Rapture

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Material Safety Data Sheet

SECTION I. IDENTIFICATION OF THE COMPANY/ UNDERTAKING AND OF THE


SUBSTANCE/ PRODUCT
Distributor:

Leads Environmental Health Products Corporation


Unit 1208 Paragon Plaza, EDSA corner Reliance St.
1550 Mandaluyong City, Philippines
Telephone Number: 687-9010
Fax Number: 687-0461
Website: www.leads-eh.com
Email Address: [email protected]

Product Name:
Active Ingredient:
Use:

RAPTURE 10 EC
Permethrin
General purpose insecticide as surface and space spraying

SECTION II. COMPOSITION/INFORMATION ON INGREDIENTS


Common Name
CAS Number
Concentration (g/L)
Permethrin
52645-53-1
100
(active ingredient)
SECTION III. HAZARDS IDENTIFICATION
Hazardous substance - Non-dangerous good.
Harmful if swallowed, may cause lung damage. Not flammable.
Not dangerous goods for transport by road or rail.
For shipment by sea, this product is a MARINE POLLUTANT.
SECTION IV. FIRST AID MEASURES
If poisoning occurs, immediately seek medical advice.
Skin Contact:
Eye Contact:
Ingestion:
Inhalation:
Symptoms

Medical Attention

Remove and wash contaminated clothing. Thoroughly wash


contaminated areas with plenty of soap and water.
Rinse eyes thoroughly with clean water for at least 15 minutes. If
irritation persists, obtain medical attention.
Do not induce vomiting. Give a glass of water.
Remove from contaminated area to fresh air. Administer artificial
respiration if breathing has stopped.
Inhalation of spray may produce respiratory irritation and can result in
headaches, dizziness, drowsiness, and possibly nausea.
There is no specific antidote. Treat symptoms. This product contains a synthetic
pyrethroid insecticide and a hydrocarbon solvent. Small amounts of liquid
solvent aspirated into the respiratory system during ingestion or from vomiting
may cause broncho pneumonia or pulmonary oedema.

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Material Safety Data Sheet


SECTION V. FIREFIGHTING MEASURES
Suitable extinguishing media:
Use dry chemical, carbon dioxide for small fire.
Water spray, for or regular foam for large fire.
Special Fire Fighting Procedures:

Fight fires from a protected location. Dike fire control water for
later disposal.

Hazardous Thermal Decomposition: In case of extreme temperatures that may result fire, may
combust to give off toxic gases such as carbon dioxide, carbon
monoxide, nitrogen oxides, hydrogen chlorides and chlorine gas
Precautions to Fire Fighters: This product is a combustible liquid. Fire fighters should wear full
protective clothing and self contained breathing apparatus. Do not
release contaminated water into the environment.

SECTION VI. ACCIDENTAL RELEASE MEASURES


Personal Precautions:
Wear appropriate safety clothing.
Environmental Precautions: Collect all waste material and place in closed marked containers. Dike
runoff to prevent entry to water or drainage systems. If product has
contaminated surface water, inform appropriate authorities.
Contaminated soil should be dug out.
Methods for cleaning up:

In the event of minor spillage absorb in sand or other inert materials.


Use appropriate containment to avoid environmental contamination.
In the event of major spillage collect and contain as much as free
liquid as possible. Dike spills using absorbent or impervious materials
such as sand or clay for later disposal. Do not empty into drains.

SECTION VII. HANDLING AND STORAGE


Handling: Take precaution to avoid contact with skin, eyes, and clothing. Do not contaminate water,
food or feedstuffs, by storage, handling, or by disposal. Read and observe all precautions
and instructions on the label.
STORAGE: Store container closed, upright, and at room temperature. Avoid exposure to extreme
temperatures. Always store pesticides in the original container. Store away from food,
feedstuffs, seeds and fertilizers.
SECTION VIII. EXPOSURE CONTROL/PERSONAL PROTECTION
Engineering Measures:
Facilities storing or utilizing this material should be equipped with an
eyewash facility and safety shower. Ventilate treatment area thoroughly
before re-entry
Hygiene Measures:

Wash hands thoroughly after handling. Wash clothing separately before


re-use.

