Ba Tho 5000toce Full Calibration Sop en 58130094b
Ba Tho 5000toce Full Calibration Sop en 58130094b
Ba Tho 5000toce Full Calibration Sop en 58130094b
58130094
5000TOCe Sensor
Standard Operating Procedure
for
TOC Calibration
Conductivity Calibration
Temperature Calibration
Flow Rate Calibration
Mettler-Toledo Thornton, Inc. 2010
No part of this manual may be reproduced or transmitted in any form or by any means, electronic or mechanical, including
photocopying (other than where specifically noted), for any purpose without the express written permission of Mettler-Toledo, Inc.
U.S. Government Restricted Rights: This documentation is furnished with Restricted Rights.
This document contains proprietary information, which is protected by copyright. All rights are reserved. No part of this
document may be photocopied (other than where specifically noted), reproduced or translated, into another language without
the prior written consent of Mettler-Toledo Thornton, Inc.
IMPORTANT SAFETY INFORMATION
Please read thoroughly before operating the 5000TOCe System Suitability Test Kit and the 5000TOCe
Calibration Kit -
Follow all warnings, cautions, and instructions indicated on and supplied with this product.
Install equipment as specified in this instruction manual. Follow appropriate local and national codes.
Use only factory documented components for repair. Tampering or unauthorized substitution of parts and procedures can
affect the performance and cause unsafe operation of your process as well as void factory warranties.
Protective covers must be in place unless qualified personnel are performing maintenance.
If this equipment is used in a manner not specified by the manufacturer, the protection provided by it against hazards may
be impaired.
Prior to shipping the sensor back to the factory for repair or re-calibration, water MUST be drained from sensor to avoid
damage due to freezing.
WARNINGS:
Installation of cable connections and servicing of this product require access to shock hazard voltage levels.
Main power must employ a switch or circuit breaker as the disconnecting device for the equipment.
Electrical installation must be in accordance with the National Electrical Code and/or any other applicable national or local
codes.
Safety and performance require that this instrument be connected and properly grounded through a three-wire power
source.
This manual includes safety information with the following designations and formats:
2. Scope
This document provides procedures to calibrate the Thornton 5000TOCe or 5000TOC Total Organic Carbon Sensor (PN 58 036
001, PN 58 036 002, 58 036 003, 58 036 004). The 5000TOCe Sensor is used with the Thornton 770MAX transmitter.
Calibration of the 770MAX transmitter is covered in separate documentation. Throughout this manual, references will be made
to the 5000TOCe sensor model. In all cases, this can be interpreted to include the 5000TOCe and 5000TOC sensor models.
3. Equipment Required
3.1. Full Calibration
For a complete calibration (flow, temperature, conductivity, and TOC), the following equipment is required.
5000TOCe CAL/SST Module Kit (Thornton PN 58 091 559). This consists of a calibrated conductivity sensor, patch cable,
316L SS flow housing, holding brackets, SOP for Calibration, pump, power supply, and miscellaneous connectors and
tubing, all stored in a case.
5000TOCe Calibration Solution Set (Thornton PN 58 091 529).
Stop watch or other timing device with 1 second resolution for flow calibration process.
100 mL or larger volumetric container such as graduated cylinder with <3% tolerance for flow calibration process.
Latex/nitrile gloves are recommended during the procedure when wetted components such as tubing are handled.
Note: Instructions for use of the previous version of the 5000TOCe Calibration and SST Kits (Thornton PN 58 091 534, or PN
58 091 525 with 58 091 528) can be found in Appendix 3 Using SST and Calibration kit 58 0791 534.
5000TOCe Calibration Test Kit (Thornton PN 58 091 534) or System Suitability Test Kit (Thornton PN 58 091 525) is
required. The 5000TOCe Calibration Test Kit is described above. The System Suitability Test Kit consists of a holding
brackets, pump, power supply, and miscellaneous connectors and tubing, all stored in a case.
5000TOCe Calibration Solution Set (Thornton PN 58 091 529).
