Fire Hazard Properties of Flammable Liquids
Fire Hazard Properties of Flammable Liquids
Fire Hazard Properties of Flammable Liquids
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Reaffirmed July 1992 Supersedes: September 1979 and D.S. 7-19S September 1979 Revised September 1998 Page 1 of 106
Table of Contents
Page 1.0 GENERAL INFORMATION ..................................................................................................................... 3 1.1 Scope ................................................................................................................................................ 3 1.2 Purpose .......................................................................................................................................... 3 1.3 Definitions of Fire Hazard Properties .............................................................................................. 3 1.4 Extinguishing Methods .................................................................................................................... 7 1.5 Suggested Hazard Identification ..................................................................................................... 9 1.6 Additional Information .................................................................................................................... 11 1.7 Indexing .......................................................................................................................................... 11 2.0 APPENDIX ............................................................................................................................................ 12 2.1 Labeling Requirements For Hazardous Materials Shipping Containers ....................................... 12 2.2 Chlorinated Solvents ..................................................................................................................... 13
List of Tables
Fire Hazard Properties of Flammable Liquids, Gases, and Volatile Solids Table ........................................ 14
1992 Factory Mutual Engineering Corp. All rights reserved. No part of this document may be reproduced, stored in a retrieval system, or transmitted, in whole or in part, in any form or by any means, electronic, mechanical, photocopying, recording, or otherwise, without written permission of Factory Mutual Engineering Corp.
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NFPA Standard No. 325M-1991 Copyright by NFPA and reprinted by special permission.
The material in this data sheet is copyrighted by the NFPA and has been reprinted by special permission. Factory Mutual (FM) comments and exceptions are included in boldface, following each NFPA section to which they apply. The tables that are part of this NFPA document are included as an attachment to the text. This edition of NFPA 325M, Fire Hazard Properties of Flammable Liquids, Gases and Volatile Solids, was prepared by the Technical Committee on Classification and Properties of Flammable Liquids, released by the Correlating Committee on Flammable Liquids, and acted on by the National Fire Protection Association, Inc. at its fall meeting held November 1214, 1990, in Miami, Florida. It was issued by the Standards Council on January 11, 1991, with an effective date of February 8, 1991, and supersedes all previous editions. The 1991 edition of this document has been approved by the American National Standards Institute. Changes other than editorial are indicated by a vertical rule in the margin of the pages on which they appear. These lines are included as an aid to the user in identifying changes from the previous edition. Vertical rules (identifying revisions) do not appear in this data sheet due to the numbers of revisions from the 1979 version. Origin and Development of NFPA 325M The first edition of NFPA 325M was presented to the Association in 1930. Successively revised and enlarged editions were published in 1935, 1941, 1945, 1947, 1951, 1954, 1960, 1965, 1969, 1977 and 1984. This 1991 edition is an amended version of the 1984 edition. The major change is a complete rewrite of the explanatory material that is presented in Chapter 1. Several new entries were also added, and a number of existing entries have been updated with new or additional data. These are indicated by a vertical rule in the left-hand margin. This document is not a code, standard or recommended practice, as these terms are defined by NFPA. It is only a compilation of basic fire protection properties of various material, prefaced by an explanation of the properties covered. The data contained have been collected from numerous authoritative sources, including the U.S. Bureau of Mines, Factory Mutual Research Corporation, and Underwriters Laboratories, as well as from the manufacturers of the materials. The originating source of the data is on file at NFPA headquarters and may be obtained upon request. The table presented here summarizes available data on the fire hazard properties of about 1,500 substances, listed alphabetically by their chemical name. In addition, about 500 synonyms are listed alphabetically and cross-referenced to their proper entries. The values for any given property are representative and deemed suitable for general use. Where differences exist in reference sources, the value selected for inclusion in this compilation is conservative. Slight differences are to be expected between data sources due to differences in the purity of test samples, minor differences in test apparatus, and minor differences in technique and observation. In almost all cases, these minor variations have little practical significance. Where there is difference of opinion as to the actual value of a property of a given material or where the validity of the data presented is questioned, further tests should then be conducted on representative samples of the specific material in question by a qualified testing laboratory.
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RELATED STANDARDS. There are a number of references to other NFPA standards. In most instances, Factory Mutual has its own corresponding standard that should take precedence. NFPA 325M Fire Hazard Properties of Flammable Liquids, Gases and Volatile Solids 1991 Edition GENERAL INFORMATION 1.1 Scope This manual applies to flammable liquids, flammable gases and volatile flammable solids. 1.2 Purpose The purpose of this manual is to provide the user with basic fire hazard information on the materials covered by the scope. 1.3 Definitions of Fire Hazard Properties
1.3.1 No single fire hazard property, such as flash point or ignition temperature, should be used to describe or appraise the fire hazard or fire risk of a material, product, assembly or system under actual fire conditions. The fire hazard properties given in this manual have been determined under controlled laboratory conditions and may properly be used to measure or describe the response of materials, products, assemblies or systems under these conditions. Properties measured under these conditions may be used as an element of a fire risk assessment only when such assessment takes into account all of the factors that are pertinent to the evaluation of the fire hazard of a given situation. 1.3.2 The pertinent literature seldom mentions the degree of purity of the material being tested; even boiling point or melting point data are frequently missing. These data, if available, would permit judging the purity of the material and, hence, the reliance to be placed on the values reported, particularly with respect to flash point and flammable range. Finally, it must be remembered that there is little industrial use of high purity materials. As a consequence of these considerations, no values of purity are given in this compilation. The melting points and boiling points should be regarded as approximations. 1.3.3 Flash Point. The flash point of a liquid is the minimum temperature at which the liquid gives off sufficient vapor to form an ignitible mixture with air near the surface of the liquid or within the test vessel used. By ignitible mixture is meant a mixture that is within the flammable range (between the upper and lower limits) and, thus, is capable of propagation of flame away from the source of ignition. Some evaporation takes place below the flash point, but not in quantities sufficient to form an ignitible mixture. Flash point applies mostly to flammable and combustible liquids, although certain solids, such as camphor and naphthalene, that slowly volatilize at ordinary room temperature, or certain liquids, such as benzene, that freeze at relatively high temperatures, will exhibit a flash point in the solid state.
The flash points given in this manual are, for the most part, closed cup flash points. Where the only available data is based on open cup tests, this is designated by the initials oc after the entry. In the case of some of the older data in this manual, it could not be determined whether a closed cup or open cup procedure had been used. In these cases, it has been assumed that the data is based on closed cup tests. For further information on the flash point test procedures used, see NFPA 321, Standard on Basic Classification of Flammable and Combustible Liquids. A flammable liquid does not burn itself, but rather the vapors from the liquid burn. The rate at which different liquids vaporize varies greatly, depending on their vapor pressure. Vaporization increases with rises in temperature, and a flammable liquid at elevated temperature is more hazardous than the same liquid at ambient temperature if accidentally released or normally exposed to the atmosphere. Many flammable liquids have flash points at or below room temperatures and are normally covered by a layer of flammable vapors. These flammable vapors can combine with air to form a flammable vapor-air zone near the liquid that will ignite immediately if an ignition source is present.
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Fire Point. The lowest temperature at which a liquid in an open container will give off enough vapors to continue to burn once ignited is the fire point. It is generally slightly above the open-cup flash point.
1.3.4 Ignition Temperature. The ignition temperature of a substance, whether solid, liquid or gas, is the minimum temperature required to cause self-sustained combustion, independently of the heating or heated element. Ignition temperatures observed under one set of conditions may differ markedly from those observed under another set of conditions. For this reason, ignition temperatures should be regarded as approximations.
Some of the variables known to affect ignition temperature are: the percentage of the gas or vapor in the mixture, the shape and size of the test vessel, the rate and duration of heating, the kind and temperature of the ignition source, and catalytic or other effects of materials that may be present. As there are many differences in ignition temperature test methods, such as the size and shape of the test vessel, the material of construction of the test vessel, method and rate of heating, residence time, and method of flame detection, it is not surprising that reported ignition temperatures may differ for the same material. The phrase independently of the heating or heated element should be construed to mean in the absence of a spark or flame. The majority of the data reported in this manual has been obtained by one of two methods: ASTM D286 and ASTM D2155. Both have been withdrawn by the American Society for Testing and Material. ASTM D2155 has been replaced by ASTM E659, Standard Test Method for Autoignition Temperatures of Liquid hemicals. An earlier test method, ASTM D2883, Test Method for Reaction Threshold Temperature of Liquid and Solid Materials, provides for the study of autoignition phenomena at reduced and elevated pressures. Federal Test Method Standard 791B, Method 5050, is another current test method that provides for the measurement of autoignition properties in the same terms used by the ASTM procedures. Previous test methods relied only on visual detection of flame. Consequently, the ignition temperatures obtained by these procedures were the minimum temperatures at which hot-flame ignition occurred. The current test methods employ thermoelectric flame detection, thus permitting the detection of nonluminous or barely luminous reactions that were difficult or impossible to detect by the older procedures. As a result, the following terms have come into use:
Hot-Flame Ignition. A rapid, self-sustaining, sometimes audible gas-phase reaction of the sample or its decomposition products with an oxidant. A readily visible yellow or blue flame usually accompanies the reaction. Cool-Flame Ignition. A relatively slow, self-sustaining, barely luminous gas-phase reaction of the sample or its decomposition products with an oxidant. Cool flames are visible only in a darkened area. Pre-Flame Reaction. A slow, nonluminous gas-phase reaction of the sample or its decomposition products with an oxidant. Catalytic Reaction. A relatively fast, self-sustaining, energetic, sometimes luminous, sometimes audible reaction that occurs as a result of the catalytic action of any substance on the sample or its decomposition products, in admixture with an oxidant. Non-Combustive Reaction. A reaction other than combustion or thermal degradation that is undergone by certain substances when they are exposed to heat. Thermal polymerization is an example of this type of reaction. Reaction Threshold. The lowest temperature at which any reaction of the sample or its decomposition products occurs, for any sample/oxidant ratio. Autoignition Temperature (AIT). The currently accepted term for the Hot-Flame Ignition Temperature. Cool-Flame Reaction Threshold (CFT). The lowest temperature at which cool-flame ignitions are observed for a particular system. Previously undefined. Preflame-Reaction Threshold (RTT). The lowest temperature at which exothermic gas-phase reactions are observed for a particular system. Previously undefined.
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Previously, reported ignition temperatures, including those given in this manual, have corresponded roughly to the autoignition temperature (AIT), provided that proper allowances were made for empirical differences in the measurement technique. In the future, it is expected that CFT and RTT will routinely be reported. Both are lower than AIT and are significant factors to be evaluated in the assessment of the overall ignition risk of a given system. Cool flames are self-sustaining, exothermic ignition reactions that, under proper circumstances, may act as the initiator of more energetic hot-flame reactions. Pre-flame reactions have the capacity, under adiabatic or near adiabatic conditions, to elevate the temperature of a fuel/air mixture to the point where cool- or hot-flame ignition may occur. As an illustration of the effects of test methods, the ignition temperature of hexane, as determined by three different methods, are 437F (225C), 637F (336C) and 950F (510C). The effect of percentage composition is shown by the following ignition temperatures for pentane: 1018.4F (548.4C) at 1.5%, 935.6F (502.4C) at 3.75% and 888.8F (476.3C) at 7.65%. The following ignition temperatures for carbon disulfide demonstrate the effect of the size of the test vessel: 248F (120C) in a 200 ml flask, 230F (110C) in a 1 liter flask and 205F (96C) in a 10 liter flask. The effect of the material of construction of the test vessel is shown by the following ignition temperatures for benzene: 1060F (572C) in a quartz vessel and 1252F (678C) in an iron vessel. The ignition temperature of a combustible solid is influenced by the rate of air flow, rate of heating and size of the sample. Small sample tests have shown that, as the rate of air flow or the rate of heating is increased, the ignition temperature decreases to a minimum value, then increases. Susceptibility to Spontaneous Ignition. Many flammable liquids combine readily with the oxygen in the air at ordinary temperatures and give off heat. When these materials are present in waste, rubbish or other material under conditions in which heat is produced faster than it is dissipated, the temperature rises and ignition may occur.
1.3.5 Flammable (Explosive) Limits. In the case of gases or vapors that form flammable mixtures with air, oxygen or other oxidizers, such as chlorine and nitrous oxide, there is a minimum concentration of the material below which propagation of flame does not occur. Similarly, there is a maximum concentration above which propagation of flame does not occur. These boundary mixtures, which, if ignited, will just propagate flame, are known as the lower and upper flammable or explosive limits and are usually expressed as percent by volume of the material in air (or other oxidant). In popular terms, a mixture below the lower flammable limit (LFL) is too lean to burn, while a mixture above the upper flammable limit (UFL) is too rich to burn.
The values for the flammable limits given in this manual are based on atmospheric temperatures and pressures, unless otherwise indicated. There will be considerable variation in flammable limits at temperatures and pressures above or below ambient. The general effect of an increase in temperature or pressure is to decrease the lower limit and to increase the upper limit, i.e., broaden the range between the two limits. A decrease in the temperature or pressure has the opposite effect. In most cases, the values given in this manual represent the concentration limits over which hot-flame ignitions have been observed. If cool-flame ignitions are considered, wider flammable ranges are observed. Research has shown that flammability limits are not a fundamental combustion property but depend on many variables, including the surface-to-volume ratio of the test vessel, the direction of air flow and the velocity of air flow. In some experiments conducted at laminar flow velocities, the upper limit increased with increasing flow velocity reached a maximum that was independent of the diameter of the test vessel, then decreased as flow became turbulent. The lower limit has been unaffected by air flow rate. ASTM E681 is the current test method for determining flammable limits. However, much of the data were obtained in small diameter tubes with ignition at the bottom so that flame propagation was upward. For most hydrocarbons, this method is appropriate. However, for highly oxygenated, aminated or halogenated materials, larger diameter equipment is required to avoid quenching of the flame. Larger diameter test equipment or more energetic ignition sources may better reflect real world burning conditions. The terms flammable limits and explosive limits are interchangeable. The range of concentration between the lower flammable limit and the upper flammable limit is known as the flammable range, also referred to and synonymous with explosive range. All concentrations of a gas or vapor in air that lie between the flammable limits are ignitible.
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If a flammable vapor or gas-air mixture within the flammable limits is confined and ignited, an explosion results. Many common flammable liquids and gases have very wide explosive ranges. That of carbon disulfide is 1 to 50% and that of hydrogen is 4 to 75%, which shows that only very lean or unusually rich mixtures of these materials in air have no explosion potential.
1.3.6 Specific Gravity. The specific gravity of a substance is the ratio of the weight of that substance to the weight of an equal volume of another substance. In this manual, the other substance is water. The values given in this manual for specific gravity are rounded to the nearest tenth. For materials whose specific gravity is from 0.95 to 1.0, the value is shown as 1.0-. For materials whose specific gravity is from 1.0 to 1.05, the value is given as 1.0+. In a few cases, such as fuel oils, where the percentage composition of the substance varies, specific gravity is given as less than (<) or greater than (>) 1.
Most flammable liquids will float on water where they can burn freely and flow over a large area. Others are heavier than water and water will float on them and extinguish a fire. The specific gravity of a flammable liquid is important in determining the proper type of fire extinguishing agent and whether overflow drains on open tanks of flammable liquids or other special precautions are needed.
1.3.7 Vapor Density. The vapor density of a substance is the ratio of the weight of a volume of pure vapor or gas (no air present) to an equal volume of dry air at the same temperature and pressure. It is calculated as the ratio of the molecular weight of the substance to the molecular weight of air, 29. A vapor density of less than 1 indicates that the substance is lighter than air and will tend to rise in a relatively calm atmosphere. A vapor density of greater than 1 indicates that the substance is heavier than air and may travel along grade level for a considerable distance to a source of ignition and flash back, assuming the gas or vapor is flammable.
The vapors of all flammable liquids are heavier than air. This is the reason why flash fires in flammable vapors often cover large areas and travel long distances along the floor or ground, and why ventilating outlets should be located near the floor level. Many combustible gases, by contrast, are lighter than air and require ventilation from near the ceiling.
1.3.8 Boiling Point. The boiling point of each liquid is given at a pressure of 14.7 psia (760 mm). Where an accurate boiling point is not available for a specific entry or where a specific entry is actually a mixture of components and does not have a constant boiling point, the boiling point given is the 10% distillation point as determined by ASTM D86, Standard Method of Test for Distillation of Petroleum Products.
The lower the boiling point, the more volatile and therefore the more hazardous a flammable liquid.
1.3.9 Melting Point. Melting points are reported in this manual for most materials that melt at 70F (21C) or higher. However, the melting point is not available for some of these materials.
The melting point is important in materials that are solid at ordinary temperatures but assume the characteristics of flammable liquids when melted, such as naphthalene, tallow and similar substances.
1.3.10 Water Solubility. Water solubility data are reported only for those materials for which reliable information is available, due to the lack of uniformity with which water solubility data are reported in the literature, and the conflicting statements that sometimes accompany these data. Where such data is reported in this manual, No indicates that the materials solubility is less than 10 grams per 100 milliliters (ml) of water; Slight indicates solubility is between 10 and 24 grams per 100 ml of water; Yes indicates solubility of 25 or more grams per 100 ml of water.
No, Very Slight, Slight, and Yes are sometimes used without definition in the literature to describe water solubility. In those cases where doubt exists as to a materials solubility in water, tests should be conducted. Information on the degree to which a material is soluble in water is useful in determining effective extinguishing methods and agents. For example, alcohol-resistant fire fighting foams are usually recommended for water-soluble flammable and combustible liquids. Also, fires involving water-soluble liquids can be extinguished by dilution with water, although this method is not commonly used because of the amount of water needed to dilute most flammable liquids to the point of noncombustibility and because of the danger of frothing if the liquid is heated to the boiling point of water, 212F (100C).
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Water solubility may also be referred to as water miscibility. When mixed with water, liquids that are water-miscible are conductors of electricity and cannot accumulate static charges. 1.4 Extinguishing Methods
1.4.1 General. The extinguishing methods commonly used for fires involving flammable liquids are suitable for use on fires involving most of the materials listed in this manual. Carbon dioxide, dry chemical, foam, and vaporizing liquid extinguishing agents have all been found to be suitable for use on flammable liquid fires of moderate size, such as in dip tanks or small spills of no appreciable depth. The following comments apply to other extinguishing methods that have been found effective for the control or extinguishment of some flammable liquid fires.
Water spray or fog can be particularly effective on fires involving flammable liquids and volatile solids whose flash points exceed 100F (37.8C). However, with liquids whose flash points exceed 212F (100C), frothing may occur. For information on the installation of water spray protection for flammable and combustible liquids, see NFPA 15, Standard for Water Spray Fixed Systems for Fire Protection. Although fires in liquids having flash points below 150F (66C) may be extinguished with water spray under certain conditions, FM recognizes water spray only for liquids having flash points at or above 150F (66C). Automatic sprinklers are similar to water spray systems in extinguishing effectiveness. Their principal value is in absorbing the heat from the fire and keeping the surroundings cool until the flammable liquids fire either burns out or is extinguished by other means. Automatic sprinklers have a good record of fire control in garages, in paint and oil rooms, and in storage areas where liquids are kept in closed containers. In some industries that use water-soluble liquids, such as the distilled spirits industry, sprinkler systems have been used to achieve protection and extinguishment with excellent results. Where automatic sprinklers are used to protect open tanks, overflow drains are necessary to prevent sprinkler discharge from overflowing the tank and spreading burning liquid to others parts of the property. For further information on automatic sprinklers, see NFPA 13, Standard for the Installation of Sprinkler Systems. FM does not equate sprinklers to water spray in extinguishing effectiveness. Standard sprinkler systems will usually extinguish fire in liquids having flash points above 200F (93C). Although both standard sprinklers and water spray-nozzles will not normally extinguish fires in low flash point liquids, these devices will reduce the intensity of burning and protect buildings and equipment from severe damage. Hose streams, both spray and straight streams, are frequently used to cool tanks, containers and equipment from the heat of an exposing fire. They are also used for washing burning spills away from areas where the burning liquid could ignite other material. However, hose streams may also spread and extend the spill fire, if improperly used. Also, hose streams applied to open containers of burning liquid will only serve to spread the fire, either by splashing the burning liquid out of the container or by causing frothing of the liquid. Use of automatic-closing covers on open tanks or equipment containing flammable or combustible liquid is also effective in fire control and extinguishment. The covers should be operated by a fusible link, with a manual override. Such covers are suitable for any size tank except where objects being dipped or conveyor systems may prevent tight closing of the cover.
1.4.2 Selecting an Extinguishing Method. The selection of the extinguishing method used should be made with some degree of caution. Flowing fires, such as may be caused by a leaking overhead pipe with burning liquid on the ground, are always difficult to extinguish. The amount of extinguishing agent and its rate and method of application must be carefully chosen in relation to the size and type of fire anticipated and may call for special engineering judgment. The use of approved extinguishing equipment is also a major consideration.
The chemical and physical properties of the material involved will also affect the choice of extinguishing method and agent. Standard fire fighting foam cannot be used on fires involving water-soluble flammable liquids; the liquid destroys the foam blanket. Those properties that affect extinguishment were taken into consideration when selecting the methods given for each material in the column headed Extinguishing
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Methods. The following information describes the properties of the material that dictate the numerically designated entries in this column. 1
Water May Be Ineffective. This precaution applies to materials that have a flash point below 100F (37.8C). Obviously, the lower the flash point, the less effective the water will be. However, water can be used on low-flash point liquids when applied as a spray to absorb heat and to protect exposed material or structures. Much of the effectiveness of using water spray, particularly from hose lines, will depend on the method of application. With proper selection of nozzles, even gasoline spill fire can be extinguished when several coordinated hose streams are used to sweep the flames from the surface of the burning liquid. Water has also been used to extinguish fires involving water-soluble flammable liquids by cooling and diluting the liquid. The distilled spirits industry has been especially successful in using water to control and extinguish fires of this type.
Thus, the phrase water may be ineffective indicates that, although water can be used to cool and protect exposed material, water may not be capable of extinguishing the fire unless used under favorable conditions by experienced fire fighters trained in fighting all types of flammable liquids fires.
Water or Foam May Cause Frothing. This statement applies to liquids having flash points above 212F (100C) and is included only as a precaution. It does not indicate that water or fire fighting foam should not be used. The frothing may be violent and could endanger any fire fighters located too close to the burning liquid, particularly when solid streams of water are directed onto the hot, burning liquid. On the other hand, a carefully applied water spray has frequently been used to achieve extinguishment by deliberately causing frothing only on the surface of the liquid; the foaming action blankets the surface of the liquid and extinguishes the fire by excluding oxygen. This tactic is especially successful with high viscosity liquids. For example, certain asphalts have a low-flash point solvent added for fluidity, but because of the relatively high viscosity, frothing action is able to achieve fire control and extinguishment. Water May Be Used to Blanket Fire. This statement is applicable to those liquids that have a specific gravity of 1.1 or greater and are not water-soluble. However, the water must be gently applied to the surface of the liquid, preferably with a fine spray or fog nozzle. Water May Be Ineffective, Except as a Blanket. This statement is used as a warning for liquids whose flash points are below 100F (37.8C) and applies only to those liquids that have a specific gravity of 1.1 or greater and are not water-soluble. Here again, the water must be gently applied to the surface of the liquid. Alcohol Foam. Alcohol-resistant fire fighting foam is recommended for use on all water-soluble liquids or polar solvent-type liquids, except for those that are only very slightly soluble. Certain judgment factors are introduced, however, since ordinary fire fighting foam may be used on some liquids that are only slightly soluble, particularly if the foam is applied at higher-than-normal application rates. Conversely, some flammable liquids, such as the higher molecular weight alcohols and amines, will destroy alcohol-resistant foams, even when applied at very high rates. Foams should not be used on water-reactive materials.
Some recently developed alcohol-resistant foams have been listed for use on both polar and nonpolar liquids. These multipurpose foams are suitable for use on nearly all flammable liquids except those that are water-reactive and are preferred for flammable liquid fires because they greatly minimize the problems of foam selection. Fire fighting foam suppliers should be consulted for recommendations regarding types of foam and application rates.
Stop Flow of Gas. For fires involving flammable gases, the best procedure is to stop the flow of the gas before attempting extinguishment of the fire. To extinguish the fire while allowing continued flow of the gas is extremely dangerous; an explosive cloud of gas/air mixture may be created that, if ignited, may cause far more damage than the original fire. Extinguishing the flame using carbon dioxide or dry chemical may be desirable to allow immediate access to valves to shut off the flow of gas, but this must be done carefully. In many cases, it will be preferable to allow continued burning, while protecting exposures with water spray, until the flow of gas can be stopped.
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1.5.1 The increased use of chemicals, many of which introduced hazards other than flammability, led to the need for a simple hazard identification system that could be immediately recognized by emergency response personnel. This need led to the development of the NFPA 704 Hazard Identification System, otherwise known as the NFPA 704 diamond. This system is completely described in NFPA 704, Standard System for the Identification of the Fire Hazards of Materials. The system provides simple, readily recognized and easily understood markings that give, at a glance, a general idea of the inherent hazards of the material and the order of severity of these hazards as they relate to fire protection, exposure and control. The systems objectives are to provide an appropriate alert signal and on-the-spot information to safeguard the lives of both public and private emergency response personnel. The system also assists in planning for effective fire fighting operations and may be used by plant design engineers and plant protection and safety personnel.
