Welded joints of high-Cr ferritic heat-resistant steel, ASTM

A335 Gr. P91, were subjected to post weld heat treatment

(PWHT) to improve mechanical properties and to reduce
residual stress. We have measured the A
c1
of weld metals
for Gr. P91 steel, containing varying amounts of Mn+Ni,
and have examined the effects of PWHT temperatures on
the mechanical properties of each weld metal. The upper
limits of the PWHT temperature for the respective weld
metals are considered.
Introduction
High-Cr ferritic heat-resistant steel is a material
that, along with austenitic heat-resistant steel, has
long been studied and utilized. This ferritic steel has
a smaller coefficient of thermal expansion compared
with the austenitic heat-resistant steel and exhibits
excellent creep rupture strength thanks to, among
other things, the addition of Nb, V and N. Therefore,
this steel is widely used in thermal power plants
that run and stop repeatedly, in accordance with the
power demand, in an environment of steam at high
temperature and pressure. The steel ASTM A335 Gr.
P91 is a typical high-Cr ferritic heat-resistant steel and
is applied particularly to large diameter thick-walled
pipes such as the main steam pipes in thermal power
plants.
The welded joints of Gr. P91 steel are generally
subjected to post weld heat treatment (hereinafter
referred to as "PWHT") to reduce residual stress and
to improve the performance of the weld. If the PWHT
is conducted at an appropriate temperature and
time, the welded joint exhibits favorable mechanical
properties. However, if the PWHT temperature
is too low, the weld metal exhibits inadequate
toughness due to insufficient tempering effect. On
the other hand, if the PWHT temperature is too
high, the tensile strength at ambient and elevated
temperatures becomes insufficient due to excessive
tempering effect. Especially in cases where the PWHT
temperature exceeds the A
c1
transformation point of
the weld metal, the weld metal undergoes reverse
transformation, which results in a microstructure
containing fresh martensite with high strength and
low toughness. This microstructure deteriorates
the performance of the welded joint. To avoid these
problems, the PWHT temperature is controlled
in the actual implementation.
1), 2)
In connection
with selecting welding consumables, chemical
constituents, such as Mn and Ni, that lower the A
c1
transformation point are regulated.
3)
However, not
much has been done to validate the applicability of
this control and regulation to the weld metals from
the aspect of mechanical properties.
In this study, two types of weld metals for Gr. P91
steel, containing different amounts of Mn+Ni, were
mainly used to study the change of their mechanical
properties during PWHTs performed at temperatures
exceeding their A
c1
transformation points. The upper
limit of the PWHT temperature allowable for each
weld metal is considered.
1. Experimental method
1.1 Tested materials
The materials tested were the weld metals
TRUSTARC
TM, note)
CM-9Cb (hereinafter "CM-9Cb")
and TRUSTARC CM-95B9 (hereinafter "CM-95B9").
Both are Kobe Steel's covered electrodes for Gr. P91
steel. The CM-9Cb has been used for over 20 years,
mainly in thermal power plants in Japan. On the other
hand, CM-95B9 is a covered electrode that meets the
American Welding Society (AWS) standard, A5.5
E9015-B9: 2006, and features a lower content of Mn
and Ni in the weld metal, compared with CM-9Cb. In
the following description, the weld metal of CM-9Cb
is referred to as "A", and that of CM-95B9 is referred
to as "B".
Fig. 1 shows the shape of the welding groove
configuration. Plates of JIS G3106 SM490A were used
for the test. Prior to the test, each groove surface
Efects of Post Weld Heat Treatment (PWHT) Temperature
on Mechanical Properties of Weld Metals for High-Cr
Ferritic Heat-Resistant Steel
Genichi TANIGUCHI
1
, Ken YAMASHITA
1
*
1
Welding Process Dept., Technical Center, Welding Business
note )
TRUSTARC ( ) is a trademark of Kobe
Steel.
Fig. 1 Groove confguration and pass sequences
KOBELCO TECHNOLOGY REVIEW NO. 32 DEC. 2013 33
was provided with three layers of buttering welding
using respective welding consumables tested and
machined smoothly so as to prevent the fluctuation
of the chemical composition due to dilution by the
base material. Table 1 shows the welding conditions
inside the groove.