Page 1
Measurement C: Temperature displayed in degrees Celsius (C) (resolution: 2 decimal places)
Measurement D: Reference Conductivity displayed in S/cm (resolution: 3 decimal places)
Measurement E: Reference temperature displayed in degrees Celsius (C) (resolution: 2 decimal places)
To simplify the calibration process, this procedure will use conductivity in units of S/cm and temperature in degrees Celsius.
Alternative measurement units may be used.
Caution: Be sure to adjust needle valve to less than 3 turns from closed position before re-installing into process line!
CAL/SST Module Kit 58 091 559 provides the apparatus needed to perform a system suitability test on the 5000TOCe Sensor
(PNs 58 036 001, 58 036 002, 58 036 003 and 58 036 004). Components contained in this kit include the pump
module, a mounting bracket, connecting tubing equipped with quick-disconnect fittings, a universal power supply and assorted
tools, This kit is designed for use with Thornton Standard Solution bottles included in the calibration Solutions Kit (p/n 58 091
529).
Page 2
Figure 1. CAL/SST Pump Module Installation and Setup
9. Remove the threaded grey, protective cap from the bottom of the CAL/SST Pump Module.
10. Wearing clean protective gloves to avoid contamination, insert a silicone suction tube onto the suction fitting
located in the bottle receptacle as shown in Figure 2. A fresh suction tube should be used for each SST test.
Protective gloves and a replacement suction tube are provided with each SST solution kit.
11. Break the protective seal on the SST solution bottle and remove cap. Set cap aside for re-use if any SST
solutions remain after completion of the test.
12. Insert free end of the suction tube into the mouth of the bottle while raising the bottle into place. Screw SST
solution bottle directly into the solution bottle receptacle at the base of the CAL/SST pump module.
13. Install a bottle of blank water onto the CAL/SST Module now, and proceed to the next section.
Page 3
5.3. Final Installation of the 5000TOCe Sensor Calibration Kit
1. Connect the Reference Conductivity sensor smart connector to the 770MAX patch cable.
2. Connect the other end of the 770MAX patch cable to an unused calibrated channel on the 770MAX transmitter. If no
channel is available, then another calibrated 770MAX transmitter should be utilized.
3. Set up a measurement to display the Reference Sensor temperature and temperature compensated conductivity. For
example, Measurement B could be set to display conductivity and Measurement C could be set to display temperature (see
suggested 770MAX configuration in Section 4.2 770MAX Configuration).
4. Turn on the pump. The setup should now be such that water continuously circulates through the Blank Water bottle and the
5000TOCe Sensor.
5. Adjust the flow rate to its maximum rate. This may be done by adjusting the needle valve knob fully counterclockwise until
it stops.
6. The system is now ready for temperature calibration. The pump may be left on if you are proceeding to the next section.
If a calibration of only the TOC measurement is scheduled, go to Section 6.3. TOC As Found. If the temperature and
conductivity are to be calibrated, then continue to Section 6.1. T1 Temperature As Found.
Page 4
5. Record the As Found Conductivity C1 Multiplier and Adder found in the Measurement Menu on the 770MAX.
6. Record the conductivity (at least three significant figures) of the Reference Conductivity Sensor displayed on the 770MAX,
Cref.
7. Record the UUT conductivity of C1 (at least three significant figures) displayed on the 770MAX, Cbefore.
8. Compute the % difference according to eq 1.
100 (Cbefore - Cref )
Cref eq 1
9. If the absolute value of the % difference is less than the limit, then a C1 conductivity calibration is not required.
10. Press Menu (exit) to return to measurement mode.
1. Disconnect tube from the TOC sample outlet and remove it completely from the test assembly.
2. At the CAL/SST Module, disconnect the tube attached to the TOC Sample Inlet, and re-connect it to the mating connector
found on the top right-side of the CAL/SST Module.
