Unit 13 - Nuclear Chemistry - Notes - KEY

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Unit 13: Nuclear Chemistry Radioactivity & Radiation Process by which materials give off rays The rays

and particles that are emitted by a radioactive source.

Discovery of Radiation

Roentgen found invisible rays were emitted which caused photographic plates to become exposed The Curies found it was uranium ore that was producing the rays Bacquerel found certain materials emit light (phosphorescence) after being exposed to sunlight.

Isotopes

Radioisotopes - isotopes of atoms with unstable nuclei. Nuclear stability is determined by the ratio between the protons and neutrons

3 Types of Radiation Alpha (Symbol: Beta (Symbol: ) )

Particle Type Helium nucleus High energy electron

Charge (if applicable) +2 -1

Blocked By? piece of paper wood lead or concrete

Gamma (Symbol: ) Types of Radioactive Decay

High energy radiation (photons with no mass)

Alpha Decay Radio isotope breaks apart producing an alpha particle Emits? alpha particle (helium nucleus) Beta Decay Radioisotope breaks apart producing a beta particle; commonly associated with the release of gamma radiation. Emits? High energy electron

Radiochemical Dating

The process of determining the age of an object by measuring the amount of a certain radioisotope remaining in that object. ex. Carbon- 14 dating

Half-Life

Time required for one half of the isotopes nuclei to decay into its products Equation: Final Amount = (Initial Amount) x 1/2(t/T) t = time elapsed T = half-life

Nuclear Fission

The splitting of a nucleus into fragments Similar to radioactive decay, however it is induced by bombarding sample with particles Some radioisotopes have great mass and result in a chain reaction when fission is induced; the byproducts go on to split other atoms and so on

Nuclear Reactors

Fissionable Uranium Oxide in corrosion resistant fuel rods powers the reactor Started by a neutron emitting source, and has a reflector source around it to reflect the neutrons back at the fuel rods Water which cools the rods circulates through it producing steam which turns turbines to produce power Control rods are lowered into the core to absorb the neutrons and control the rate of reaction; otherwise can result in a chain reaction Spent control rods and radioactive waste must be contained; first in storages pools, then transport it to underground waste facilities like Yucca Mountain, Nevada

Nuclear Fusion

The combining of two or more nuclei to form a stable nuclei Fusion products are not radioactive, but to make it happen, it takes extremely high temperatures Because of the amount of heat they are also called thermonuclear reactions

Detecting Radiation

Ionizing radiation radiation energetic enough to ionize matter Geiger counter a metal tube filled with a gas that is connected to a power supply. When ionizing radiation penetrates the tube, the gas absorbs the radiation making the free electrons flow Film Badge detects the amount of radiation a person has been exposed to over time, based on the developing of the film

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