1.2 PWHT conditions
Each specimen for mechanical properties
evaluation was subjected to PWHTs. For weld metal
A, the PWHTs were conducted at five temperatures:
i.e., 670, 730, 760, 790 and 820. For weld metal B,
PWHTs were conducted at four temperatures; i.e.,
720, 760, 800 and 850. The holding time for each
PWHT was 4 hrs. The lower control limit for the
PWHT temperature was 300, while the heating
rate and cooling rate above the lower control limit
temperature were 55/h or lower.
1.3 Measurement of A
c1
transformation points of
weld metals
In order to measure the A
c1
transformation
point, a solid cylindrical specimen of 8 66mm
was taken from each weld metal, as-welded. Each
specimen was taken in the direction parallel to the
welding direction and from a location at the center
of the bead width and of the plate thickness. The A
c1

transformation point is defined as the temperature at
which the austenitic phase starts to form during the
heating process. A general method for measuring
the A
c1
transformation point involves detecting the
expansion and contraction of the specimen during
the phase transformation.
4)
This type of measurement
technique, however, often yields measurement
values that vary significantly, because its accuracy
depends on the method of the expansion/contraction
measurement and the measurement conditions.
Therefore, a preliminary study was conducted to
verify the validity of the method adopted in this
study for measuring the A
c1
transformation point.
5)

The measurement method adopted involves heating a
specimen by induction in a high vacuum atmosphere
of approximately 10
-3
Pa, and detecting the diameter
change of the specimen during the heating, using
a non-contact high-precision measuring system
equipped with an LED device. The heating rate of
the specimen was 10/min up to 600 and was 5/
min in the temperature range from 650 to 1,050, the
range in which reverse transformation is expected to
occur. On the other hand, a carbon steel containing
0.19mass%C was used as a standard sample to
verify the validity of the measurement result. For this
verification, comparisons were made between the A
c1
transformation point measured and the A
1
point that
is roughly derived from the Fe-C phase diagram.
1.4 Mechanical properties evaluation of weld metal
The mechanical properties evaluated were tensile
strength at room temperature, Charpy impact
absorbed energy at 20 and the creep rupture time
at 600 (applied stress108MPa and 147MPa).
The specimens, in accordance with AWS A5.5, were
prepared from each weld metal after the PWHT for
the room temperature tensile test and Charpy impact
test. Each creep rupture specimen had a diameter
of6.0mm with extensometer limb and was taken
in the direction parallel to the welding direction and
from a location at the center of the bead width and of
the plate thickness.
1.5 Observation on the state of carbonitride
precipitation and the extracted residue analysis
A transmission electron microscopy (TEM)
study was conducted on the precipitation state of
carbonitride after the PWHT. Each TEM observation
sample was taken from a cross-section vertical to the
welding direction at the center of the bead width and
of the plate thickness. The observation was conducted
by an extraction replica technique. Extracted residue
analysis was conducted to identify the amount and
composition of carbonitride, using a solid cylindrical
specimen of820mm. Each specimen was taken
from the same location as the TEM observation sample,
but in the direction parallel to the welding direction.
2. Experimental results and discussion
2.1 The chemical compositions of weld metals
Table 2 shows the chemical compositions of weld
metals A and B, as well as that of the carbon steel used
as the standard sample for the measurement of A
c1

transformation point. The amounts of Mn+Ni in the weld
metals were 2.49 mass% for A and 1.38 mass% for B.
2.2 A
c1
transformation point of weld metals
Table 3 shows the A
c1
transformation points
Table 1 Welding conditions
KOBELCO TECHNOLOGY REVIEW NO. 32 DEC. 2013 34
measured. The A
c1
transformation point of the 0.19
mass%C carbon steel, used as the standard sample,
was found to be 732. This temperature agrees well
with the A
1
transformation point of approximately
727 derived from the Fe-C system phase diagram.
This result verifies the reliability of the method used
to measure the A
c1
transformation point in the present
study; i.e., the method involving heating a specimen
by induction in a high vacuum atmosphere, and
detecting the change in the diameter of the specimen
using a non-contact high-precision measuring system
with an LED device.
The A
c1
transformation points of weld metals A
and B, measured in accordance with this method, were
733 and 785, respectively. These measurement
results are hereinafter used as the A
c1
transformation
points of the respective weld metals.
2.3 Effect of PWHT temperature on mechanical
properties of weld metals
Fig. 2 and Fig. 3 show the relationships between
the PWHT temperature and mechanical properties
at room temperature of the weld metals A and B,
respectively. Also included in each figure is the
strength of Gr. P91 steel specified by ASTM.