3. Re-position the selector valve on the CAL/SST pump module to SST/TOC CAL position.
4. Record the As Found TOC Multiplier(s) and Adder(s) found in the Measurement Menu on the 770MAX.
5. Access the 770MAX TOC menus and record Lamp Lifetime (hrs).
6. Record the TOC of the Reference Solution, TOCref.
7. Remove he Blank Water bottle from the CAL/SST Moduel and replace it with a 500 ppb TOC (sucrose) solution bottle.
8. Re-connect the original drain tube to the Sample Outlet of the 5000TOCe Sensor and run it to atmospheric drain. It is
critical not to re-circulate this solution. Tubing should now appear as in Figure 3.
Figure 3
9. Turn on the pump. Water should now be visible at the drain line at the atmospheric drain. Note: the ~500 mL volume of
the calibration solution will provide more than 20 minutes of operation at the nominal flow rate of 20 mL/min.
10. Verify that UV Lamp is on. The lamp must be on to measure and display TOC.
11. Adjust the flow rate to 20 mL/min per Section 14.
12. Allow the 500 ppb TOC (sucrose) solution to flow through the 5000TOCe Sensor until the readings stabilize, approximately
5 minutes.
Page 5
13. Record the TOC of the 5000TOCe Sensor for the 500 ppb Solution, TOCbefore.
14. Compute the difference, TOCref - TOCbefore.
15. If the absolute value of the difference for both the 500 ppb is less than the limit, then a TOC calibration is not required.
As Found is complete.
NOTE: Since it is possible for the person performing this calibration to come into contact with the process water, use of
protective gloves, or other suitable safety equipment is recommended.
Caution: If the process water is hot, protection from direct contact should be used, or an alternate source of water must be
provided.
10. Record the number of LEDs on the front of the 5000TOCe as the Set Flow Rate.
11. If (Fref- - 20) is within the limit, then flow rate adjustment is not required. Change Set Flow Rate back to No. Press Menu
to exit and proceed to Section 8. Temperature Calibration. Otherwise, leave the 770MAX in its current state and proceed to
the next section.
Figure 4
9. Place a dry volumetric container under the drain line to capture the water, and begin the time measurement using the stop
watch. It is important that the water collection and time start be closely matched.
10. Collect a known volume of water with the volumetric container for a measured time, at least 3 minutes.
11. In Section B, record the volume of water in mL and the elapsed time in seconds.
12. Using eq 2, calculate the water flow rate and record as Fref1.
13. Enter the reference flow rate into the 770MAX and press Page-Down.
14. Wait while the first part of the calibration is being performed. 770MAX display will appear as shown in Figure 5.
Figure 5
15. After the first calibration point is complete adjust the flow rate to about 16 1 mL/min.
16. Empty the volumetric container. Repeat steps 9-11.
17. Using eq 2, calculate the water flow rate and record data as Fref2.
18. Enter the reference flow rate into the 770MAX and press Page-Down.
19. Wait while the last part of the calibration is being performed.
Page 7
20. After the flow sensor calibration is completed, enter the correct date. Press Page-Down.
21. Select YES to save the new calibration data within the 5000TOCe Sensor.
Note: if NO is selected, the calibration data will only be temporarily saved, and the calibration factors will revert back to
the previous values should power be lost or the 5000TOCe Sensor patch cable is unplugged.
8. Temperature Calibration
This procedure is to be performed on T1 and T2, which correspond to the temperature sensors embedded in the two
conductivity sensors.
Note: if NO is selected, the calibration data will only be temporarily saved, and the calibration factors will revert back to
the previous values should power be lost or the 5000TOCe Sensor patch cable is unplugged.
Page 8
25. Press S or T to select the letter for the measurement of the 5000TOCe Sensor displaying temperature.
26. Press Page Down.
27. Record the value of Multiplier1 from the 770MAX display.
28. Record the value of Adder1 from the 770MAX display.
29. Verify Multiplier1 and Adder1 are within limits. If they exceed limits, repeat Section 8.1 T1 Temperature Calibration.
