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Chem 41c Quiz 1

This document contains summaries of two chemistry quizzes assigned by Professor Stoltz in Spring 2011. Both quizzes are closed book/notes and contain 5 multiple choice or short answer questions worth a total of 25 points. The first quiz is due on April 11th and covers reactions including nucleophilic substitution, hydrolysis, and reductions. The second quiz on April 25th also contains reaction prediction and transformation questions.

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Minh Tieu
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54 views6 pages

Chem 41c Quiz 1

This document contains summaries of two chemistry quizzes assigned by Professor Stoltz in Spring 2011. Both quizzes are closed book/notes and contain 5 multiple choice or short answer questions worth a total of 25 points. The first quiz is due on April 11th and covers reactions including nucleophilic substitution, hydrolysis, and reductions. The second quiz on April 25th also contains reaction prediction and transformation questions.

Uploaded by

Minh Tieu
Copyright
© Attribution Non-Commercial (BY-NC)
Available Formats
Download as PDF, TXT or read online on Scribd
Download as pdf or txt
Download as pdf or txt
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Chem 41c Quiz 1

Quiz Grade_________
Stoltz, Spring 2011 April 8, 2011 Due April 11, 2011 9:00 AM You have 30 min to take this quiz. It is closed note, closed book, and no collaboration is allowed. Please do not discuss the quiz with anyone until you receive it back graded. Place a box around your answers. There is no partial credit. The quiz is worth 25 out of 20 points.

1. Provide a reagent or reagents to accomplish the following transformation (5 points)


O O O OH CH2N2, Et2O O or K2CO3, MeI, acetone O O OCH3

Predict the products of each reaction. (5 points each) 2.


OH HCl (1 mol%) Et2O O O CO2H

3.
O MeO MeO H H2C=PPh3 THF MeO MeO

4.
Br 1. Mg, Et2O 2. CO2 (s) 3. H3O+/H2O CO2H

5.
O O O H H O H 1. HS H3O+ Cl 2. Raney Nickel O SH O H H H O

Chem 41c Quiz 3


Stoltz, Spring 2011 April 22, 2011 Due April 25, 2011 9:00 AM You have 30 min to take this quiz. It is closed note, closed book, and no collaboration is allowed. Please do not discuss the quiz with anyone until you receive it back graded. Place a box around your answers. There is no partial credit. The quiz is worth 25 out of 20 points.

Name______________________________________

Chem 41c Quiz 3


Quiz Grade_________
Stoltz, Spring 2011 April 22, 2011 Due April 25, 2011 9:00 AM You have 30 min to take this quiz. It is closed note, closed book, and no collaboration is allowed. Please do not discuss the quiz with anyone until you receive it back graded. Place a box around your answers. There is no partial credit. The quiz is worth 25 out of 20 points.

Predict the products of each reaction. (5 points each) 1.


Et2NH pyridine

Cl

CONEt2

2.
1. Mg, Et2O 2. O Br N OMe O

3. H3O+/H2O

3.
O MeN 1. LiAlH4 2. HCl 3. KOH MeN

4. Provide a reagent or reagents to accomplish the following transformation (5 points)


O O O OH SOCl2 or ClCOCOCl, DMF O O O Cl

5. Provide a mechanism and all of the reasonable organic products having a molecular weight of at least 100 g/mol (hint: there are three!). (TAs will give partial credit).

O O O H H O H O H 1. MeMgBr (>3 equiv) THF, 0 C 2. H3O+, H2O HO H H

OH

OH

2 diastereomers possible

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