The system identifies the hazards of a material in terms of three categories: Health, Flammability, and Reactivity. It indicates the order of severity of these hazards by means of a numerical rating of 0, indicating no special hazard, to 4, indicating extreme hazard. The three hazard categories were selected after studying about 35 inherent and environmental hazards of materials that could affect fire fighting operations. The five degrees of hazard were decided upon as necessary to give the required information. Finally, the system had to be relatively simple and readily understood. While the system is basically simple in application, the hazard evaluation required for the use of the system in a specific location must be made by experienced, technically competent persons. Their judgment must be based on factors that encompass a knowledge of the inherent hazards of different materials, including the extent of change in behavior to be anticipated under conditions of fire exposure and control.
1.5.2 Degrees of Hazard. The columns under Suggested Hazard Identification in this manual give the NFPA 704 severity ratings for each of the hazard categories for which information was available. Blank spaces indicate that sufficient information was not available for a severity rating to be assigned. It should be understood that the assignment of the ratings is based on judgment and that extenuating circumstances in plants and processes may dictate a change in any individual rating.
The following commentary on the degrees of hazard are an interpretation of the information contained in NFPA 704, and are specifically related to fire fighting. See NFPA 704 for more detailed information. Note: The hazard identification rating definitions below and the actual ratings in the text are based on definitions from the 1985 edition of NFPA 704. Materials have not been rated using the new definitions appearing in the 1990 edition of NFPA 704.
1.5.3 Health Hazard Rating. In general, the health hazard in fire fighting is that of a single exposure that may vary from a few seconds to as much as an hour. The physical exertion demanded in fire fighting operations or other emergencies may be expected to intensify the effects of any exposure. Only hazards arising out of the inherent properties of the material are considered. The following information on the five degrees of hazard are based on the information in NFPA 704 and relate to the protective equipment normally available to fire fighters.
4 Materials that, on very short exposure, could cause death or major residual injury, including those that are too dangerous to be approached without specialized protective equipment. A few whiffs of the vapor or gas can cause death, or contact with the vapor or liquid may be fatal, if it penetrates the fire fighters normal protective gear. The normal full protective clothing and breathing apparatus available to the typical fire fighter will not provide adequate protection against inhalation or skin contact with these materials. Materials that, on short exposure, could cause serious temporary or residual injury, including those requiring protection from all bodily contact. Fire fighters may enter the area only if they are protected from all contact with the material. Full protective clothing, including self-contained breathing apparatus, coat, pants, gloves, boots, and bands around legs, arms and waist, should be provided. No skin surface should be exposed.
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Materials that, on intense or continued (but not chronic) exposure, could cause temporary incapacitation or possible residual injury, including those requiring the use of respiratory protective equipment that has an independent air supply. These materials are hazardous to health, but areas may be entered freely if personnel are provided with full-face mask, self-contained breathing apparatus that provide complete eye protection. Materials that, on exposure, would cause irritation but only minor residual injury, including those requiring the use of an approved air-purifying respirator. These materials are only slightly hazardous to health and only breathing protection is needed. Materials that, on exposure under fire conditions, offer no hazard beyond that of ordinary combustible material.
1.5.4 Flammability Hazard Rating. Susceptibility to ignition and burning is the basis for assigning the degree of hazard within this category. The method of attacking the fire is influenced by this susceptibility factor. For further information, refer to Section 1-4, Extinguishing Methods. The following information is based on the definitions of Flammability Hazard Rating contained in NFPA 704.
4 This degree includes flammable gases, pyrophoric liquids and Class IA flammable liquids. The preferred method of fire attack is to stop the flow of material or to protect exposures while allowing the fire to burn itself out. This degree includes Class IB and IC flammable liquids and materials that can be easily ignited under almost all normal temperature conditions. Water may be ineffective in controlling or extinguishing fires in such materials. This degree includes materials that must be moderately heated before ignition will occur and includes Class II and IIIA combustible liquids and solids and semi-solids that readily give off ignitable vapors. Water spray may be used to extinguish fires in these materials because the materials can be cooled below their flash points. This degree includes materials that must be preheated before ignition will occur, such as Class IIIB combustible liquids and solids and semi-solids whose flash point exceeds 200F (93.4C), as well as most ordinary combustible materials. Water may cause frothing if it sinks below the surface of the burning liquid and turns to steam. However, a water fog that is gently applied to the surface of the liquid will cause frothing that will extinguish the fire. This degree includes any material that will not burn.
1.5.5 Reactivity Hazard Rating. The assignment of the degree of reactivity hazard is based on the potential of the material to release energy either by itself or when in contact with water. In assigning this rating, fire exposure was considered, along with exposure to shock and pressure. The following information is based on the definitions of Reactivity Hazard Rating contained in NFPA 704.
4 This degree includes those materials that, in themselves, are readily capable of detonation, explosive decomposition or explosive reaction at normal temperatures and pressures. This includes materials that are sensitive to localized mechanical or thermal shock. If a material having this Reactivity Hazard Rating is involved in an advanced or massive fire, the area should be immediately evacuated. This degree includes materials that, in themselves, are capable of detonation, explosive decomposition, or explosive reaction, but require a strong initiating source or heating under confinement. This includes materials that are sensitive to thermal and mechanical shock at elevated temperatures, and pressures and materials that react explosively with water. Fires involving these materials should be fought from a protected location. This degree includes materials that are normally unstable and readily undergo violent chemical change, but are not capable of detonation. This includes materials that can undergo chemical change with rapid release of energy at normal temperatures, and pressures and materials that can undergo violent chemical changes at elevated temperatures and pressures. This also includes materials that may react violently with water or that may form potentially explosive mixtures with water. In advanced or massive
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fires involving these materials, fire fighting should be done from a safe distance or from a protected location. 1 This degree includes materials that are normally stable, but that may become unstable at elevated temperatures and pressures, and materials that will react with water with some release of energy, but not violently. Fires involving these materials should be approached with caution. This degree includes materials that are normally stable, even under fire exposure conditions, and that do not react with water. Normal fire fighting procedures may be used.
1.5.6 Additional Markings. The fourth space in the NFPA 704 rating is reserved for the use of two special symbols: OX, to denote materials that are oxidizing agent, and W, to denote materials that are water-reactive.
1.6 Additional Information
1.6.1 Mixtures with Oxygen. Unless otherwise indicated, all values in this manual are based on tests conducted in normal air. For mixtures involving enriched oxygen atmospheres, the values may differ and an increase in hazard is probable. 1.6.2 Mixtures of Materials. Mixtures of two or more materials may have different fire hazard properties than any of the components. Although it is common practice to base the fire hazard of a mixture on that of the most hazardous component, consideration should be given to testing the mixture itself. 1.6.3 Mists and Froths. In finely divided form, such as a mist or spray, liquids can be ignited at temperatures considerably below their flash point. As in the case of vapors, the droplets of mist or spray must be present at a minimum concentration. Similarly, froths may be ignited at temperatures below the flash point.
1.7 Indexing
1.7.1 The materials in this manual are listed alphabetically by the name considered to be the most common. Other names and synonyms are indexed to this common name. 1.7.2 The following prefixes are considered to be a part of the name of the material. As such, they are generally not hyphenated and are used to alphabetically index the material when they appear at the beginning of the name.
Bis Di Hexa Iso Mono Penta Tetra Tri Tris
1.7.3 The prefix mono is often omitted. Thus, monochlorobenzene is frequently referred to as chlorobenzene. This manual uses the more common form. The alternate form is not given unless it is also frequently used. 1.7.4 The following prefixes are not considered to be part of the name of the material. As such, they are hyphenated, but they are not used to alphabetically index the material.
o (ortho) m (meta) p (para) n (normal) sec (secondary) tert (tertiary) d (dextro) l (levulo) N (nitro) (alpha) (beta) (gamma)
These prefixes may be written out in full, as in paradichlorobenzene. In this manual, they are usually abbreviated. Thus, paradichlorobenzene appears in this manual as p-dichlorobenzene and is indexed under D. In accordance with custom, the prefix n-, for normal, is omitted, unless it appears in the middle of a name.
1.7.5 The prefixes cis and trans may be placed either at the beginning or the end of a name. In this manual, they are always listed at the end.
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2.0 APPENDIX 2.1 Labeling Requirements For Hazardous Materials Shipping Containers The Hazardous Materials Transportation Act charges the Secretary of Transportation with the responsibility to protect the nation adequately against the risks to life and property that are inherent in the transportation of hazardous materials in commerce. This responsibility is met through the issuance and enforcement of the Hazardous Materials Regulations of the Department of Transportation by Air, Rail, Highway, Water and Military Explosives by Water Including Specifications for Shipping Containers, which is currently referred to in the Code of Federal Regulations as Title 49Transportation. These regulations cover labeling, placarding and shipping container specifications for hazardous materials transportation and apply to all such interstate shipments and also to intrastate shipments by common carriers engaged in interstate or foreign commerce. These regulations require labeling of shipping containers with Department of Transportation (DOT) labels that include but are not limited to the following: Red: Flammable liquids with closed-cup flash points less than 141F (60.5C) and flammable compressed gases. Red & White Vertical Stripes: Flammable solids Yellow: Oxidizing materials (e.g., chlorates, permanganates, peroxides, nitrates) and organic peroxides (e.g., benzoyl peroxide, MEK peroxide) White & Black (Half & Half): Corrosive liquids and solids including acids and alkalines Green: Nonflammable compressed gases. Special labels are also required for poisonous substances, explosives, etiologic agents (i.e., biomedical materials), spontaneously combustible materials and radioactive materials. It is important to recognize that this labeling system has many limitations, particularly for evaluating the storage and handling hazards of these materials. The absence of a label does not necessarily mean that the material is nonhazardous. Nor does the presence of a label necessarily provide sufficient information about the hazardous contents or the degree of hazard for some materials. One example is the labeling requirements for flammable/ combustible liquids. A flammable liquid is defined by Title 49 as a liquid with a close-cup flash point less than or equal to 141F (60.5C). A combustible liquid is defined as a liquid with a closed-cup flash point greater than 141F (60.5C) and less than or equal to 200F (93C). A mixture of flammable and combustible liquids is defined as a flammable liquid if more than 1% of the mixture has a flash point less than 141F (60.5C). DOT flammable liquid labels are required by Title 49 for all liquids meeting the above definition. A DOT label is not required when: 1. The container size is limited. Up to 1 gal (4 l) containers do not require labels depending on their packaging. 2. The liquid is a consumer commodity and meets the above criteria for limited quantities. 3. The liquid is an alcoholic beverage with a container size up to 1 gal (4 l). 4. The liquid is an aqueous solution of alcohol with 24% or less alcohol and at least 50% water. This solution is considered a combustible liquid. 5. The liquid has a flash point greater than 141F (60.5C), combustible liquid. The above definition and labeling requirements for flammable liquids highlight the need for careful evaluation of these materials. The DOT labeling ignores combustible liquids and flammable liquids in small containers or consumer commodities. The labeling may also overstate the hazard created by a liquid (e.g., 30% alcoholwater solution is considered a flammable liquid, however, the actual hazard is less than acetone which would have the same DOT label). Also, DOT labels should not be
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used to classify liquids for evaluation with FM data sheets since the definitions are different. Some other examples of the limitations of the DOT labeling system are: 1. Some material shipping containers may require labels that do not indicate recognized hazardous characteristics of the material. One example is anhydrous ammonia. DOT labeling requires a green nonflammable compressed gas label on anhydrous ammonia containers instead of a red flammable gas label. This is due to the definition of a flammable gas in Title 49, (i.e., is ignitable at 14.7 psia [1 bar a] when in a mixture of 13% or less by volume with air.) Anhydrous ammonia has a LEL of 15% and is considered by FM to be a flammable gas. 2. DOT labels do not indicate the degree of hazard for certain classes of materials. For example, all oxidizing materials and organic peroxides are marked with their respective hazard class label, despite the wide variation in hazard among materials within these general hazard classes. 3. DOT labels are not required on containers that are used to transfer materials within a plant. Lack of a label on a container may only indicate it is not shipped off the plant grounds. It may still contain hazardous materials. 2.2 Chlorinated Solvents Some chlorinated solvents presently used in industry have confusing flammability properties. Three specific liquids are trichloroethane, trichloroethylene and methylene chloride. Each of these liquids has a flammable range, however, they do not have flash points. The existence of a flammable range alone would seem to indicate that the liquids could create an explosion hazard when heated. Their chemical structure indicates that they will burn; however, the fire severity (i.e., heat of combustion and heat release rate) is significantly less than that for ordinary hydrocarbons or alcohols. FM loss history does not contain either an equipment or room explosion caused by any of these liquids. Due to their very limited fire severity and the lack of any loss history, these three chlorinated solvents should not be considered as creating a fire or explosion hazard.
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Fire Hazard Properties of Flammable Liquids, Gases, and Volatile Solids Table
Flammable Limits Percent by Vol. Lower
1.6
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
0.8 4.1
Upper
10.4
4.0
60
0.8
1.5
70 (21)
Note: Polymerizes. See Hazardous Chemicals Data. See Acetal. See Aldol. 985 10 (530) 1.21 4.65 582 (306) Note: Melting point 237 (114). 3 1
Acetic Acid, Glacial CH3COOH Acetic Acid, Water Solutions (Ethanoic Acid)
103 (39)
867 (463)
4.0
1.0+
2.1
245 (118)
Yes
Note: See Hazardous Chemicals Data. Note: Ordinary acetic acid is the same as glacial acetic acid with water. The properties of ordinary acetic acid depend upon the strengtn of the solution. In concentrated form its properties approach those of glacial acetic acid. In dilute solution it is nonhazardous. See Isopropyl Acetate. See Methyl Acetate. See Propyl Acetate. See Acetaldehyde. 120 (49) 600 (316) 2.7 10.3 1.1 3.5 284 (140) Note: See Hazardous Chemicals Data. See Ethyl Acetate. See Ethyl Acetate. 365 (185) (oc) o-Acetoacet Anisidide CH3COCH2CONHC6H4OCH3 325 (168) (oc) Acetoacet-para-Phenetide CH3COCH2CONHC6H4OCH2CH3 Acetoacet-ortho-Toluidide CH3COCH2CONHC6H4CH3 m-Acetoacet Xylidide CH3COCH2CONHC6H3(CH3)2 325 (163) Note: Melting point 210-219 (99-104). 320 (160) Note: Melting point 214 (101). 340 (171) (oc) Note: Melting point 197 (92). Acetoacetic Acid, Ethyl Ester Acetoethylamide Acetone CH3COCH3 (Dimethyl Ketone) (2-Propanone) -4 (-20) 869 (465) 2.5 12.8 0.8 See Ethyl Acetoacetate. See N-Ethylacetamide. 2.0 133 (56) Yes 1 5 1 3 0 1.2 Slight 5 2 2 1 0 Decomposes 2 2 1 1 melting point Note: Melting point 187.9 (87). 1.0+ Decomposes 2 2 1 1 1.1@ melting point Note: Melting point 185 (85). 1.1@ 7.0 No 2 2 1 0 Slight 5 2 2 1 0 Yes 5 2 2 1 Yes
Acetic Acid, Isopropyl Ester Acetic Acid, Methyl Ester Acetic Acid, n-Propyl Ester Acetic Aldehyde Acetic Anhydride (CH3CO)2O (Ethanoic Anhydride) Acetic Ester Acetic Ether Acetoacetanilide CH3COCH2CONHC6H5
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See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
0.9 2.9
Upper
12.0
Note: See Hazardous Chemicals Data. 975 (524) 3.0 16.0 0.8 1.4 179 (82) Note: See Hazardous Chemicals Data. 174 (79) 920 (499) 1058 (570) 1.2 5.4 1.0+ 4.1 1.03.9 378 (192) 396 (202) 583 (306) See 2,4-Pentanedione. 734 1.1 2.7 124 Violent Do not Decomuse position water or foam. 3 3 2 No 2 1 No 1 2 0 Yes 5 1 1 0 Yes 1 5 2 3 0
CH3COCl (Ethanoyl Chloride) Acetylene CH CH (Ethine) (Ethyne) Acetylene Dichloride-cis Acetylene Dichloride-trans N-Acetyl Ethanolamine CH3C:ONHCH2CH2OH [N-(2-Hydroxyethyl) acetamide] N-Acetyl Morpholine CH3CONCH2CH2OCH2CH2 Acetyl Oxide Acetyl Peroxide 25% solution in Dimethyl Phthalate (CH3CO)2O2 Acetylphenol Acrolein CH2:CHCHO (Acrylic Aldehyde) Acrolein Dimer (CH2:CHCHO)2
(4) Gas
Note: Low pressure. Acetylene dissolved in acetone in closed cylinders can carry a 2 reactivity. See Hazardous Chemicals Data. See Dichloroethylene-cis. See Dichloroethylene-trans. 355 (179) (oc) 235 (113) See Acetic Anhydride. 1.2 4.1 Explodes on heating Note: See Hazardous Chemicals Data. See Phenyl Acetate. -15 (-26) 428 (220) Unstable Note: See Hazardous Chemicals Data. 118 (48) (oc) Note: See Hazardous Chemicals Data. 1.1 304 (151) Yes 5 1 2 1 2.8 31 0.8 1.9 125 (52) Yes 1 5 3 3 2 Slight 1 2 4 1.1 860 (460) 1.1 304-308 (151-153) @ 10 mm Decomposes Decomposes Yes 5 2 2 1 1 Yes 5 2 1 1 1
820 (438)
2.4
8.0
1.1
2.5
287 (142)
Yes
Note: Polymerizes. See Hazardous Chemicals Data. Acrylic Aldehyde See Acrolein.
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See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
0.8 1.8
Upper
17
Note: Polymerizes. See Hazardous Chemicals Data. Adipic Acid HOOC(CH2)4COOH Adipic Ketone Adiponitrile NC(CH2)4CN 200 (93) (oc) Note: See Hazardous Chemicals Data. Adipoyl Chloride (-CH2CH2COCl)2 (Adipyl Chloride) Adipyldinitrile CN(CH2)4CN (Adiponitrile) (Tetramethylene Dicyanide) Alcohol Aldol CH3CH(OH)CH2CHO (3-Hydroxybutanal) (-Hydroxybuteraldehyde) Allyl Acetate CH3COCH2CH:CH2 Allyl Alcohol CH2:CHCH2OH Allylamine CH2:CHCH2NH2 (2-Propenylamine) Allyl Bromide CH2:CHCH2Br (3-Bromopropene) Allyl Caproate CH3(CH2)4COOCH2CH:CH2 (Allyl Hexanoate) (2-Propenyl Hexanoate) Allyl Chloride CH2:CHCH2Cl (3-Chloropropene) Allyl Chlorocarbonate Allyl Chloroformate CH2:CHCH2OCOCl (Allyl Chlorocarbonate) See Hazardous Chemicals Data. Allyl Diglycol Carbonate Allylene Allyl Ether (CH2:CHCH2)2O (Diallyl Ether) 20 (-7) (oc) 0.8 3.4 See Diethylene Glycol Bis (Allylcarbonate). See Propyne. 203 (95) Slight 5 1 3 3 2 88 (31) 1.1 See Allyl Chloroformate. 4.2 223-237 (106-114) No 5 4 3 3 1 -25 (-32) 737 (485) 2.9 11.1 0.9 2.6 113 (45) No 5 3 3 1 150 (66) 0.9 367-370 (186-188) No 5 1 2 0 30 (-1) 563 (295) 4.4 7.3 72 (22) (oc) 70 (21) -20 (-29) 713 (378) 705 (374) 1.4 4.2 2.2 22 0.8 2.0 2.5 18.0 0.9 2.0 206 (97) Note: See Hazardous Chemicals Data. 128 (53) Note: See Hazardous Chemicals Data. 160 (71) No 5 4 3 3 1 Yes 1 5 3 3 1 Yes 1 5 3 3 0 705 (374) 0.9 3.45 150 (66) (oc) 482 (250) See Ethyl Alcohol, Methyl Alcohol, Denatured Alcohol, etc. 1.1 3.0 174-176 (79-80) @ 12 mm Decomposes @ 176 (80) 219 (104) No 5 1 1 3 0 Yes 5 3 2 2 199 (93) (oc) 0.96 3.73 162 (72) 257-262 (125-128) @ 11 mm 563 (295) No 4 2 5 2 2 0 1.0385 (196) 788 (420) 1.37 5.04 509 (265) @ 100 mm See Cyclopentanone. 563 (295) Slight 5 4 2 0 No 1 0
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See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
1.1
See Mustard Oil. See 1,4-Hexadiene. See 1,2,3-Trichloro Propane. 1.2 6.05 243 (117.5) See Vinyl Allyl Ether. See Picoline-alpha. See Aniline. See 2-Biphenylamine. See Butylamine. 0.9 3.1 352 (178) See Cyclohexylamine. See Decylamine. See Ethylamine. See Ethanolamine. See p-Phenetidine. See Ethanolamine. 695 (368) 1.0 1.04.5 4.4 1.0+ 470 (243) 395.6 (202.8) 432 (222) See Heptylamine. See 1-Amino-2-Propanol. See 1,3-Dimethylbutylamine. 0.9 3.0 329 (165) See Octylamine. See sec-Amylamine. See p-Phenetidine. 1.1 423 (217) @ 100 mm < 1.0 363-367 (184-186) 705 (374) 1.02.6 320 (160) Yes 5 2 2 0 Yes 5 3 2 0 Yes 5 2 2 1 0 Yes 5 2 2 0 Yes 5 2 2 0 Yes Yes 5 2 5 2 2 0 2 1 0 Yes 5 2 2 0 1 3 3 2
0.9
5.4
Yes
1.0-
438 (226)
Yes
5 2
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See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
0.7@ -33C 0.6
Upper
28
This gas is 1 instead of 4 because it is hard to burn. See Amyl Phenyl Ether. 0.9 4.5 300 (149) Slight 1 5 1 3 0
Amoxybenzene Amyl Acetate CH3COOC5H11 (1-Pentanol Acetate) Comm. sec-Amyl Acetate CH3COOCH(CH3)(CH2)2)CH3 (2-Pentanol Acetate) Amyl Alcohol CH3(CH2)3CH2OH (1-Pentanol) sec-Amyl Alcohol CH3CH2CH2CH(OH)CH3 (Diethyl Carbinol) Amylamine C5H11NH2 (Pentylamine) sec-Amylamine CH3(CH2)2CH(CH3)NH2 (2-Aminopentane) (Methylpropylcarbinylamine) p-tert-Amylaniline (C2H5)(CH2)2CC6H4NH2 Amylbenzene C6H5C5H11 (Phenylpentane) Amyl Bromide CH3CH2CH2CH2CH2Br (1-Bromopentane) Amyl Butyrate C5H11OOCC3H7 Amyl Carbinol Amyl Chloride CH3(CH2)3CH2Cl (1-Chloropentane) tert-Amyl Chloride CH3CH2CCl(CH3)CH3 Amyl Chlorides (Mixed) C5H11Cl Amylcyclohexane C5H11C6H11 Amylene -Amylene-cis C2H5CH:CHCH3 (2-Pentene-cis) -Amylene-trans C2H5CH:CHCH3 (2-Pentene-trans) Amylene Chloride < -4 (< -20) 0.67 < -4 (< -20) 0.66 38 (3) (oc) 462 (239) 0.8 55 (13) (oc) 653 (345) 0.9 1.5 7.4 1.4 500 (260) 1.6 8.6 0.9 135 (57) 0.9 215 (102) 150 (66) (oc) 90 (32) 1.2 0.80.9 0.9 20 (-7) 0.7 91 (33) 572 (300) 1.2 10.0 @ 212 (100) 1.2 9.0 0.8 0.8 60 (16) 70 (21) 89 (32) 0.9 680 (360) 1.1 7.5
4.5
249 (121)
Slight
1 5
3.0
280 (138)
Slight
3.0
245 (118)
Slight
1 5
(Und. Lab. Class 40-45) 22 0.8 3.0 210 (99) 3.0 198 (92) Yes Yes 1 5 5 1 2 3 0 3 3 0
498-504 (259-262) 5.1 365 (185) 128-9 (53-54) @ 746 mm 5.46 365 (185) See Hexyl Alcohol. 3.7 223 (106) 3.7 187 (86) 185-228 (85-109) 395 (202) See 1 -Pentene. 2.42 99 (37) 2.42 97 (36) See 1,5-Dichloropentane.