30. Return the 770MAX to measurement mode by pressing the Menu (exit) key.
9. Conductivity Calibration
This procedure is to be performed on C1 and C2 which correspond to the two conductivity sensors within the unit.
Page 9
11. Enter Output Hold Time. Press Enter (or Page Down). Output Hold Time is the amount of time that you want the present
relay status and analog output value to be held (unchanged) while calibration is performed.
12. Press S or T to select the letter for the measurement of the 5000TOCe Sensor displaying TOC. Press Enter.
13. Press S or T to select 1-point. Press Enter or X.
14. Press S or T to select C1. Press Page Down.
15. Enter the conductivity of the Reference Sensor into the 770MAX and press Page-Down. To avoid inaccuracy due to
changes in ambient temperature, this value should be entered as soon as practical after reading the Reference Sensor.
16. Wait for calibration to complete.
17. Enter the correct date (if needed). Press Page-Down.
18. Select YES to save the new calibration data within the 5000TOCe Sensor. Press Enter.
Note: if NO is selected, the calibration data will only be temporarily saved, and the calibration factors will revert back to
the previous values should power be lost or the 5000TOCe Sensor patch cable is unplugged.
Page 10
15. Record the value of Adder2.
16. Verify Multiplier2 and Adder2 are within limits. If they exceed limits, repeat Section 9.2 C2 Conductivity Calibration.
17. Return the 770MAX to measurement mode by pressing the Menu (exit) key.
18. Turn off the pump.
Conductivity Calibration is now complete.
Page 11
14. Wait for calibration to complete..
15. Turn off pump.
16. Remove the transfer cap from the 500 ppb TOC solution, and install the cap onto the 250 ppb TOC solution and place into
the bracket.
17. Turn on the pump.
18. Verify that UV Lamp is on. The lamp must be on to measure and display TOC.
19. Press S or T to set the flow rate to YES.
20. The LED lights will now indicate flow.
21. Adjust the flow rate to 20 mL/min per Section 13, if necessary.
22. Press S or T to set the flow rate to NO. Press Page Down.
23. Allow the 250 ppb TOC solution to flow through the 5000TOCe Sensor until the readings stabilize, approximately 5-10
minutes.
24. Enter the TOC of the Reference Solution, as written on the label or its certificate, into the 770MAX for Cal pt 2.
25. Press page down.
26. Wait for calibration to complete.
27. Enter the correct date (if needed). Press Page-Down.
28. Select YES to save the new calibration data within the 5000TOCe Sensor.
Note: if NO is selected, the calibration data will only be temporarily saved, and the calibration factors will revert back to
the previous values should power be lost or the 5000TOCe Sensor patch cable is unplugged.
29. Return the 770MAX to measurement mode by pressing the Menu (exit) key twice.
30. Record the TOC as written on the label of the 250 ppb TOC solution or its certificate. This is TOCref.
31. Record the measured TOC displayed on the 770MAX, TOCafter.
32. Verify that difference is within acceptable limits in this worksheet.
33. Turn off pump.
34. Remove the transfer cap from the 250 ppb TOC solution, and install the cap onto the 500 ppb TOC solution and place in
the bracket.
35. Turn on the pump..
36. Verify that UV Lamp is on. The lamp must be on to measure and display TOC.
37. Adjust the flow rate to 20 mL/min per Section 13, if necessary.
38. Allow the 500 ppb TOC solution to flow through the 5000TOCe Sensor until the readings stabilize, approximately 5-10
minutes.
39. Return the 770MAX to measurement mode by pressing the Menu (exit) key twice.
40. Record the TOC as written on the label of the 500 ppb TOC solution or its certificate. This is TOCref.
41. Record the measured TOC displayed on the 770MAX, TOCafter.
42. Verify that difference is within acceptable limits in this worksheet.
43. Enter the lamp life.
44. Press Menu (exit) to go to MAIN MENU.
45. Press S or T to select Measurement. Press Enter (or Page Down).
46. Press S or T to select the letter for the measurement of the 5000TOCe Sensor displaying TOC.
47. Press Page Down.
48. Record the value of TOC Multiplier(s) from the 770MAX display.
49. Record the value of TOC Adder(s) from the 770MAX display.
50. If the difference is not within acceptable limits, repeat Section TOC Calibration Procedure for 770MAX Software revision 5.2.
