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Methoxypropyl Acetate: Technical Leaflet Petrochemicals

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Govindanayagi Pattabiraman

Methoxypropyl acetate is a clear, slightly hygroscopic liquid with a mild odor that is soluble in most organic solvents and has limited solubility in water. It has good solvent power for numerous resins and dyes. Its main applications are in coatings and printing inks where it can replace ethoxyethyl acetate. It has a boiling point between 145-147°C and density of 0.965-0.970 g/cm3. Methoxypropyl acetate is supplied inhibited with BHT to prevent formation of peroxides when exposed to air.

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Methoxypropyl Acetate: Technical Leaflet Petrochemicals

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Govindanayagi Pattabiraman
59 views3 pages
Methoxypropyl acetate is a clear, slightly hygroscopic liquid with a mild odor that is soluble in most organic solvents and has limited solubility in water. It has good solvent power for numerous resins and dyes. Its main applications are in coatings and printing inks where it can replace ethoxyethyl acetate. It has a boiling point between 145-147°C and density of 0.965-0.970 g/cm3. Methoxypropyl acetate is supplied inhibited with BHT to prevent formation of peroxides when exposed to air.

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Methoxypropyl Acetate

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Methoxypropyl acetate is a clear, slightly hygroscopic liquid with a mild odor that is soluble in most organic solvents and has limited solubility in water. It has good solvent power for numerous resins and dyes. Its main applications are in coatings and printing inks where it can replace ethoxyethyl acetate. It has a boiling point between 145-147°C and density of 0.965-0.970 g/cm3. Methoxypropyl acetate is supplied inhibited with BHT to prevent formation of peroxides when exposed to air.

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59 views3 pages

Methoxypropyl Acetate: Technical Leaflet Petrochemicals

Uploaded by

Govindanayagi Pattabiraman
Methoxypropyl acetate is a clear, slightly hygroscopic liquid with a mild odor that is soluble in most organic solvents and has limited solubility in water. It has good solvent power for numerous resins and dyes. Its main applications are in coatings and printing inks where it can replace ethoxyethyl acetate. It has a boiling point between 145-147°C and density of 0.965-0.970 g/cm3. Methoxypropyl acetate is supplied inhibited with BHT to prevent formation of peroxides when exposed to air.

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You are on page 1/ 3

Technical Leaflet

M 5888 e
October 2010

Petrochemicals
Page 1 of 3

Supersedes edition dated March 2008

Methoxypropyl Acetate
Medium-volatility solvent with a mild odour. Does not contain any
hydroxyl groups, and has good solvent power for numerous resins
and dyes. Its main applications are in the coatings and printing inks,
where it can replace ethoxyethyl acetate in many cases.
Chemical nature





1-Methoxy-2-propyl acetate;
Propylene glycol monomethyl ether-1,2-acetate
H3C O CH2 CH CH3
|
O
|
H 3C C = O

Molecular formula:

C6H12O3

Molar mass:

132.16 g/mol

CAS-Number:

108-65-6

Delivery specification

Property

Value

EINECS No.:
Unit

203-603-9
Test method


Mass fraction

of methoxypropyl acetate* min. 99.5 %


of water
max. 0.05 %

Gas chromatography,
BASF-method
DIN 51777, part 1

Platinum-cobalt colour

DIN ISO 6271

* Methoxypropyl acetate contains less than 0.3% of the 2-methoxy-1-propyl


acetate isomer.
For general instructions on gas chromatography see [1].

max. 10

Properties
Methoxypropyl acetate is a clear, slightly hygroscopic liquid with a mild
odour. It is freely miscible with most common organic solvents, but has only
limited miscibility with water.
By virtue of its ether and ester groups, methoxypropyl acetate enters into
reactions that are characteristic of ethers and esters and display their solvent power. For instance, it dissolves numerous natural and synthetic resins,
waxes, fats and oils.
Since methoxypropyl acetate may react with the oxygen in the air to form
peroxides, BASF supplies it inhibited with 2.6-di-tert-butyl-para-cresol
(butylated hydroxytoluene BHT).

