763 Rust Transformer PDF
763 Rust Transformer PDF
763 Rust Transformer PDF
inaccordancewithREACH(1907/2006/EC,asamendedby453/2010/EC)
Revisiondate: 29November2012
Initialdateofissue: 6July2007
SDSNo. 168B18
SECTION1:IDENTIFICATIONOFTHESUBSTANCE/MIXTUREANDOFTHECOMPANY/UNDERTAKING
1.1.Productidentifier
763RustTransformer(Bulk)
1.2.Relevantidentifiedusesofthesubstanceormixtureandusesadvisedagainst
AcidBasecoating.Stopsrustingandpreventsfurthercorrosivedamagetometalandformsasoundbaseforprimercoating.
1.3.Detailsofthesupplierofthesafetydatasheet
Company:
A.W.CHESTERTONCOMPANY
860SalemStreet
Groveland,MA018341507,USA
Tel.:+19784696446Fax:+19784696785
(Mon.Fri.8:305:00PMEST)
Email(SDSquestions):[email protected]
Email:[email protected]
SDSrequests:www.chesterton.com
Supplier:
1.4.Emergencytelephonenumber
24hoursperday,7daysperweek
CallInfotrac:18005355053
OutsideN.America:+13523233500(collect)
SECTION2:HAZARDSIDENTIFICATION
2.1.Classificationofthesubstanceormixture
2.1.1.ClassificationaccordingtoDirective1999/45/EC
CorrosiveCR34
R10
R20/22
HarmfulXnR20/22
2.1.2.CanadianWHMISclassification
B2:FlammableliquidsE:CorrosivematerialsD2A:Verytoxicmaterialscausingothereffects
2.1.3.Australianclassification
HazardousaccordingtocriteriaofSafeWorkAustralia.
2.1.4.Additionalinformation
ForfulltextofRphrases:seeSECTIONS2.2and16.
A.W.ChestertonCompany,2012AllRightsReserved.Reg.USPatentandTMOffice
Page1of7
Product:763RustTransformer(Bulk)
Date:29November2012
2.2.Labelelements
SDSNo.168B18
LabellingaccordingtoDirective1999/45/EC
Dangersymbols:
CCorrosive
Rphrases:
R10
R34
R20/22
Sphrases:
S23
Donotbreathevapour/spray.
S51
Useonlyinwellventilatedareas.
S36/37/39 Wearsuitableprotectiveclothing,glovesandeye/faceprotection.
S26
Incaseofcontactwitheyes,rinseimmediatelywithplentyofwaterandseekmedicaladvice.
S28
Aftercontactwithskin,washimmediatelywithplentyofwater.
S45
Incaseofaccidentorifyoufeelunwell,seekmedicaladviceimmediately(showthelabelwhere
possible).
Otherinformation:
None
Flammable.
Causesburns.
Harmfulbyinhalationandifswallowed.
2.3.Otherhazards
Itwillstaintheskinafterprolongedcontact.Thestainwillfadeintimeoritcanberemovedbyrinsingthehandswithadilute
solutionofbleach.Safetygogglesandglovesmustbewornwhileusingthisproduct.
SECTION3:COMPOSITION/INFORMATIONONINGREDIENTS
3.2.Mixtures
HazardousIngredients
%Wt.
CASNo./
ECNo.
REACH
Reg.No.
Classification
(acc.to1272/2008/EC)
Classification
(67/548/EEC)
Ethyleneglycol
1525
NA
AcuteTox.4*,H302
XnR22
Isopropanol
1020
107211
2034733
67630
2006617
NA
F,XiR113667
PhosphinicAcid,BariumSalt
15
Flam.Liq.2,H225
EyeIrrit.2,H319
STOTSE3,H336
AcuteTox.4,H302,H332
14871795
NA
2389421
PhosphinicAcid
15
6303215
NA
SkinCorr.1B,H314
2286015
TannicAcid
1015
1401554
NA
Notclassified
2157532
Indicationsofdangeracc.to67/548/EEC: Xn:HarmfulF:HighlyflammableXi:IrritantC:Corrosive
ForfulltextofHstatementsandRphrases:seeSECTION16.