No No
3 1
1 2
0 0
No
No
No
No No
3 1
1 1
3 3
0 0
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See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
0.80.9 5.5
0.9 1.0-
4.0 5.5
No Very slight No No
1 1
3 2
0 0
2 2
0 0 2
1 1 3
0 0
0.8
176-257 (80-125)
No
Note: See Hazardous Chemicals Data. Amyl Naphthalene C10H7C5H11 Amyl Nitrate CH3(CH2)4NO3 Amyl Nitrite CH3(CH2)4NO2 Amyl Oleate C17H33COOC5H11 Amyl Oxalate (COOC5H11)2 (Diamyl Oxalate) o-Amyl Phenol C5H11C6H4OH p-tert-Amyl Phenol p-sec-Amylphenol C5H11C6H4OH 2-(p-tert-Amylphenoxy) ethanol C5H11C6H4OCH2CH2OH 2-(p-tert-Amylphenoxy) ethyl Laurate C11H23COO(CH2)2OC6H4C5H11 p-tert-Amylphenyl Acetate CH3COOC6H4C5H11 p-tert-Amylphenyl Butyl Ether C5H11C6H4OC4H9 Amyl Phenyl Ether CH3(CH2)4OC6H5 (Amoxybenzene) p-tert-Amylphenyl Methyl Ether C5H11C6H4OCH3 Amyl Phthalate 210 (99) 0.9 462-469 (239-243) See Diamyl Phthalate. 0 1 0 270 (132) 280 (138) 410 (210) 240 (116) 275 (135) 185 (85) 0.9 5.7 0.9 1.00.9 1.0+ 1.0219 (104) (oc) See Pentaphen. 482-516 (250-269) 567-590 (297-310) 464-500 (240-260) @ 6 mm 507-511 (264-266) 540-550 (282-288) 421-444 (216-229) No 0 2 0 No 2 0 1 0 2 0 1 0 2 0 1 0 No 2 1 1 0 No 2 1 1 0 1.0455-482 (235-250) Slight 5 2 2 1 0 366 (186) 245 (118) 1.0255 (124) (oc) 118 (48) (oc) 410 (210) 0.9 0.9 4.0 220 (104) 392-464 (200-240) @ 20 mm 464-523 (240-273) No 2 0 1 0 No 2 0 1 0 Slight 5 1 2 1.0306-315 (153-157) No 2 2 0 OX 1.0550 (288) No 2 0 1 0
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See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
0.9
1.1 0.9
No No
2 2
0 0
1 1
0 0
0.9
338-356 (170-180)
No
0.9
400-415 (204-213)
No
1.1
334 (168)
0.9
480-500 (249-260)
No
1139 (615)
1.3
1.1
1.0+
3.2
364 (184)
Slight
Note: See Hazardous Chemicals Data. 1.22 4.46 473 (245) Note: Melting point 389 (198). 3 1
2-Anilinoethanol C6H5NHCH2CH2OH (-Anilinoethanol Ethoxyaniline) (-Hydroxyethylaniline) -Anilinoethanol Ethoxyaniline o-Anisaldehyde o-Anisidine H2NC6H4OCH3 (2-Methoxyaniline) Anisole C6H5OCH3 (Methoxybenzene) (Methyl Phenyl Ether) Anol Anthracene (C6H4CH)2 Anthraquinone C6H4(CO)2C6H4 Artificial Almond Oil Asphalt (Cutback)
1.1
547 (286)
Very slight
See 2-Anilinoethanol. See o-Methoxy Benzaldehyde. 244 (118) (oc) 125 (52) (oc) See Cyclohexanol. 250 (121) 365 (185) 1004 (540) 1.44 7.16 0.6 1.24 6.15 644 (340) Note: Melting point 423 (217). 716 (380) Note: Melting point 354 (179). See Benzaldehyde. < 50 (< 10) No 2 0 3 0 No 0 1 0 1 887 (475) 1.03.7 309 (154) No 1 2 0 1.1 435 (224) No 5 2 2 1 0
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See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1) Boiling Point F (C) Identification ExtinWater guishing FlamReacSoluble Methods Health mability tivity
No 2 0 2 0
(min)
(min)
No
Grade SC-70
No
Grade SC-250
Grade SC-800
Grade SC-3000
1.01.1
> 700 (> 371) See Ethyleneimine. Decomposes Note: Melting point 221 (105). See Pyrrole. See Isoamyl Acetate.
No
No
377 (192)
1.1
3.7
355 (179)
No
0.93
4.67
392 (200)
928 (498)
1.2
7.8
0.9
2.8
176 (80)
No
Note: See Hazardous Chemicals Data. See Benzaldehyde. See Benzoyl Chloride. See Petroleum Ether. 477 (247) 1058 (570) 1.27 4.21 0.96 306 (152) 482 (250) Note: Melting point 252 (122). See Benzene. 450 (232) 1040 (560) Note: Melting point 234-237 (112-114). 1.3 3.7 1.0 7.0 <1 140-210 (60-99) Note: Flash point and ignition temperature will vary depending on the manufacturer. Sublimes No 1 2 1 No 1 2 3 0 Slight 2 1
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See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
1.4
1.2
5.0
216 (102)
No
Note: See Hazardous Chemicals Data. 1.2 4.9 387 (197) Decomposes in water. Note: See Hazardous Chemicals Data. Benzyl Acetate CH3COOCH2C6H5 Benzyl Alcohol C6H5CH2OH (Phenyl Carbinol) Benzyl Benzoate C6H5COOCH2C6H5 Benzyl Butyl Phthalate C4H9COOC6H4COOCH2C6H5 (Butyl Benzyl Phthalate) Benzyl Carbinol Benzyl Chloride C6H5CH2Cl (-Chlorotoluene) Benzyl Cyanide C6H5CH2CN (Phenyl Acetonitrile) (-Tolunitrile) N-Benzyldiethylamine C6H5CH2N(C2H5)2 Benzyl Ether Benzyl Mercaptan C6H5CH2SH (-Toluenethiol) Benzyl Salicilate OHC6H4COOCH2C6H5 (Salycilic Acid Benzyl Ester) Bicyclohexyl [CH2(CH2)4CH]2 (Dicyclohexyl) Biphenyl C6H5C6H5 (Diphenyl) (Phenylbenzene) 2-Biphenylamine NH2C6H4C6H5 (2-Aminobiphenyl) Bis (p-tert-Butylphenyl) phenyl Phosphate (C4H9C6H4O)2POOC6H5 Bis [2-(2-Chloroethoxy) ethyl] Ether (CH2ClCH2OCH2CH2)2O (Tetraglycol Dichloride) 482 (250) >250 (>121) 1.2 1.1 842 (450) 235 (113) 1004 (540) 165 (74) 473 (245) 0.7 @ 212 (100) 0.6 @ 232 (111) 5.1 @ 302 (150) 5.8 @ 311 (155) Note: Melting point 158 (70). 5.8 570 (299) Note: Melting point 121 (49). 500-527 (260-275) @ 5 mm 237 (114) Slight 5 2 2 1 0 No 2 1 0 No 2 2 1 0 1.2 489 (254) No 2 2 1 0 0.9 5.7 462 (239) Slight 5 1 2 0 >212 (>100) 1.2 406 (208) No 5 1 1 0 158 (70) 1.06 170 (77) (oc) See Dibenzyl Ether. 4.28 383 (195) 2 2 0.9 405-420 (207-216) 2 2 0 235 (113) (oc) 153 (67) 1085 (585) 1.0+ 1.1 1.1 See Phenethyl Alcohol. 4.4 354 (179) Note: See Hazardous Chemicals Data. 452 (233.5) No 5 2 2 1 0 No 3 2 2 1 298 (148) 390 (199) 896 (480) 1.1 1.1 614 (323) 698 (370) No 2 1 1 0 No 2 1 1 0 195 (90) 200 (93) 860 (460) 817 (436) 1.0+ 1.1 417 (214) 403 (206) Slight Slight 5 2 5 2 2 1 0 1 1 0 Decomposes 3 2 1
7-19N
Page 23
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
1.2 4.9
1.2
425 (218)
See Dichloroisopropyl Ether. 1.1 500 (260) 0.9 394 (201) @ 50 mm 770 (410) See N,N-Diethyl-1,3-Butanediamine. 0.8 537 (281) Slight 5 2 3 1 0 0.9 5 2 2 1 0 No 5 2 2 1 1 0 1 1 0
C6H4[NHCH(CH3)CH2CH2CH(CH3)2]2 (175)
0.9
421 (216) @ 50 mm
Slight
5 2
0.9
408 (209) @ 10 mm
No
5 2
1.0-
No
5 2
0.9
495 (257) @ 50 mm
Slight
5 2
0.8
No
1.1
639
(195) (oc)
(337) See Gas. See Borneol. 1.0+ 413 (212) Sublimes 1.1 259 (126) See Ethyl Alcohol and Water. See Carnauba Wax. 1049 (565) 1.5 5.4 313 (156) See Butyl Bromide. No 3 2 2 0 Decomposes 3 2 1 Decomposes in water. No 2 2 0
7-19N
Page 24
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1) Boiling Point F (C)
592 (311) See Ethyl Bromide. See Methyl Bromide. See Amyl Bromide. See Allyl Bromide. 1.4 1.4 5.9 5.9 359 (182) 363 (184) No No 3 2 2 0 No 3 2 2 0
May be below 80 (27). Gas 788 (420) 2.0 12.0 1.9 24 (-4)
No
Note: Polymerizes. See Hazardous Chemicals Data. Butadiene Monoxide CH2:CHCHOCH2 (Vinylethylene Oxide) Butanal Butanal Oxime Butane CH3CH2CH2CH3 1,3-Butanediamine NH2CH2CH2CHNH2CH3 (1,3-Diaminobutane) 1,2-Butanediol CH3CH2CHOHCH2OH (1,2-Dihydroxybutane) (Ethylethylene Glycol) 1,3-Butanediol 1,4-Butanediol HOCH2CH2CH2CH2OH 250 (121) (oc) Note: Melting point 64-66 (18-19). 2,3-Butanediol CH3CHOHCHOHCH3 2,3-Butanedione CH3COCOCH3 (Diacetyl) 1-Butanethiol CH3CH2CH2CH2SH (Butyl Mercaptan) 2-Butanethiol C4H9SH (sec-Butyl Mercaptan) 1-Butanol 2-Butanol 2-Butanone 2-Butenal 1-Butene CH3CH2CH:CH2 (-Butylene) 2-Butene-cis CH3CH:CHCH3 2-Butene-trans CH3CH:CHCH3 (-Butylene) Gas Gas 617 (325) 615 (324) 1.8 9.7 1.9 1.7 9.0 0.6 1.9 38.7 (4) -34 (1) No 6 1 4 0 6 1 4 0 Gas 725 (385) 1.6 10.0 See Butyl Alcohol. See sec-Butyl Alcohol. See Methyl Ethyl Ketone. See Crotonaldehyde. 1.9 21 (-6) No 6 1 4 0 -10 (-23) 0.8 3.11 185 (85) No 5 1 2 3 0 35 (2) 0.8 3.1 208 (98) Slight 5 1 2 3 0 80 (27) 756 (402) 1.03.0 1.0+ 363 (184) 190 (88) Yes 5 1 3 0 Yes 5 1 1 0 1.0+ See -Butylene Glycol. 3.1 442 (228) Yes 2 5 1 1 0 -76 (-60) 125 (52) (oc) 104 (40) 1.0 3.1 381 (194) Slight 5 1 2 0 550 (287) 0.9 3.0 1.9 8.5 See Butyraldehyde. See Butyraldoxime. 2.0 31 (-1) 289-302 (143-150) Yes 5 3 2 0 No 6 1 4 0 < -58 (< -50) 0.9 2.4 151 (66) 1 2 3 2
7-19N
Page 25
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
1.1 3.0
Note: Melting point 45 (7). See Butenediol. See Crotononitrile. See Butyl Phenyl Ether See Dibutyl Ether. 1.0 509 (265) 0.9 6.1 392-437 (200-225) 445 (229) Yes 5 2 2 1 0 2 2 0
See Diethylene Glycol Bis (2-Butoxyethyl Carbonate). 1.0+ 367-378 (186-192) See 3-Methoxybutyl Acetate. 0.9 1.0797 (425) 1.7 9.8 0.9 4.0 1.7 7.6 0.9 4.0 455-464 (235-240) 531-538 (277-281) 260 (127) 234 (112) 1.05.5 417 (214) 725 (385) 559 (292) 650 (343) 1.4 11.2 0.8 2.6 1.7 9.9 0.9 4.4 0.9 428 (220) 260 (127) Polymerizes 243 (117) No 1 5 1 3 0 No 2 2 2 No 2 2 1 0 Slight Slight Slight 1 5 1 5 5 1 2 0 1 3 0 1 3 0 No 2 2 1 0 2 2 1 0 No 2 0 1 0
761 (405)
0.8
2.6
201 (94)
Slight
1 5
892 (478)
2.4
0.8
2.6
181 (83)
Yes
1 5
594 (312)
1.7
9.8
0.8
2.5
172 (78)
Yes
1 5
0.72 716 (380) 1.7 @ 212 (100) 8.9 @ 212 (100) 0.7
2.52 2.5
3 2
3 4 0
7-19N
Page 26
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
0.9
0.9
5.5
200-221 (93-105)
No
0.9
465 (241)
Slight
5 2
0.8
5.8
0.9
4.6
356 (180)
No
0.9 0.9
4.6 4.6
No No
2 2
2 2
0 0
1.0
No
806 (430) 509 (265) 2.6 @ 212 (100) 6.6 @ 212 (100) 0.9 1.3
7.26 4.7
0 2
1 3 0
5.0
305 (152)
Slight
See N-Butylurethane. 0.8 3.0 237 (114) See Diethylene Glycol Monobutyl Ether. 1.0+ 464 (240) 0.87 3.20 1.8 10.1 0.9 3.2 545 (285) 170 (77) 155 (68) 0.87 3.20 124 (51) 1.1 1.01.0475 (246) 531 (277) 0.8 0.8 453-484 (234-251) 451-469 (233-243) 278-280 (137-138) 352-356 (178-180) 351 (177) 0 0 0 0 No 2 2 1 0 No 2 2 0 No 2 2 1 0 2 3 2 3 No 1 2 3 0 No 2 2 1 0 Slight 1 5 2 3 0
7-19N
Page 27
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
0.8 0.8
480 (250)
0.8
314 (157) 2 2
0 1 1 2 1 1 1
0 0 0 0
1.0-
504 (262)
Yes
5 2
1.0-
Yes
2 5
See Diethylene Glycol Bis (Butyl Carbonate). See 1-Butene. See 2-Butene-trans. See 2-Methylpropene. 1.01 3.10 377 (192) 743 (395) 1.01 3.10 1.0 399 (204) 356 (180) Yes 5 2 0 2 1 1 0 0 2
1.5 1.7
18.3 19
0.83 0.8
2.49 2.2
Slight Yes 5 1
2 2
3 3
2 2
Note: See Hazardous Chemicals Data. See Butyl Oxalate. 0.9 4.0 377 (192) See Dibutyl Ether. See 2-Ethylhexanal. See 1-Hexene. See Ethyl Butyl Ether. 612 (322) 1.7 8.2 0.9 3.5 225 (107) Yes 1 5 2 3 0 Yes 5 1 2 0
1.01 0.9
4.45
0 1
2 4 4 OX
7-19N
Page 28
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
0.9 3.00
5.45 5.0
0 1 2 0
See 1-Butanethiol. See 2-Methyl-2-Propanethiol. 0.9 4.9 325 (163) See Butyl Formate. 0.9 4.0 378 (192) No 1.0+ 0.8 0.9 4.1 277 (136) 486 (252) 440.6-442.4 (227-228) @ 15 mm 1.0472 (244) Explodes on heating. No 1 2 3 4 No 2 0 1 0 No 2 0 1 0 No 2 1 1 0 No 2 1 1 1 1 3 0 3 Yes 5 1 2 0 No 2 2 0
Note: Rapid decomposition at 200 (93). See Hazardous Chemicals Data. 1.0+ Explodes on heating. No 1 3 4 OX
See Hazardous Chemicals Data. tert-Butyl Peroxypivalate diluted with 25 of mineral spirits (CH3)3COOCOC(CH3)3 -(p-tert-Butyl Phenoxy) Ethanol (CH3)3CC6H4OCH2CH2OH -(p-tert-Butylphenoxy) Ethyl Acetate (CH3)3CC6H4OCH2CH2OCOCH3 >155 (> 68) (oc) Note: Rapid decomposition at 90 (32). See Hazardous Chemicals Data. 248 (120) (oc) 324 (162) (oc) 1.0+ 579-585 (304-307) No 2 0 1 0 1.0+ 293-313 (145-156) No 2 0 1 0 Explodes on heating. No 0 3 4 OX
7-19N
Page 29
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
0.9 5.2
No
1 3
1 1
1.1
653 (345)
No
799 (426)
4.5
No No No
1 2 2
2 1 1
3 1 1
0 0 0
0.9 0.9
No No
1 2
1 2
0 2
2 2
1 2
0 0
See Vinyl Butyl Ether. 1.4 0.69 1.86 81 (27) 425 (218) 1.9 12.5 0.8 2.5 169 (76) Note: See Hazardous Chemicals Data. 0.9 280 (138) @ 50 mm 0.9 3.0 306 (152) 830 (443) 2.0 10.0 1.03.0 327 (164) Note: See Hazardous Chemicals Data. See Ethyl Butyrate. See Butyraldehyde. 535 (279) 0.9 5.8 1.05.4 388 (196) Decomposes 5 1 2 1 Yes 5 2 2 0 Slight 5 2 2 0 Slight 5 2 2 0 No 1 2 3 0 4
7-19N
Page 30
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
1.1
See 4-Heptanone. 935 (501) 871 (466) 0.9 0.6 3.5 1.05.24 1.65 0.8 2.4 243 (117) 399 (204) 347-392 (175-200) See Hexanol. 716 (380) 0.8 4.4 0.9 400 (204) 335 (168) Very slight 2 2 0 No 2 2 1 0 No 2 2 0 No 0 2 0 Slight 5 3 3 0
See Caprylaldehyde 1.05.6 384 (196) See Diethylene Glycol Monoethyl Ether. See Phenol. See Carbon Disulfide. 194 (90) 1128 12.5 74 1.0 1.3 50.0 1.3 2.6 115 (46) Note: See Hazardous Chemicals Data. -314 Slight or very slight, 2, 3ml per 100 ml 6 2 4 0 No 4 2 3 0 Decomposes 5 3 2 1
CO Carbon Oxysulfide COS (Carbonyl Sulfide) Carbonyl Sulfide Carnauba Wax (Brazil Wax) Castor Oil (Ricinus Oil) Castor Oil (Hydrogenated) (C18H35O3)3C3H5 Cellulose Nitrate Wet with Alcohol (Nitrocellulose) Cetane China Wood Oil Chlorex Chlorine Monoxide Cl2O Gas 540 (282) Gas
(609) 12 29 2.1
(-192) -58 (-50) See Carbon Oxysulfide. 1.0Note: Melting point 185 (85). No 2 0 1 0 6 3 4 1
840 (449)
1.0-
595 (313)
No No No
2 2 1 5
0 0 2
1 1 3
0 0 3
Note: See Hazardous Chemicals Data. See Hexadecane. See Tung Oil. See Bis (2-chloroethyl) Ether. 23.5 100 Explodes @ 39 (4) Yes 3 4 3 Explodes on heating.
7-19N
Page 31
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
1.58 1.32 3.26 5.32
1.0+
320-354 (160-179) @ 22 mm
2 2
2 1
1 1
0 0
1.2
Slight
1099 (593)
1.3
9.6
1.1
3.9
270 (132)
No
Note: See Hazardous Chemicals Data. See Chlorobenzene. 1.35 1.4 6.24 6.2 282 (139) 306 (152) See 2-Chloro-1,3-Butadiene. 4.0 20.0 1.0 3.0 138 (59) Slight 1 5 2 3 0 2 2 1 2 0
See Butyl Chloride. 2.3 9.3 0.9 3.1 143-159 (62-71) See Dinitrochlorobenzene. See Ethyl Chloride. 797 (425) 4.9 15.9 1.2 2.8 264-266 (129-130) Yes 5 3 2 0 Very slight 1 2 3 0
1.2 1.2
4.2 4.2
No No
3 3
2 2
2 2
0 0
See 2-Chloroethanol. 1.0+ 4.9 364 (184) See Vinyl Chloride. See Vinyl 2-Chloroethyl Ether. 1.1 0.9 4.2 613 (323) 270 (132) See 1-Chloro-2-Propanol. No Slight 2 5 1 3 0 1 0 No 1 2 0
7-19N
Page 32
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1) Boiling Point F (C) Identification ExtinWater guishing FlamReacSoluble Methods Health mability tivity
See Methyl Chloride. See Isobutyl Chloride. >1036 (>558) 1.6 1.2 5.6 505 (263) 446 (230) 1.3 3.8 344 (173) 1.2 4.3 285 (141) 1.2 4.3 273 (134) Explodes upon rapid heating Explodes on heating Slight 5 2 Slight 5 3 3 Slight 2 5 2 2 1 1 0 0 0 1 0 Slight 2 3 Slight 5 2 3 Slight 5 2 3 2 1 3 No 2 1 1 0
(2-Chloro-,,-Trifluoro-5-Nitrotoluene)
1-Chloropentane -Chlorophenetole C6H5OCH2CH2 (-Phenoxyethyl Chloride) o-Chlorophenol ClC6H4OH p-Chlorophenol C6H4OHCl 2-Chloro-4-Phenylphenol C6H5C6H3ClOH Chloroprene 1-Chloropropane 2-Chloropropane 2-Chloro-1-Propanol CH3CHClCH2OH (-Chloropropyl Alcohol) (Propylene Chlorohydrin) 1-Chloro-2-Propanol CH2ClCHOHCH3 (Chloroisopropyl Alcohol) (sec-Propylene Chlorohydrin) 1-Chloro-1-Propene 3-Chloropropene -Chloropropionic Acid CH3CHClCOOH 3-Chloropropionitrile ClCH2CH2CN 2-Chloropropionyl Chloride -Chloropropyl Alcohol 1-Chloropropylene CH3CH:CHCl (1-Chloro-1-Propene) 2-Chloro Propylene CH3CCl:CH2 (-Chloropropylene) (2-Chloropropene) < -4 (< -20) 4.5 16 0.93 < 21 (< -6) 4.5 16 0.9 225 (107) 168 (76) 88 (31) 1.3 932 (500) 1.1 1.3 125 (52) (oc) 1.1 125 (52) 1.1 147 (64) 250 (121) 345 (174) <1 1.31 1.3 225 (107) 1.1
See Amyl Chloride. 306-311 (152-155) 347 (175) 4.43 428 (220) 613 (323) Note: Melting point 172-176 (78-80). See 2-Chloro-1, 3-Butadiene. See Propyl Chloride. See Isopropyl Chloride. 3.3 271-273 (133-134) Yes 5 2 2 0
3.3
261 (127)
Yes
See 1-Chloropropylene. See Allyl Chloride. 352-374 (178-190) 3.0 348.8 (176) Decomposes 0.12 230 (110) See 2-Chloro-1-Proponol. 95-97 (35-36) 2.63 73 (23) 2 4 0 1 2 4 2 Reacts Yes Yes 5 2 5 2 1 1 0
7-19N
Page 33
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1) Boiling Point F (C) Identification ExtinWater guishing FlamReacSoluble Methods Health mability tivity
See Epichlorohydrin. See Epichlorohydrin. 1.08 4.37 320 (160) See Benzyl Chloride. See Trifluorochloroethylene. See 2-Chloro-5-Nitrobenzotrifluoride. See o-Chlorobenzotrifluoride. See Dipentene. See Styrene 0.9 197-199 (92-93) No 5 0 2 0 2 2 0
0.9
117 (47)
No
0.85
227 (108.4)
No
(CH3)2C:CH(CH2)2CH(CH3)(CH2)2OH (96) 444 (229) 453.2 (234) or higher 0.8 @ 302 (150) 0.8 Initial 357.8 (181) or higher 0.8
No
No
See Gas. See Fuel Oil No. 1. <1 >1 529 (276) See Cobalt Naphtha. 0.9 No 2 0 1 0 0.9 No No No 2 2 0 1 3 1 2 0 0 0
Note: Melting point 72 (22). Cod Liver Oil Collodion C12H16O6(NO3)4C13H17O7(NO3)3 Solution of Nitrated Cellulose in Ether-Alcohol Cologne Spirits Columbian Spirits Colza Oil See Ethyl Alcohol. See Methyl Alcohol. See Rape Seed Oil. 412 (211) <0 (< -18) 1 5 1 4 0 0.9 No 2 0 1 0
7-19N
Page 34
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
0.9 <1
650 (343)
0.9 <1
No No
2 2 0 1 0
No No
3 3
2 3
2 2
0 0
See Hazardous Chemicals Data. 1038 (558) 1.1 @ 302 (150) Note: Melting point of meta: 53.6 (12); of para: 94.6 (35). See Hazardous Chemicals Data. 1.0 395 (201) No 3 1 0
