This document provides safety information about the product Gardobond 24D R. It contains the following key points:
1. Gardobond 24D R is a phosphating solution for metal surfaces that contains several hazardous components like zinc bis(dihydrogen phosphate), orthophosphoric acid, and nickel compounds.
2. It is harmful if swallowed, may cause sensitization, and is irritating to eyes and skin. Long term exposure could have a limited carcinogenic effect.
3. The product also poses environmental risks as it is very toxic to aquatic life and may cause long term damage to aquatic environments.
4. Exposure should be avoided through proper personal protective equipment and handling. Spills should be
This document provides safety information about the product Gardobond 24D R. It contains the following key points:
1. Gardobond 24D R is a phosphating solution for metal surfaces that contains several hazardous components like zinc bis(dihydrogen phosphate), orthophosphoric acid, and nickel compounds.
2. It is harmful if swallowed, may cause sensitization, and is irritating to eyes and skin. Long term exposure could have a limited carcinogenic effect.
3. The product also poses environmental risks as it is very toxic to aquatic life and may cause long term damage to aquatic environments.
4. Exposure should be avoided through proper personal protective equipment and handling. Spills should be
This document provides safety information about the product Gardobond 24D R. It contains the following key points:
1. Gardobond 24D R is a phosphating solution for metal surfaces that contains several hazardous components like zinc bis(dihydrogen phosphate), orthophosphoric acid, and nickel compounds.
2. It is harmful if swallowed, may cause sensitization, and is irritating to eyes and skin. Long term exposure could have a limited carcinogenic effect.
3. The product also poses environmental risks as it is very toxic to aquatic life and may cause long term damage to aquatic environments.
4. Exposure should be avoided through proper personal protective equipment and handling. Spills should be
This document provides safety information about the product Gardobond 24D R. It contains the following key points:
1. Gardobond 24D R is a phosphating solution for metal surfaces that contains several hazardous components like zinc bis(dihydrogen phosphate), orthophosphoric acid, and nickel compounds.
2. It is harmful if swallowed, may cause sensitization, and is irritating to eyes and skin. Long term exposure could have a limited carcinogenic effect.
3. The product also poses environmental risks as it is very toxic to aquatic life and may cause long term damage to aquatic environments.
4. Exposure should be avoided through proper personal protective equipment and handling. Spills should be
Gardobond 24D R Version: 2 16.06.2008 1 / 7 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING English Product information Commercial Product Name Gardobond 24D R Recommended use: Phosphating solution for metal surfaces. Company: Chemetall plc Denbigh Road Bletchley Milton Keynes MK1 1PB Lead Organisation: Contact person: Telephone: 01908 649333 Telefax: 01908 373939 Product safety: Telephone: +44(0)1908 649333 E-mail address: [email protected] Emergency telephone: 01908 649333 2. HAZARDS IDENTIFICATION Risk advice to man and the environment Classification: Harmful R22 Harmful if swallowed. Carcinogenic Category 3 R40 Limited evidence of a carcinogenic effect. sensitizing R42/43 May cause sensitization by inhalation and skin contact. Irritant R36/38 Irritating to eyes and skin. Dangerous for the environment R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components Zinc bis(dihydrogen phosphate) 10.00 - 25.00 % CAS-No.: 13598-37-3 EINECS-No. : 237-067-2 Classification: Xn; R22 N; R50/53 SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Gardobond 24D R Version: 2 16.06.2008 2 / 7 Orthophosphoric acid 10.00 - 25.00 % CAS-No.: 7664-38-2 EINECS-No.: 231-633-2 Classification: C; R34 Nickel(II)compound 2.50 - 10.00 % CAS-No.: 13138-45-9 EINECS-No. : 236-068-5 Classification: O; R 8 Xn; R22 Carc.Cat.3; R40 R42/43 N; R50, R53 Zinc hexafluorosilicate 2.50 - 10.00 % CAS-No.: 16871-71-9 EINECS-No. : 240-894-1 Classification: Xn; R22 N; R50, R53 WEL substance: Manganese bis(dihydrogen phosphate) 2.50 - 10.00 % CAS-No.: 18718-07-5 EINECS-No. : 242-520-2 4. FIRST AID MEASURES General advice: Take off contaminated clothing and shoes immediately. Eye contact: In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Skin contact: Wash off immediately with soap and plenty of water. Inhalation: Move to fresh air. If symptoms persist, call a physician. Ingestion: Clean mouth with water and drink afterwards plenty of water. Call a physician immediately. 5. FIRE-FIGHTING MEASURES Specific hazards during fire fighting: Combustion may cause: nitrogen oxides (NOx) Special protective equipment for fire-fighters: In the event of fire, wear self-contained breathing apparatus. Suitable extinguishing media: Carbon dioxide (CO2), Dry powder, Water spray, Alcohol-resistant foam Further information: Collect contaminated fire extinguishing water separately. This must not be discharged into drains. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Use personal protective equipment. Environmental precautions: Do not flush into surface water or sanitary sewer system. Methods for cleaning up: Soak up with liquid binder (sand, kieselguhr, acid binder, universal binder). Sweep up or vacuum SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Gardobond 24D R Version: 2 16.06.2008 3 / 7 up spillage and collect in suitable container for disposal. Ensure adequate ventilation. 