Sodium Bisulphate 2011 March
Sodium Bisulphate 2011 March
Sodium Bisulphate 2011 March
JXFPR
Status ISSUED by
AJAXFC
BS: 1.10.9
Product Name
SODIUM BISULPHATE
Product Code
A41944
Company Name
Address
Emergency Tel.
1800 638 556 (24 hr) Aust / (NZ): 0800 154 666
Telephone/Fax
Number
Recommended Use Used in mineral fusion, carbonic acid baths, pickling metals,
carbonising wools, bleaching and swelling leathers, pH
adjustment of swimming pools and in magnesia cement.
Other Names
Name
SODIUM HYDROGEN SULPHATE
SODIUM HYDROGEN SULPHATE
Product Code
1540
11001
Other
Information
2. HAZARDS IDENTIFICATION
Hazard
Classification
Australia:
Classified as Hazardous according to criteria of National
Occupational Health & Safety Commission, Australia (NOHSC).
Classified as Dangerous Goods according to the Australian Code
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Safety Phrase
(s)
3. COMPOSITION/INFORMATION ON INGREDIENTS
Ingredients
Name
CAS
Sodium Hydrogen
7681-38-1
sulphate anhydrous
(technical)
Proportion
100 %
Inhalation
Ingestion
Do NOT induce vomiting. Wash out mouth with water and give
plenty of water to drink. Seek medical attention.
Skin
Eye
First Aid
Facilities
Advice to
Doctor
Treat symptomatically.
Other
Information
Suitable
Extinguishing
Media
Hazards from
Combustion
Products
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Specific
Hazards
Hazchem Code
2X
Emergency
Procedures
Precautions for Corrosive solid. Attacks skin and eyes. Causes burns. Wear
Safe Handling
suitable protective clothing, gloves and eye/face protection
when mixing and using. Use in designated areas with adequate
ventilation. Avoid breathing in dust. Keep containers closed
when not in use. Ensure a high level of personal hygiene is
maintained when using this product, that is, always wash hands
after handling, and before eating, drinking, smoking or using
the toilet facilities.
Conditions for
Safe Storage
National
Exposure
Standards
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follows:
Australian National Occupational Health And Safety Commission
(NOHSC) exposure standards:
Dust TWA 10 mg/m (inspirable fraction)
New Zealand Workplace Exposure Standards (OSH):
Particulates TWA 10 mg/m (inhalable) TWA 3 mg/m (respirable)
TWA (Time Weighted Average): The average airborne concentration
of a particular substance when calculated over a normal eighthour working day, for a five-day week.
Biological
Limit Values
Engineering
Controls
Respiratory
Protection
Eye Protection
Appearance
Odour
Melting Point
315C
Boiling Point
Not applicable
Solubility in
Water
Specific
Gravity
2.43 (13C)
pH Value
<1.0
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(Air=1)
Not applicable
Flash Point
Not applicable.
Auto-Ignition
Temperature
Not applicable.
Flammable
Limits - Lower
Not applicable.
Flammable
Limits - Upper
Not applicable.
Chemical
Stability
Conditions to
Avoid
Incompatible
Materials
Hazardous
Decomposition
Products
Hazardous
Polymerization
Toxicology
Information
Acute toxicity:
LD50 (Oral, Rat): 2,800mg/kg
Inhalation
Ingestion
Skin
Eye
Ecotoxicity
Not available
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Persistence /
Degradability
Not available
Mobility
Not available
Environment
Protection
Disposal
Considerations
Product Disposal:
Product wastes are controlled wastes and should be disposed of
in accordance with all applicable local and national
regulations. This product can be disposed through a licensed
commercial waste collection service. The product should be
rendered non-hazardous before being sent to a licensed landfill
facility.
Do not dispose directly into the sewerage system. Do not
discharge into drains or watercourses or dispose where ground or
surface waters may be affected.
Personal protective clothing and equipment as specified in
Section 8 of this SDS must be worn during handling and disposal
of this product. The ventilation requirements as specified in
the same section must also be followed, and the precautions
given in Section 7 of this SDS regarding handling must also be
followed.
In New Zealand, the disposal agency or contractor must comply
with the New Zealand Hazardous Substances (Disposal) Regulations
2001. Further details regarding disposal can be obtained on the
ERMA New Zealand website under specific group standards.
Container Disposal:
The container or packaging must be cleaned and rendered
incapable of holding any substance. It can then be disposed of
in a manner consistent with that of the substance it contained.
In this instance the packaging can be disposed through a
commercial waste collection service.
Alternatively, the container or packaging can be recycled if the
hazardous residues have been thoroughly cleaned or rendered nonhazardous.
In New Zealand, the packaging (that may or may not hold any
residual substance) that is lawfully disposed of by householders
or other consumers through a public or commercial waste
collection service is a means of compliance with regulations.
Transport
Information
Australia:
This material is classified as a Class 8 (Corrosive Substances)
Dangerous Goods according to the Australian Code for the
Transport of Dangerous Goods by Road and Rail (7th edition).
Class 8 Dangerous Goods are incompatible in a placard load with
any of the following:
- Class 1, Explosives
- Division 4.3, Dangerous When Wet Substances
- Division 5.1, Oxidising Agents
- Division 5.2, Organic Peroxides
- Class 6, Toxic or Infectious Substances, if the Class 6
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dangerous goods are cyanides and the Class 8 dangerous goods are
acids
- Class 7, Radioactive Substances
and are incompatible with food and food packaging in any
quantity.
Strong acids must not be loaded in the same freight container or
on the same vehicle with strong alkalis. Packing Group I and II
acids and alkalis should be considered as strong.
New Zealand:
This material is classified as a Class 8 Corrosive Substance
according to NZS 5433:2007 Transport of Dangerous Goods on Land.
Must not be loaded in the same freight container or on the same
vehicle with:
- Class 1, Explosives
- Division 5.1, Oxidising substances
- Division 5.2, Organic peroxides
- Class 7, Radioactive materials unless specifically exempted
And are incompatible with food and food packaging in any
quantity.
Note 1: Cyanides (Division 6.1) must not be loaded in the same
freight container or on the same vehicle with acids (Class 8).
Note 2: Strong acids must not be loaded in the same freight
container or on the same vehicle with strong alkalis. Packing
Group I and II acids and alkalis should be considered as strong.
Must not be loaded with in the same freight container; and on
the same vehicle must be separated horizontally by at least 3
metres unless all but one are packed in separate freight
containers with:
- Class 4.3, Dangerous when wet substances
Goods of packing group II or III may be loaded in the same
freight container or on the same vehicle if transported in
segregation devices with:
- Class 4.3, Dangerous when wet substances
- Class 5.1, Oxidising substances
- Class 5.2, Organic peroxides
And are incompatible with food and food packaging in any
quantity.
U.N. Number
3260
Hazchem Code
2X
Packaging
Method
3.8.8
Packing Group
III
IERG Number
37
Regulatory
Information
Australia:
Classified as Hazardous according to criteria of National
Occupational Health & Safety Commission (NOHSC), Australia.
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HSNO Approval
Number
S5
New Zealand:
Classified as Hazardous according to the New Zealand Hazardous
Substances (Minimum Degrees of Hazard) Regulations 2001.
All components of this product are listed on the New Zealand
Inventory of Chemicals (NZIoC) or exempted.
HSNO (CCID) Name:
Sodium hydrogen sulphate
HSR003951
Date of
preparation or
last revision
of MSDS
Contact
Person/Point
End of MSDS
BS: 1.10.9
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