XnR20/22
CR34
Notclassified
Classifiedaccordingto: *29CFR1910.1200,1915,1916,1917,Mass.RighttoKnowLaw(ch.40,M.G.L..O.111F),CaliforniaProposition65
*1272/2008/EC,67/548/EEC,99/45/EC,REACH
*ControlledProductsRegulations
*SafeWorkAustralia[NOHSC:1008(2004)]
SECTION4:FIRSTAIDMEASURES
4.1.Descriptionoffirstaidmeasures
Inhalation:
Removetofreshair.Ifnotbreathing,administerartificialrespiration.Contactphysician.
Skincontact:
Washskinwithplentyofwater.Washclothingbeforereuse.Consultphysician.
Eyecontact:
Flusheyesforatleast30minuteswithlargeamountsofwater.Consultphysician.
Ingestion:
Donotinducevomiting.Ifconscious,dilutestomachcontentswithlargequantitiesofwater.Contactphysician
immediately.
4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed
Severeeyeandskinirritantmaycauseburns.Excessiveinhalationofvapormayresultindizziness,headacheandothercentral
nervoussystemeffects.Prolongedorrepeatedskincontactmaydefattheskinandcausedermatitis.Repeatedoverexposureto
EthyleneGlycolcancausekidneyandlivereffects.EthyleneGlycolhasproducedbirthdefectsinanimals.
4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded
Treatsymptoms.
A.W.ChestertonCompany,2012AllRightsReserved.Reg.USPatentandTMOffice
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Product:763RustTransformer(Bulk)
Date:29November2012
SECTION5:FIREFIGHTINGMEASURES
5.1.Extinguishingmedia
SDSNo.168B18
CarbonDioxide,drychemicalorfoam
5.2.Specialhazardsarisingfromthesubstanceormixture
None
5.3.Adviceforfirefighters
Coolexposedcontainerswithwater.RecommendFirefighterswearselfcontainedbreathingapparatus.
FlammabilityClassification:
HAZCHEMEmergencyActionCode:
3 Z
SECTION6:ACCIDENTALRELEASEMEASURES
6.1.Personalprecautions,protectiveequipmentandemergencyprocedures
Evacuatearea.Provideadequateventilation.UtilizeexposurecontrolsandpersonalprotectionasspecifiedinSection8.
6.2.EnvironmentalPrecautions
Keepoutofsewers,streamsandwaterways.
6.3.Methodsandmaterialforcontainmentandcleaningup
Containspilltoasmallarea.KeepawayfromsourcesofignitionNosmoking.Ifremovalofignitionsourcesisnotpossible,then
flushmaterialawaywithwater.Pickupwithabsorbentmaterial(sand,sawdust,clay,etc.)andplaceinasuitablecontainerfor
disposal.
6.4.Referencetoothersections
Refertosection13fordisposaladvice.
SECTION7:HANDLINGANDSTORAGE
7.1.Precautionsforsafehandling
Washbeforeeating,drinkingorsmoking.Groundandbondproducttransfer.Utilizeexposurecontrolsandpersonalprotectionas
specifiedinSection8.
7.2.Conditionsforsafestorage,includinganyincompatibilities
Storeincool,dryarea.
7.3.Specificenduse(s)
Nospecialprecautions.
SECTION8:EXPOSURECONTROLS/PERSONALPROTECTION
8.1.Controlparameters
HazardousIngredients
OSHAPEL
ppm
mg/m3
Ethyleneglycol
Isopropanol
PhosphinicAcid,BariumSalt
PhosphinicAcid
TannicAcid
ACGIHTLV
ppm
mg/m3
(C)
100
400
980
(asBa)
0.5
200
STEL:
400
(asBa)
0.5
UKWEL
ppm
mg/m3
20
STEL:
40
400
500
50
104
999
STEL:
1250
AUSTRALIAES
ppm
mg/m3
20
40
400
STEL:
500
52
STEL:
104
983
1230
0.5
8.2.Exposurecontrols
8.2.1.Engineeringmeasures
Useonlyinwellventilatedareas.