7. HANDLING AND STORAGE Handling Safe handling advice: Have eye wash bottle or eye rinse ready at the work place. Avoid contact with eyes. Provide sufficient air exchange and/or exhaust in work rooms. Advice on protection against fire and explosion: No special protective measures against fire required. Storage Requirements for storage areas and containers: Keep container tightly closed in a dry and well-ventilated place. Store at room temperature in the original container. Further information: Avoid contact with metals. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Orthophosphoric acid 7664-38-2 Value Update Basis TWA 1.00 mg/m3 02 2006 EU ELV STEL 2.00 mg/m3 02 2006 EU ELV TWA 1.00 mg/m3 2007 EH40 WEL STEL 2.00 mg/m3 2007 EH40 WEL Manganese bis(dihydrogen phosphate) 18718-07-5 Value Update Basis TWA 0.50 mg/m3 as Mn 2007 EH40 WEL Nickel(II)compound 13138-45-9 Value Update Basis TWA 0.10 mg/m3 as Ni 2007 EH40 WEL SKIN_DES as Ni Can be absorbed through the skin. 2007 EH40 WEL TWA 0.50 mg/m3 as Ni 2007 EH40 WEL SKIN_DES as Ni Can be absorbed through the skin. 2007 EH40 WEL Personal protective equipment Respiratory protection: Not required; except in case of aerosol formation. Hand protection: Material: Neoprene General advice: The selected protective gloves have to satisfy the specifications of EU Directive 89/689/EEC and the standard EN 374 derived from it., The exact break through time can be obtained from the protective glove producer and this has to be observed. SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Gardobond 24D R Version: 2 16.06.2008 4 / 7 Eye protection: Tightly fitting safety goggles Skin and body protection: Protective suit Hygiene measures: Avoid contact with the skin and the eyes. Keep away from food, drink and animal feedingstuffs. Take off contaminated clothing and shoes immediately. Wash hands before breaks and at the end of workday. 9. PHYSICAL AND CHEMICAL PROPERTIES Form: liquid Odour: none Melting point/range: < -5 C Boiling point/range: ca. 100 C Flash point: not applicable Density: 1.4 g/cm3 Water solubility: completely miscible pH: ca.2 10. STABILITY AND REACTIVITY Conditions to avoid: To avoid thermal decomposition, do not overheat. Materials to avoid: Contact with organic substances or other reducing agents can form mixed nitrous gases (toxic)., Incompatible with bases. Hazardous decomposition products: nitrogen oxides (NOx) Hazardous reactions: Gives off hydrogen by reaction with metals. Thermal decomposition: > 320 C 11. TOXICOLOGICAL INFORMATION Skin irritation: Irritating to skin. Eye irritation: Irritating to eyes. SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Gardobond 24D R Version: 2 16.06.2008 5 / 7 Sensitisation: May cause sensitization by inhalation and skin contact. Further toxicological information: Limited evidence of a carcinogenic effect. 12. ECOLOGICAL INFORMATION Elimination information (persistence and degradability): Chemical Oxygen Demand (COD): 0 mg/g Further information: Do not flush into surface water or sanitary sewer system. Avoid subsoil penetration. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. water endangering 13. DISPOSAL CONSIDERATIONS Waste key for the unused product: 110106 acids not otherwise specified Product: Dispose of as hazardous waste in compliance with local and national regulations. Contaminated packaging: Dispose of as hazardous waste in compliance with local and national regulations. 14. TRANSPORT INFORMATION Regulation : ADR UN/ID No.: 1805 Proper shipping name: Phosphoric acid Packaging group: III Class: 8 ADR/RID-Labels: 8 Regulation : RID UN/ID No.: 1805 Proper shipping name: Phosphoric acid Packaging group: III Class: 8 ADR/RID-Labels: 8 Regulation : IMDG UN/ID No.: 1805 Proper shipping name: PHOSPHORIC ACID Packaging group: III Class: 8 EmS: F-A S-B SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Gardobond 24D R Version: 2 16.06.2008 6 / 7 Regulation : IATA_C UN/ID No.: 1805 Proper shipping name: PHOSPHORIC ACID Packaging group: III Class: 8 Regulation : IATA_P UN/ID No.: 1805 Proper shipping name: PHOSPHORIC ACID Packaging group: III Class: 8 15. REGULATORY INFORMATION Hazardous components which must be listed on the label: Nickel(II)compound Labelling: Harmful Dangerous for the environment R-phrase(s): R22 Harmful if swallowed. R36/38 Irritating to eyes and skin. R40 Limited evidence of a carcinogenic effect. R42/43 May cause sensitization by inhalation and skin contact. R50/53 Very toxic to aquatic organisms, may cause long- term adverse effects in the aquatic environment. S-phrase(s): S23 Do not breathe vapour. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37 Wear suitable protective clothing and gloves. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S60 This material and its container must be disposed of as hazardous waste. S61 Avoid release to the environment. Refer to special instructions/ Safety data sheets. Other regulations: German regulation: Soluble nickel salts are carcinogenic substances, category 1. Other regulations: The product is classified and labelled in accordance with EC directives or respective national laws. SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Gardobond 24D R Version: 2 16.06.2008 7 / 7 16. OTHER INFORMATION Text of R phrases mentioned in Section 3 R 8 Contact with combustible material may cause fire. R22 Harmful if swallowed. R34 Causes burns. R40 Limited evidence of a carcinogenic effect. R42/43 May cause sensitization by inhalation and skin contact. R50 Very toxic to aquatic organisms. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R53 May cause long-term adverse effects in the aquatic environment. Text of R phrases mentioned in Section 3 The information provided is based on our current knowledge and experience and apply to the product as delivered. Regarding the product properties, these are not guaranteed. The delivery of this safety datasheet does not free the recipient of the product from his own responsibility to follow the relevant rules and regulations concerning this product.
L5 Control of Substances Hazardous to Health: The Control of Substances Hazardous to Health Regulations 2002. Approved Code of Practice and Guidance, L5