TOC Calibration is complete. Proceed to section 11.
Page 12
SECTION B
For 770MAX software revision 5.1 or earlier proceed as follows:
Page 13
the silicon suction tube, and replace the protective cap for the solution bottle interface. Remove the CAL/SST module and
mounting bracket from the TOC Sensor.
1. Connect both provided tubes to the quick-disconnect fittings on the lower right side of the CAL/SST Module.
2. Set the selector valve to the Cond/Res and Temp Cal position.
3. Connect a bottle of the supplied blank water to the CAL/SST Module. If the remaining blank water is not sufficient, a blank
water bottle may be filled with process water of RO quality or better to flush the CAL/SST Module.
4. Turn the pump on and flush the CAL/SST Module for a minimum of 5 minuets. Ensure that the discharge tube from the
CAL/SST module (marked To TOC Sample Inlet) is directed to an appropriate drain. If an adequate drain is not available,
use an empty test solution bottle to collect the flushing water.
5. Remove the blank water bottle from the CAL/SST module. Allow the CAL/SST Module pump to run until all solution has
been discharged from the CAL/SST module.
6. Remove and discard the silicon suction tube from the solution bottle interface, and replace the protective cap.
7. With both lines attached to the CAL/SST module and the selector valve in the Con/Res and Temp Cal position, connect the
provided syringe and quick-disconnect assembly to the quick-disconnect fitting located at the bottom of the CAL/SST
module. Pull the plunger of the syringe back to draw the residual water out of the Conductivity sensor flow housing.
Remove the syringe from the silicone tubing and empty the syringe into an appropriate drain or container. If necessary,
repeat this process until all solution has been removed.
8. Remove the CAL/SST module and mounting bracket from the TOC Sensor. Remove all connected tubing from the CAL/SST
module and return all components to the supplied storage case.
Page 14
Worksheet 1: Unit Under Test Information
Use the table below to record relevant information for the unit under test (UUT).
Note: The reference 770MAX can be the same as the UUT 770MAX if the transmitter has been calibrated according to the
770MAX Multiparameter Analyzer/Transmitter Instruction Manual, part number 84372.
Name (printed)
Signature
Date
Comments
Page 15
Worksheet 2: Reference Equipment Information
Use the table below to record relevant information for reference equipment.
Note: The reference 770MAX transmitter can be the same as the UUT 770MAX transmitter, if the transmitter has been
calibrated according to the 770MAX Multiparameter Analyzer/Transmitter Instruction Manual, part number 84372.
Glassware
Other
Name (printed)
Signature
Date
Comments
Page 16
Worksheet 3: As Found Data for T1 and C1
Check if not applicable
Reference As Found
100 (Cbefore - Cref )
Conductivity Conductivity Adjustment
Measurement Type Cref Cbefore Cref Limit Required
and Sensor # (S/cm) (S/cm) (%) (%) (Y/N)
Conductivity C1 2.0
Name (printed)
Signature
Date
Comments
Page 17
Worksheet 4: As Found Data for TOC
Check if not applicable
Name (printed)
Signature
Date
Comments
*Note: If software revision 5.2 or higher is being used with multi calibration type, a second multiplier/adder will appear.
Page 18
Worksheet 5: Flow Rate Verification and Calibration
Check if not applicable
Name (printed)
Signature
Date
Comments
Page 19
Worksheet 6: Temperature Sensor Verification and Calibration
Check if not applicable
Name (printed)
Signature
Date
Comments
* The Temperature Multiplier factor typically set to 1.0000 and it is the Temperature Adder that is adjusted during calibration.