8.2.2.Individualprotectionmeasures
Respiratoryprotection:
Notnormallyneeded.Ifexposurelimitsareexceeded,useapprovedorganicvaporrespirator.
A.W.ChestertonCompany,2012AllRightsReserved.Reg.USPatentandTMOffice
Page3of7
Product:763RustTransformer(Bulk)
Date:29November2012
Protectivegloves:
SDSNo.168B18
Chemicalresistantgloves
Isopropanol:
Contacttype
Glovematerial
Layerthickness
Full
Nitrilerubber
0.40mm
Splash
neoprene
0.65mm
*DeterminedaccordingtoEN374standard.
Eyeandfaceprotection:
Safetygoggles.
Other:
Imperviousclothingasnecessarytopreventskincontact.
Breakthroughtime*
>480min.
>120min.
8.2.3.Environmentalexposurecontrols
Refertosections6and12.
SECTION9:PHYSICALANDCHEMICALPROPERTIES
9.1.Informationonbasicphysicalandchemicalproperties
Physicalstate
Colour
Initialboilingpoint
Meltingpoint
%Volatile(byvolume)
Flashpoint
Method
Viscosity
Autoignitiontemperature
Decompositiontemperature
Upper/lowerflammabilityor
explosivelimits
Flammability(solid,gas)
Explosiveproperties
liquid
darkbrown
100C(212F)
notdetermined
66%
34C(93F)
PMClosedCup
notdetermined
notdetermined
nodataavailable
notdetermined
Odour
Odourthreshold
Vapourpressure@20C
%Aromaticsbyweight
pH
Relativedensity
Weightpervolume
Coefficient(water/oil)
Vapourdensity(air=1)
Rateofevaporation(ether=1)
Solubilityinwater
sweetodor
notdetermined
notdetermined
0%
1.5
1,07kg/l
8.9lbs/gal.
>1
>1
<1
complete
notapplicable
notapplicable
Oxidisingproperties
notapplicable
9.2.Otherinformation
None
SECTION10:STABILITYANDREACTIVITY
10.1.Reactivity
Refertosections10.3and10.5.
10.2.Chemicalstability
Stable
10.3.Possibilityofhazardousreactions
Nodangerousreactionsknownunderconditionsofnormaluse.
10.4.Conditionstoavoid
Openflamesandredhotsurfaces.
10.5.Incompatiblematerials
StrongoxidizerslikeliquidChlorineandconcentratedOxygen.
10.6.Hazardousdecompositionproducts
CarbonMonoxide,CarbonDioxideandothertoxicfumes.
A.W.ChestertonCompany,2012AllRightsReserved.Reg.USPatentandTMOffice
Page4of7
Product:763RustTransformer(Bulk)
Date:29November2012
SECTION11:TOXICOLOGICALINFORMATION
11.1.Informationontoxicologicaleffects
Primaryrouteofexposure
undernormaluse:
Acuteeffects:
SDSNo.168B18
Inhalation,skinandeyecontact.
Severeeyeandskinirritantmaycauseburns.Excessiveinhalationofvapormayresultindizziness,
headacheandothercentralnervoussystemeffects.
Substance
Test
Result
Ethyleneglycol
LD50oral,rat
4700mg/kg
Ethyleneglycol
Humanlethaldose
786mg/kg
Ethyleneglycol
LC50inhalation,rat
>20mg/l
Isopropanol
LD50dermal,rabbit
12800mg/kg
Isopropanol
LD50oral,rat
5045mg/kg
Isopropanol
Humanlethaldose
3570mg/kg
Isopropanol
LC50inhalation,rat
46.5mg/l/4h
Chroniceffects:
Prolongedorrepeatedskincontactmaydefattheskinandcausedermatitis.Repeatedoverexposureto
EthyleneGlycolcancausekidneyandlivereffects.EthyleneGlycolhasproducedbirthdefectsinanimals.