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Material Safety Data Sheet


Personal Protective Equipment
Respiratory Protection:

Use NIOSH/MSHA approved respirator for pesticide mist.

Hand Protection:

Use impervious gloves

Eye Protection:

Use safety glasses or face shields.

Skin and Body Protection: Wear clean long-sleeved, body covering clothing and resistant boots.
SECTION IX. PHYSICAL AND CHEMICAL PROPERTIES
Appearance

: Clear yellow to brown liquid

Odor

: Mild hydrocarbon odor

Vapor Pressure

: 0.07 mPa at 20 oC

Boiling Point

: ~200OC

Melting Point

: 34-35 oC

Solubility

: Emulsifies

Density

: 0.905 g/cc at 25OC

pH

: 6.50.05 in 2% aq.

Flash Point

: 88OC average range: 87-90OC

Flammability

: Flammable liquid

Octanol/water partition coefficient

: Not available

SECTION X. STABILITY AND REACTIVITY


Chemical Stability

Stable under normal conditions of use.

Hazardous Polymerization

Not available

Conditions to avoid

Incompatible materials

Do not apply in the presence of naked flames, hot surfaces or


unprotected electrical equipment. Use proper grounding
procedures.
Incompatible with strong oxidizing agents.

Hazardous decomposition products: No information available

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Material Safety Data Sheet


SECTION XI. TOXICOLOGICAL INFORMATION
Acute Oral Toxicity:

LD50 = >2000 mg/Kg (rat)

Acute Dermal Toxicity:

LD50 = >2000 mg/Kg (rat)

Acute Inhalation Toxicity:

LC50 = >2.03 mg/L in rats

Skin Irritation:

Slightly irritating (rabbit)

Eye Irritation:

Not Irritating (rabbit)

Sensitization:

Not a sensitisizer (Buhler method)

SECTION XII. ECOLOGICAL INFORMATION


Do not contaminate streams, rivers or waterways with the chemical or used containers.
Fish toxicity

Permethrin is toxic to fish

Daphnia toxicity
Bird toxicity

:
:

LC50 (48h) 0.6g/L


Typical oral LD50 values for cis/trans ratio of c40.60 for chickens
>3000mg/kg
Mallard ducks: >9800

Bee toxicity

Permethrin is toxic to bees.


LD50 (24h) (oral) 0.098g/bee; (topical 0.029g/bee

Environmental fate,
persistence and degradation: Permethrin degrades rapidly in soil and water.
SECTION XIII. DISPOSAL CONSIDERATIONS
Steps to be taken in case of material leakage and spillage
Wear suitable protective clothing and boots. Prevent spill from entering drains, sewers or any body of
water. Contain and absorb with sand, earth or inert absorbent. Scoop or shovel absorbent material into
sealable containers for disposal in accordance with applicable local, state and federal regulations.
Waste Disposal
Do not discharge into drains. Triple or preferably pressure rinse containers before disposal. Add
rinsing to dye bath or spray mix in disposal pit. Do not dispose of undiluted chemicals on site. Break,
crush, or puncture and bury empty containers in a local authority landfill. If no landfill is available,
bury the containers below 500 mm in a disposal pit specifically marked and set up for the purpose,
clear of waterways, desirable vegetation and tree roots. Empty containers and product should not be
burnt.

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Material Safety Data Sheet


SECTION XIV. TRANSPORT INFORMATION
Proper Shipping name: Pesticides, liquid, toxic(Permethrin)
Shipping Precautions: Keep away from food and feedstuffs
Storage and Transport:

Keep the product in original container, tightly closed and correctly


labeled. Store in a suitable, cool, dry, well-ventilated place under lock
and key away from children, animals, food and animal feeding stuffs.
Store away from incompatible substances and sources of ignition.
Do not transport along with food, feed or incompatible substances. If
spill or leaks occur during transport, inform the local protection
authority immediately.

SECTION XV. REGULATORY INFORMATION


Not available.
SECTION XVI. OTHER INFORMATION
The data given here is based on current knowledge and experience. The purpose of this Material
Safety Data Sheet is to describe the product in terms of its safety requirements. The data does not
signify any warranty with regard to the products properties.

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