Question 1 No. Of Q Explanation Marks Total Mark 1 (a) (i) Melting point is the temperature at which solid change into liquid at standard temperature and pressure. (b) (ii) Proton number / positive charge increase / / force.
Question 1 No. Of Q Explanation Marks Total Mark 1 (a) (i) Melting point is the temperature at which solid change into liquid at standard temperature and pressure. (b) (ii) Proton number / positive charge increase / / force.
Question 1 No. Of Q Explanation Marks Total Mark 1 (a) (i) Melting point is the temperature at which solid change into liquid at standard temperature and pressure. (b) (ii) Proton number / positive charge increase / / force.
Question 1 No. Of Q Explanation Marks Total Mark 1 (a) (i) Melting point is the temperature at which solid change into liquid at standard temperature and pressure. (b) (ii) Proton number / positive charge increase / / force.
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SULIT 4541/2 (PP)
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4541/2 (PP) 2014 Hak Cipta Panitia Kimia SMKSAJ SULIT
SMK SULTAN ABDUL JALIL, KLUANG, JOHOR ______________________________________________
PEPERIKSAAN PERCUBAAN SPM 2014 4541/2 TINGKATAN LIMA
Chemistry Kertas 2 Peraturan Pemarkahan September 2014
UNTUK KEGUNAAN PEMERIKSA SAHAJA
___________________________________________________________________________ Peraturan pemarkahan ini mengandungi 11 halaman bercetak
AMARAN
Peraturan pemarkahan ini SULIT dan Hak Cipta Panitia Kimia SMKSAJ. Kegunaannya khusus untuk pemeriksa yang berkenaan sahaja. Sebarang maklumat dalam peraturan pemarkahan ini tidak boleh dimaklumkan kepada sesiapa. Peraturan pemarkahan ini tidak boleh dikeluarkan dalam apa-apa bentuk media.
SULIT 4541/2 (PP)
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Question 1
No. of Q Explanation Marks Total Mark 1 (a) (i) Melting point is the temperature at which solid change into liquid at standard temperature and pressure. 1 (a) (ii) 83 o C 1 (a) (iii) 136 o C 1 (a) (iv) (a) Solid + liquid 1 (a) (iv) (b) Gas 1 (a) (v) 1. Heat energy loss to the surrounding 2. balanced by heat energy liberated by particles to attract each other.
1
1
(a) (vi)
1
(b) (i) Able to state the meaning of diffusion Sample answer: A process when particles of a substance /gas P/Q move between the particles of another substance/gas Q/P
1
(b) (ii) Able to state the colour correctly Answer: Brown // Light brown
1 Total 10
Question 2
No. of Q Explanation Marks Total Mark 2 (a) (i) 2.8.4 1 (a) (ii) 14 1 (b) (i) Decrease // become smaller 1 SULIT 4541/2 (PP)
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No. of Q Explanation Marks Total Mark (b) (ii) Proton number / positive charge increase // force attraction increase 1 (c) Achieve octet electron arrangement // has 8 valence electron Do not accept or share electron 1 1
(d) (i) Al // Aluminium 1 (d) (ii) Al 2 O 3 1 (e)
Pt 1: Label nucleus and correct number of shell Pt 2: Octet electron arrangement and correct charges
1 1
Total 10
Question 3
No. of Q Explanation Marks Total Mark 3
(a)
Is a representation of a chemical substance using letters for atoms and subscripts for each type of atoms present
1
1 (b) (i) [ Able to name suitable acid and metal and its equation ] For example Hydrochloric acid and zinc metal 1 1 (ii) Zn + 2HCl ZnCl 2 + H 2 1 1 (c) Hydrogen gas must be flowed/through/into the combustion tube for a few minutes before heating/ The flow of hydrogen gas must be continuous throughout the experiment/ [ Accept any one answer] 1 1 (d) (i) Number of mole of copper = 1.62 64 = 0.025mole 1 1 SULIT 4541/2 (PP)
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No. of Q Explanation Marks Total Mark (ii) Number of mole of copper = 0.40 16 = 0.025mole 1 1 (iii) Number of mole of copper: Number of mole of oxygen 0.025 : 0.025 The simplest ratio 1 : 1 The empirical formula of copper(II) oxide is CuO