Carcinogenicity:
Asper29CFR1910.1200(HazardCommunication),thisproductcontainsnocarcinogensaslistedbythe
NationalToxicologyProgram(NTP),theInternationalAgencyforResearchonCancer(IARC),the
OccupationalSafetyandHealthAdministration(OSHA)orRegulation(EC)No1272/2008.
Otherinformation:
Noneknown
SECTION12:ECOLOGICALINFORMATION
Ecotoxicologicaldatahavenotbeendeterminedspecificallyforthisproduct.Theinformationgivenbelowisbasedonaknowledge
ofthecomponentsandtheecotoxicologyofsimilarsubstances.
12.1.Toxicity
ManyaquaticspeciesareintolerantofpHlevelsbelow4.
12.2.Persistenceanddegradability
Ethyleneglycol,Isopropanol:oxidizesrapidlybyphotochemicalreactionsinairinherentlybiodegradable
12.3.Bioaccumulativepotential
Ethyleneglycol,Isopropanol:lowpotentialforbioaccumulation(BCF<100).
12.4.Mobilityinsoil
Liquid.Solubleinwater.Indeterminingenvironmentalmobility,considertheproduct'sphysicalandchemicalproperties(see
Section9).Ethyleneglycol,Isopropanol:expectedtohaveveryhighmobilityinsoils.
12.5.ResultsofPBTandvPvBassessment
Notavailable
12.6.Otheradverseeffects
Noneknown
SECTION13:DISPOSALCONSIDERATIONS
13.1.Wastetreatmentmethods
Incinerateorlandfillabsorbedmaterialwithaproperlylicensedfacility.Treatmentstandardsforignitable,corrosivewasteand
bariummustbemetfordisposalifapplicable.Checklocal,stateandnational/federalregulationsandcomplywiththemost
stringentrequirement.Thisproductisclassifiedasahazardouswasteaccordingto91/689/EEC.
EuropeanListofWastescode:
110198
SECTION14:TRANSPORTINFORMATION
14.1.UNnumber
UN2924
ADR/RID/ADN/IMDG/ICAO:
UN2924
TDG:
UN2924
USDOT:
14.2.UNpropershippingname
FLAMMABLELIQUID,CORROSIVEN.O.S.(ISOPROPANOL/TANNICACID)
ADR/RID/ADN/IMDG/ICAO:
FLAMMABLELIQUID,CORROSIVEN.O.S.(ISOPROPANOL/TANNICACID)
TDG:
FLAMMABLELIQUID,CORROSIVEN.O.S.(ISOPROPANOL/TANNICACID)
USDOT:
14.3.Transporthazardclass(es)
3,(8)
ADR/RID/ADN/IMDG/ICAO:
A.W.ChestertonCompany,2012AllRightsReserved.Reg.USPatentandTMOffice
Page5of7
Product:763RustTransformer(Bulk)
Date:29November2012
TDG:
USDOT:
14.4.Packinggroup
ADR/RID/ADN/IMDG/ICAO:
TDG:
USDOT:
14.5.Environmentalhazards
SDSNo.168B18
3,(8)
3,(8)
III
III
III
NOENVIRONMENTALHAZARDS
14.6.Specialprecautionsforuser
NOSPECIALPRECAUTIONSFORUSER
14.7.TransportinbulkaccordingtoAnnexIIofMARPOL73/78andtheIBCCode
NOTAPPLICABLE
14.8.Otherinformation
USDOT:ERGNO.132
MaybeshippedasLimitedQuantitiesinpackaginghavingaratedcapacitygrossweightof66lb.orlessandininnerpackages
notover5Liters(49CFR173.150(b,3)).
IMDG:EmSFE,SC,IMDGsegregationgroup1Acids
ADR:ClassificationcodeFC,Tunnelrestrictioncode(D/E)
SECTION15:REGULATORYINFORMATION
15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture
15.1.1.EUregulations
AuthorisationsunderTitleVII: Notapplicable
RestrictionsunderTitleVIII: None
OtherEUregulations: Directive94/33/EContheprotectionofyoungpeopleatwork.