p-Cresyl Acetate CH3C6H4OCOCH3 (p-Tolyl Acetate) Cresyl Diphenyl Phosphate (C6H5O)2[(CH3)2C6H4O]PO4 Cresylic Acid Crotonaldehyde CH3CH:CHCHO (2-Butenal) (Crotonic Aldehyde) (Propylene Aldehyde) Crotonic Acid CH3CH:CHCOOH
1.1
1.2
0.9
2.4
216 (102)
Slight
1 5
Note: See Hazardous Chemicals Data. 190 (88) (oc) Note: Melting point 162 (72). 745 (396) 1.0@ 176 (80) See Crotonaldehyde. < 212 (< 100) 81 (27) 660 (349) 4.2 35.3 0.85 2.49 0.8 2.3 230-240.8 (110-116) 250 (121) To 16 3 2 No 1 0 3.0 372 (189) Yes 5 3 2 0
Crotonic Aldehyde Crotononitrile CH3CH:CHCN (2-Butenenitrile) Crotonyl Alcohol CH3CH:CHCH2OH (2-Buten-1-ol) (Crotyl Alcohol) 1-Crotyl Bromide CH3CH:CHCH2Br (1-Bromo-2-Butene) 1-Crotyl Chloride CH3CH:CHCH2Cl (1-Chloro-2-Butene) Cumene C6H5CH(CH3)2 (Cumol) (2-Phenyl Propane) (Isopropyl Benzene) 96 (36) 795 (424) 0.9 6.5 0.9 4.2 19.0 4.6 12.0
4.66
3.13
4.1
306 (152)
No
7-19N
Page 35
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1) Boiling Point F (C)
Explodes on heating. Note: See Hazardous Chemicals Data. See Cumene. 1.07 1.45 500 (260) Decomposes Note: Melting point 111 (44). 4 1 3
2-Cyanoethyl Acrylate CH2CHCOOCH2CH2CN N-(2-Cyanoethyl) Cyclohexylamine C6H11NHC2H4CN Cyanogen (CN)2 Cyclamen Aldehyde (CH3)2CHC6H4CH(CH3)CH2CHO (Methyl Para-Isopropyl Phenyl Propyl Aldehyde) Cyclobutane C4H8 (Tetramethylene) 1,5,9-Cyclododecatriene C12H18 Cycloheptane CH2(CH2)5CH2 Cyclohexane C6H12 (Hexahydrobenzene) (Hexamethylene) 1,4-Cyclohexane Dimethanol C8H16O2 (CHDM) Cyclohexanethiol C6H11SH (Cyclohexylmercaptan) Cyclohexanol C6H11OH (Anol) (Hexalin) (Hydralin) Cyclohexanone C6H10O (Pimelic Ketone) Cyclohexene CH2CH2CH2CH2CH:CH 3-Cyclohexene-1Carboxaldehyde Cyclohexenone C6H8O Cyclohexyl Acetate CH3CO2C6H11 (Hexalin Acetate)
255 (124) (oc) 255 (124) (oc) Gas 190 (88) 6.6 32
1.1
4.3
Polymerizes
No
0.9
5.2
No
1.8 1.0-
-6 (-21)
6 5
4 2
2 0
Gas
1.8
1.9
55 (13)
No
160 (71) < 70 (< 21) -4 (-20) 473 (245) 1.3 8 1.1 6.7
No 0
2 3
0 0
0.8
29
179 (82)
No
600 (316)
1.0-
525 (274)
Yes
5 2
0.95
4.00
315-319 (157-159)
No
572 (300)
1.0-
3.5
322 (161)
Slight
9.4
0.9
3.4
313 (156)
Slight
0.8
2.8
181 (83)
No
See 1,2,3,6-Tetrahydrobenzaldehyde. 93 (34) 136 (58) 635 (335) 1.04.9 3.3 313 (156) 350 (177) No 1 2 0 1 1 3 0
7-19N
Page 36
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
0.9 3.4
Note: See Hazardous Chemicals Data. 0.9 459 (237) 0.99 4.08 288 (142) 2 3 0 No 2 1 0
1.01.01 4.42
No
1 2
0 0
See Methylcyclohexane. 1.0+ Note: Melting point 116 (47). 196 (91) (oc) 95 (35) < 20 (< -7) -20 (-29) 124 (51) 79 (26) 0.9 2.3 682 (361) 743 (395) 0.95 2.97 0.8 2.35 1.5 0.7 2.4 0.9 3.66 304 (151) 121 (49) 111 (44) 286 (141) 267 (131) Slight 1 5 2 3 0 0 2 0 1 1 3 1 No 1 1 3 0 No 1 3 0 1.2 7.5 298 (148) @ 10 mm 406 (208) No 3 2 2 1 Slight 5 2 2 1 0
2.4
10.4
1.5
-29 (-34)
No
5.6 5.6
0.9
4.6
349 (176)
No
See Dimethyldichlorosilane. 0.9 416 (213) Note: See Hazardous Chemicals Data. 0.9 4.8 382 (194) 0.87 4.77 369 (187) See Decahydronaphthaiene. 410 (210) 550 (288) 0.8 5.5 0.8 5.4 0.7 4.9 345 (174) 444.2 (229) No 0 2 0 No 0 2 0 0 2 0 No 2 2 0 482 (250) 491 (255) 0.7 @ 212 (100) 0.7 4.9 @ 212 (100) 5.4 Slight 3 2 1
7-19N
Page 37
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
0.74 0.9 4.84
See Decanol. 0.8 429 (221) 0.9 0.9 0.9 1.06.0 491-536 (255-280) 410-424 (210-218) 635-680 (335-360) 261 (127) @ 11 mm 690 (366) 518 (270) Note: Melting point 228-232 (109-111). 750 (399) 0.8 1.6 175 (79) Yes 1 5 0 3 0 No 2 1 1 0 No 2 1 0 No 2 1 1 0 2 2 0 No 2 2 1 0 Slight 5 2 1 0
75
7-19N
Page 38
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
0.9 4.0
Upper
6.9
See 2,3-Butanedione. See Allyl Ether. 1.1 554 (290) See 1,3-Butanediamine. 1.1 266 (130) See 1 ,3-Propanediamine. 0.8 5.4 356 (180) Note: See Hazardous Chemicals Data. 0.9 491-536 (255-280) 1.0687-759 (364-404) 0.9 554-572 (290-300) See Diamylbiphenyl. 0.8 302 (150) See Amyl Ether. 1.00.9 505-572 (263-300) 624 (329) 0.9 527 (275) 1.0615 (324) 1.0 475-490 (246-254) @ 50 mm 0.9 338-356 (170-180) 8.43 Note: Melting point 297 (147). 1.0 568 (298) No 2 0 1 0 1 0 No 2 2 0 No 2 0 1 0 No 2 0 1 0 No 2 2 1 0 No 2 0 1 0 No 2 0 1 0 0 2 0 No 2 0 1 0 No 2 0 1 0 No 2 0 1 0 Slight 5 3 2 0 Yes 2 5 2 1 0 No 2 2 1 0
7-19N
Page 39
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
1.0-
Upper
88
(38-52) Note: Ignites spontaneously in moist air. See Hazardous Chemicals Data. Dibutoxy Ethyl Phthalate C6H4(COOC2H4OC4H9)2 Dibutoxymethane CH2(OC4H9)2 Dibutoxy Tetraglycol (C4H9OC2H4OC2H4)2O (Tetraethylene Glycol Dibutyl Ether) N,N-Dibutylacetamide CH3CON(C4H9)2 Dibutylamine (C4H9)2NH Di-sec-Butylamine [C2H5(CH3)CH]2NH Dibutylaminoethanol (C4H9)2NC2H4OH 1-Dibutylamino-2-Propanol N,N-Dibutylaniline C6H5N(CH2CH2CH2CH3)2 Di-tert-Butyl-p-Cresol C6H2(C4H9)2(CH3)OH Dibutyl Ether (C4H9)2O (1-Butoxybutane) (Butyl Ether) 2,5-Di-tert-Butylhydroquinone [C(CH3)3]2C6H2(OH)2 (DTBHQ) Dibutyl Isophthalate C6H4(CO2C4H9)2 N,N1-Di-sec-Butyl-pPhenylenediamine C6H4[-NHCH(CH3)CH2CH3]2 Dibutylisopropanolamine CH3CHOHCH2N(C4H9)2 Dibutyl Maleate (-CHCO2C4H9)2 Dibutyl Oxalate C4H9OOCCOOC4H9 Di-tert-Butyl Peroxide (CH3)3COOC(CH3)3 420 (216) (oc) Note: Melting point 410 (210). 322 (161) 270 (132) 205 (96) (oc) 285 (141) (oc) 220 (104) 65 (18) (oc) Note: See Hazardous Chemicals Data. 0.8 1.0+ 472 (244) 231 (111) Slight 1 3 2 4 OX No 2 0 1 0 1.0Decomposes 2 1 1 0 625 (329) 0.6 @ 329 0.8 444 (229) Slight 0.9 5 2 5 2 1 0 2 1 0 No 2 0 1 0 790 (421) Note: See Hazardous Chemicals Data. No 2 1 1 0 230 (110) 261 (127) 77 (25) 382 (194) 1.5 7.6 0.8 4.5 0.9 407 (208) (oc) 140 (60) 305 (152) (oc) 225 (107) 117 (47) 75 (24) (oc) 200 (93) (oc) See Dibutylisopropanolomine. 505-527 (263-275) 495-511 (257-266) Note: Melting point 154.4 (68). 286 (141) No 1 5 2 3 0 No 2 0 1 0 No 2 3 1 0 0.9 432 (222) No 3 2 0 0.8 4.5 1.1 0.8 4.5 0.9 469-482 (243-250) 322 (161) 270-275 (132-135) Yes 5 3 3 0 Slight 5 3 2 0 2 0 1 0 0.9 0.8 330-370 (166-188) Note: Melting point 140 (60). 635 (335) Slight 2 5 2 1 0 No 0 2 0 1.1 437 (225) No 5 2 0 1 0
7-19N
Page 40
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
1.0-
1.0+
1.0-
650 (343)
No
0.9
No
544 (284)
1.1
650 (343)
No
1.1
1.0-
9.8
No
5.1
Note: Melting point 161 (72). See Hazardous Chemicals Data. o-Dichlorobenzene C6H4Cl2 (o-Dichlorobenzol) p-Dichlorobenzene C6H4Cl2 o-Dichlorobenzol 2,3-Dichlorobutadiene-1,3 CH2:C(Cl)C(Cl):CH2 1,2-Dichlorobutane CH3CH2CHClCH2Cl 1,4-Dichlorobutane CH2ClCH2CH2CH2Cl 2,3-Dichlorobutane CH3CHClCHClCH3 1,3-Dichloro-2-Butene CH2ClCH:CClCH3 3,4-Dichlorobutene-1 CH2ClCHClCHCH2 1,3-Dichlorobutene-2 CH2ClCH:CClCH3 Dichlorodimethylsilane 1,1-Dichloroethane 1,2-Dichloroethane Dichloroethanoyl Chloride 126 (52) 194 (90) (oc) 80 (27) 113 (45) 80 (27) 4.3 1.1 4.31 1.2 4.31 262 (128) 316 (158) 258 (126) See Dimethyldichlorosilane. See Ethylidene Dichloride. See Ethylene Dichloride. See Dichloroacetyl Chloride. 1 2 3 0 3 2 1 No 1 3 3 2 1.1 4.4 50 (10) 694 (368) 527 (275) 1.1 4.4 311 (155) Note: See Hazardous Chemicals Data. 241-253 (116-123) 2 2 0 No 3 2 2 0 4.38 1.0 12.0 1.2 150 (66) 151 (66) 1198 (648) 1.5 5.1 2.2 9.2 1.3 5.1 356 (180) Note: See Hazardous Chemicals Data. 345 (174) Note: Melting point 127 (53). See o-Dichlorobenzene. 4.24 212 (100) 2 2 0 No 1 3 3 2 No 3 2 2 0 No 3 2 2 0
7-19N
Page 41
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1) Boiling Point F (C) Identification ExtinWater guishing FlamReacSoluble Methods Health mability tivity
See Vinylidene Chloride. 860 (460) 5.6 12.8 1.3 3.4 119 (48) No 4 2 3 2
696 (369)
2.7
1.2
4.93
352 (178)
No
Note: See Hazardous Chemicals Data. See Bis(2-Chloroethyl) Formal. See Bis(2-Chloroethyl) Formal. 2 1.1 6.0 369 (187) 1.11 5.90 369 (187) See Methylene Chloride. 1.4 5.0 255 (124) 1.3 5.5 289 (143) 1.0+ 4.8 266 (130) 1.1 4.9 352-358 (178-181) No 4 2 3 0 No 2 2 0 Slight 5 2 2 3 No 3 2 2 3 2 2 0 No 3 2 2 0 0
5.6
410 (210)
Slight
5 2
Note: Melting point 113 (45). See Propylene Dichloride. 1.4 4.4 346 (174) 5.3 2.6 14.5 7.8 1.2 1.2 3.8 3.8 219 (104) 201 (94) 136 (36) No 4.1 99 1.2 3.5 47 Yes Avoid water. 2 2 1 2 3 4 2 Slight 3 3 0 No 2 3 0 Slight 5 2 2 0
7-19N
Page 42
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
1.0-
Note: Melting point 91 (33). Didecyl Ether (C10H21)2O (Decyl Ether) Diesel Fuel Oil No. 1-D 100 Min. (38) or Legal Diesel Fuel Oil No. 2-D 125 Min. (52) or Legal Diesel Fuel Oil No. 4-D 130 Min. (54) or Legal Diethanolamine (HOCH2CH2)2NH 342 (172) (oc) Note: Melting point 82 (28). 1,2-Diethoxyethane Diethylacetaldehyde Diethylacetic Acid N,N-Diethylacetoacetamide CH3COCH2CON(C2H5)2 Diethyl Acetoacetate CH3COC(C2H5)2COOC2H5 Diethylaluminum Chloride (C2H5)2AlCl 250 (121) (oc) 170 (77) 1.06.4 412-424 (211-218) Decomposes 3 3 3 Do not use water, foam or halogenated extinguishing agents. Note: Ignites spontaneously in air. See Hazardous Chemicals Data. Diethylaluminum Hydride (C2H5)2AlH 3 3 Do not use water, foam or halogenated extinguishing agents. Note: Ignites spontaneously in air. Diethylamine (C2H5)2NH 2-Diethyl (Amino) Ethanol 2-(Diethylamino) Ethyl Acrylate CH2:CHCOOCH2CH2HN(CH3CH2)2 3-(Diethylamino)-Propylamine (C2H5)2NCH2CH2CH2NH2 (N,N-Diethyl-1,3-Propanediamine) 195 (91) (oc) 138 (59) (oc) 0.8 4.5 337 (169) Yes 5 2 2 0 0.9 -9 (-23) 594 (312) 1.8 10.1 0.7 2.5 134 (57) Note: See Hazardous Chemicals Data. See N,N-Diethylethanolamine. 5.9 Decomposes Decomposes 2 2 1 Yes 5 1 2 3 0 Very slight 2 2 0 1.0See Diethyl Glycol. See 2-Ethylbutyraldehyde. See 2-Ethylbutyric Acid. 5.4 Decomposes Yes 2 5 0 1 0 1224 (662) 1.1 514 (268) Yes 5 2 1 1 0 No 0 2 0 No 0 2 0 No 0 2 0 419 (215) 10.3 0 1 0
(Chlorodiethylaluminum)
7-19N
Page 43
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
1.05.0
No No No Yes 5
2 2 2 2
2 2 2 2
0 0 0 0
1.0+
No
5 2
Yes
5 2
See sec-Amyl Alcohol. 1.04.1 259 (126) 464 (240) 0.8 @ 140 (60) 6.0 @ 230 (110) 1.1 620 (327) Note: Melting point 160 (71). 299 (150) See p-Dioxane. 435 (224) 1.1 1.1 472 (244) 320 (160) @ 2 mm 1.1 392-403 (200-206) @ 2 mm 1.1 327 (164) @ 2 mm 1.2 437-444 (225-229) @ 2 mm 442 (228) 563 (295) 0.98 7.05 1.0448 (231) 475 (246) Yes 5 2 1 0 1 1 0 No 2 0 1 1 Slight 5 2 1 1 1 Slight 5 2 1 1 1 No Yes 5 2 2 1 1 0 1 1 0 Yes 2 1 1 0 0.8 344 (173) 2 2 0 No 1 2 3 1
[CH3(CH2)3O(CH2)2OOCOCH2CH2]2O (193)
7-19N
Page 44
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
1.1
1.14
10.4
5 5 2 5
1 1 1 0
2 1 1 1
1 0 0 0
465 (240)
1.38
22.7
1.04
4.14
379 (193)
1.04
5.59
410 (210)
0.85
24.6
1.0-
5.6
448 (231)
Yes
0.76
10.7
1.0-
476 (247)
Slight
5 2
1.0-
396 (202)
Yes
680 (360)
1.0+
424 (218)
Yes
5 2
Diethylene Glycol Monoisobutyl Ether (CH3)2CHCH2O(CH2)2O(CH2)2OH Diethylene Glycol Monomethyl Ether CH3O(CH2)O(CH2)2OH Diethylene Glycol Mono-Methyl Ether Formal CH2(CH3OCH2CH2OCH2CH2O)2
452-485 (233252)
0.98
1.0-
422-437 (217-225)
Yes
5 2
1.0+
381 (194)
Yes
1.0+
581 (305)
Yes
5 2
7-19N
Page 45
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
1.1 See Tetrahydrofuran.
676 (358)
6.7
1.0-
3.56
404 (207)
Yes
5 2
Note: See Hazardous Chemicals Data. N,N-Diethylethanolamine (C2H5)2NC2H4OH (2-(Diethylamino) Ethanol) Diethyl Ether N,N-Diethylethylenediamine (C2H5)2NC2H4NH2 Diethyl Fumarate C2H5OCOCH:CHCOOC2H5 Diethyl Glycol (C2H5OCH2)2 (1,2-Diethoxyethane) Di-2-Ethylhexyl Adipate C4H8[COOCH2CH(C2H5)C4H9]2 (Dioctyl Adipate) (DOA) Diethylhexylamine Diethylhexylethanolamine Di(2-Ethylhexyl) Maleate Di(2-Ethylhexyl) Phosphoric Acid Di(2-Ethylhexyl) Succinate Diethyl Ketone C2H5COC2H5 (3-Pentanone) N,N-Diethyllauramide C11H23CON(C2H5)2 Diethyl Maleate (-CHCO2C2H5)2 Diethyl Malonate CH2(COOC2H5)2 (Ethyl Malonate) Diethyl Oxide 3,3-Diethylpentane CH3CH2C(C2H5)2CH2CH3 Diethyl Peroxide 554 (290) Explodes on heating. 322 (161) (oc) p-Diethyl Phthalate N,N-Diethyl-1,3-Propanediamine 2,2-Diethyl-1,3-Propanediol HOCH2C(C2H5)2CH2OH 215 (102) (oc) 0.9 @ 142 (61) 855 (457) 2.3 0.8 7.7 0.7 5.7 0.8 55 (13) (oc) >150 (>66) (oc) 250 (121) (oc) 200 (93) (oc) See Ethyl Ether. 4.4 295 (146) Explodes on heating. 4 4 No 0 3 0 1.1 390 (199) No 3 0 1 0 662 (350) 1.1 0.9 8.8 331-351 (166-177) @ 2 mm 438 (226) No 2 1 1 0 No 2 0 842 (450) 1.6 0.8 See Bis(2-Ethylhexyl) Amine. See Bis(2-Ethylhexyl) Ethanolamine. See Bis(2-Ethylhexyl) Maleate. See Bis(2-Ethylhexyl) Phosphoric Acid. See Bis(2-Ethylhexyl) Succinate. 3.0 217 (103) Slight 1 5 1 3 0 385 (196) 0.9 783 (417) No 5 2 0 1 0 115 (46) (oc) 220 (104) 95 (35) 401 (205) 1.0+ @ 68 (20) 0.84 4.07 252 (122) Slight 3 0 442 (217) Slight 5 2 1 1 0 0.8 140 (60) (oc) See Ethyl Ether. 4.0 293 (145) Yes 5 3 2 0 608 (320) 0.9 4.0 324 (162) Yes 5 3 2 0
C2H5OOC2H5 Diethyl Phthalate C6H4(COOC2H5)2 0.7 @ 368 (186) See Diethyl Terephthalate. See 3-(Diethylamino) Propylamine. 320 (160) @ 50 mm Note: Melting point 142 (61). Yes 5 2 2 1 0 1.1 565 (296) No 2 0 1 0
7-19N
Page 46
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
1.2 0.9 4.7
Upper
5 2 5
1 3
1 1
0 1
(C2H5)2SO4 (Ethyl Sulfate) Diethyl Tartrate CHOHCOO(C2H5)2 Diethyl Terephthalate C6H4(COOC2H5)2 (p-Diethyl Phthalate) 3,9-Diethyl-6-tridecanol Diethylzinc (C2H5)2Zn
(436)
Note: See Hazardous Chemicals Data. 1.2 1.1 536 (280) 576 (302) Note: Melting point 112 (44). See Heptadecanol. No Yes
2 5 2 0 0 1 1 0 0
3W
Note: Ignites spontaneously in air. (Zinc Diethyl) Difluoro-1-Chloroethane CF2ClCH3 (R-142B) (1-Chloro-1,1-Difluoroethane) Diglycol Chlorformate O:(CH2CH2OCOCl)2 Diglycol Chlorohydrin HOCH2CH2OCH2CH2Cl Diglycol Diacetate (CH3COOCH2CH2)2:O Diglycol Dilevulinate [CH2CH2OOC(CH2)2COCH3]2:O Diglycol Laurate C16H32O4 Dihexyl Dihexylamine [CH3(CH2)5]2NH Dihexyl Ether Dihydropyran CH2CH2CH2:CHCHO o-Dihydroxybenzene C6H4(OH)2 (Pyrocatechol) p-Dihydroxybenzene C6H4(OH)2 (Hydroquinone) 1,2-Dihydroxybutane 2,2-Dihydroxyethyl Ether 2,5-Dihydroxyhexane 329 (165) 959 (515) 1.36 3.81 547 (286) Note: Melting point 338 (170). See 1,2-Butanediol. See Diethylene Glycol. See 2,5-Hexanediol. 0 (-18) 260 (127) 1.34 3.79 0.9 220 (104) (oc) See Hexyl Ether. 2.9 186 (86) 473 (245) Slight Slight 5 0.8 295 (146) (oc) 225 (107) (oc) 255 (124) 340 (171) 290 (143) 1.0559-617 (293-325) See Dodecane. 451-469 (233-243) No 2 1.1 1.1 6.5 482 (250) Yes Yes 2 5 2 5 2 1.2 256-261 (124-127) @ 5 mm 387 (197) Yes 5 2 2 Gas 6.2 17.9 See Hazardous Chemicals Data. 4 (-16)
0 0 0
1 1 1
7-19N
Page 47
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1) Boiling Point F (C) Identification ExtinWater guishing FlamReacSoluble Methods Health mability tivity
3 3 Do not use water, foam or halogenated extinguishing agents. No 5 1 No 5 1 2 0 3 3 0
Diisobutylamine [(CH3)2CHCH2]2NH [Bis (-Methylpropyl) Amine] Diisobutyl Carbinol [(CH3)2CHCH2]2CHOH (Nonyl Alcohol) Diisobutylene Diisobutylene (CH3)3CCH2C(CH3):CH2 (2,4,4-Trimethyl-I2-Pentane) Diisobutyl Ketone [(CH3)2CHCH2]2CO (2,6-Dimethyl-4-Heptanone) (Isovalerone) Diisobutyl Phthalate C6H4[COOCH2CH(CH3)2]2 Diisodecyl Adipate C10H21O2C(CH2)4CO2C10H21 Diisodecyl Phthalate C6H4(COOC10H21)2 Diisooctyl Phthalate (C8H17COO)2C6H4 Diisopropanolamine [CH3CH(OH)-CH2]2NH Diisopropyl Diisopropylamine [(CH3)2CH]2NH
85 (29) 165 (74) 0.8 @ 212 (100) 23 (-5) 120 (49) 736 (391) 745 (396) 0.8 @ 200 (93) 365 (185) (oc) 225 (107) (oc) 450 (232) (oc) 450 (232) 260 (127) (oc) 705 (374) 755 (402) 0.3 @ 508 810 (432) 0.4 @ 448 7.1 @ 200 (93) 0.8 6.1 @ 212 (100)
0.7
273-286 (134-141)
0.8
5.0
353 (178)
See 2,4,4-Trimethyl-1-Pentene. 4.8 0.7 3.87 214 (101) 0.8 4.9 335 (168) No 1 2 0 1 1 3 0
1.0+
621 (327)
No
5 2 2
0.9
660 (349)
1.0-
482 (250)
No
5 2
1.01.0-
No Yes
2 5 2
0 2
1 1
0 0
30 (-1) (oc)
600 (316)
1.1
7.1
0.7
3.5
183 (84)
Yes
1 5
Note: See Hazardous Chemicals Data. Diisopropyl Benzene [(CH3)2CH]2C6H4 N,N-Diisopropylethanolamine [(CH3)2CH]2NC2H4OH Diisopropyl Ether Diisopropyl Maleate (CH3)2CHOCOCH: CHCOOCH(CH3)2 Diisopropylmethanol Diisopropyl Peroxydicarbonate (CH3)2CHOCOOCOOCH(CH3)2 Diketene CH2:CCH2C(O)O (Vinylaceto--Lactone) 93 (34) 1.1 220 (104) (oc) See 2,4-Dimethyl-3-Pentanol. Note: Rapid decomposition at 53 (12). Melting Point 46-50 (8-10). 2.9 Explodes on heating. 261 (127) Note: See Hazardous Chemicals Data. No 0 4.00 4 OX 1.0+ 170 (77) (oc) 175 (79) (oc) See Isopropyl Ether. 444 (229) Slight 5 2 1 1 0 0.9 5.0 376 (191) No 1 2 0 840 (449) 0.9 5.6 401 (205) No 0 2 0
7-19N
Page 48
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1) Boiling Point F (C)
518 (270) Note: Melting point 156-163 (69-73).