Page 20
Worksheet 7: Conductivity Sensor Verification and Calibration
Check if not applicable
Reference
100 (Cafter - Cref )
Conductivity As Found Within
Measurement Type Cref Conductivity Cref Limit Limits
and Sensor # (S/cm) Cafter(S/cm) (%) (%) (Y/N)
Conductivity C1 2.0
Conductivity C2 5.0
Name (printed)
Signature
Date
Comments
* The Conductivity Adder factor typically set to 0.000 and it is the Conductivity Multiplier that is adjusted during calibration.
Page 21
Worksheet 8: TOC Calibration and Verification
Check if not applicable
Reference
TOCref TOCafter TOCref TOCafter Limit Within Limits?
(ppb) (ppb) (ppb) (ppb) (Y or N)
TOC, 500 ppb 50
TOC, 250 ppb* 25
Name (printed)
Signature
Date
Comments
*Note: If software revision 5.2 or later is used with multi calibration type, a second multiplier/adder will appear.
Page 22
13. Appendix 1: Calibration Process
The Thornton 5000TOCe Total Organic Carbon Sensor and 770MAX transmitter measure the amount of organic carbon in high
purity waters by oxidizing organic carbon to CO2 with appropriate UV radiation. The resulting increase between two
temperature-compensated conductivity measurements of the sample flow stream at points before and after the oxidation process
is used to calculate the amount of organic carbon present. The complete calibration of the 5000TOCe Sensor consists of
calibration of the following.
13.1. Scope
This document provides procedures to calibrate the Thornton 5000TOCe Total Organic Carbon Sensor (PNs 58 036 001,
58 036 002, 58 036 003, 58 036 004 and related part numbers). The 5000TOCe Sensor is used with the Thornton 770MAX
transmitter. Calibration of the 770MAX transmitter is described in separate documentation.
This document provides strategies for the frequency and content of As Found data and the calibration process with respect to
lamp changes and performing System Suitability Tests (SST) to meet specific pharmacopeial requirements.
Determination of answers for these questions, as shown in the flowchart, will determine the sequence of operations. The
answers are determined by the users of this instrumentation, but the following is recommended by Thornton as a minimum
service cycle.
Table 1. Scheduled Calibration, Lamp change, and SST Service
Maintenance Frequency/Schedule Recommendations/Comments
Replace lamp 4500 hours of lamp operation or TOC Calibration recommended after lamp change.
1 calendar year, whichever is SST recommended after lamp change (where SST is
shorter. required). Refer to SST operation manual(Part# 58 130
093).*
TOC Calibration As determined by user. Recommended after lamp change, not to exceed 1
calendar year.
Complete Calibration As determined by user. Recommended not to exceed 1 calendar year.
(includes flow, TOC,
conductivity, temperature)
System Suitability Test As determined by user. Recommended after lamp change, not to exceed 4500
(SST) hrs operation.
*See USP <643> and EP 2.2.44
Page 23
6. If TOC only calibration is to be performed, go to step 8 if as found data is required, or step 16 if as found data is not
required.
7. Fill out Worksheet 3: As Found Data for T1 and C1. If required, get As Found T1 and C1 data. Get As Found T1 and C1
Calibrations Factors.
8. Fill out Worksheet 4: As Found Data for TOC. If required, get As Found TOC data. Get As Found TOC Calibrations Factors.
9. If required, change lamp.
10. If TOC only calibration is to be performed, go to step 16.
11. Fill out Worksheet 5: Flow Rate Verification and Calibration. Perform Flow Rate Verification. If acceptable, to go to step 12.
Otherwise, perform Flow Rate Calibration, then perform Flow Rate Verification.
12. Fill out Worksheet 6: Temperature Sensor Verification and Calibration. Perform T1 Calibration. This step may be skipped if
the T1 As Found was acceptable. Verify T1 Calibration factors are acceptable.
13. Continue with Worksheet 6: Temperature Sensor Verification and Calibration. Perform T2 Calibration. Verify T2 Calibration
factors are acceptable.