1 1 2 (e) Iron(II) oxide / Tin(II) oxide / Lead(II) 1 1 (f) Burning of metal in excess oxygen
1 1 Total 10
Question 4
No. of Q Explanation Marks Total Mark
4
(a) C 4 H 10 1 1 (b)
1+1
2 (c) - Butene is an unsaturated hydrocarbon/ has double bond - Butane is a saturated hydrocarbon/ has single bond 1 1
2 C 4 H 8 + H 2
C 4 H 10
- correct reactants and products 1
- balanced equation
1
1 (e) (i)
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No. of Q Explanation Marks Total Mark - Functional diagram - Labelled diagram
1 1
2 (ii) Hexene produced more soot More carbon in one molecule of hexene compare to one molecule of hexane 1 1
2 Total 10
Question 5
No. of Q Explanation Marks Total Mark 5 (a) (i) Acid (substance) which ionises partially// has lower degree of dissociation in water to produce low concentration of H + ion 1 (a) (ii) The concentration of hydrogen ions in hydrochloric acid is higher 1 The higher the concentration of hydrogen ions, the lower the pH value 1 (b) (i) Neutralisation 1 (b) (ii) Sodi um chl ori de 1 (b) (iii) Pi nk t o col ourl ess 1 (b) (iv) HCI + NaOH NaCI + H 2 O No of mole of NaOH = 0.1 (25) 1000 = 0.0025 mol
1 mol of NaOH react completely with 1 mol of HCl 0.0025 mol of NaOH react completely with 0.0025 mol HCI
1
1
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No. of Q Explanation Marks Total Mark Molarity of HCI = 0.0025 x 1000 12.5 = 0.2 mol drri 3
1 Total 10
Question 6
No. of Q Explanation Marks Total Mark 6 (a) (i) Ethanol 1 (ii) The heat released when one mole of ethanol completely burnt in Oxygen (under standard condition) is 1260 kJ 1 (b) (i) No of moles of alcohol = 0.23 /46 = 0.005 mol 1 mol of alcohol burnt released 1260 kJ Thus 0.005 mol of alcohol burnt released 6.3 kJ 1
1 1
(ii) = H mc = 6300 200 x 4. 2 = 7. 5 o C
1
1
(c) Heat is lost to the surrounding // Heat is absorbed by the apparatus or containers // Incomplete combustion of alcohol 1 (d)
Label energy and di agram has 2 di fferent energy l avel s Bal anced chemi cal equati on
Total 10
SULIT 4541/2 (PP)
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Question 7
No. of Q Explanation Marks Total Mark 7 (a) (i) Electrode P : Iodide ion / I - ion and hydroxide ion / OH - ion Electrode Q : Hydrogen ion / H + ion and Potassium ion / K +
ion 1 1
2 (ii) Electrode P : Oxygen molecule gas // Oxygen gas Electrode Q : Hydrogen molecule gas // hydrogen gas R : formula 1 1
2 (iii) Electrode P : iodine molecule // iodine Electrode Q : hydrogen molecule // hydrogen gas
Half equation : Electrode P : 2 I - I 2 + 2e Electrode Q: 2 H + + 2 e H 2
Confirmatory test at P : Starch solution is added into the solution around electrode P Blue colouration / precipitate is formed 1 1
1 1
1 1
6 (b) Cell X Cell Y Type of cell Electrolytic cell Voltaic cell The energy change Electrical energy to chemical energy Chemical energy to electrical energy The terminal of cell Anode : Copper electrode
Cathode : Brown deposit // brown solid is deposited // become thicker
Anode : become thinner
Cathode : Brown deposited // brown solid deposited // become thicker
1
1
1
1
1
1
1
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No. of Q Explanation Marks Total Mark Half equation for both electrodes Anode : Cu Cu 2+ + 2e
Cathode: Cu 2+ + 2e Cu Anode : Al Al 3+ + 3e
Cathode : Cu 2+ + 2e Cu Name of the process occurred at both electrodes Anode : Oxidation process Cathode : Reduction process
1
1
1
10
Total 20
Question 8
No. of Q Explanation Marks Total Mark 8 (a) The temperature in a refrigerator is lower Bacterial activity is lower, less toxin is produced by bacteria In a kitchen cabinat, the temperature is higher , bacteria activity is higher Therefore the rate of food spoilage is faster in a kitchen cabinet than in a refrigerator. 1 1