The room-temperature tensile strength of weld
metal A decreases with rising PWHT temperature
until the PWHT temperature reaches 760, but
increases when the PWHT temperature exceeds
760. The room-temperature tensile strength of weld
metal B, on the other hand, decreases monotonically
with rising PWHT temperature and becomes almost
equal to the lower-limit strength value specified for
the steel at the PWHT temperature of 800. At 850,
0.2% proof strength at room temperature drops
below the lower-limit strength value specified for the
steel.
The absorbed energy of weld metal A increases
with rising PWHT temperature until the temperature
reaches 760, but decreases when the PWHT
temperature exceeds 760. The absorbed energy of
weld metal B, on the other hand, increases with rising
PWHT temperature and appears to reach a maximum
at a PWHT temperature between 800 and 850.
Fig. 4 shows the relationship between the PWHT
temperature and creep rupture time of weld metals
A and B. When the applied stress is low (108MPa),
the creep rupture times of both weld metals A and B
become shorter with rising PWHT temperature. The
Table 2 Chemical compositions of testing materials
Table 3 Measurement results for A
c1
Fig. 2 Relationship between PWHT temperature and
mechanical properties of weld metal A at RT
Fig. 3 Relationship between PWHT temperature and
mechanical properties of weld metal B at RT
KOBELCO TECHNOLOGY REVIEW NO. 32 DEC. 2013 35
creep rupture time of weld metal B decreases abruptly
at PWHT temperatures exceeding 800. When the
applied stress is high (147MPa), the creep rupture
time of weld metal A shortens with rising PWHT
temperature until the temperature reaches 790,
but, in contrast to this, above 790, it lengthens.
The creep rupture time of weld metal B, on the other
hand, shortens with rising PWHT temperature and
decreases abruptly at PWHT temperatures exceeding
760.
In the case of weld metal A, a reversal
phenomenon was observed, at a boundary of the
PWHT temperature, in each mechanical property,
i.e., the room-temperature tensile strength, absorbed
energy and creep rupture time under high applied
stress. This phenomenon is considered to be
caused by fresh martensite precipitated at PWHT
temperatures exceeding the A
c1
transformation
point. Fresh martensite is formed from the austenitic
phase that is formed at temperatures exceeding the
A
c1
transformation point, undergoing martensitic
transformation in the cooling process. The primary
objective of PWHT is tempering; however, the fresh
martensite is not tempered and exhibits high strength
and low toughness. This is considered to have caused
the reversal phenomena in the mechanical properties.
There are two facts that should be noted. The first
fact is that the reversal of the mechanical properties
of weld metal A occurs at temperatures higher than
its A
c1
transformation point. This fact is roughly
explained by the reverse transformation ratio. Fig. 5
shows the reverse transformation ratios of weld
metals A and B. Each reverse transformation ratio
was determined from the temperature vs. expansion/
contraction curve obtained by the A
c1
transformation
point measurement. For each of weld metals A and
B, the ratio of the reverse transformation to the
austenitic phase is rather small in the temperature
range immediately above the A
c1
transformation
point, which makes the amount of fresh martensite
precipitated in the cooling process small and not
enough to cause the reversal of the mechanical
properties. On the other hand, as the PWHT
temperature rises, the reverse transformation ratio
increases, increasing the amount of fresh martensite
with high strength and low toughness. This is
considered to have caused the reversal phenomena
described above. Meanwhile, unlike weld metal A,
weld metal B did not show any reversal of mechanical
properties even when the PWHT temperature
greatly exceeded its A
c1
transformation point and
the reverse transformation ratio became sufficiently
large. This phenomenon cannot simply be explained
by the reverse transformation ratio alone. For an
explanation, two assumptions were considered;
i.e., the precipitation of low C fresh martensite and
the precipitation of ferrite phase
6)
. The former, in
particular, was considered on the basis of the fact
that weld metal B has a smaller amount of Mn + Ni
compared with weld metal A. When the amount of
Mn + Ni is small, only a small amount of solid solute
C is generated in the austenitic phase by the reverse
transformation. As a result, low C fresh martensite
that is relatively soft is considered to precipitate in the
cooling process.
The following experiment was conducted to
verify these assumptions. The specimens for the A
c1
transformation point measurement were prepared
from weld metals A and B, both as-welded.