2,5-Dimethoxychlorobenzene C8H9ClO2 1,2-Dimethoxyethane Dimethoxyethyl Phthalate C6H4(COOCH2CH2OCH3)2 [Bis(2-methoxyethyl) Phthalate] Dimethoxymethane Dimethoxy Tetraglycol CH3OCH2(CH2OCH2)3CH2OCH3 (Tetraethylene Glycol Dimethyl Ether) Dimethylacetamide (CH3)2NC:OCH3 (DMAC) Dimethylamine (CH3)2NH 2-(Dimethylamino) Ethanol (CH3)2NCH2CH2OH (Dimethylethanolamine) 2-(Dimethylamino) Ethyl Methacrylate C8H15NO2
243 (117) 410 (210) (oc) 285 (141) (oc) 158 (70) (oc) Gas 752 (400) 105 (41) (oc) 165 (74) (oc) 0.9 563 (295) 0.9 2.8 914 (490) 1.8 @ 212 11.5 @ 320 14.4 1.0 750 (399) 0.7 @ 440 (227) 1.2
5.9
460-467 (238-242)
Slight
2 5
See Ethylene Glycol Dimethyl Ether. 644 (340) See Methylal. 1.0+ 528 (276) Yes 2 5 1 1 0 No 5 2 0 1 0
Yes
Yes
Note: See Hazardous Chemicals Data. 3.1 272 (133) 5.4 207 (97) @ 40 mm Note: Polymerizes. 3-(Dimethylamino)-propionitrile (CH3)2NC2H4CN 3-(Dimethylamino)-propylamine (CH3)2N(CH2)3NH2 Di(Methylamyl) Maleate N,N-Dimethylaniline C6N5N(CH3)2 C.P. o-Dimethylaniline Dimethyl Anthranilate CH3OOCC6H4NHCH3 (N-Methyl Methyl Anthranilate) 1,2-Dimethylbenzene 1,3-Dimethylbenzene 1,4-Dimethylbenzene Dimethylbenzylcarbinyl Acetate C6H5CH2C(CH3)2OOCCH3 (alpha, alpha-Dimethylphenethyl Acetate) 2,2-Dimethylbutane (CH3)3CCH2CH3 (Neohexane) 2,3-Dimethylbutane (CH3)2CHCH(CH3)2 (Diisopropyl) 1,3-Dimethylbutanol See Methyl Isobutyl Carbinol. -20 (-29) 761 (405) 1.2 7.0 0.7 3.0 136 (58) No 1 1 3 0 -54 (-48) 761 (405) 1.2 7.0 0.6 205 (96) Note: Melting point 84-86 (29-30). 3.0 122 (50) No 1 1 3 0 1.0See o-Xylene. See m-Xylene. See p-Xylene. 1 1 0 195 (91) 11 145 (63) 165 (74) (Und. Lab. Class 20-25) See o-Xylidine. 1 2 0 700 (371) 149 (65) (oc) 100 (38) (oc) See Bis(2,4-Dimethylbutyl) Maleate. 1.04.2 379 (193) Slight 5 3 2 0 0.8 3.5 278 (137) Yes 5 3 2 0 0.86 3.35 338 (170) 2 1 Yes Yes 1 5 5 2 2 0 2 2 0
7-19N
Page 49
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
0.68 0.71 0.9 0.7 2.91 2.91 5.0 3.5
See Isopropyl Alcohol. See Methyl Carbonate. 450 (232) 0.88 579 (304) 583 (306) 579 (304) 0.8 3.9 0.8 3.87 0.8 2.42 3.87 1.0+ 259-270 (126-132) 320 (160) 260 (127) ~256 (124) 248 (120) 255 (124) 246 (119) 455 (235) 0.7 @ 200 (93) 3.4 5.3 @ 300 (149) > 9.5 1.1 4.4 158 (70) 248 (oc) 0.9 4.0 (120) @ 14 mm 243 (117) 1.0 - @ 122 (50) See Ethylene Oxide. See 2-(Dimethylamino) Ethanol. See Methyl Ether. See 2-Methyl-2-Butanol. 0.74 4.43 279 (137) 833 (445) 2.2 @ 212 (100) 0.9 3.3 200 (93) Slight 1 5 2 3 0 15.2 0.9 2.5 307 (153) Yes 5 1 2 0 0 3 0 585-588 (307-309) No Slight Slight 5 2 1 5 2 0 1 0 2 3 0 Decomposes 3 3 1 Decomposes in water. 3 1 1.0 455 (235) 0 2 0 0 3 0 0 3 0 No 1 1 3 0 No 1 0 3 0 No 0 0 4 2 1 2 2 0
7-19N
Page 50
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
1.8
0.73
4.43
279 (137)
See Diisobutyl Ketone. 0.7 3.9 237 (114) 0.7 3.9 229 (109) 0.85 4.35 302 (150) 480 (249) 2 95 0.8 2.0 145 (63) Yes 5 1 3 3 1 0 2 0 No 1 0 3 0 No 1 0 3 0
See 1,1 -Dimethylhydrazine. No Note: Melting point 153-154 (67-68). 95 (35) (oc) See Acetone. 1.2 393 (201) 0.9 4.0 296 (147) 437 (225) 0.75 0.8 4.91 3.9 0.74 4.91 327 (164) 324 (162) 293 (145) 635 (335) 0.7 0.8 3.5 4.0 1.1 6.7 0.7 3.5 194 (90) 177 (81) 284 (140) 915 (490) 0.9 @ 358 (180) 0.92 3.94 329 (165) 842 (450) 1.4 7.5 2.5 49 (9) See tert-Butyl Carbinol. No 6 0 4 0 2 2 0 1.2 540 (282) Very slight No 2 0 1 0 0 2 0 No 1 0 3 0 No 1 0 3 0 1 2 3 0 0 2 0 0 2 0 Yes 5 2 2 0 No 2 1 1 0 0.9 3.6 257 (125) Yes 1 5 2 3 0 2 0 1 0
7-19N
Page 51
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
0.99 3.72
1.0-
370 (188)
1.3
4.4
370 (188)
Very slight
Note: See Hazardous Chemicals Data. <0 (< -18) 203 (95) (oc) Note: Melting point 65 (18). Dimethyl Terephthalate C6H4(COOCH3)2 (Dimethyl-1,4-BenzeneDicarboxylate) (DMT) 2,4-Dinitroaniline (NO2)2C6H3NH2 1,2-Dinitro Benzol C6H4(NO2)2 (o-Dinitrobenzene) Dinitrochlorobenzene C6H3Cl(NO2)2 (Chlorodinitrobenzene) 2,4-Dinitrotoluene (NO2)2C6H3CH3 Dioctyl Adipate [-(CH2)2COOCH2CH(C2H5)C4-H9]2 [Bis(2-Ethylhexyl) Adipate] [Di(2-Ethylhexyl) Adipate] Dioctylamine Dioctyl Azelate (CH2)7[COOCH2CH(C2H5)C4H9]2 [Bis(2-Ethylhexyl) Azelate] [Di(2-Ethylhexyl) Azelate] Dioctyl Ether (C8H17)2O (Octyl Ether) Dioctyl Phthalate C6H4[CO2CH2CH(C2H5)C4H9]2 [Di(2-Ethylhexyl) Phthalate] [Bis(2-Ethylhexyl) Phthalate] p-Dioxane OCH2CH2OCH2CH2 (Diethylene Dioxide) Dioxolane OCH2CH2OCH2 35 (2) (oc) 420 (215) (oc) 54 (12) 356 (180) 735 (390) 0.3 @ 474 (245) 2.0 22 1.0+ 3.0 214 (101) Note: See Hazardous Chemicals Data. 1.1 2.6 165 (74) Yes 1 5 2 3 2 Yes 1 5 2 3 1 1.0No 2 0 1 0 >212 (>100) 401 (205) 0.82 8.36 558 (292) 0 1 0 440 (227) (oc) 705 (374) 0.3 @ 510 (266) 0.9 See Bis(2-Ethylhexyl) Amine. 709 (376) No 5 2 0 1 0 404 (207) 402 (206) (oc) 710 (377) 0.4 @ 467 (242) 0.9 1.52 382 (194) 2.0 22 1.7 308 (153) (oc) 435 (224) Note: Melting point 370 (188). 302 (150) 1.57 5.79 604 (318) Note: Melting point 244 (118). 599 (315) Note: Melting point 109 (43). See Hazardous Chemicals Data. 6.27 572 (300) Note: Melting point 158 (70). 680 (360) No 5 2 0 1 0 3 1 3 No 2 3 1 4 3 1 4 1.6 No 2 3 1 3 965 (518) 543 (284) No 5 2 1 1 0 403 (206) 419 (215) 2.6 42 1.1 2.2 19.7 0.8 2.1 99 (37) Note: See Hazardous Chemicals Data. 372 (189) Yes 5 1 1 0 Slight 1 2 4 0
7-19N
Page 52
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
0.9 4.7
Upper
6.1 @ 302 (150)
See Biphenyl. 1173 (634) 851 (455) 1.2 1.0+ 0.98 7.26 1.2 575 (302) Note: Melting point 127 (53). 561 (294) See Dypnone. 581 (305) No 2 0 1 0 Yes 2 3 1 0 0 1 0 No 2 3 1 0
Melting point 64 (18). 1,1-Diphenylethane (uns) (C6H5)2CHCH3 1,2-Diphenylethane (sym) C6H5CH2CH2C6H5 Diphenyl Ether Diphenylmethane (C6H5)2CH2 (Ditane) Diphenyl (o-Xenyl) Phosphate (C6H5O)2PO(OC6H4C6H5) Diphenyl Oxide (C6H5)2O (Diphenyl Ether) 1,1-Diphenylpentane (C6H5)2CHC4H9 1,1-Diphenylpropane CH3CH2CH(C6H5)2 Diphenyl Phthalate C6H4(COOC6H5)2 Dipropylaluminum Hydride (C3H7)2AlH >212 (>100) >212 (>100) 435 (224) 824 (440) 860 (460) 1.3 0.97 6.77 0.97 437 (225) 239 (115) 1144 (618) 7.74 0.7 6.0 1.1 1.2 266 (130) 905 (485) 1.0 >212 (>100) 264 (129) 824 (440) 896 (480) 1.0 6.29 1.0 6.29 546 (286) 544 (284) See Diphenyl Oxide. 508 (264) Note: Melting point 79 (26). 482-545 (250-285) @ 5 mm 496 (258) Note: Melting point 81 (27). 586 (308) 541 (283) 761 (405) Note: Melting point 158 (70). 3 3 Do not use water, foam or halogenated extinguishing agents. Note: Ignites spontaneously in air. Dipropylamine (C3H7)2NH Dipropylene Glycol [CH3CHOHCH2]2O Dipropylene Glycol Methyl Ether CH3OC3H6OC3H6OH Dipropyl Ether Dipropyl Ketone Ditane Ditridecyl Phthalate C6H4(COOC13H27)2 470 (243) (oc) 1.063 (17) (oc) 250 (121) (oc) 186 (86) 1.1 @ 200C See n-Propyl Ether. See 4-Heptanone. See Diphenylmethane. 547 (286) @ 5 mm 2 0 1 0 3.0 1.0 5.11 408 (209) Partly 0 2 0 1.0+ 4.63 449 (232) Yes 2 5 0 1 0 570 (299) 0.7 3.5 229 (109) No 1 3 3 0 No 2 0 1 0 0 1 0 0 1 0 No 2 1 1 0 2 0 1 0 No 2 1 1 0 0 1 0 0 1 0
7-19N
Page 53
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
2.69
0.7
6.2
0.9
392 (200)
No
680 (360)
1.7
27
0.8
2.4
102 (39)
No
Note: See Hazardous Chemicals Data. 1.2 545-626 (285-330) @ 5 mm 397 (203) 0.8 0.6 0.8 5.9 421 (216) 289 (143) @ 15 mm 527 (275) 0.9 0.8 491 (255) 554-770 (290-410) No 2 1 1 0 No 2 0 1 0 No 5 2 2 1 0 No 0 2 0 2 0 1 0
See Lauryl Bromide. 491 (255) 0.76 5.81 406 (208) See 1-Dodecanethiol. 0.9 428-451 (220-233) 715 (379) Note: Melting point 109 (43). 0.9 9.0 597-633 (314-334) 1.1 475 (246) @ 50 mm 450 (232) 772 (411) 3.8 21.0 1.2 3.2 0.79 9.75 651 (344) 239 (115) Note: See Hazardous Chemicals Data. Yes 5 3 2 1 1 0 Slight 2 5 1 1 0 No 2 0 1 0 No 2 1 0 No Note: See Hazardous Chemicals Data. 2 1 0 0 1 0
See Ethylene Oxide. See 1,3-Butadiene. See Acetaldehyde. 882 (472) 3.0 12.5 1.0 -128 (-89) See Ethylene Glycol. No 6 1 4 0
7-19N
Page 54
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
1.2
See Ethyl Mercaptan. See Acetic Acid. See Acetic Anhydride. See Ethyl Alcohol. 770 (410) 3.0 23.5 1.0+ 2.1 342 (172) Yes 5 2 2 0 @ 140C
See Acetyl Chloride. See Ethylene. See Vinyl Acetate. See Divinyl Ether. See Ethyl Ether. See Acetylene. 0.8 1.02.4 4.2 124 (51) 342 (172) No 0 2 0 No 1 2 3 1
1.0-
289 (143)
Very slight
See Ethylene Glycol Monoethyl Ether. 716 (380) 0.98 3.52 1.7 1.04.6 313 (156) 275 (135) See Ethyl Propyl Ether. 0.9 1.0+ 1.0+ 3.5 275 (135) 426 (219) 492 (256) 1.0+ 662 (350) 0.9 401 (205) 0.9 800 (426) 2.0 11.5 0.9 5.6 3.0 400 (204) 171 (77) Slight 1 5 1 3 0 No Yes 5 2 0 2 0 1 1 0 No Yes Yes 5 2 2 5 2 0 1 0 0 1 0 2 1 0 Yes 5 2 3 0 2 2 0 Yes 5 2 2 0
7-19N
Page 55
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
1.0+ 4.5
Upper
95 @ 350 (176)
1.09
5.04
~365 (~185)
No
702 (372)
1.4
14
0.9
3.5
211 (99)
Slight
1 5
Note: Polymerizes. See Hazardous Chemicals Data. Ethyl Alcohol C2H5OH Ethyl Alcohol and Water 96% 95% 80% 70% 60% 50% 40% 30% 20% 10% 5% Ethylaluminum Dichloride C2H5AlCl2 (Dichloroethylaluminum) 55 (13) 62 (17) 63 (17) 68 (20) 70 (21) 72 (22) 75 (24) 79 (26) 85 (29) 97 (36) 120 (49) 144 (62) 3 3 3 Do not use water, foam or halogenated extinguishing agents. Notes: Fumes vigorously in air. May ignite spontaneously. Ethylaluminum Sesquichloride (C2H5)3Al2Cl3 -4 (-20) 1.1 297 (147) 3 3 Do not use water, foam or halogenated extinguishing agents. Yes 1 5 3 4 0 685 (363) 3.3 19 0.8 1.6 173 (78) Yes 1 5 0 3 0
Note: Ignites spontaneously in air. Ethylamine C2H5NH2 70 aqueous solution (Aminoethane) Ethyl Amino Ethanol C2H5NHC2H4OH [2-(Ethylamino)ethanol] Ethylaniline C2H5NH(C6H5) 160 (71) (oc) 185 (85) (oc) Note: See Hazardous Chemicals Data. 1.04.2 401 (205) No 3 2 0 Note: See Hazardous Chemicals Data. 0.92 3.06 322 (161) 2 0 <0 (< -18) 725 (385) 3.5 14.0 0.8 1.6 62 (17)
7-19N
Page 56
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
0.9 3.7
Upper
6.7
Note: See Hazardous Chemicals Data. 914 (490) 1.1 1.0+ 414 (212) See Ethylbenzene. 291-298 (144-148) <932 (500) Slight decomp. 0.9 952 (511) 1.5 6.8 8.0 1.4 5.0 3.8 233 (112) 100 (38) 318 (159) See 2-Ethylbutyraldehyde. See Ethy Butyrate. See 2-Ethylbutyl Alcohol. 599 (315) 1.00.69 2.90 144 (62) 392 (200) @ 100 mm 0.9 5.0 324 (162) 0.9 180 (82) @ 10 mm 0.8 3.5 301 (149) 0.7 3.5 232 (111) See N-Butylurethane. 0.9 0.8 5.0 3.7 275 (135) 198 (92) 0.90 5.05 386 (197) 0.8 4.0 299 (148) 0.9@ 122F (50C) 352 (178) @ 50 mm Note: Melting point 107 (42). Yes 2 5 2 1 0 No 1 2 0 Slight 1 5 0 2 0 2 3 0 2 2 1 No 1 3 3 0 No 1 2 0 No 2 2 0 No 1 2 0 No 2 2 1 0 0 3 0 No 3 2 0 Slight 1 2 1 0 Decomposes 2 3 0 1.0+ 594 (312) No 5 2 2 1 0 No 2 0 1 0 No 1 1 0
7-19N
Page 57
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
0.8 3.5
Upper
7.7
865 (463)
0.9
4.0
248 (120)
No
1 5
752 (400)
0.9
Slight
0.9
4.97
333 (167)
No
0.9
405-408 (207-209)
No
See Diethyl Carbonate. 966 (519) 3.8 15.4 0.9 2.2 54 (12) Slight 1 2 4 0
Note: See Hazardous Chemicals Data. 1.2 295 (146) See Ethyl Chloroformate. 932 (500) 1.1 3.7 201 (94) Decomposes 3 1 No 3 3 0
See Ethy Chloroformate. 0.9 1.1 410 (210) 460 (238) 0.8 4.4 0.9 6.6 0.8 3.9 1.2 7.7 2.9 3.9 282 (139) 401-408 (205-209) 160 (71) 269 (132) Slight 1 5 500 (260) 0.9 1.1 6.7 0.8 3.4 218 (103) 469 (243) 1.1 1.0+ 4.45 168 (75.5) 487 (253) Yes 2 5 2 1 0 Yes 1 3 3 0 No 5 0 1 0 1 3 0 3 3 0 No 1 3 0 No 1 3 0 2 2 1 0 No 1 2 3 0
7-19N
Page 58
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
1.0
Upper
36.0
See Isopentane.
Note: See Hazardous Chemicals Data. See Glycol Diacetate. 351 (177) @ 100 mm Note: Melting point 96 (36). See 2-Chloroethanol. 1.1 445 (229) Decomposes Note: See Hazardous Chemicals Data. 725 (385) 2.5 @ 100C 1.0239-252 (115-122) 775 (413) 6.2 16 1.3 3.4 183 (84) Note: See Hazardous Chemicals Data. See Succinonitrile. See Triethylene Glycol. See 1,2-Ethanediol Diformate. 748 (398) 3.2 1.1 387 (197) Yes 5 2 1 1 0 No 4 2 3 0 Yes 5 12.0 0.9 2.1 (116) 241 Yes 5 3 2 0 Yes 2 5 2 1 1 Yes 2 5 2 1 1
1.1
10.6
0.897
4.10
340 (171)
Yes
See Glycol Diacetate. 0.8 406 0.8 4.07 399 (204) 251 (122) See 1,2-Ethanediol Diformate. 395 (202) 0.9 0.9 174 (79) @ 630 mm 386 (197) 0.9 442 (228) 0.9 3.58 289 (143) 1.1 357 (181) 1.1 410 (210) Yes Yes Yes No 5 2 5 1 5 2 5 2 2 1 1 0 1 0 1 3 0 0 1 0 No 5 1 2 0 Slight 5 2 2 0 Slight 5 1 1 3 0 No 5 1 2 0
7-19N
Page 59
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
1.1
0.9
4.1
340 (171)
645 (340)
0.9
377 (192)
No
Ethylene Glycol Monoethyl Ether HOCH2CH2OC2H5 (2-Ethoxyethanol) Ethylene Glycol Monoethyl Ether Acetate CH3COOCH2CH2OC2H5 (Cellosolve Acetate) Ethylene Glycol Monoisobutyl Ether (CH3)2CHCH2OCH2CH2OH Ethylene Glycol Monomethyl Ether CH3OCH2CH2OH (2-Methoxyethanol) Ethylene Glycol Monomethyl Ether Acetal CH3CH(OCH2CH2OCH3)2 Ethylene Glycol Monomethyl Ether Acetate CH3O(CH2)2OOCCH3
110 (43)
455 (235)
0.9
3.0
275 (135)
Yes
124 (52) 136 (58) 102 (39) 200 (93) (oc) 120 (49)
1.7
1.0-
4.72
313 (156)
Yes
0.9
4.1
316-323 (158-162)
Yes
1.0-
2.6
255 (124)
Yes
1.0-
405 (207)
Yes
740 (392)
1.0+
4.1
293 (145)
Yes
Ethylene Glycol Monomethyl Ether Formal CH2(OCH2CH2OCH3)2 Ethylene Glycol Phenyl Ether C6H5OC2H4OH (2-Phenoxyethanol) Ethylenimine NHCH2CH2 (Aziridine) Ethylene Oxide CH2OCH2 (Dimethylene Oxide) (1,2-Epoxyethane) (Oxirane) Ethyl Ethanoate N-Ethylethanolamine C2H5NHC2H4OH
155 (68) (oc) 260 (127) 12 (-11) 608 (320) 3.3 54.8
1.0-
5.65
394 (201)
Yes
1.1
4.8
473 (245)
No
0.8
1.5
132 (56)
Yes
Note: See Hazardous Chemicals Data. -20 1058 with No Air 3.0 100 0.9 1.5 51 (11) Yes 1 2 4 3
Vapors explosive.
Note: See Hazardous Chemicals Data. See Ethyl Acetate. 160 (71) (oc) 0.9 3.0 322 (161) Yes 5 1 2 0
7-19N
Page 60
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
0.7 2.6
Upper
36.0
Note: See Hazardous Chemicals Data. See 1,2-Butanediol. 0.72 @ 7.2 atm 851 (455) 2.8 16.0 0.9 2.6 130 (54) No 1 5 2 3 0 1.66 -36 (-38) 4 0
0.90
5.11
291 (144)
See 2-Ethoxyethyl Acetate. See 2-Ethylhexanal. 375 (190) 0.85 @ 200 (93) 680 (360) 700 (371) 448 (231) 0.88 9.7 0.8 4.5 0.8 6.0 0.9 5.0 0.9 472 (244) 440 (227) 359 (182) Slight 5 2 2 0 No Slight 2 5 2 1 1 0 1 1 0 7.2 @ 275 (135) 0.8 4.4 325 (163) Very slight 2 2 1
See 2-Ethyl-3-Propylacrolein. See 2-Ethylhexanoic Acid. 515 (268) 485 (252) 0.8 4.5 0.9 0.76 8.14 0.9 5.9 390 (199) 266 (130) @ 50 mm 337 (169) 0.9 379 (193) @ 50 mm 0.9 5.1 343 (173) 0.8 342 (172) @ 50 mm 0.8 517 (269) See Vinyl-2-Ethylhexyl Ether. No 2 1 1 0 No 2 2 1 0 No 2 2 0 No 2 3 1 0 Yes 5 2 2 0 No 2 2 2 No 2 2 0
7-19N
Page 61
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
1.2
Upper
11.4
824 (440)
6.2
16
1.25 0.87
3.42 4.0
600 (316)
0.8
752 (400)
1.0+
4.1
309 (154)
Yes
See Diethyl Malonate. 572 (300) 2.8 18.0 0.8 2.1 95 (35) No 1 2 4 0
0.9
3.9
239-248 (115-120)
No
See Ethyl Formate. See Ethyl Methacrylate. See Methyl Ethyl Ether. 0.8 507 (264) See Methyl Ethyl Ketone. 0.9 4.0 280 (138) 896 (480) 4.0 1.1 3.1 1.02 5.39 496 (258) 190 (88) 194 (90) 4.0 50. 0.9 2.6 63 (17) Note: See Hazardous Chemicals Data. 446 (230) 445 (229) 1.1 5.0 0.74 4.91 0.74 4.91 333 (167) 328 (164) See Ethyl Silicate. 367 (186) Slight gradual decomposition See Ethyl Ether. See Ethyl Acetoacetate. 0 2 0 0 2 0 0 2 0 No 2 4 4 No 4 2 3 4 Yes 1 5 0 1 0 2 3 0 Very slight 2 0 1 0
Decomposes
7-19N
Page 62
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
1.0@ 140F (60C) Note: Melting point 115 (46).
