iodo-2-propynl butyl carbamate

Defoamers
Trade name D-FOAM-R C113 D-FOAM-R C114 Chemical description Mineral oil-based Mineral oil-based Application and Properties General purpose defoamer for water based latex paints and coatings 100% active defoamer for paints & coatings, good persistence and compatibility, superior bubble-break on rollout Mineral oil-based for easier incorporation in coating formulations. Provides easy incorporation, excellent efficiency and good compatibility in coatings based on a wide variety of synthetic polymers. 0.5 2 Readily dispersible 0.5 2 0.5 2 Dosage (% w/w)

D-FOAM-R C113E and 114E versions of D-FOAM-R C113 and C114 D-FOAM-R C117 D-FOAM-R C330 D-FOAM-R C740 D-FOAM-R C920 Organic Synthetic Organo-silicone emulsion Silicone

Highly effective defoamer for acrylic, acrylic copolymer, and polyvinyl alcohol systems 0.5 2 Highly effective, excellent compatibility in water based coatings, quick knock down and excellent duration in high speed/shear applications, very effective control of microfoam 0.05 0.5 100% active silicone-based anti-foam for solvent-borne and solvent-free epoxy, urethane, and acrylic (UV and EV curable) coatings. 0.01 0.2

www.ics.clariant.com Clariant Corporation Industrial & Consumer Specialties

P.O. Box 866 625 East Catawba Avenue Mount Holly, NC 28120 USA Customer Service: 800.942.7239 [email protected]

We accept no liability whatsoever for any damage resulting from improper conditions or operation of the system. This information is based upon information believed to be reliable and is intended to provide general notes on our products and their uses. It should not therefore be construed as guaranteeing specific properties of the products described or their suitability for a particular application. Any existing industrial property rights must be observed. The quality of our products is guaranteed under our General Conditions of Sale.
2010 Clariant Corporation

Industrial & Consumer Specialties

Exactly your emulsifier.

Functional Additives for Emulsion Polymerization

Clariant offers a broad range of surfactants to be used as emulsifiers in the emulsion polymerization process. Products from the EMULSOGEN, GENAPOL, HOSTAPUR and HOSTAPHAT series allow the control of particle size distribution and foaming properties, improve electrolyte and freeze-thaw stability and reduce grit formation.

Nonionic Emulsifiers
Nonionic emulsifiers contribute to the stability of the polymer latexes in two ways: They reduce the amount of coagulum formed during the polymerization and improve the final latex properties by enhancing the electrolyte and shear stability. Furthermore the presence of non-ionic emulsifiers is beneficial for the freeze-thaw stability of polymer dispersions. Fatty Alcohol Ethoxylates The Emulsogen range serves as efficient emulsifier in the polymerization of pure acrylic, styrene-acrylic and vinyl acetate latexes as well as for the manufacture of styrene-butadiene latexes. The Emulsogen range offers ideal alternatives to the standard nonylphenol ethoxylates (NPEs) used in emulsion polymerization. Product
Genapol X Series Genapol UD Series Emulsogen EPN Series Emulsogen LCN Series

Chemical Composition
C13 Oxo Alcohol with 3 to 100 moles EO C11 Oxo Alcohol with 3 to 11 moles EO Alkyl polyglykol ether with 11 to 40 moles EO Alkyl polyglykol ether with 7 to 40 moles EO

Application and Properties

NPE free non-ionic emulsifier, reduces coagulation, improves freeze thaw stability and electrolyte resistance NPE free non-ionic emulsifier NPE free non-ionic emulsifier, reduces grit level, improves freeze thaw stability, electrolyte resistance and sheer stability NPE free non-ionic emulsifier, improves shear temperature and electrolytic stability

HLB value
7 to 18 9 to 15 15 to 18 13 to 18

Ethylene Oxide Propylene Oxide Block Copolymers These products serve as low foaming emulsifiers in the polymerization of pure acrylic, styrene-acrylic and vinyl acetate latexes. Product
Genapol PF Series Emulsogen 4084

Chemical Composition
EO/PO block copolymers from 10 to 80% EO EO-PO block copolymer with 60% EO

Application and Properties

Low foaming emulsifiers for acrylic, styrene-acrylic and vinyl acetate latexes For polymerization of vinyl acetate, acrylate and styrene/acrylate emulsions, stabilizes rheology and improves electrolyte and shear stability

HLB value
2 to 16
12

Anionic Emulsifiers
Anionic emulsifiers have a strong influence on the polymerization rate and have a direct impact on particle size and particle size distribution. Common types of anionic surfactants used in emulsion polymerization are sulphate esters, either as alkyl sulfates or in the form of alkyl ether sulfates. Sulfate Esters, Sulfonates and Phosphate Esters Product
Emulsogen APS 100 Emulsogen EPA 073 and 078 Hostapur SAS Series

Chemical Composition
Allyl polyoxyalkylene sulfate with 10 moles EO Alkyl ether sulfate with 7 moles EO Secondary alkyl sulfonate

Application and Properties

Anionic copolymerizable emulsifier, Improves the latex stability, reduces grit, improves shelf life and electrolyte stability Good particle size control and narrow particle size distribution, low grit formation during polymerization, 30 and 80% active PVC emulsion polymerization

www.ics.clariant.com Clariant Corporation Industrial and Consumer Specialties Coatings and Construction Chemicals

625 East Cataswba Avenue Mount Holly NC 28120 USA Phone: 800-942-7239 Email: [email protected]

We accept no liability whatsoever for any damage resulting from improper conditions or operation of the system. This information is based upon information believed to be reliable and is intended to provide general notes on our products and their uses. It should not therefore be construed as guaranteeing specific properties of the products described or their suitability for a particular application. Any existing industrial property rights must be observed. The quality of our products is guaranteed under our General Conditions of Sale. 2010 Clariant Corporation