14. Fill out Worksheet 7: Conductivity Sensor Verification and Calibration. Perform C1 Calibration. This step may be skipped if
the C1 As Found was acceptable. Verify C1 Calibration factors are acceptable.
15. Continue with Worksheet 7: Conductivity Sensor Verification and Calibration. Perform C2 Calibration. Verify C2 Calibration
factors are acceptable.
16. Fill out Worksheet 8: TOC Calibration and Verification. If 770MAX software is v5.2 or later, perform TOC Calibration with
250 ppb and 500 ppb TOC solutions. Get As Found TOC Calibrations Factors. This step may be skipped if the TOC As
Found was acceptable.
17. Restore unit to operation or perform SST, as required.
yes yes
Get As Found
SST data
Change Lamp
Optional process (if needed)
Page 24
3. Select the measurement letter (A, B, C) for the TOC measurement of interest.
4. Press Page Down (twice) until the Press 5 for TOC menu appears.
5. Press enter to activate Set Flow Rate option. Change this setting to Yes. This immediately initiates the Set Flow Rate mode
at the sensor. It will stay in this mode until the user changes the Set Flow Rate: Yes back to Set Flow Rate: No. If the
user does not set the flow rate once the Set Flow Rate mode has been initiated, the 770MAX will time out, at which time the
mode automatically goes back to Set Flow Rate: No and the instrument returns to the measurement display screen.
6. See Figure 6. The flow rate is set by adjusting the needle on the 5000TOCe Sensor. NOTE: Clockwise (CW) to decrease
flow, counterclockwise (CCW) to increase flow.
Fault
Error
Sensor Status
UV Lamp On
= LED illuminated = LED not illuminated
When the flow rate is at 20 mL/min (2.5%), all four LEDs will be on. This is acceptable.
When the flow rate is at 20 mL/min (7.5%), the top three LEDs OR the bottom three LEDs will be on. This is acceptable.
If the flow rate is too high, the top two LEDs will be on. Turn the adjustment knob clockwise.
If the flow rate is too low, the bottom two LEDs will be on. Turn the adjustment knob counterclockwise.
If the flow rate is far from 20 mL/min, only the top (Fault) LED or the bottom (UV Lamp) LED will be on.
Page 25
As the flow rate approaches the an acceptable value, more LEDs will turn on. For example, if the flow rate is too high, as the
adjustment knob is turned clockwise, first the Fault LED will be on, then the Fault and Error LEDs will be on, then the Fault, Error
and Sensor Status LEDs will be on and finally all four LEDs will be on when the flow rate is 20 mL/min (2.5%).
Very LOW LOW NEAR SET SET NEAR SET HIGH Very HIGH
Fault
Error
Sensor Status
UV Lamp On
= LED illuminated = LED not illuminated
Figure 7. LED Indicator for Flow rate
Page 26
15. Appendix 3 Using SST and Calibration kit 58 0791 534
THUMB SCREWS
Figure 8
4. Refer to Figure 9. Align the slotted hole in the pump assembly over the left thumb screw, and then slide the pump
assembly to the left to hold in position.
REFERENCE SENSOR
ASSEMBLY
PUMP
BOTTLE HOLDER
BRACKET
Figure 9
5. Align the slotted hole in the Bottle Holder Bracket over the right thumb screw, and then slide the bracket to the left to hold in
position.
6. For conductivity/resistivity calibration, install the Reference Sensor Assembly onto the Reference Sensor Holder. For
conductivity/resistivity or temperature calibration, the Reference Sensor Assembly may be omitted.
7. Secure the entire assembly by tightening the thumb screws. The entire bracket assembly is now complete and should look
like Figure 10.
