DR

Page 1/6

Safety Data Sheet

according to 1907/2006/EC, Article 31
Date of printing: 08.01.2010

Date of issue: 27.02.2009

1 Identification of the substance/preparation and of the company/undertaking

Product details
Trade name: Black magnetic ink B 103 C Spraycan
Application of the substance / the preparation Magnetic ink
Manufacturer/Supplier:
Supplier:
BabbCo SA
15, rue des Frres Lumire
Z.I. des EBISOIRES
78370 PLAISIR (France)
Tel: +33 (0)1.30.80.81.82
Fax: +33 (0)1.30.80.81.99
e-mail: [email protected]
http: //www.babbco.fr

SherwinBabbCo

Tel: +33 (0)1.30.80.81.98

e-mail: [email protected]

Further information obtainable from: Product safety department

Information in case of emergency:
Tel: +33 (0)1.40.05.48.48 (Centre anti-poison de Paris)
Tel: +33 (0)1.30.80.81.98
Additional information:
Attention Medical Authorities,
In accordance with law, to the best of its knowledge, and in good faith, SherwinBabb Co herewith indicates known, or possible, risks
arising from the use of the product described below.
There may be similar products on the market for which the suppliers have not indicated certain risks.
Suppliers are responsible for completing MSDS forms in a manner that...
... does not give a product's user a false sense of security concerning the product's risks, or which,
... misrepresents the product in a manner that could be construed as unfair competition, or which,
... could lead to legal proceedings against the supplier.
Please contact us to answer any questions, or for additional information, concerning this document, or the product(s) described.

2 Hazards identification
Hazard description: Not applicable.
Information concerning particular hazards for human and environment:
At long or repeated contact with skin it may cause dermatitis due to the degreasing effect of the solvent.
Warning! Pressurized container.
R 66 Repeated exposure may cause skin dryness or cracking.
Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50C. Do not pierce or burn, even after
use.
Additional information: See Chapters 3 and 15 for details.

3 Composition/information on ingredients
Chemical characterization
Description: Mixture of substances listed below with nonhazardous additions.
Dangerous components:
CAS: 64742-47-8
Distillates (petroleum), hydrotreated light
EINECS: 265-149-8

Xn; R 65-66

50-100%

Additional information:
Distillates (petroleum), hydrotreated light: Note H applies to this product:
The classification and label shown for this substance applies to the dangerous property(ies) indicated by the risk phrase(s) in
combination with the category(ies) of danger shown. The manufacturers, distributors and importers of this substance shall be
obliged to carry out an investigation to make themselves aware of the relevant and accessible data which exists for all other
properties to classify and label the substance. The final label shall follow the requirements of section 7 of Annex VI of this Directive.
This note applies to certain coal- and oil-derived substances and to certain entries for groups of substances in Annex I.
For the wording of the listed risk phrases refer to section 16.
GB

(Contd. on page 2)

DR

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Safety Data Sheet

according to 1907/2006/EC, Article 31
Date of printing: 08.01.2010

Date of issue: 27.02.2009

Trade name: Black magnetic ink B 103 C Spraycan

(Contd. of page 1)

4 First aid measures

After inhalation: Supply fresh air; consult doctor in case of complaints.
After skin contact: Generally the product does not irritate the skin.
After eye contact: Rinse opened eye for several minutes under running water.
After swallowing: If symptoms persist consult doctor.

5 Fire-fighting measures
Suitable extinguishing agents:
Water haze
Foam
ABC powder
For safety reasons unsuitable extinguishing agents: Water spray
Special hazards caused by the substance, its products of combustion or resulting gases: Carbon monoxide and carbon dioxide
Special protective equipment for fire-fighters:
Wear self-contained respiratory protective device.
Wear fully protective suit.

6 Accidental release measures

Person-related safety precautions:
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Measures for environmental protection: No special measures required.
Measures for cleaning/collecting: Ensure adequate ventilation.

7 Handling and storage

Handling:
Information for safe handling:
No special measures required.
Store in cool, dry place in tightly closed receptacles.
Ensure good ventilation/exhaustion at the workplace.
Work only in fume cupboard.
Information about fire - and explosion protection:
Do not spray onto a naked flame or any incandescent material.
Keep ignition sources away - Do not smoke.
To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before
transferring material. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Avoid contact of spilled
material and runoff with soil and surface waterways. Wash thoroughly after handling. To avoid fire or explosion, dissipate static
electricity during transfer by grounding and bonding containers and equipment before transferring material.
Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50C, i.e. electric lights. Do not pierce or
burn, even after use.
Storage:
Requirements to be met by storerooms and receptacles:
Observe official regulations on storing packagings with pressurized containers.
Information about storage in one common storage facility: Not required.
Further information about storage conditions: Store receptacle in fume cupboard.
*

8 Exposure controls/personal protection

Additional information about design of technical facilities: No further data; see item 7.
(Contd. on page 3)
GB

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Safety Data Sheet

according to 1907/2006/EC, Article 31
Date of printing: 08.01.2010

Date of issue: 27.02.2009

Trade name: Black magnetic ink B 103 C Spraycan

(Contd. of page 2)

Ingredients with limit values that require monitoring at the workplace:

124-38-9 carbon dioxide (1.0-2.5%)
WEL Short-term value: 27400 mg/m, 15000 ppm
Long-term value: 9150 mg/m, 5000 ppm
Additional information: The lists valid during the making were used as basis.
Personal protective equipment:
General protective and hygienic measures:
Wash hands before breaks and at the end of work.
Do not inhale gases / fumes / aerosols.
Respiratory protection: Use suitable respiratory protective device in case of insufficient ventilation.
Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from
manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not
be calculated in advance and has therefore to be checked prior to the application.
Nitrile rubber, NBR
Natural rubber, NR
Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.
Eye protection: Not required.
Body protection: Use protective suit.
*

9 Physical and chemical properties

General Information

Form:
Colour:
Odour:

Aerosol
Black
Characteristic

Change in condition

Melting point/Melting range: Undetermined.