15.1.2.Nationalregulations
USEPASARATITLEIII
312Hazards:
313Chemicals:
Immediate
Ethyleneglycol 107211
1525%
Delayed
PhosphinicAcid,BariumSalt 14871795
15%
Fire
JAPANPRTR ClassIChemicals:
None
HazardousMaterialsIdentificationSystem(HMIS)
4=SevereHazard
3
HEALTH
3=SeriousHazard
2=ModerateHazard
1=SlightHazard
0=MinimalHazard
*=SeeSection8
FLAMMABILITY
REACTIVITY
3
1
PersonalProtection
ClassIIChemicals:
None
Othernationalregulations: NationalimplementationoftheECDirectivereferredtoinsection15.1.1.
15.2.Chemicalsafetyassessment
NoChemicalSafetyAssessmenthasbeencarriedoutforthissubstance/mixturebythesupplier.
A.W.ChestertonCompany,2012AllRightsReserved.Reg.USPatentandTMOffice
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Product:763RustTransformer(Bulk)
Date:29November2012
SDSNo.168B18
SECTION16:OTHERINFORMATION
Abbreviations
ACGIH:AmericanConferenceofGovernmentalIndustrialHygienists
andacronyms: ADN:EuropeanAgreementconcerningtheInternationalCarriageofDangerousGoodsbyInlandWaterways
ADR:EuropeanAgreementconcerningtheInternationalCarriageofDangerousGoodsbyRoad
CLP:ClassificationLabellingPackagingRegulation(1272/2008/EC)
ES:ExposureStandard
GHS:GloballyHarmonizedSystem
ICAO:InternationalCivilAviationOrganization
IMDG:InternationalMaritimeDangerousGoods
LC50:LethalConcentrationto50%ofatestpopulation
LD50:LethalDoseto50%ofatestpopulation
LOEL:LowestObservedEffectLevel
N/A:NotApplicable
NA:NotAvailable
NOEL:NoObservedEffectLevel
OSHA:OccupationalHealth&SafetyAdministration
PBT:Persistent,BioaccumulativeandToxicsubstance
PEL:PermissibleExposureLimit
REACH:Registration,Evaluation,AuthorisationandRestrictionofChemicalsRegulation(1907/2006/EC)
RID:RegulationsconcerningtheInternationalCarriageofDangerousGoodsbyRail
SDS:SafetyDataSheet
STEL:ShortTermExposureLimit
STOT:SpecificTargetOrganToxicity
TDG:TransportationofDangerousGoods(Canada)
TLV:ThresholdLimitValue
USDOT:UnitedStatesDepartmentofTransportation
vPvB:veryPersistentandveryBioaccumulativesubstance
WEL:WorkplaceExposureLimit
WHMIS:WorkplaceHazardousMaterialsInformationSystem
Otherabbreviationsandacronymscanbelookedupatwww.wikipedia.org.
Keyliteraturereferences
andsourcesfordata:
RelevantHstatements:
Commissiondelasantetdelascuritdutravail(CSST)
EuropeanchemicalSubstancesInformationSystem(ESIS)
EuropeanChemicalsAgency(ECHA)InformationonChemicals
HazardousSubstancesDataBank(HSDB)
HazardousSubstancesInformationSystem(HSIS)
SwedishChemicalsAgency(KEMI)
H225: Highlyflammableliquidandvapour.
H302: Harmfulifswallowed.
H319: Causesseriouseyeirritation.
H336: Maycausedrowsinessordizziness.
RelevantRphrases: R11:Highlyflammable.
R20:Harmfulbyinhalation.
R22:Harmfulifswallowed.
R34:Causesburns.
R36:Irritatingtoeyes.
R67:Vapoursmaycausedrowsinessanddizziness.
ChangestotheSDSinthisrevision: Sections116,updatedtonewformat.
Furtherinformation:
None
Thisinformationisbasedsolelyondataprovidedbysuppliersofthematerialsused,notonthemixtureitself.Nowarrantyisexpressedorimplied
regardingthesuitabilityoftheproductfortheusersparticularpurpose.Theusermustmaketheirowndeterminationastosuitability.
A.W.ChestertonCompany,2012AllRightsReserved.Reg.USPatentandTMOffice
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