Each specimen was held for 1h at a temperature
approximately 30 higher than its respective A
c1
transformation point and was subjected to the cooling
process at a cooling rate of 2/min. The temperature
Fig. 4 Relationship between PWHT temperature and 600
creep rupture time of weld metals A and B
Fig. 5 Relationship between temperature and reverse transformation ratio of weld metals A and B
KOBELCO TECHNOLOGY REVIEW NO. 32 DEC. 2013 36
vs. expansion/contraction curve was measured
during the cooling process to confirm the precipitated
phase. Fig. 6 shows the results. Weld metal A exhibits
a linear expansion behavior, an indication of fresh
martensite formation, at around 400. Weld metal B,
on the other hand, exhibits another linear expansion
behavior, an indication of third phase precipitation,
at around 750. Fig. 7 shows the microstructures of
weld metals A and B after this test, and Fig. 8 shows
the Kernel Average Misorientation (KAM) images of
the respective fields. The KAM images are obtained
by electron backscatter diffraction (EBSD) analysis
and provide measures of crystal misorientation and
lattice strain. A KAM image represents the average
crystal misorientations between a pixel and the
nearest neighboring pixels in the image, and displays
the crystal misorientation distribution in the observed
field. Martensite has a large lattice strain in its crystal
lattice, enabling the KAM image to discriminate
between ferrite and martensite in the microstructure.
Comparing weld metals A and B in Fig. 7, it can be
seen that the microstructure of weld metal B has a
coarse white texture in the perpendicular direction in
the middle of the photograph. This white structure
corresponds to the area of concentrated blue in
the KAM image of weld metal B shown in Fig. 8,
which indicates that the lattice strain of this area is
significantly smaller than that of the structure in
the surrounding area. This implies that the white
structure observed in weld metal B may possibly be
ferrite. The identification of this precipitate phase will
be pursued further.
The second fact that should be noted is that weld
metal A shows a reversal in the relationship between
PWHT temperature and creep rupture time under
high applied stress, which, however, is not the
case for the low applied stress. This is considered
to have been caused by the difference between
the deformation behavior of the creep rupture test
specimens under high stress and that under low
stress.
7)
In other words, when a high stress is applied,
deformation occurs throughout the entire specimen.
Fresh martensite, with highly dense dislocations
in its crystal grain, contributes to the prolonged
creep rupture time. On the other hand, under a low
applied stress, deformation preferentially occurs
in the vicinity of prior austenitic grain boundaries.
Hence, the fresh martensite is considered not to have
contributed to the prolonged creep rupture time.
The above results confirm that the upper limit
of allowable PWHT temperature is governed by
the mechanical properties, rather than by the A
c1
transformation point.
2.4 Effect of PWHT temperature on the precipitation
state and composition of carbonitride precipitation
in weld metals
An investigation was made regarding the effect
of PWHT temperature on the precipitation state
and precipitate amount/composition of carbonitride
in weld metal A. Fig. 9 shows the TEM images of
weld metal A after PWHT at each temperature. No
Fig. 6 Phase transformation temperature of weld metals A
and B during cooling process
Fig. 7 Microstructures of weld metals A and B after phase
transformation temperature analysis
Fig. 8 KAM images of weld metals A and B after phase
transformation temperature analysis
Fig. 9 TEM images of weld metal A after PWHT at diferent
temperatures
KOBELCO TECHNOLOGY REVIEW NO. 32 DEC. 2013 37
significant difference was found in the precipitation
amount and distribution of carbonitride between the
PWHT temperatures of 670 and 760. However,
it was clearly observed that the precipitates of
intragranular carbonitride are more thinly distributed
at 790, and the lath carbide on grain boundaries has
been coarsened at 820.
Extracted residue analysis was conducted to
quantitatively compare the precipitation amount of
carbonitride at the respective PWHT temperatures.
Fig.10 shows the analysis results. It is confirmed that
the elements Cr, Mo, V and N all decrease abruptly
when the PWHT temperature exceeds 760. This
is considered to have been caused by the increased
PWHT temperature promoting the dissolution of
carbonitride into the matrix to form a solid solution.
3. The upper limit PWHT temperature allowable for
each weld metal
The A
c1
transformation points of weld metals A
and B were measured and found to be 730 and
780, respectively. If the construction standard
that stipulates that the PWHT temperature must be
lower than the A
c1
transformation point is followed,
the upper limits of the PWHT temperature for
weld metals A and B should be approximately
730 and 780, respectively. However, the PWHT
temperature of 730 provides weld metal A
with tempering insufficient to achieve the desired
mechanical properties. In the case of weld metal
B, on the other hand, the PWHT temperature of
780 makes the room-temperature tensile strength
almost equal to the lower limit value of the standard
for Gr. P91 steel, which raises a concern that the
margin against the specification becomes too small.