Ethyl Phenylacetate C6H5CH2COOC2H5 Ethyl Phenyl Ether Ethyl Phenyl Ketone C2H5COC6H5 (Propiophenone) Ethyl Phosphate Ethyl Phthalyl Ethyl Glycolate C2H5OCOC6H4OCOCH2OCOC2H5 Ethyl Propenyl Ether CH3CH:CHOCH2CH3 Ethyl Propionate C2H5COOC2H5 2-Ethyl-3-Propylacrolein C3H7CH:C(C2H5)CHO (2-Ethylhexenal) 2-Ethyl-3-Propylacrylic Acid C3H7CH:C(C2H5)COOH Ethyl Propyl Ether C2H5OC3H7 (1-Ethoxypropane) Ethyl Silicate (C2H5)4SiO4 (Ethyl Orthosilicate) (Tetraethyl Orthosilicate) Ethyl Sulfate Ethyl Sulfhydrate m-Ethyltoluene CH3C6H4C2H5 (1-Methyl-3-Ethylbenzene) o-Ethyltoluene CH3C6H4C2H5 (1-Methyl-2-Ethylbenzene) p-Ethyltoluene CH3C6H4C2H5 (1-Methyl-4-Ethylbenzene) Ethyl p-Toluene Sulfonamide C7H7SO2NHC2H5 Ethyl p-Toluene Sulfonate C7H7SO3C2H5 Ethyltrichloro Silane CH3CH2SiCl3 Ethyl Vinyl Ether Ethyne Fish Oil
1.0+
No
1.01
4.63
425 (218)
Note: Melting point 70 (21). See Triethyl Phosphate. 365 (185) >19 (>-7) (oc) 54 (12) 155 (68) (oc) 330 (166) (oc) <-4 (<-20) 125 (52) (oc) See Diethyl Sulfate. See Ethyl Mercaptan. 896 (480) 824 (440) 887 (475) 260 (127) 316 (158) 72 (22) (oc) 1.2 1.2 1.3 0.88 4.15 0.88 4.15 0.88 4.15 322 (161) 329 (165) 324 (162) 208 (98) @ 745 mm 345 (174) 208 (98) @ 745 mm See Vinyl Ethyl Ether. See Acetylene. 420 (216) No 2 0 1 0 1 3 3 0 No 2 1 0 2 1 0 2 0 2 0 2 0 0.9 7.2 1.7 9.0 0.8 147 (64) 334 (168) Decomposes 2 2 0 Yes 5 1 3 0 0.9 450 (232) Slight 2 5 2 1 1 824 (440) 0.9 4.4 1.9 11 0.9 3.5 210 (99) 347 (175) No 5 2 2 1 No 1 3 0 0.8 1.2 608 (320) 158 (70) Yes 2 5 1 2 3 1 0 1 0
7-19N
Page 63
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
1.03 3.31
See Methylal. See Formaldehyde. 795 (424) 7.0 73 1.0 -3 (-19) 214 (101) 2 Note: See Hazardous Chemicals Data. 1.1 410 (210) Decomposes 1004 (539) 813 (434) Note: See Hazardous Chemicals Data. See Butyl Formate. See Ethyl Formate. See Methyl Formate. 410 (210) 0.7 5 <1 304-574 (151-301) No 0 2 0 18 57 1.2 1.6 213 (101) Yes 5 3 2 0 Yes 2 2 1 2 5 2 2 0 Yes 6 2 4 0
No No No
0 0 0
2 2 2
0 0 0
765 (407)
No
600 (316)
2.1
19.3
1.2
3.3
322 (161)
Slight
7-19N
Page 64
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
1.1 4.8
915 (491)
1.8
16.3
1.1
3.4
340 (171)
Yes
1.05
3.35
See Isoamyl Alcohol. 35 5.3 4.4 9001170 (482632) 3.86.5 4.8 20-30 7.0 5.6 640 (338) 1.4 536 (280) 1.4 1.5 853 (456) Note: Values may vary considerably for different grades of gasoline. 824 (440) 880 (471) No 1 1 4 0 1.2 7.1 1 3 0 1.3 7.1 1 3 0 1.4 7.6 7.6 7.4 1.4 7.6 7.6 0.8 3-4 0.5 74 32 34 1317 32.5 70-80 72 46.2 5.0 <1 500-700 (260-371) 100-400 (38-204) No 1 1 3 0 No 6 6 6 6 2 2 2 2 0 4 4 4 4 2 0 0 0 0 0 6 6 6 6 2 2 2 1 4 4 4 4 0 0 0 0
0.9
446 (230)
No
(CH3)2C:CH(CH2)2C(CH3):CHCH2OH (>100)
0.9
468-473 (242-245)
No
0.9
304 (151)
No
0.9
235 (113)
No
0.9
7-19N
Page 65
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
1.2
698 (370)
1.3
3.1
340 (171)
Yes
2 5
1.4
Yes
1.2
496 (258)
Slight
2 5
1.0+
597 (314)
No
5 2
See 1,2,3-Trichloropropanc. See Nitroglycerine. 790 (421) 779 (415) 0.8 @ 367 1.1 4.4 1.1 540 (282) 135 (57) @ 2 mm See Ethylene Glycol. 662 (350) 900 (482) 1.6 8.4 1.1 1.07 5.20 493 (256) 375 (191) Slight 5 1 1 0 No 0 1 0 No No 5 2 0 2 0 0 1 0
See Ethylene Dichloride. See 1,2-Ethanediol Diformate. 1.3 280 (138) 1.2 mm See Ethylene Glycol Monoacetate. See Ethyl Alcohol. See Deuterium. 0.7 5.4 384 (196) 0.8 588 (309) Note: Melting point 130 (54). 399 (204) 0.8 0.8 4.0 4.0 1.05 6.7 0.7 3.5 209 (98) 320 (160) 313 (156) See Ethyl Butyl Ketone. Slight 5 0 2 0 No 0 2 0 No 1 1 3 0 No 2 0 1 0 No 1 0 2 0 No 5 2 2 1 0
7-19N
Page 66
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
0.8 3.9
See Heptylene. 0.7 3.39 203 (95) 0.8 4.0 311 (155) 500 (260) 0.7 3.34 0.7 3.39 201 (94) 208 (98) 1130 (610) 1148 (620) 396 (202) 0.8@ 68 (20) 0.9 298-307 (148-153) @ 11 mm 464 (240) 0.78 7.72 525 (274) See tert-Hexadecanethiol. 1.01.3 8.1 0.9 516 (269) 339 (171) 2.0 6.1 0.7 2.8 151 (66) See Cyclohexylamine. See Cyclohexane. See Piperidine. See Methylcyclohexane. See 1,4-Dimethylcyclohexane. See Hexanal. See Cyclohexanol. See Cyclohexyl Acetate. See Cyclohexane. 0.8 3.6 268 (131) No 1 2 3 1 Very slight No 1 0 3 0 2 2 0 Yes 2 3 1 0 No 0 1 0 No 2 0 1 0 7.8 549 (287) No 0 1 0 13.0 2 1 1 8.99 2 1 1 0 3 0 No 0 3 0 Slight 5 2 2 0 No 1 0 3 0
437 (225)
1.1
7.5
0.7
3.0
156 (69)
No
7-19N
Page 67
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
1.0-
See Acetonyl Acetone. 1.1 352 (178) @ 5 mm See Caproic Acid. See Hexyl Alcohol. See Methyl Butyl Ketone. ~1 ~8 0.82 3.46 253 (123) 487 (253) 473 (245) 0.69 0.85 2.90 3.45 0.7 3.0 0.7 3.0 146 (63) 155 (68) 156 (69) 313 (156) Slight 5 1 2 0 0 3 0 No 1 1 3 0 No 1 1 3 0 1 3 0 Yes 2 5 1 1 0
See Methyl Isobutyl Ketone. 0.9 5.0 285 (141) 0.8 3.5 311 (155) Slight 5 1 2 0 No 5 1 2 0
0.81
3.53
284 (140)
0.8
3.5
269 (132)
Slight
1 5
See 1-Chlorohexane. 1.0486 (252) 0.9 385 (196) 365 (185) 0.8 6.4 440 (227) See Hexane. 0.9 5.9 388-464 (198-240) See 2-Octanone. See Ethylene Cyanohydrin. See Cyclohexanol. 0 2 0 No 2 2 0 2 1 1 0 5 1 0
7-19N
Page 68
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
1.0+ 1.1
Upper
98
Ignition temperatures vary widely in contact with iron rust 74 (23); black iron 270 (132); stainless steel 313 (156); glass 518 (270). Note: See Hazardous Chemicals Data. Hydrindane C9H16 (Hexahydroindane) (Octahydroindene) Hydrochloric Ether Hydrocyanic Acid-96% HCN (Prussic Acid) (Hydrogen Cyanide) Hydrogen H2 Hydrogen Cyanide Hydrogen Sulfide H2S Hydroquinone C6H4(OH)2 (HQ) (Quinol) (Hydroquinol) Hydroquinone Di-(-Hydroxyethyl) Ether C6H4(-OCH2CH2OH)2 435 (224) 875 (468) 365-392 @ 0.3 mm (185-200) Note: Melting point 201-205 (94-96). Hydroquinone Monomethyl Ether CH3OC6H4OH (HQMME) (4-Methoxy Phenol) (Para-Hydroxyanisole) o-Hydroxybenzaldehyde 3-Hydroxybutanal -Hydroxybutyraldehyde Hydroxycitronellal (Citronellal Hydrate) (3,7-Dimethyl-7-Hydroxyoctanal) N-(2-Hydroxyethyl)-acetamide 2-Hydroxyethyl Acrylate (HEA) -Hydroxyethylaniline N-(2-Hydroxyethyl) Cyclohexylamine C6H11NHC2H4OH 249 (121) (oc) Note: Melting point 97-102 (36-39). (2-Hydroxyethyl)Ethylenediamine CH2OHCH2NHCH2CH2NH2 4-(2-Hydroxyethyl) Morpholine CH2H4OC2H4NC2H4OH 275 (135) 210 (99) (oc) 1.1 1.0+ 460-464 (238-240) 437 (225) Yes Yes 2 5 5 2 1 0 1 1 0 214 (101) 1.8 @ 100C 1.1 See N-Acetyl Ethanolamine. 410 (210) See 2-Anilinoethanol. Yes 2 5 3 1 0 Yes 2 1 2 >212 0.9 (CH3)2C(OH)(CH2)3CH(CH3)CH2CHO(>100) Note: Melting point 126 (52). See Salicylaldehyde. See Aldol. See Aldol. 201-205 (94-96) @ 1 mm Slight 5 1 0 270 (132) (oc) 790 (421) 1.5 475 (246) No 2 1 0 Slight 2 1 0 329 (165) Gas 500 (260) 960 (516) 1.3 4.0 44.0 Gas 932 (500) 4.0 75 Note: See Hazardous Chemicals Data. 0.1 -422 (-252) Note: See Hazardous Chemicals Data. See Hydrocyanic Acid. 1.2 -76 (-60) Note: See Hazardous Chemicals Data. 547 (286) No 5 2 2 1 0 Yes 6 3 4 0 Slight 6 0 4 0 0 (- 18) 1000 (538) 5.6 40.0 0.7 See Ethyl Chloride. 0.9 79 (26) Yes 4 4 2 Vapors extremely toxic. 565 (296) 0.9 318 (159) 5 0
7-19N
Page 69
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
1.1 4.5
1.0-
465 (241)
Yes
2 5
1.2
Yes
See Hazardous Chemicals Data. 4-Hydroxy-4-Methyl-2-Pentanone 2-Hydroxy-2-methyl-propionitrile Hydroxypropyl Acrylate o-Hydroxytoluene Ionone Alpha (-Ionone) C(CH3)2CH2CH2CH:C(CH3)CHCH:CHC(CH3):O (-Cyclocitrylideneacetone) [4-(2,6,6-Trimethyl2-Cyclohexen-1-yl)-3-Buten-2-one] Ionone Beta (-Ionone) C(CH3)2CH2CH2CH2C(CH3):CCHCHC(CH3):O (-Cyclocitrylidene-acetone) [4-(2,6,6-Trimethyl-1Cyclohexen-1-yl)-3-Buten-2-one] Iron Carbonyl Fe(CO)5 Isano Oil 5 (-15) 1.0Exothermic reaction above 502 (261) may become explosive. Isoamyl Acetate CH3COOCH2CH2CH(CH3)2 (Banana Oil) (3-Methyl-1-Butanol Acetate) (2-Methyl Butyl Ethanoate) Isoamyl Alcohol (CH3)2CHCH2CH2OH (Isobutyl Carbinol) (Fusel Oil) (3-Methyl-1-Butanol) tert-Isoamyl Alcohol Isoamyl Butyrate C3H7CO2(CH2)2CH(CH3)2 (Isopentyl Butyrate) Isoamyl Chloride (CH3)2CHCH2CH2Cl (1-Chloro-3-Methylbutane) Isobornyl Acetate C10H17OOCCH3 Isobutane (CH3)3CH (2-Methylpropane) Isobutyl Acetate CH3COOCH2CH(CH3)2 (-Methyl Propyl Ethanoate) 64 (18) 790 (421) 1.3 10.5 0.9 4.0 244 (118) No 5 1 1 3 0 190 (88) Gas 860 (460) 1.8 8.4 2.0 1.0428-435 (220-224) 11 (-12) No 6 1 4 0 No 5 1 2 0 <70 (<21) 1.5 7.4 0.89 3.67 212 (100) 3 138 (59) 0.88 See 2-Methyl-2-Butanol. 5.45 352 (178) 2 109 (43) 662 (350) 1.2 9.0 @ 212 (100) 0.8 3.0 270 (132) Slight 5 1 2 0 77 (25) 680 (360) 1.0 @ 212 (100) 7.5 0.9 4.5 290 (143) Slight 5 1 1 1.45 6.74 221 (105) 1 3 May explode above 502 (261). 3 0 2 3 1 >212 (>100) 0.9 284 (140) @ 18 mm No 5 1 0 >212 (>100) 0.9 See Diacetone Alcohol. See Acetone Cyanohydrin. See Propylene Glycol Monoacrylate. See o-Cresol. 259-262 (126-128) @ 12 mm Slight 5 1 0
7-19N
Page 70
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
0.9 4.42
0.8
2.6
225 (107)
Yes No
5 1
2 2 0
3 2 2
0 0
See Isoamyl Alcohol. 2.0 8.8 0.9 3.2 156 (69) 525 (274) 608 (320) 770 (410) 0.8 ~1.7 ~8 0.88 3.52 0.8 336 (169) See 2-Methylpropene. 208 (98) 412-426 (211-219) No 5 2 2 0 3 0 0 2 3 0
810 (432)
0.96
7.59
4.97
No
5 5
0 0
2 1 1
0 0
9.12
302 (150) @ 20 mm
See Vinyl Isobutyl Ether. 385 (196) 900 (481) 625 (329) 900 (482) 0.8 2.38 1.0 6.2 1.05.5 2.0 9.2 1.03.0 1.6 10.6 0.8 2.5 142 (61) 306 (152) 360 (182) 214-216 (101-102) Slight 5 1 3 3 0 Decomposes 5 1 2 1 Yes Slight 5 1 5 1 2 0 2 3 1
0.8
5.4
387 (197)
No
410 (210)
0.73
4.91
333 (167)
0.9
5.9
489 (254)
No
0.8
5.5
428 (220)
No
7-19N
Page 71
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
1.1
1.0
6.0
0.7
3.45
194 (90)
No
1.0 1.0
6.0 7.0
No No
1 1
1 1
3 3 2
0 0 0
0.7
3.94
210 (99)
No
0.9
5.0
No
0.7 0.8
3.87
1 5
0 0
3 2
0 0
1.0-
No
0.8
2.97
250 (121)
Slight
5 1
788 (420)
1.4
7.6
0.6
82 (28)
No
0.9
361 (183)
No
0.9
419 (215)
Slight
1.4
6.9
529 (276)
No
Note: Melting point 109.9 (43). - 65 (- 54) 743 (395) 1.5 8.9 0.7 2.4 93 (34) See Isopropyl Alcohol. See 1-Amino-2-Propanol. 808 (431) 0.9 3.5 207 (97) Slight 5 1 2 3 0 No 1 2 4 2
7-19N
Page 72
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
0.7 2.3
See Isopropyl Ether. 0.9 3.9 149 (65) @ 10 mm 860 (460) 750 (399) 1.8 @ 100 (38) 2.0 12.7 @ 200 (93) 0.8 2.1 181 (83) Yes 5 1 1 3 0 8 0.9 3.5 194 (90) Slight 5 1 1 3 0 Slight 5 1 2 1
756 (402)
0.7
2.0
Yes
5 1
1.0+ 446 (230) 815 (435) 0.5 @ 302 (150) 0.5 @ 347 (175) 1100 (593) 541 (283) 0.8 2.8 4.1 @ 400 (204) 3.2 @ 392 (200) 1.00.9
No 2
1 0
1 1 0
10.7
0.9
2.7
Very slight
0.8
4.9
No
830 (443)
1.4
7.9
0.7
3.5
156 (69)
Very slight
5 1
Note: See Hazardous Chemicals Data. See 3-Methyl-1-Butene. 905 (485) 491 (255) 0.87 3.04 0.9 3.0 153 (67) 155 (68) See Isopropyl Lactate. 1.04.2 331-334 (166-168) See Isopropyl Formate. See p-Cymene. See Vinyl Isopropyl Ether. Yes 5 2 2 0 0 2 0 Slight 2 3 0
7-19N
Page 73
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1) Boiling Point F (C)
400-550 (204-288) 1 3 0
1.3
8.0
0.6
3.7
0.8
<1
250 (121)
No
See Peanut Oil (cooking). See Fuel Oil No. 1. See Ultrasene. 0.98 833 (445) 833 (445) <1 No 2 0 1 0 <1 2.45 361 (183) No 2 0 1 0 Yes 4 2 1
0.9
No
See 1-Dodecanol. 1.0+ 356 (180) @ 45 mm See 1-Dodecanethiol. 0.9 383-390 (195-199) No 5 2 0 No 2 1 1 0
650 (343)
0.9
600+ (316+)
No
See Camphor Oil (light). 300-450 500-700 (149232) 169 (76) 400 (204) (oc) (260371) 478 (248) 700 (371) <1 No 2 0 1 0 <1 <1 680 (360) No 0 2 0 No 2 0 1 0
7-19N
Page 74
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
0.9
890 (477)
1.4
7.1
0.9
Slight
5 2
See Hazardous Chemicals Data. Marsh Gas Menhaden Oil (Pogy Oil) 2-Mercaptoethanol HSCH2CH2OH Mesitylene Mesityl Oxide (CH3)2CCHCOCH3 Metaldehyde (C2H4O)4 -Methacrolein Methacrylic Acid CH2:C(CH3)COOH 171 (77) (oc) Note: Polymerizes. See Hazardous Chemicals Data. Methacrylonitrile C4H5N Methallyl Alcohol CH2C(CH3)CH2OH Methallyl Chloride CH2C(CH3)CH2Cl Methane CH4 (Marsh Gas) Methanol Methanethiol Methox o-Methoxybenzaldehyde CH3OC6H4CHO (o-Anisaldehyde) Methoxybenzene 3-Methoxybutanol CH3CH(OCH3)CH2CH2OH 3-Methoxybutyl Acetate CH3OCH(CH3)CH2CH2OOCCH3 (Butoxyl) 3-Methoxybutyraldehyde CH3CH(OCH3)CH2CHO (Aldol Ether) 2-Methoxyethanol 2-Methoxyethyl Acrylate C2H3COOC2H4OCH3 180 (82) (oc) See Ethylene Glycol Monomethyl Ether. 1.01 4.49 142 (61) @ 17 mm 0 2 0 140 (60) 0.94 3.52 262 (128) 0 2 0 165 (74) (oc) 170 (77) 1.05.0 275-343 (135-173) Slight 5 1 2 0 0.9 3.6 104 (40) (oc) See Anisole. 322 (161) Yes 5 1 2 0 1.1 See Methyl Alcohol. See Methyl Mercaptan. See Methoxy Ethyl Phthalate. 275 (135) No 2 2 1 0 34 (1.1) (TCC) 92 (33) 11 (-12) Gas 999 (537) 5.0 15.0 0.6 3.2 8.1 0.9 3.1 0.9 2.5 237 (114) 162 (72) -259 (-162) No No Slight 1 5 1 5 6 1 4 0 2 3 1 2 3 0 2 6.8 0.8 2.3 194 (90) Slight 2 3 2 154 (68) 1.6 8.8 1.0+ 87 (31) 97 (36) 652 (344) 1.4 7.2 0.9 435 (224) 165 (74) (oc) See 1,3,5-Trimethylbenzene. 3.4 266 (130) Note: See Hazardous Chemicals Data. subl. 233-240 (112-116) See 2-Methylpropenal. 2.97 316 (158) Yes 5 3 2 2 No 1 1 3 1 Slight 1 5 3 3 0 828 (442) 1.1 2.7 315 (157) Yes 5 2 2 0.9 See Methane. No 2 0 1 0
7-19N
Page 75
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
1.2 0.92 2.94
0.86 1.0+
3.07
2 0
3 1
0 0
1.1
266 (130)
Yes
2 5
1.0+
No
850 (454)
3.1
16
0.9
2.8
140 (60)
Yes
1 5
See Methyl Acetate. 536 (280) 1.01.1 4.0 338 (170) 439 (226) No 5 0 1 0 Yes 5 2 2 0
See Propyne. See 2-Methylpropenal. 875 (468) 2.8 25 1.03.0 176 (80) Note: Polymerizes. See Hazardous Chemicals Data. Very slight 1 2 3 2
Methylal CH3OCH2OCH3 (Dimethoxymethane) (Formal) Methyl Alcohol CH3OH (Methanol) (Wood Alcohol) (Columbian Spirits) Methylaluminum Sesquibromide (CH3)3Al2Br3
2.2
13.8
0.9
2.6
111 (44)
Yes
1 5
6.0
36
0.8
1.1
147 (64)
Yes
1 5
Do not use water, foam or halogenated extinguishing agents. Note: Ignites spontaneously in air. 3 3 Do not use water, foam or halogenated extinguishing agents. Gas 806 (430) 4.9 20.7 1.0 21 (-6) Note: See Hazardous Chemicals Data. See N-Methylethanolamine. See Hexyl Acetate. See Methyl Isobutyl Carbinol. Yes 6 3 4 0
7-19N
Page 76
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
0.8 3.9
Upper
7.9 @ 250 (121)
See o-Toluidine. See p-Toluidine. 1.2 275 @ 15 mm (135) See Toluol. 1.1 4.7 302 (150) See Phenyl Methyl Carbinol. 1.04.2 371 (188) 0.9 5.2 384 (196) 1.0 548 (287) 936 (502) 0.9 3.6 1.0+ 492 (255) 156 (69) 999 (537) 10 16.0 1.7 3.3 38.4 (4) Note: See Hazardous Chemicals Data. See Isoprene See Isopentane 0.85 3.59 230 (110) 725 (385) 819 (437) 1.2 9.0 0.8 3.0 0.8 3.0 262 (128) 215 (102) Slight 5 1 1 3 0 Slight No 5 1 5 2 2 0 2 3 0 No 3 1 0 Decomposes 2 3 1 No 2 5 2 0 2 1 0 Slight 5 2 2 0 Slight 5 2 2 0 No 3 0 2 0 Slight 5 0 1 0
non-flammable
See Isoamyl Alcohol. See Isoamyl Acetate. 0.7 2.4 88 (31) 0.7 2.4 101 (38) 689 (365) 1.5 9.1 0.6 2.4 68 (20) No Slight 1 5 1 2 4 0 2 3 0 No 1 2 4 0
7-19N
Page 77
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
0.7 3.0
See Isoamyl Acetate. 795 (423) 0.9 2.9 8 0.8 3.5 262 (128) 218 (103) 0.8 2.97 198-199 (92-93) Note: See Hazardous Chemicals Data. No Yes Slight 1 5 1 5 5 1 2 3 0 2 3 0 2 3 0