Boiling point/Boiling range: Not applicable, as aerosol.
Flash point:
> 93C (ASTM D-93)
Auto-ignition temperature:

210C

Self-igniting:

Product is not selfigniting.

Danger of explosion:

Product does not present an explosion hazard.

Explosion limits:

Lower:
Upper:

0.6 Vol %
7.0 Vol %

Vapour pressure at 20C:

0.03 hPa

Density at 20C:

0.815 g/cm (ASTM D-1298)

Solubility in / Miscibility with

water:

Not miscible or difficult to mix.

Solvent content:

Organic solvents:
VOC (EC)

96,1 %
0,0 %

10 Stability and reactivity

Thermal decomposition / conditions to be avoided: Stable at environment temperature.
(Contd. on page 4)
GB

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Safety Data Sheet

according to 1907/2006/EC, Article 31
Date of printing: 08.01.2010

Date of issue: 27.02.2009

Trade name: Black magnetic ink B 103 C Spraycan

(Contd. of page 3)

Dangerous reactions No dangerous reactions known.

Dangerous decomposition products: No dangerous decomposition products known.

11 Toxicological information
Acute toxicity: Information on hazardous ingredients
LD/LC50 values relevant for classification:
64742-47-8 Distillates (petroleum), hydrotreated light
Oral
LD50 >15000 mg/kg (rat)
Dermal LD50 >3160 mg/kg (rabbit)
Primary irritant effect:
on the skin: No irritant effect.
on the eye: No irritating effect.
Sensitization: No sensitizing effects known.
* 12 Ecological

information

Ecotoxical effects:
Acquatic toxicity: Information on hazardous ingredients
General notes: Generally not hazardous for water

13 Disposal considerations
Product:
Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Waste/ unused products
Collect all waste in suitable and labelled containers and dispose according to local legislation.
European waste catalogue 07 07 04
Uncleaned packaging:
Recommendation:
Waste / used products
Waste products and empty packages dispose of in accordance with local regulations.

14 Transport information
Land transport ADR/RID (cross-border)

ADR/RID class:
2 5A Gases.
Danger code (Kemler): UN-Number:
1950
Packaging group:
Hazard label:
2.2
Description of goods:
1950 AEROSOLS
Limited quantities (LQ) LQ2
Tunnel restriction code E
(Contd. on page 5)
GB

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Safety Data Sheet

according to 1907/2006/EC, Article 31
Date of printing: 08.01.2010

Date of issue: 27.02.2009

Trade name: Black magnetic ink B 103 C Spraycan

(Contd. of page 4)

Remarks:

Aerosols can be transported under LIMITED QUANTITIES (LQ).

See ADR 3.4 - LQ2. That means no label 2.

Maritime transport IMDG:

IMDG Class:
UN Number:
Label
Packaging group:
EMS Number:
Marine pollutant:
Proper shipping name:
Remarks:

2.2
1950
2.2
F-D,S-U
No
AEROSOLS
Aerosols can be transported under LIMITED QUANTITIES (LQ).
See IMDG 3.4 - LQ2. That means no label 2.

Air transport ICAO-TI and IATA-DGR:

ICAO/IATA Class:
UN/ID Number:
Label
Packaging group:
Proper shipping name:
Remarks:

* 15 Regulatory

2.2
1950
2.2
AEROSOLS, non-flammable
Quantity Limitation - Passenger Aircraft
75kg
Quantity Limitation - Cargo Aircraft
150kg
Packaging Instruction:
Passenger Aircraft - PI 203
Cargo aircraft - PI 203

information

Labelling according to EU guidelines:

The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous Materials.
Risk phrases (R):
66 Repeated exposure may cause skin dryness or cracking.
Safety phrases (S):
9 Keep container in a well-ventilated place.
16 Keep away from sources of ignition - No smoking.
23 Do not breathe aerosol.
Special labelling of certain preparations:
Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50C. Do not pierce or burn, even after
use.
Waterhazard class: Generally not hazardous for water.

16 Other information
(Contd. on page 6)
GB

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Safety Data Sheet

according to 1907/2006/EC, Article 31
Date of printing: 08.01.2010

Date of issue: 27.02.2009

Trade name: Black magnetic ink B 103 C Spraycan

(Contd. of page 5)

To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of
its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards
and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only
hazards that exist.
European regulation (REACH) requires that in paragraph 16 all R sentences dealing with raw materials appearing in paragraph 2
and 3 be written. This regulation states which sentences will finally be written on labels (paragraph 15) depending on the respective
concentration of every raw material in the preparation. That's why some or all of the sentences or signs shows in paragraph 16 may
not be written on the label. BabbCo complies with the law. Any MSDS with the R sentences of the raw material not shown in the
paragraph 16 doe not comply with regulation.
Relevant R-phrases
65 Harmful: may cause lung damage if swallowed.
66 Repeated exposure may cause skin dryness or cracking.
Prepared by Babb Co S.A.
* Data compared to the previous version altered.
GB