1
1
4 (b) (i) Volume of gas released = 50 cm 3
Time taken = 55 s Average rate of reaction = 50/55 = 0.91 cm 3 s -1
1 1
2 (b) (ii) Experiment I and Experiment II The temperature for the reaction II is higher than experiment I Increase the kinetic energy of the reacting particle Increase the rate of collision between calcium carbonate particles and hydrochloric acid particles Increase the rate of effective collision. Hence, experiment II has a higher rate of reaction than experiment I
Experiment II and Experiment III The size of calcium carbonate in reaction III is smaller than
1 1
1 1
1
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No. of Q Explanation Marks Total Mark reaction II Smaller size of reactant has bigger total surface area exposed Increase the rate of collision between calcium carbonate particles and hydrochloric acid particles Increase the rate of effective collision. Hence, experiment III has a higher rate of reaction than experiment II
1 1
1 1
1
10 (b) (iii) No. moles of HCl = 0.5 x 30 1000 = 0.015 mol
2 mol of HCl produce 1 mol of CO 2
Therefore 0.015 mol of HCl produce 0.0075 mol CO 2
Volume = 0.0075 x 24 = 0.18 dm 3
1
1 1
1
4 Total 20
Question 9
No. of Q Explanation Marks Total Mark 9 (a) (i) NaOH 1 1 (ii) Materials : Solid sodium hydroxide and distilled water Apparatus : 50cm 3 beaker, 250cm 3 volumetric flask, electronic balance, glass rod, filter funnel.
Calculation : Determine the mass of sodium hydroxide, NaOH:
No. of moles of NaOH = MV = 1 x 250 = 0.25 mol 1000 1000
Mass of NaOH needed = No. of moles x Molar mass, of NaOH = 0.25 x [23 + 16 + 1 ] = 10 g
Steps : 1. Using an electronic balance, 10 g of sodium hydroxide is exactly weighed and placed into a beaker, 1 1
1
1 1
1
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No. of Q Explanation Marks Total Mark 2. Distilled water is added to the beaker to dissolve all the solid sodium hydroxide, 3. Then the solution is poured into a 250cm 3 volumetric flask. The beaker is rinsed with distilled water and the solution is poured into the volumetric flask. 4. The solution in the volumetric flask is topped up with distilled water until its calibration mark.
1
1
1
9 (ii) To identify Mg 2+ ion -Magnesium nitrate solution is poured into a test tube -NaOH solution is added until excess -white precipitate formed and insoluble in excess and -test with NH 3 solution -same step and same result will obtained when test with NH 3 solution
NO 3 - ion -Magnesium nitrate solution is poured into a test tube -dilute sulfuric acid is added -followed by iron(II) sulphate solution -shake the test tube -concentrated sulphuric acid is added slowly/through the wall of the test tube -brown ring formed
1 1 1 1
1 1 1 1
1 1
10 Total 20
Question 10
No. of Q Explanation Marks Total Mark 10 (a) Part X hydrophobic/hydrocarbon Part Y hydrophilic/ionic Part X dissolves in grease Part Y dissolves in water 1 1 1 1
4 (b) 1.The cloth in experiment II is clean whereas the cloth in Experiment I is still dirty. 2.In hard water,soap react with magnesium ion / calcium ion
1 1
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No. of Q Explanation Marks Total Mark 3.to form scum 4.Detergent are more effective in hard water 5.Detergent does not form scum 6.Detergent are better cleansing agen then soap to remove oily stain.
1 1 1
1
6 (c)(i) Pure metal atoms has similar size and shape Easily to slide
1 1
2
(c)(ii) Draw for pure copper Draw for its alloy and labels for copper and zinc
1 1
2
(c)(iii) Increase the strength and hardness of metal Prevent the corrosion of metal Improve the appearance 1 1 1
3
(c)(iv) Duralumin Its stronger / harder Can withstand compression