M 5888 e October 2010

Page 2 of 3

Methoxypropyl Acetate

Physical data The following physical data have been compiled from the literature as well as
from BASF measurements and calculations. They provide no guarantee of
properties in the legal sense, however.







Boiling range at 1013 mbar


(DIN 53171; 95 Vol.-%; 297 ml)

145147 C

Density at 20 C (DIN 51757)

0.9650.970 g/cm3

Refractive index n20


D (DIN 53169)

1.4011.403

Solidification point

<75 C


T [C] Vapour
Density
Viscosity Specific
Thermal

pressure
heat
conductivity

P [mbar] [g/cm3] [mPas] Cp [kJ/(kgK)] [mW/(mK)]

40
0.009 1.0310
8.26

20
0.10 1.0099
3.33

10
0.28 0.9992
2.43

0
0.70 0.9885
1.86

10
1.60 0.9777
1.48

20
3.37 0.9669
1.20

40
12.43 0.9451
0.85
2.080

50
22.06 0.9341
0.73
2.100

60
37.47 0.9230
0.64
2.110

80
96.4
0.9006
0.50

100
218.7
0.8780
0.41

120
447.5
0.8552
0.34

140
841.8
0.8321
0.28

146.4 1013


Surface tension

at 20 C
at 40 C

Enthalpy of formation ( Hf)

at 25 C

Hansen solubility parameters at 25 C:

d = 15.6 (MPa)1/2
p = 5.6 (MPa)1/2
h = 9.8 (MPa)1/2

t = 19.3 (MPa)1/2

Evaporation rate (DIN 53170; ether = 1)


Solubility at room temperature
of methoxypropyl acetate in water
of water in methoxypropyl acetate

* extrapolated
28.2 mN/m
25.2 mN/m

at 25 C

Heat of combustion ( Hc)

at 25 C

Enthalpy of vaporization ( Hv)

at the boiling

point

141.2
140.7
140.2
139.2
138.7
138.1*
137.0*
135.9*

24208 kJ/kg
380.6 kJ/kg
317.3 kJ/kg
5036 kJ/kg

>33
approx. 22%-wt
approx. 6%-wt

M 5888 e October 2010

Page 3 of 3

Methoxypropyl Acetate

Applications

Selected applications of methoxypropyl acetate are presented below.

Coatings Industry

By virtue of its good solvent power for numerous resins and dyes, methoxypropyl acetate can be used as a solvent, flow improver and coalescent in
coatings.

It is particularly suitable for coatings containing polyisocyanates. In this


case, it is important that the peroxide fraction is as small as possible, as
otherwise the colour of the final product may change. It is for this reason
that we stabilize our solvent with 2,6-di-t-butyl-p-cresol (BHT).
Other applications for methoxypropyl acetate include
flexographic, gravure and screen printing inks
adhesives
ball pen pastes
dyes in furniture polishes or wood stains
dye solutions and pastes for printing and colouring leather and textiles.

Yet another application for methoxypropyl acetate is as a binder for core


sands in foundries.
Literature

[1]Technical Information Leaflet of BASF SE: Gas-chromatographic determination of the degree of purity of solvents and plasticizers (a review)
(TI-CIW/ES 001 e).

Safety
When using this product, the information and advice given in our Safety
Data Sheet should be observed. Due attention should also be given to
the precautions necessary for handling chemicals.

Note
The data contained in this publication are based on our current knowledge
and experience. In view of the many factors that may affect processing
and application of our product, these data do not relieve processors from
carrying out their own investigations and tests; neither do these data imply
any guarantee of certain properties, nor the suitability of the product for
a specific purpose. Any descriptions, drawings, photographs, data, proportions, weights etc. given herein may change without prior information
and do not constitute the agreed contractual quality of the product. It is
the responsibility of the recipient of our products to ensure that any
proprietary rights and existing laws and legislation are observed.

October 2010

BASF SE
Operating Division Petrochemicals
Regionale Business Unit Plasticizers and Solvents Europe
67056 Ludwigshafen, Germany
Visits us on-line at http:www.basf.de/solvents

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