Page 27
Figure 10
15.2. Installing 5000TOCe Calibration Kit Tubing for Conductivity and Temperature Calibration
1. Refer to Figure 11. Clean the Transfer Cap assembly using de-ionized or process water (water to be tested).
2. Take one of the Blank Water bottles and shake it to homogenize the contents.
3. Remove the Blank Water bottle cap and replace it with the cleaned Transfer Cap.
4. Slide the Blank Water bottle and Transfer Cap onto the assembled Bottle Holder Bracket.
TRANSFER CAP
ASSEMBLY
Figure 11
5. See Figure 12. Clean Tube A using de-ionized or process water (water to be tested).
6. Insert one end of Tube A into the Transfer Cap until it comes to approximately 1 cm from the bottom of the Blank Water
bottle.
7. Place the other end of Tube A into the IN port of the Pump.
8. Connect Tube B from the OUT port of the Pump to the input of the Reference Sensor Assembly.
9. Connect one end of Tube C to the output of the Reference Sensor Assembly.
10. Connect the other end of Tube C to the inlet filter on the Sample Inlet of the 5000TOCe Sensor.
11. Clean Tube D using de-ionized or process water (water to be tested).
12. Connect one end of Tube D to the Sample Outlet of the 5000TOCe Sensor. Do not connect the other end of Tube D.
13. Place the other end of Tube D over a container that can hold at least 100 mL of water. Do not allow the end of the tube to
become contaminated.
14. Verify the pump switch is in the OFF position.
Page 28
15. Connect the Universal Power Supply to the pump and to 100240 VAC 50-60 Hz power. The kit includes a North
American AC power cord. Replace or adapt the power cord as necessary and in accordance with local regulations.
16. Turn the pump power switch to ON and operate pump for approximately 2 minutes to remove any residual water from the
pump and the 5000TOCe Sensor.
17. Turn the pump OFF.
18. Once the residual water has been successfully purged, insert about 4 inches (10 cm) of the exposed end of Tube D into
the Transfer Cap. The assembly is now complete and should now appear as Figure 12.
B
C
NEEDLE VALVE
Figure 12
NOTE: When the pump is first put into service, or after extended storage, it may need to be primed by injecting reagent water
into the inlet fitting with the provided syringe. Place the pump in its normal vertical position with the inlet tube from the bottle
removed from the inlet fitting and the outlet tube placed to discharge to a nearby drain or into a container. Draw reagent or
clean process water into the syringe, place the tip of the 30 mL syringe into the pump inlet fitting, turn on the pump and push
about 10 mL of water into the fitting or until water appears at the outlet fitting. Excess water will run from the inlet fitting. Turn
off the pump. Reattach the tube from the bottle to the pump inlet fitting, and proceed. Reagent water, known to be low TOC, is
ideal to be utilized for flushing the 5000TOCe Sensor.
Page 29
15.4. TOC Calibration Apparatus Installation
1. Carefully place the assembled bracket, with pump, over the 5000TOCe Sensor. Slide the assembly to the left
slightly, leaving the UV Lamp On key accessible. Figure 3 shows the proper location and orientation of the
System Suitability Apparatus.
Ce
SAMPLE
OUTLET
SAMPLE
INLET
FLOW CONTROL
85 PSIG MAX PRESSURE
IMPORTANT NOTE:
When the pump is first put into service, or after extended storage, it may need to be primed by injecting reagent water into the
inlet fitting with the syringe provided. Place the pump in its normal vertical position with the inlet tube from the bottle removed
from the inlet fitting and the outlet tube placed to discharge into a container. Draw reagent water into the syringe, place the tip
of the 30cc syringe into the pump inlet fitting, turn on the pump and push about 10 ml of water into the fitting or until water
appears at the outlet fitting. Excess water will run from the inlet fitting. Turn off the pump. Reattach the tube from the bottle to
the pump inlet fitting and proceed.
Page 30
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Mettler-Toledo Thornton, Inc. www.mt.com/thornton
36 Middlesex Turnpike
Bedford, MA 01730
Tel. +1-781-301-8600
Fax +1-781-301-8701
Toll Free +1-800-510-PURE ( US and Canada only)
[email protected]
Part 58130094
Rev.B 02/10