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Practice Problems For Chapter 3: CH CH CHCH CH CH C (CH) CH CH

This document contains 11 practice problems for identifying organic compounds and structures using IUPAC nomenclature. The problems cover naming alkanes, cycloalkanes, functional groups, drawing structural isomers, identifying primary, secondary, tertiary and quaternary carbons, and naming branched alkanes with halogens.

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133 views4 pages

Practice Problems For Chapter 3: CH CH CHCH CH CH C (CH) CH CH

This document contains 11 practice problems for identifying organic compounds and structures using IUPAC nomenclature. The problems cover naming alkanes, cycloalkanes, functional groups, drawing structural isomers, identifying primary, secondary, tertiary and quaternary carbons, and naming branched alkanes with halogens.

Uploaded by

ankitguhesmailbox
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© Attribution Non-Commercial (BY-NC)
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Download as PDF, TXT or read online on Scribd
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Practice Problems for Chapter 3 1. Name the following compounds using IUPAC nomenclature.

2 9 8 7 6 5 4 1

CH 2CH 3
3

CH 3CH 2CHCH 2CH 2CH 2C(CH 3)2 Br


5

7-bromo-3,3-dimethylnonane

CH2CH3
1 2

CH3

4 3

Cis -1-ethyl-3-methylcyclopentane 2. Name the functional groups in the compound at right and draw an arrow from each functional group to its appropriate name
O C H2N carbonyl group O C OH double bond carboxyl group

amino group

3. Draw all nine of the constitutional (structural) isomers of C7H16 in skeletal form 1
C6 +C1 2-methylhexane 3-methylhexane

C5+C1+C1 3,3-dimethylpentane

2,3-dimethylpentane C4+C1+C1+C1

2,4-dimethylpentane

2,2-dimethylpentane

2,2,3-trimethylbutane C5+C2

3-ethylpentane

4. Show the general structure for each functional group below


R = generic alkyl group a) amine R NH2 d) ether R O R b) ester R O R c) aldehyde R H O e) carboxylic acid R C O H f) nitrile R C N O C O C

5. Draw all the structural isomers for alcohols with the formula C5H12O.
alcohols contain the -OH functional group C 5+OH HO CH 2CH 2CH 2CH 2CH 3 C 4+C 1+OH OH CH 3 C CH 2CH 3 CH 3 C 3+C 1+C 1+OH CH 3 CH 3 C CH 2-OH CH 3 OH CH 3 CH CHCH 3 CH 3 CH 3 HO CH 2CH 2CHCH 3 HO CH CHCH CH 2 2 3 CH 3 OH OH

CH 3 CHCH 2CH 2CH 3 CH 3CH 2 CHCH 2CH 3

6. Name the following compounds using IUPAC nomenclature.


CH3 CH2CH3 CH2CH3
6 8 7 4 5 3

CH3CHCHCH2CHCH(CH3)2

3-ethyl-2,5,6-trimethyloctane
CH 3 H H CH 2CH 3

trans-1-ethyl-3-methylcyclohexane

7. Label the carbons in the structure at right as either 1, 2, 3 or 4


2 2 2 1 2 3 4 3 2 2 1

8. Circle each functional group in the structure, below, and connect the circle to the name for the functional group.
cyano group carbonyl group N carboxylate O group C CH3 O oxo group C O double bond O N O CH2 NH CH3 OH O hydroxyl group C OH amino group amido group

carboxyl group

9. Show the IUPAC name for the structure at right.


8 7 CH 3CHCH 3 CH 3

CH 3CHCH 2CH 2CCH 2CH 3 3 6 5 4 CH 3CHCH 3 2 1

3-ethyl-2,3,6,7-tetramethyloctane

10. Identify each carbon, in the structure at right, as 1, 2, 3, or 4.


2 2 2 2 1 3 4 1 1 2

11. Draw, below, all the structural isomers for bromoalkanes with the formula C5H12Br.
C 5+Br Br C 4+C 1+Br Br Br C 3+C 1+C 1+Br Br Br Br Br

Br

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