Methyl Butyrate CH3OOCCH2CH2CH3 Methyl Carbonate CO(OCH3)2 (Dimethyl Carbonate) Methyl Cellosolve Acetate CH3COOC2H4OCH3 (2-Methoxyethyl Acetate) Methyl Chloride CH3Cl (Chloromethane) Methyl Chloroacetate CH2ClCOOCH3 (Methyl Chloroethanoate) Methyl Chloroethanoate Methyl para-Cresol CH3C6H4OCH3 (p-Methylanisole) (p-Cresyl Methyl Ether, p-Methoxy Toluene) Methyl Cyanide Methylcyclohexane CH2(CH2)4CHCH3 (Cyclohexylmethane) (Hexahydroxytoluene) 2-Methylcyclohexanol C7H13OH 3-Methylcyclohexanol CH3C6H10OH 4-Methylcyclohexanol C7H13OH Methylcyclohexanone C7H12O 4-Methylcyclohexene CH:CHCH2CH(CH3)CH2CH2 Methylcyclohexyl Acetate C9H16O2 Methyl Cyclopentadiene C6H8
0.9 1.1
3.5 3.1
Slight Slight
1 5 1 5
2 2
3 3
0 1
1.0
4.07
292 (144)
Yes
-50
1170 (632)
8.1
17.4
1.8
-11 (-24)
Slight
Note: See Hazardous Chemicals Data. 135 (57) (oc) See Methyl Chloroacetate. 140 (60) 1.04.21 5 2 0 7.5 18.5 1.2 3.8 266 (130) Very slight 2 2 1
See Acetonitrile. 25 (-4) 482 (250) 1.2 6.7 0.8 3.4 214 (101) No 1 2 3 0
149 (65) ~158 (~70) 158 (70) 118 (48) 30 (-1) (oc) 147 (64) 120 (49)
0.9
3.9
329 (165)
Slight
5 0
2 2 2 2
0 0 0 0 0
Slight No No
0.9 833 (445) 1.3 @ 212 (100) 7.6 @ 212 (100) 0.9
1 1
2 2
0 1
7-19N
Page 78
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
0.8 0.74 2.9 5.39 3.97
Upper
8.35
6.0
55
1.1
Note: See Hazardous Chemicals Data. 1.0+ 464 (240) 851 (455) 1.0+ 1033 (556) 13 23 1.3 2.9 0.86 5.12 394 (201) 689-698 (365-370) 104 (40) Note: See Hazardous Chemicals Data. Methylenedianiline H2NC6H4CH2C6H4NH2 (MDA) (p,p -Diaminodi-Phenylmethane) Note: Melting point 198-199 (92-93). Methylene Diisocyanate CH2(NCO)2 Methylene Oxide N-Methylethanolamine CH3NHCH2CH2OH (2-(Methylamino) Ethanol) Methyl Ether (CH3)2O (Dimethyl Ether) (Methyl Oxide) Methyl Ethyl Carbinol 2-Methyl-2-Ethyl-1,3-Dioxolane (CH3)(C2H5)COCH2CH2O Methyl Ethylene Glycol Methyl Ethyl Ether CH3OC2H5 (Ethyl Methyl Ether) 2-Methyl-4-Ethylhexane (CH3)2CHCH2CH(C2H5)2 (4-Ethyl-2-Methylhexane) 3-Methyl-4-Ethylhexane C2H5CH(CH3)CH(C2H5)2 (3-Ethyl-4-Methylhexane) Methyl Ethyl Ketone C2H5COCH3 (2-Butanone) (Ethyl Methyl Ketone) Methyl Ethyl Ketoxime CH3C(C2H5):NOH 156-170 (69-77) 0.9 3.0 306-307 (152-153) Slight 5 2 0 16 (-9) 759 (404) 1.4 @ 200 (93) 11.4 @ 200 (93) 0.8 2.5 176 (80) Yes 1 5 1 3 0 75 (24) 0.72 4.43 284 (140) 0 3 0 < 70 (<21) 536 (280) ~0.7 -35 (-37) 374 (190) 0.72 4.43 2.0 10.1 0.7 74 (23) (oc) See Propylene Glycol. 2.1 51 (11) Note: See Hazardous Chemicals Data. 273 (134) 0 3 0 Yes 1 5 2 4 1 0.9 See sec-Butyl Alcohol. 4.0 244 (118) No 1 2 3 0 165 (74) (oc) Gas 662 (350) 3.4 27.0 1.6 -11 (-24) Yes 6 2 4 1 0.9 185 (85) (oc) See Formaldehyde. 2.6 319 (159) Yes 5 2 2 0 1 2 1 428 (220) 1.1 748-750 (398-399) @ 78 mm Slight 2 3 1 0 Slight 2 1 0 2 1 1 0 Yes 2 5 0 2 0 1 1 0
7-19N
Page 79
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
0.72 3.94
0.8
4.4
326 (163)
Slight
1.1
6.6
0.9
4.2
353 (178)
Slight
1.0+
196-203 (91-95)
No
840 (449)
4.5
23
1.0-
2.1
90 (32)
Yes
1 5
329 (165) Note: Melting point 127 (53) @ 3 mm 4.35 343-345 (173-174) 0.9 0.9
No
135 (57)
No
4.9
361-383 (183-195)
No
0 0 0
3 3 2
0 0 0
382 (194)
2.5
92
0.9 1.1
1.6 4.1
Slight Yes
1 5 5
3 1
3 2 0
0.9
291 (144) @ 16 mm
No
375 (191)
0.8
3.9
294 (146)
No
7-19N
Page 80
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
0.8
Upper
5.5
See 4-Methyl-2-Pentanol Acetate. 840 (448) 1.2 @ 200 (93) 1.8 994 (534) 1.1 5.3 8.0 @ 200 (93) 9.0 26 1.02.9 1.97 208 (98) 102 (39) 504-507 (262-264) 725 (385) 2.2 @ 212 (100) 3.9 21.8 0.9 1.7 42.4 (6) 491 (255) 1.7 8.2 0.9 3.6 1.03 3.60 ~329 (~165) 212 (100) Note: Polymerizes. See Hazardous Chemicals Data. Very slight 1 2 3 2 2 0 Yes 5 2 4 0 1.1 3.6 293 Yes 1 2 0 No 5 0 1 0 Yes 5 2 3 3 2 0 0.8 3.5 244 (118) Slight 5 1 2 3 0
(145) Decomposes
Methyl Methanoate 4-Methylmorpholine C2H4OC2H4NCH3 1-Methylnaphthalene C10H7CH3 Methyl Nonyl Ketone C9H19COCH3 Methyl Oxide Methyl Pentadecyl Ketone C15H31COCH3 2-Methyl-1,3-Pentadiene CH2:C(CH3)CH:CHCH3 4-Methyl-1,3-Pentadiene CH2:CHCH2:C(CH3)2 Methylpentaldehyde CH3CH2CH2C(CH3)HCHO (Methyl Pentanal) Methyl Pentanal 2-Methylpentane (CH3)2CH(CH2)2CH3 (Isohexane) <20 (<-7) 583 (306) 1.2 7.0 0.7 248 (120) <-4 (< -20) -30 (-34) 68 (20) (oc) 0.8 0.7 0.72 192 (89) 75 (24) 984 (529) 0.8@ 86 (30) 1.0+ 0.9
See Methyl Formate. 3.5 239 (115) 472 (244) 5.9 433 (223) See Methyl Ether. 313 (156) @ 3 mm 2.83 169 (76) 168 (76) 3.5 243 (117) Very slight 1 2 3 1 No 1 0 3 1 0 3 0 No 2 0 1 0 No 0 2 0 No Yes 1 5 2 2 0 2 3 0
7-19N
Page 81
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
0.7 1.00.92 4.07 3.0
Upper
7.0
712 (378) 590 (310) 660 (349) 0.9 5.83 1.1 9.65
0.9
4.0
381 (194)
No
0.8
3.5
298 (148)
No
See Methyl Isobutyl Carbinol. 0.9 5.0 295 (146) Very slight 1 2 0
}
@ 212 (100) 0.7 0.7 0.7 0.7 0.9 3.4 2.9 2.9 2.9 1.1 1.0+ 1.0+ 1.2 0.9 3.5 0.8 3.1
See Methyl Isobutyl Ketone. 572 (300) 572 (300) 143 (62) 129 (54) 153 (67) 133-137 (56-58) 250 (121) See o-Cresol. 424 (218) 399 (204) Slight 5 0 2 0 No 5 0 2 0 Yes 5 1 2 0 1 1 3 0 1 1 3 0 1 1 3 0 1 1 3 0
No
See Anisole 590 (310) 280 (138) See Isobutyraldehyde. See Isobutane. 149-153 (65-67) See Isobutyl Alcohol. See tert-Butyl Alcohol. No 1 2 3 0 Yes 5 2 2 0 No 2 2 1 0
7-19N
Page 82
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
0.8 2.4
869 (465)
1.8
9.6
1.9
20 (-7)
No
876 (469)
2.5
13
0.9 0.73
3.0 2.83
No
3 3
0.8
3.0
247 (119)
No
See sec-Amylamine. 0.91 846 (452) 1.02 3.25 1.5 8.2 0.8 2.56 3.0 102 (39) 216 (102) Slight 1 5 2 2 0 2 3 0 0 3 0
See 2-Picoline. 0.9 2.8 234 (112) 0.8 655 (346) 1.0+ 2.9 3.4 180 (82) 396 (202) Yes Slight 5 1 5 2 1 0 2 3 1 No 1 2 3 1
850 (454)
1.2
432 (222)
No
No No
0 1
1 2
0 1
See Dimethyl Sulfate. 0.9 3.0 176 (80) 315 (157) @ 8 mm Note: Melting point 75 (24). No Slight 1 5 2 2 1 0 2 3 0
7-19N
Page 83
See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
1.29 5.16
Upper
>20
0.8
248 (120)
No
390 (199)
0.8
3.45
240 (116)
5 1
See Isopropenyl Acetate. See Vinyl Methyl Ether. 915 (491) 0.8-0.9 2.1 15.6 2.4 177 (81) 680 (360) 0.8 480-680 (249-360) 473 (245) 0.8 @ 212 (100) See Wax, Ozocerite. See Chlorobenzene. 555 (290) 1.4 11.2 1.0 3.0 262 (128) Note: Decomposes at 489 (250). Note: See Hazardous Chemicals Data. Yes 5 2 3 0 0.8 3.9 300 (149) No 0 2 0 No 0 2 0 No 2 0 1 0 1 3 3 2
Muriatic Ether Mustard Oil C3H5N:C:S (Allyl Isothiocyanate) Naphtha 49 Be-Coal Tar Type Naphtha, Petroleum Naphtha, Safety Solvent Naphtha V.M. & P., 50 Flash (10) 50 (10) Naphtha V.M. & P., High Flash 85 (29) Naphtha V.M. & P., Regular 28 (-2) Naphthalene C10H8 (White Tar) -Naphthol C10H7OH (-Hydroxy Naphthalene) (2-Naphthol) 1-Naphthylamine C10H7NH2 315 (157) 1.2 307 (153) 1.22 174 (79) 450 (232) 450 (232) 450 (232) 979 (526) 0.9 5.9 1.1 0.9 6.0 <1 1.0 6.0 <1 0.9 6.7 <1 107 (42) 531 (277) 115 (46) 1.0+
See Ethyl Chloride. 3.4 304 (151) No See Petroleum Ether. See Cleaning Solvent. 4.1 240-290 (116-143) Note: Flash point and ignition temperature will vary depending on the manufacturer. 4.3 280-350 (138-177) Note: Flash point and ignition temperature will vary depending on the manufacturer. 212-320 (100-160) Note: Flash point and ignition temperature will vary depending on the manufacturer. 4.4 424 (218) Note: Melting point 176 (80). See Hazardous Chemicals Data. 4.98 545 (285) Note: Melting point 253 (123). 572 (300) Note: Melting point 122 (50). No 2 2 1 0 1 0 No 2 2 0 No 1 1 3 0 No 1 1 3 0 No 1 1 3 0 2 2 0 No 3 2 0
7-19N
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0.9
Note: Melting point 84-106 (29-41). See 2,2-Dimethylbutane. See 2,2-Dimethylpropane. 750 (399) 1.1 410 (210) Yes 2 1 1 0
Note: Melting point 255-266 (124-130). Nickel Carbonyl Ni(CO)4 Nicotine C10H14N2 Niobe Oil Nitric Ether 2,2,2-Nitrilotriethanol 1,1,1-Nitrilotri-2-propanol p-Nitroaniline NO2C6H4NH2 Nitrobenzene C6H5NO2 (Nitrobenzol) (Oil of Mirbane) Note: See Hazardous Chemicals Data. 1,3-Nitrobenzotrifluoride C6H4NO2CF3 (,,-Trifluoronitro-toluene) Nitrobenzol Nitrobiphenyl C6H5C6H4NO2 Nitrocellulose Nitrochlorobenzene C6H4ClNO2 261 (127) 1.5 290 (143) 1.2 217 (103) (oc) See Nitrobenzene. 626 (330) See Cellulose Nitrate. 457 (236) Note: Melting point 111 (44). Note: See Hazardous Chemicals Data. p-Nitrochlorobenzene C6H4ClNO2 (1-Chloro-4-Nitro-benzene) Note: Melting point 181 (83). Nitrocyclohexane CH2(CH2)4CHNO2 Nitroethane C2H5NO2 Nitroglycerine C3H5(NO3)3 (Glyceryl Trinitrate) Nitromethane CH3NO2 95 (35) 785 (418) 7.3 1.1 2.1 190 (88) (oc) 82 (28) Explodes 778 (414) 518 (270) 1.6 3.4 1.1 2.6 1.07 4.46 403 (206) Decomposes 237 (114) Note: See Hazardous Chemicals Data. 502 (261) Explodes 214 (101) Note: May detonate under high temperature and pressure conditions. See Hazardous Chemicals Data. Slight 1 5 1 3 3 No 2 2 4 Slight 4 5 1 3 3 Explodes on heating. 2 2 3 261 (127) 1.37 5.44 468 (242) 2 1 3 No 2 3 1 1 No 2 2 1 0 1.44 6.59 397 (203) 1 390 (199) 190 (88) 900 (482) 1.8 @ 200 (93) 1.2 4.3 1.44 <-4 (<-24) 471 (244) 0.7 4.0 1.0 5.6 2 1.32 5.89 110 (43) 475 (246) See Methyl Benzoate. See Ethyl Nitrate. See Triethanolamine. See Triisopropanolamine. 4.77 637 (336) Note: Melting point 298 (148). 412 (211) No 3 3 2 0 3 1 3 Yes 2 5 4 1 0 4 3 3
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See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
1.3
Note: Melting point 140 (60). 789 (421) 2.2 1.0 3.1 268 (131) Note: See Hazardous Chemicals Data. 2-Nitropropane CH3CH(NO2)CH3 (sec-Nitropropane) sec-Nitropropane Nitrotoluene m-Nitrotoluene C6H4CH3NO2 o-Nitrotoluene C6H4CH3NO2 p-Nitrotoluene NO2C6H4CH3 223 (106) 223 (106) 223 (106) Note: Melting point 125 (52). 2-Nitro-p-toluidine CH3C6H3(NH2)NO2 Nitrous Ether Nonadecane CH3(CH2)17CH3 Nonane C9H20 Nonane (iso) C6H13CH(CH3)2 (2-Methyloctane) Nonane (iso) C5H11CH(CH3)C2H5 (3-Methyloctane) Nonane (iso) C4H9CH(CH3)C3H7 (4-Methyloctane) Nonene C9H18 (Nonylene) Nonyl Acetate CH2COOC9H19 Nonyl Alcohol Nonylbenzene C9H19C6H5 tert-Nonyl Mercaptan C9H19SH Nonylnaphthalene C9H19C10H7 Nonylphenol C6H4(C9H19)OH 210 (99) 154 (68) (oc) <200 (<93) 285 (141) 1.00.9 8.8 626-653 (330-345) 559-567 (293-297) Very slight 2 5 2 1 0 No 0 2 0 0.9 5.53 0.9 78 (26) (oc) 155 (68) 0.9 6.4 378 (192) See Diisobutyl Carbinol. 468-486 (242-252) 370-385 (188-196) No 5 2 2 0 No 0 1 0 Very slight 5 1 2 0 0.7 4.35 270-290 (132-143) No 1 0 3 0 437 (225) 0.72 4.43 288 (142) 0 3 0 428 (220) 0.72 4.43 291 (144) 0 3 0 >212 (>100) 88 (31) 446 (230) 401 (205) 428 (220) 0.71 4.43 0.8 2.9 0.7 4.4 0.79 315 (157) Note: Melting point 259 (126). See Ethyl Nitrite. 9.27 628 (331) Note: Melting point 90 (32). 303 (151) 290 (143) 0 3 0 No 1 0 3 0 0 1 0 1.31 5.25 1.3 1.16 4.73 1.16 75 (24) 802 (428) 2.6 11.0 1.03.1 248 (120) Note: See Hazardous Chemicals Data. See 2-Nitropropane. See p-Nitrotoluol. 4.73 450 (232) Note: Melting point 61 (16). 432 (222) Note: Melting point 25 (-4). 461 (238) Note: See Hazardous Chemicals Data. 2 1 4 No 2 3 1 0 2 1 4 2 1 4 Slight 5 2 3 1 May explode on heating. Slight 5 1 3 1 May explode on heating.
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See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
0.9 3.17
0.78
8.73
603 (317)
Note: Melting point 82 (28). 0.79 8.71 599 (315) Note: Melting point 64 (18). 1.0 716 (380) See Vinyl Octadecyl Ether. See Caprylaldehyde. 403 (206) 0.85 5.04 1.0 6.5 0.7 3.9 258 (126) 390 (199) See Octyl Alcohol. 0.8 446 (230) 0.7 3.9 0.7 4.5 3.9 363 (184) 250 (121) 257 (125) See 2-Ethylhexyl Acetate. 0.8 4.5 381 (194) 0.8 4.5 338 (170) 1.41 4.46 284 (140) 0.9 635 (335) 0.8 5.0 0.9 5.1 359 (182) 475 (246) 318-329 (159-165) 780 (416) Note: Melting point 162-165 (72-74). Oil of Mirbane Oil of Wintergreen Oleic Acid C8H17CH:CH(CH2)7COOH (Red Oil) Distilled 364 (184) 372 (189) 685 (363) 0.9 See Nitrobenzene. See Methyl Salicylate. 547 (286) No 2 0 1 0 2 1 1 0 No 2 2 0 No 2 1 1 0 No 1 2 0 3 0 Slight 5 2 2 0 No 1 2 0 No 1 1 3 0 No 1 1 3 0 No 1 2 0 No 5 2 2 0 No 1 0 3 0 Yes 3 2 2 0 1 0
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See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
0.9
650 (343)
0.9 See Ethyl Oxalate. See Hydroxylamine. See Ethylene Oxide. See Palm Oil. 0.9
600 (316)
0.9
No
Note: Melting point 80-110 (27-43). 2 572 (300) Note: Melting point 248-356 (120-180). See Hazardous Chemicals Data. Paraldehyde (CH3CHO)3 96 (36) (oc) Note: Melting point 54 (12). See Hazardous Chemicals Data. Peanut Oil Cooking (Katchung Oil) Pentaborane B5H9 0.42 0.6 2.2 140 (60) 1 3 3 2 Reacts violently with halogenated extinguishing agents. No 1 2 3 0 540 (282) 833 (445) 0.9 No 2 0 1 0 460 (238) 1.3 1.04.5 255 (124) Slight 1 5 2 3 1 7.0 73 Slight 5 0 2 1 1 0 0
Note: Ignites spontaneously in air. See Hazardous Chemicals Data. Pent-Acetate Mixture of Isomeric Amyl Acetates and Amyl Alcohols 1,3-Pentadiene (cis and trans mix) CH2:CHCH:CHCH3 (Piperylene) 1,2,3,4,5-Pentamethyl Benzene 95% C6H(CH3)5 (Pentamethylbenzene) Pentamethylene Dichloride Pentamethylene Glycol Pentamethylene Oxide O(CH2)4CH2 (Tetrahydropyran) Pentanal Pentane CH3(CH2)3CH3 1,5-Pentanediol HO(CH2)5OH (Pentamethylene Glycol) 2,4-Pentanedione CH3COCH2COCH3 (Acetyl Acetone) < -40 (< -40) 265 (129) (oc) 93 (34) 644 (340) 1.03.5 284 (140) Yes 5 2 2 0 500 (260) 635 (335) 1.01.5 7.8 0.6 See Valeraldehyde. 2.5 97 (36) 468 (242) Yes 2 5 1 1 0 No 1 1 4 0 -4 (-20) 0.9 See 1,5-Dichloropentane. See 1,5-Pentanediol. 3.0 178 (81) Yes 1 5 2 3 1 200 (93) 800 est (427) 0.9 449 (232) No 2 0 98 (37) -20 (-29) 0.7 2.35 0.9 260 (127) -45 (-43) No 1 0 4 2
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See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
0.9 3.5
See Amyl Alcohol. See Methyl Propyl Carbinol. 815 (435) 1.2 9.0 0.8 3.0 241 (116) See Amyl Acetate. See sec-Amyl Acetate. See Methyl Propyl Ketone. See Diethyl Ketone. 0.9 482 (250) Note: Melting point 195 (91). See Glucose Pentapropionate. 527 (275) 1.5 8.7 0.7 2.4 86 (30) See -Amylene-cis. See -Amylene-trans. See Amylamine. See Amyl Ether. See Amyl Propionate. 0.69 2.35 104 (40) 221 (105) Note: Decomposes violently at 230 (110). See Hazardous Chemicals Data. Yes 3 2 4 3 3 1 1 4 0 No 2 2 1 0 Slight 5 1 2 0
Explodes on heating.
Perchloroethylene, Tetrachloroethylene Cl2C=CCl2 Perhydrophenanthrene C14H24 (Tetradecahydro Phenanthrene) Perilla Oil Petroleum, Crude
None
None
None
1.6
5.8
250 (121)
No
0.9
187-192 (86-89)
0.9 <1
No No
2 1
0 1
1 3
0 0
550 (288)
1.1
5.9
0.6
2.5
95-140 (35-60)
No
120 (49)
~0.9
4.68
340 (171)
No
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See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
1.1
Note: Melting point 212 (100). 205 (96) 1.0+ 430 (221) No 2 1 1 0
442-446 (228-230)
No
5 2
1.1
378-484 (192-251)
Very slight
See Ethoxybenzene. 1319 (715) 1.8 8.6 1.1 3.2 358 (181) Note: See Hazardous Chemicals Data. Melting point 108 (42). See Ethylene Glycol, Phenyl Ether. 1.11 4.77 468 (242) Note: Melting point 58 (14). 1.1 396 (202) See -Chlorophenetole. 1.0+ 383 (195) 1.1 4.7 384 (196) 1.1 504 (262) Note: Melting point 169-171 (76-77). See Aniline. See Diphenylamine. See Biphenyl. See Bromobenzene. 0.9 4.6 346 (174) See Benzyl Alcohol. See Chlorobenzene. See Cyclohexylbenzene. 0.9 2 0 1 0 2 0 Yes 5 1 1 0 Slight 5 1 2 0 No 5 1 2 0 No 2 1 1 0 0 1 0 Yes 5 3 2 0
730 (387)
0.7
1.1
No
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See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
1.2
1.5
3.73
513 (267).