Thus, a PWHT temperature selected merely on the
basis of the A
c1
transformation point may not
be practical. Comprehensive contemplation of
mechanical properties is considered to be important
in determining the PWHT temperature.
Fig.11 shows the creep rupture strengths of weld
metals A and B. The creep master curve for the Gr. P91
steel welded joint is also included. From the results,
and now assuming that the weld metal is required
to have a creep rupture strength that is equal to or
greater than that of the welded joint, the upper limits
of the PWHT temperatures for weld metals A and B
become 760 and 800 respectively.
If the PWHT temperature of 760 is used for weld
metal A, the weld metal exhibits a favorable toughness
with its tensile strength at room temperature fully
satisfying the specification for Gr. P91 steel. In the
case where the PWHT temperature of 800 is used
for weld metal B, the weld metal exhibits a favorable
toughness; however, its room-temperature tensile
strength has only a small margin against the Gr. P91
steel specification, as described above.
After the comprehensive consideration of
mechanical properties based on the above results,
the upper limits of the PWHT temperatures for weld
metals A and B are concluded to be 760 and 800,
respectively.
Conclusions
Two types of weld metals were prepared using
CM-9Cb and CM-95B9, Kobe Steel's covered
electrodes designed for ASTM A335 Gr. P91 steel.
The weld metals are mainly characterized by their
different Mn + Ni content. Each of them was subjected
to post weld heat treatment (PWHT) at temperatures
above its A
c1
transformation point to study its
mechanical properties after the heat treatment. There
was discussion concerning the upper limit of the
PWHT temperature allowable for each of the weld
metals. The results show that the amount of Mn+Ni
for the CM-9Cb weld metal was 2.49mass%, and the
A
c1
transformation point was 733. In accordance
with the construction standard stipulating that
the PWHT temperature must be lower than the A
c1

transformation point, the upper limit of the PWHT
temperature should be 730; however, on the basis
Fig.10 Analysis of extracted residues of weld metal A after
PWHT at diferent temperatures
Fig.11 Creep rupture strengths of weld metals A and B after
PWHT at diferent temperatures
KOBELCO TECHNOLOGY REVIEW NO. 32 DEC. 2013 38
of the evaluation results for mechanical properties,
a PWHT temperature of up to 760 is judged to be
allowable.
The amount of Mn + Ni for the CM-95B9 weld metal
was 1.38mass% and A
c1
transformation point was
785. If the standard described above is followed,
the upper limit of the PWHT temperature should be
780; however, on the basis of the evaluation results
for mechanical properties, a PWHT temperature of
up to 800is judged to be allowable.
The above findings indicate that the PWHT
temperature for a weld metal of high Cr ferritic
heat-resistant steel should not be determined merely
on the basis of the Mn + Ni content and/or the A
c1

transformation point, but rather should take into
consideration the mechanical properties, including
creep rupture performance.
The present paper studying the upper limit of the
PWHT temperature focuses only on the weld metals.
However, more comprehensive research should be
done to evaluate the actual welded joints, and this
would include a study of the base material and the
heat-affected zone of the base material.
References
1) ASME B31.1. POSTWELD HEAT TREATMENT. 2001, 132.1,
p.87.
2) Thermal and Nuclear Power Engineering Society. The
interpretation for the technical standard for thermal power
plant [Chapter 10, Welding[handbook] (Revision H19).
2009, p.159.
3) AWS A5.5/A5.5M. 2006. p.8.
4) ASTM 1033-4. Standard Practice for Quantitative
Measurement and Reporting of Hypoeutectoid Carbon and
Low-Alloy Steel Phase Transformations.
5) Chen Liang et al. Effect of PWHT temperature and
mechanical properties of High-Cr ferritic heat-resistant steel
weld metal. Welding in the World. 2012, Vol.56, January-
February (1-2).
6) T. Tokunaga, et al. Phase transformation behavior of Gr. 91
ferritic steel around the A
c1
temperature. CAMP-ISIJ. 2008,
Vol.21, p.1066.
7) H. Kushima et al. Degradation of Mod. 9Cr-1Mo Steel during
Long-term Creep Deformation. TETSU-TO-HAGANE (in
Japanese). 1999, Vol.85, No.11, p. 57.
KOBELCO TECHNOLOGY REVIEW NO. 32 DEC. 2013 39