Note: Melting point 284 (140). See Ethylbenzene. 1.1 545 (285) Note: See Hazardous Chemicals Data. Slight 2 5 2 1 0
Phenylethyl Acetate () C6H5CH2CH2OOCCH3 Phenylethyl Alcohol Phenylethylene N-Phenyl-N-Ethylethanolamine C6H5N(C2H5)C2H4OH Phenylhydrazine C6H5NHNH2 Phenylmethane Phenylmethyl Ethanol Amine C6H5N(CH3)C2H4OH (2-(N-Methylaniline)-Ethanol) Phenyl Methyl Ketone 4-Phenylmorpholine C6H5NC2H4OCH2CH2 Phenylpentane o-Phenylphenol C6H5C6H4OH Phenylpropane 2-Phenylpropane Phenylpropyl Alcohol C6H5(CH2)3OH (Hydrocinnamic Alcohol) (3-Phenyl-l-propanol) (Phenylethyl Carbinol) Phenyl Propyl Aldehyde C6H5CH2CH2CHO (3-Phenylpropionaldehyde) (Hydrocinnamic Aldehyde) Phenyl Toluene o C6H5C6H4CH3 (2-Methylbiphenyl) Phenyl Trichloro Silane C6H5SiCl3 (Trichloro(phenyl)silane) Phorone (CH3)2CCHCOCHC(CH3)2
1.03
5.67
435 (224)
See Phenethyl Alcohol. See Styrene. 270 (132) (oc) 190 (88) See Toluol. 280 (138) (oc) 220 (104) (oc) See Amylbenzene. 255 (124) 986 (530) 1.2 547 (286) Note: Melting point 134 (57). See Propylbenzene. See Cumene. 212 (100) 1.0+ 426 (219) No 5 0 1 0 Slight 5 2 1 1 0 1.1 1.07 5.22 378 (192) @ 100 mm See Acetophenone. 518 (270) Slight 5 2 2 1 0 2 1 0 1.1 685 (362) 0.8 1.0+ 514 (268) @ 740 mm Decomposes Slight 5 3 2 0 Slight 2 5 2 1 0
205 (96)
1.0+
923 (495)
1.01
5.82
500 (260)
1.32
7.36
394 (201)
0.9
4.8
388 (198)
No
Note: Melting point 82 (28). Phosphine PH3 Gas 212 (100) 0.57 @ 20 atm 1.17 -126 (-88) 3 4 1
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See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
1.59 5.73
Note: Melting point 376 (191). 305 (152) 1058 (570) 1.7 10.5 1.5 543 (284) Note: Melting point 262 (128). See Isophthaloyl Chloride. 1000 (538) 1.03.2 1.03.2 262 (128) 292 (144) See Cyclohexanone. 523 (273) 491 (255) 0.9 0.7 @ 320 (160) 7.2 @ 320 (160) 0.9 4.7 312 (156) 367-439 (186-226) No No 1 0.8 336 (151) Yes 5 No
1 0
3 2
0 0
1.1
No
208 (98)
No No
0 0 5 2
2 2 2
0 0 0
294 (146)
Slight
0.9
3.0
223 (106)
Yes
1 5
0 0
1 1
0 0
0.9
No
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See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
1.56 5.53
2.6
17
0.8
2.0
120 (49)
Slight
1 5
Note: See Hazardous Chemicals Data. 2.1 9.5 0.9 1.6 2.6 -44 (-42) 276 (136) Yes 1 5 2 3 0 No 6 1 4 0
See Propylene Glycol. See Trimethylene Glycol. See Propyl Alcohol. See Isopropyl Alcohol. See Acetone. See Propionyl Chloride. 0.97 1.93 239 (115) 615 (324) 3.0 1.57 4.10 192 (89) Note: See Hazardous Chemicals Data. See Propylene. See Allylamine. 0.8 1.3 158 (70) 2.9 1.1 2.5 311 (155) See Propanal. 870 (465) 545 (285) 3.1 0.78 1.90 1.3 9.5 1.0+ 4.5 2.9 12.1 1.02.5 297 (147) Note: See Hazardous Chemicals Data. 336 (169) 207 (97) 1.1 3.2 176 (80) 842 (450) 775 (412) 604 (318) 842 (450) 833 (445) 6.77 0.8 6.0 0.9 4.1 2.0 10.4 0.7 2.0 1.7 @ 100 (38) 2.2 13.7 0.8 2.1 207 (97) 120 (49) Note: See Hazardous Chemicals Data. 319 (159) ~536 (~280) 0 1 0 No 1 2 3 0 Yes Yes 1 5 1 5 3 3 0 1 3 0 8 0.9 3.5 215 (102) Slight 1 5 Decomposes 1 3 3 1 Yes Decomposes 2 4 2 3 1 1 Decomposes in water. Yes 5 2 2 0 Yes 5 0 2 0 1 2 3 0 4 3 4 3 3 3
Decomposes in water. 1 3 0
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See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
1.35 4.34
0.87
4.49
290 (143)
See Butyl Alcohol. 968 (520) 1.1 478 (248) 516 (269) 851 (455) 2.0 11.1 1.5 0.8 0.8 4.8 2.6 11.1 0.9 2.7 115 (46) 311 (155) 313-315 (156-157) 269 (131) -53 (-47) Note: See Hazardous Chemicals Data. See Crotonaldehyde. 1.2 468 (242) See 2-Chloro-1-Propanol. See 1-Chloro-2-Propanol. 780 (416) 1035 (557) 700 (371) 2.6 12.5 1.0+ 2.62 3.4 14.5 1.2 3.9 0.9 2.6 246 (119) 205 (96) 370 (188) Yes 5 0 1 0 No Yes 1 5 4 2 3 0 2 3 0 Yes 2 5 1 1 0 No 6 1 4 1 0 0 0 0 Very slight No 2 2 0 1 2 3 0
See Methyl Glycol Acetate. 0.86 1.6 13.8 0.92 3.11 283 (140) 248 (120) 1.5 @200C 1.4 @ 100C 840 (449) 370 (188) 851 (455) 0.9 3.0 1.3 7.0 0.75 3.53 2.3 36 0.83 2.0 1.05 4.5 7.0 0.966 4.6 295 (146) 410 (210) Yes 5 3 1 2 Slight 5 0 2 0 Yes 0 3 0 Yes
94 (35)
Yes
1 5
Note: See Hazardous Chemicals Data. 194 (90) 178 (81) See Butyl Alcohol. Slight 1 5 2 3 0 3 0
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See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
1.1 0.9 4.0
Upper
100
1.2
6.12
254 (123.5)
Yes
See Hydrocyanic Acid. See 1,2,4-Trimethylbenzene. 900 (482) 1.8 12.4 1.02.7 239 (115) Note: See Hazardous Chemicals Data. No May be below. 1 1 3 0 Yes 1 5 2 3 0
1.0-
2.3
268 (131)
No
0.9
2.5
186-189 (86-87)
Yes
5 1
1.1
2.9
473 (245)
Yes
2 5
Note: Melting point 77 (25). Quenching Oil Quinoline C6H4N:CHCH:CH Range Oil Rape Seed Oil (Colza Oil) Red Oil Resorcinol C6H4(OH)2 (Dihydroxybenzol) Rhodinol >212 261 (127) 1126 (608) 1.4 @ 392 (200) Note: Melting point 232 (111). 0.9 237-239 (114-115) @ 12 mm Ricinus Oil Rosin Oil Rum Salicylaldehyde HOC6H4CHO (o-Hydroxybenzaldehyde) Salicylic Acid HOC6H4COOH 315 (157) 1004 (540) 1.1 @ 392 (200) 1.5 4.8 Sublimes @ 169 (76) Note: Melting point 316-322 (158-161). No 2 0 1 0 172 (78) 1.2 266 (130) 648 (342) 1.0See Castor Oil. >680 (>360) See Ethyl Alcohol and Water. 384 (196) Slight 5 0 2 0 No 2 0 1 0 No 0 1 0 CH2:C(CH3)(CH2)3CH(CH3)(CH2)2OH (>100) 1.28 325 (163) 836 (447) See Oleic Acid. 3.80 531 (277) 1 0 0.9 365 (185) 896 (480) 1.1 4.5 460 (238) See Fuel Oil No. 1. No 2 0 1 0 No 2 1 0 0.9 No 2 0 1 0
7-19N
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See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
1.1
1.0-
~572 (~300)
No
No
Gas Pyrophoric
1.3
-169
Slight
Avoid halon
0.9 0.9
No No
2 2
0 0
1 1
0 0
See Lubricating Oil, Spindle. 743 (395) 842 (450) 0.8 0.8 726 (386) Note: Melting point 157 (69). 410 (210) @ 15 mm Note: Melting point 131 (55). No 2 0 1 0 No 0 0 No 2 1 1 0
914 (490)
0.9
6.8
0.9
3.6
295 (146)
No
Note: Polymerizes. See Hazardous Chemicals Data. 929 (498) 1.02.1 509-513 (265-267) Note: Melting point 130 (54). 1.3 545 (285) Yes 2 2 1 0 Yes 2 5 1 0 1.1 2 2 0
Note: Melting point 81 (27). Sulfur Sulfur Chloride S2Cl2 Sweet Oil Sylvan Tallow 509 (265) Note: Melting point 88-100 (31-38). Tallow Oil 492 (256) Note: Melting point 109 (43). 0.9 No 2 0 1 0 0.9 405 (207) 245 (118) 450 (232) 453 (234) 1.7 1.8 832 (445) 280 (138) Note: See Hazardous Chemicals Data. See Olive Oil. See 2-Methylfuran. No 2 0 1 0 Decomposes 2 1 2 Decomposes in water. No
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See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1) Boiling Point F (C)
Decomposes 392 (200)
797 (425)
1.76
5.18
Note: Melting point 338 (170). Terephthalic Acid C6H4(COOH)2 (para-Phthalic Acid) (TPA) (Benzene-para-Dicarboxylic Acid) Terephthaloyl Chloride C6H4(COCl)2 (Terephthalyl Dichloride) (p-Phthalyl Dichloride) (1,4-Benzenedicarbonyl Chloride) o-Terphenyl (C6H5)2C6H4 m-Terphenyl (C6H5)2C6H4 325 (163) (oc) 375 (191) (oc) Note: Melting point 188 (87). Terpineol C10H17OH (Terpilenol) Terpinyl Acetate C10H17OOCCH3 Tetraamylbenzene (C5H11)4C6H2 1,1,2,2-Tetrabromoethane CHBr2CHBr2 (Acetylene Tetrabromide) Tetrachlorobenzene C6H2Cl4 1,2,4,5-Tetrachlorobenzene C6H12Cl4 Tetradecane CH3(CH2)12CH3 Tetradecanol C14H29OH 1-Tetradecene CH2:CH(CH2)11CH3 tert-Tetradecyl Mercaptan C14H29SH Tetraethoxypropane (C2H5O)4C3H4 Tetra (2-Ethylbutyl) Silicate [C2H5CH(C2H5)CH2O]4Si Tetraethylene Glycol HOCH2(CH2OCH2)3CH2OH 311 (155) 311 (155) 212 (100) 285 (141) (oc) 230 (110) 250 (121) 190 (88) (oc) 335 (168) (oc) 360 (182) (oc) 1.1 6.7 0.9 460 (238) @ 50 mm Decomposes Yes 2 5 1 1 0 No 2 1 1 0 1.12 6.70 455 (235) 0.9 0.8 6.8 493 (256) 496-532 (258-278) 621 (327) 5 2 0 2 0 2 1 0 No 2 0 1 0 392 (200) 0.8 0.5 0.8 1.86 1.7 475 (246) 472 (245) 487 (253) 507 (264) No 2 0 1 0 No 0 1 0 No 1 1 0 No 2 0 1 0 200 (93) 295 (146) 635 (335) 2.97 11.9 0.9 1.0428 (220) 608-662 (320-350) 275 (135) 3 0 1 No Slight 5 2 2 0 1 0 0 2 0 195 (91) 0.9 417-435 (214-224) No 0 2 0 1.2 685 (363) No 2 0 1 0 1.1 Note: Melting point 175 (79). 630 (332) No 2 0 1 0 356 (180) 498 (259) Yes 2 3 1 0 500 (260) (oc) 925 (496) 1.5 Sublimes above 572 (300) No 2 0 1 0
7-19N
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See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1) Boiling Point F (C) Identification ExtinWater guishing FlamReacSoluble Methods Health mability tivity
See Dibutoxy Tetraglycol. See Dimethoxy Tetraglycol. 610 (321) 0.9 1.0631 (333) No Yes 2 5 2 1 1 0 2 1 0
1.8
1.6
8.6
No
Note: See Hazardous Chemicals Data. 392 (200) 10.0 50.0 1.5 3.87
Note: See Hazardous Chemicals Data. Tetraglycol Dichloride 1,2,3,6-Tetrahydrobenzaldehyde CH2CH:CHCH2CH2CHCHO (3-Cyclohexene-1-Carboxaldehyde) endo-Tetrahydrodicyclopentadiene C10H16 (Tricyclodecane) Note: Melting point 171 (77). Tetrahydrofuran OCH2CH2CH2CH2 (Diethylene Oxide) (Tetramethylene Oxide) Tetrahydrofurfuryl Alcohol C4H7OCH2OH Tetrahydrofurfuryl Oleate C4H7OCH2OOCC17H33 Tetrahydronaphthalene C6H2(CH3)2C2H4 (Tetralin) Tetrahydropyran Tetrahydropyran-2-Methanol OCH2CH2CH2CH2CHCH2OH Tetrahydropyrrole Tetralin 1,1,3,3-Tetramethoxypropane [(CH3O)2CH]2CH2 1,2,3,4-Tetramethylbenzene 95% C6H2(CH3)4 (Prehnitene) 1,2,3,5-Tetramethylbenzene 85.5% C6H2(CH3)4 (Isodurene) 160 (71) 170 (77) 166 (74) 800 est. (427) 800 est. (427) 0.9 387-389 (197-198) No 0 2 0 0.9 1.0200 (93) (oc) See Pyrrolidine. See Tetrahydronaphthalene. 361 (183) 399-401 (204-205) No 0 2 0 Yes 5 0 2 0 1.0+ 167 (75) (oc) 390 (199) 160 (71) 725 (385) 0.8 @ 212 (100) 5.0 @ 302 (150) See Pentamethylene Oxide. 4.0 368 (187) Yes 5 1 2 0 1.04.6 0.9 540 (282) 1.5 9.7 6 (-14) 610 (321) 2 11.8 0.9 2.5 151 (66) Note: See Hazardous Chemicals Data. Yes 1 5 2 3 1 135 (57) (oc) 523 (273) 0.9 379 (193) 0 See Bis[2-(2-Chloroethoxy) Ethyl] Ether. 1.03.8 328 (164) Slight 5 2 2 0
1.1
Yes
No
No
7-19N
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See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
0.8 @ 178 (81) Note: Melting point 174 (79). See Cyclobutane. 4.6
734 (390)
1.0+
Yes
6.5
No
2,2,3,3-Tetramethyl Pentane (CH3)3CC(CH3)2CH2CH3 2,2,3,4-Tetramethylpentane (CH3)3CCH(CH3)CH(CH3)2 Tetramethyl Tin Sn(CH3)4 Tetraphenyl Tin (C6H5)4Sn Tetrapropionyl Glucosyl Propionate Thialdine SCH(CH3)SCH(CH3)NHCHCH3
806 (430)
0.8
4.9
0.7 0.74
0 0 2 3
3 3
0 0 0
1.9
1.3 1.5
Note: Melting point 439 (226). See Glucose Pentapropionate. 200 (93) (oc) Note: Melting point 112 (44). 2,2-Thiodiethanol (HOCH2CH2)2S (Thiodiethylene Glycol) Thiodiethylene Glycol Thiodiglycol (CH2CH2OH)2S (Thiodiethylene Glycol) (Beta-bis-Hydroxyethyl Sulfide) (Dihydroxyethyl Sulfide) Thiophene SCH:CHCH:CH 1,4-Thioxane O(CH2CH2)2S (1,4-Oxathiane) Toluene C6H5CH3 (Methylbenzene) (Phenylmethane) (Toluol) Toluene-2,4-Diisocyanate CH3C6H3(NCO)2 p-Toluenesulfonic Acid C6H4(SO3H)(CH3) 260 (127) 363 (184) 0.9 9.5 Note: See Hazardous Chemicals Data. 1.2 6.0 484 (251) Note: See Hazardous Chemicals Data. 295 (140) @ 20 mm Note: Melting point 220 (104.5). Toluhydroquinone C6H3(OH)2CH3 (Methylhydroquinone) 342 (172) (oc) Note: Melting point 259 (126). 875 (468) 545 (285) Yes 2 1 0 Yes 2 3 No 3 1 with water. 1 1 1 Reacts exothermicaliy 40 (4) 896 (480) 1.1 7.1 0.9 3.1 231 (111) No 1 2 3 0 30 (-1) 108 (42) 1.12 3.59 1.1 2.9 184 (84) 300 (149) 2 2 0 No 1 2 3 0 320 (160) 568 (298) 1.2 320 (160) (oc) See 2,2-Thiodiethanol. 541 (283) Yes 2 2 1 0 1.2 540 (282) Yes 5 2 1 1 0 1.1 Decomposes Slight 5 2 2 1
7-19N
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1.03.7
Note: See Hazardous Chemicals Data. p-Toluidine CH3C6H4NH2 (4-Methylaniline) Toluol meta-Tolydiethanolamine (HOC2H4)2NC6H4CH3 (MTDEA) 2,4-Tolylene Diisocyanate o-Tolyl Phosphate o-Tolyl p-Toluene Sulfonate C14H14O3S Transformer Oil (Transil Oil) Transil Oil Triacetin Triamylamine (C5H11)3N 215 (102) (oc) Note: See Hazardous Chemicals Data. Triamylbenzene (C5H11)3C6H3 Triamyl Borate B(C5H11O)3 Tributylamine (C4H9)3N 270 (132) (oc) 180 (82) (oc) 187 (86) (oc) Note: See Hazardous Chemicals Data. Tri-n-Butyl Borate B(OC4H9)3 Tributyl Citrate C3H4(OH)(COOC4H9)3 Tributyl Phosphate (C4H9)3PO4 Tributylphosphine (C4H9)3P Tributyl Phosphite (C4H9)3PO3 1,2,4-Trichlorobenzene C0H3Cl3 1,1,1-Trichloroethane CH3CCl3 (Methyl Chloroform) 248 (120) (oc) 222 (105) None 1060 (571) 2.5 6.6 1.5 200 (93) (oc) 315 (157) 295 (146) (oc) 392 (200) 0.9 473 (245) 244-250 (118-121) @ 7 mm 415 (213) 1.32 4.55 165 (74) No 2 1 0 No 3 2 1 0 Decomposes 2 1 1 No 0 1 0 695 (368) 1.01.0+ 450 (232) 560 (293) No 2 2 1 0 No 2 0 1 0 0.85 7.94 446 (230) 3 2 1 0.8 6.4 417 (214) No 2 2 0 0.8 9.4 430 (221) 1 2 0 0.9 575 (302) No 2 0 1 0 0.8 363 (184) 295 (146) (oc) See Transformer Oil. See Glyceryl Triacetate. 453 (234) No 2 2 1 0 0.9 No 2 0 1 0 1.2 400 (204) (oc) Note: Melting point 144 (62). See Toluene-2,4-Diisocyanate. See Tri-o-Cresyl Phosphate. 2 1 1 0 740 (393) 0.6 188 (87) 900 (482) 1.03.9 392 (200) Note: Melting point 111 (44). See Hazardous Chemicals Data. See Toluene. No 2 2 1 0 No 3 2 0
}
@ 302 (150) 7.5 12.5
7-19N
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See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
1.5 4.5
Upper
10.5
Note: See NFPA 49, Hazardous Chemicals Data. 1,2,3-Trichloropropane CH2ClCHClCH2Cl (Allyl Trichloride) (Glyceryl Trichlorohydrin) Trichlorosilane HSiCl3 Tri-o-Cresyl Phosphate (CH3C6H4)3PO4 (o-Tolyl Phosphate) Tridecanol CH3(CH2)12OH 250 (121) (oc) Note: Melting point 86 (30). 2-Tridecanone Tridecyl Acrylate CH2:CHCOOC13H27 Tridecyl Alcohol C12H25CH2OH (Tridecanol) Tridecyl Phosphite (C10H21O)13P Triethanolamine (CH2OHCH2)3N (2,2,2-Nitrilotriethanol) 1,1,3-Triethoxyhexane CH(OC2H5)2CH2CH(OC2H5)C8H7 210 (99) (oc) 0.9 7.5 271 (133) @ 50 mm Decomposes @ 760 mm Triethylaluminum (C2H5)3AI Note: Ignites spontaneously in air 3 3 3 Do not use water, foam, or halogenated extinguishing agents. 16 (-7) (oc) 1,2,4-Triethylbenzene (C2H5)3C6H3 181 (83) (oc) Triethylborane (C2H5)3B Triethyl Citrate HOC(CH2CO2C2H5)CO2C2H5 303 (151) 1.1 561 (294) Very slight 2 Note: Ignites spontaneously in air. 1 3 3 Do not use halogenated extinguishing agents. 0 1 0 56 @ 115C 0.9 5.6 423 (217) No 2 0 480 (249) 1.2 8.0 0.7 3.5 193 (89) No 1 5 2 3 0 No 1 1 0 270 (132) (oc) 180 (82) (oc) Note: Melting point 88 (31). 455 (235) (oc) 354 (179) 1.1 5.1 0.9 356 (180) @ 0.1 mm 650 (343) Yes 2 5 2 1 1 No 2 0 1 0 0.8 0.9 See Methyl Undecyl Ketone. 302 (150) @ 10 mm 485-503 (252-262) 5 0 2 0 No 2 1 1 0 0.8 6.9 7 (-14) (oc) 437 (225) 725 (385) 1.2 770 (410) Decomposes 525 (274) No 2 0 1 0 No 2 2 1 0 1.3 4.7 89 (32) Decomposes 3 4 2 160 (71) 3.2 @ 120C 12.6 @ 150C 1.4 5.1 313 (156) No 3 3 2 0
Triethylamine (C2H5)3N
7-19N
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See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
1.1 5.2
Upper
9.2
1.1
572 (300)
Yes
5 2 2
1.0-
4.7
421 (216)
See Ethoxytriglycol. See Methoxy Triglycol. 1.0+ 270 (132) 640 (338) 850 (454) 8.4 16.0 1.31 @ 5.7 atm 1.2 466 (241) 0.9 275-286 Decomposes (135-141) @ 2 mm Note: May ignite spontaneously in air. 3 3 Do not use water, foam or halogenated extinguishing agents. 185 (85) (oc) 320 (160) (oc) 207 (97) (oc) 82 (28) 398 (203) (oc) Note: Ignites spontaneously in air. 3 3 0.9 0.82 6.49 0.9 495 (237) 288 (142) 2 0 1 0 3 3 1 No 0 1 0 608 (320) 1.00.84 7.94 413 (212) 584 (307) Yes 2 5 2 1 0 3 2 1 1 0 No 2 2 1 0 4.02 1.1 1.0532 (278) 408-424 (209-218) -18 (-28) Yes Yes Yes 5 2 2 5 5 2 6 4 0 0 1 1 3 1 0 0 1 0
Decomposes in water.
Triisobutyl Borate B(OC4H9)3 Triisopropanolamine [(CH3)2COH]3N (1,1,1-Nitrolotri-2-propanol) Triisopropylbenzene C6H3(CH3CHCH3)3 Triisopropyl Borate (C3H7O)3B Trilauryl Trithiophosphite [CH3(CH2)11S]3P Trimethylaluminum (CH3)3AI
Do not use water, foam or halogenated extinguishing agents. Gas 374 (190) 111 (44) 878 (470) 0.8 6.6 0.89 4.15 2.0 11.6 2.0 38 (3) Note: See Hazardous Chemicals Data. 349 (176) 0 2 0 Yes 6 2 4 0
7-19N
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See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
0.9 4.1
0.9
6.4
0.87
4.15
329 (165)
No
0.9
4.1
328 (164)
No
See Methyl Borate. 774 (412) 707 (375) 0.71 3.39 0.69 3.46 178 (81) 172 (78) See tert-Butyl Alcohol. 0.9 597 (314) 0.9 4.9 0.8 3.75 135 (57) 283 (139) 388 (198) 0.9 4.9 388 (198) See Cyclopropane. See 1,3-Propanediamine. 752 (400) 1.1 2.6 417 (214) See 2-Methyl-2-Butene. 527 (275) 0.7 4.4 0.73 4.91 304 (151) 255 (124) 0.8 381 (194) 0.82 6.43 491 (255) 0.8 438 (226) 0.8 6.3 425 (218) 1.5 392 (200) 745 (346) 0.72 3.94 230 (110) 0 3 0 2 0 1 0 No 2 2 0 No 2 2 0 0 2 0 No 2 2 0 No 1 2 3 0 0 2 0 Yes 5 1 0 Slight 5 2 2 0 No 2 2 0 0 0 Yes 1 3 3 2 0 3 0 0 3 0
CH(OH)CH2C(CH3)2CH2CH(CH3)CH2 (74)
CH3C(CH3)2CH2CH(CH3)CH2CH2OH (93)
7-19N
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0.7 0.73 0.9 3.9 3.94
Upper
6.0
Note: Melting point 115-131 (46-55). 2,2,4-Trimethyl pentanediol Diisobutyrate C16H30O4 2,2,4-Trimethyl-1,3-Pentanediol Isobutyrate (CH3)2CHCH(OH)C(CH3)2CH2OOCCH(CH3)2 2,2,4-Trimethylpentanediol Isobutyrate Benzoate C19H28O4 2,3,4-Trimethyl-1-pentene H2C:C(CH3)CH(CH3)CH(CH3)2 2,4,4-Trimethyl-1-pentene CH2:C(CH3)CH2C(CH3)3 (Diisobutylene) 2,4,4-Trimethyl-2-pentene CH3CH:C(CH3)C(CH3)3 3,4,4-Trimethyl-2-pentene (CH3)3CC(CH3):CHCH3 Trimethyl Phosphite (CH3O)3P Trioctyl Phosphite (C8H17O)3P [Tris (2-Ethylhexyl) Phosphite] Trioxane OCH2OCH2OCH2 35 (2) (oc) <70 (<21) 130 (54) (oc) 340 (171) (oc) 113 (45) (oc) Triphenylmethane (C6H5)3CH Triphenyl Phosphate (C6H5)3PO4 Triphenylphosphine Triphenyl Phosphite (C6H5O)3PO3 Triphenylphosphorus (C6H5)3P (Triphenylphosphine) Tripropyl Aluminum (C3H7)3Al 425 (218) (oc) 356 (180) (oc) Note: Melting point 176 (80). Note: Ignites spontaneously in air. 3 3 Do not use waten foam or halogenated extinguishing agents. 9.0 1.2 >212 (>100) 428 (220) 1.3 1.01 8.43 777 (414) 3.6 29 0.9 212 (100) @ 0.01 mm 239 (115) Sublimes Note: Melting point 147 (64). 678 (359) Note: Melting point 200 (93). 750 (399) Note: Melting point 122 (50). See Triphenylphosphorus. 311-320 (155-160) @ 0.1 mm 711 (377) No 2 0 1 0 No 2 0 1 0 No 2 2 1 0 0 1 0 Slight 5 2 2 0 No 2 0 1 0 617 (325) 1.0+ 4.3 0.74 3.87 234 (112) 232-234 (111-112) No 0 2 0 0 3 0 581 (305) 0.7 3.8 221 (105) No 1 2 3 0 325 (163) (oc) <70 (<21) 23 (-5) 495 (257) 736 (391) 0.8 4.8 0.7 3.8 7.2 3.87 1.0 167 (75) @ 10 mm 214 (101) 214 (101) No 1 2 3 0 0 3 0 2 0 1 0 250 (121) (oc) 248 (120) (oc) 740 (393) 795 (424) 0.5 @ 342 (172) 0.6 @ 300 (149) 4.2 @ 393 (201) 1.0356-360 125 mm (180-182) No 2 0 1 0 0.9 9.9 536 (280) 2 0 1 0
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0.8 4.9
0.7
4.35
271-288 (133-142)
Yes
0 0
1 1
0 0
855 (457)
0.9 Note: Melting point 88 (31). See Lubricating Oil, Turbine. See Jet Fuels.
No
2 5 1
0 1 1
1 3 2
0 0 0
0.8
No
432 (222)
0.8
3.0
217 (103)
No
See Pentanoic Acid. 756 (402) 2.6 13.4 0.9 3.0 161 (72) Note: Polymerizes. See Hazardous Chemicals Data. See Diketene. 21 100 0.68 @ 1.7 atm Spont. decomposition 1.80 41 (5) 4 3 Slight 1 5 2 3 2
Vinyl Allyl Ether CH2:CHOCH2CH2O(CH2)3CH3 (Allyl Vinyl Ether) Vinylbenzene Vinylbenzylchloride ClCH2C6H4CH:CH2 Vinyl Bromide Vinyl Butyl Ether CH2:CHOC4H9 (Butyl Vinyl Ether) Vinyl Butyrate CH2:CHOCOC3H7
0.8
Very slight
220 (104) (oc) None 15 (-9) (oc) 68 (20) (oc) 1.4 8.8 986 (530) 437 (255) 9 15
1.1
444 (229)
No
1.5 0.8
3.7 3.5
No Slight 1 5 Slight 1 5
2 2
0 3
1 2
0.9
4.0
242 (117)
7-19N
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See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
1.0+ 3.7
882 (472)
3.6
33.0
.91
2.2
7 (-14)
Note: Polymerizes. See Hazardous Chemicals Data. 78 (26) (oc) See Acrylonitrile. 517 (269) 4.7 34 0.84 2.49 0.8 3.7 266 (130) See Divinyl Ether. 233 (112) See Butadiene Monoxide. 395 (202) 0.9 6.0 1.7 28 0.8 2.5 96 (36) 365 (185) 395 (202) 0.9 0.8 5.4 352 (178) 248 (120) @ 50 mm 2.6 1058 (570) 5.5 21.3 0.8 3.5 6.5 21.7 15.5 1.2 3.4 -97.5 (-72) 89 (32) Note: Polymerizes. See Hazardous Chemicals Data. -122.3 (-86) 182 (83) 0.8 5.4 347 (175) 522 (272) 0.90 3.52 3.0 133 (56) 228 (109) 549 (287) 0.8 2.0 43 (6) 297-369 (147-187) @ 5 mm No 2 0 1 0 Slight 6 2 4 2 1 5 0 3 0 2 4 2 No Slight 1 5 1 2 0 2 3 2 Slight 6 1 4 2 No 4 2 4 2 Slight 6 1 4 2 No 2 2 2 Slight 5 2 2 2 No No 1 5 2 2 2 2 4 2 Yes 0 2 0 1 0 3 2 0.9 4.0 273 (134) Slight 1 5 2 3 2
7-19N
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See Introduction for Suggested Hazard Sp. Gr. Vapor (Water Density =1) (Air=1)
0.9 3.3
1.0+
3.8
205 (96) @ 14 mm
See 1-Vinylpyrrolidone. 1000 (538) 1.3 5.61 0.8 11.0 0.9 4.08 334 (168) Note: See Hazardous Chemicals Data. 195 (91) See Gas. 0.9 0.9 473 (245) 800 (427) See Ethyl Alcohol and Water. See Naphthalene. See Ethyl Alcohol and Water. 0.9 0.9 >700 (>371) Note: Melting point 120-167 (49-75). No 2 0 1 0 No No 2 2 2 0 0 0 1 1 1 0 0 0 1 3 3 2 No 2 2 1
See Methyl Alcohol. See Pine Tar Oil. See Lanolin. 982 (527) 867 (463) 0.9 6.7 0.9 3.7 1.1 7.0 0.9 3.7 282 (139) Note: See Hazardous Chemicals Data. 292 (144) Note: See Hazardous Chemicals Data. 984 (528) 1.0 1.01.1 7.0 0.9 3.7 281 (138) Note: See Hazardous Chemicals Data. 435 (224) Note: See Hazardous Chemicals Data. See o-Xylene. See Diethylzinc. 788 (420) 1.1 0 1 0 No 3 1 0 No 1 2 3 0 No 1 2 3 0 No 1 2 3 0