Problems Identified
Problems Identified
Problems Identified
Sulphur combines
directly with almost all the elements with the exception of gold, platinum and the noble gases. It
can be found as a pure element or as sulphate or sulphide minerals. Sulphur is a valuable
commodity and integral component of the world economy used to manufacture numerous
products including fertilizers and other chemicals. The major derivative of sulphur is sulphuric
acid (H2SO4), the highest production volume chemical, used as an industrial raw material.
Sulphur occurs naturally in the environment and is the thirteenth most abundant element
in the earth's crust. It is also one of the most used chemical with the largest production every
year. With these, the group have taught of utilizing this element into more useful end products
like sulfuric acid and electricity that is why a sulfuric acid manufacture and power output solver
is created.
The manufacturing process of sulphuric acid from sulphur that had been selected
employed contact process since it has relatively low impact on environment compared to lead
chamber process. Major disadvantages in the Lead Chamber process in terms of productivity
thus include the limitations in throughput, quality and concentration of the acid produced with
respect to the Contact Process. Currently most end uses of sulfuric acid are for the high
concentrated form. Thus in terms of product capacity and concentration, the contact process is a
more attractive option.
Operating pressure and temperature occupies a significant portion on this process. High
pressures favor the forward reaction in the catalytic converter. However, larger pressures and
temperatures automatically increase the plant operating cost. Fortunately however, this high
pressure requirement only amounts to 1-2 atm in the contact process where it is sufficient to
achieve the desire 99.5% conversion. In other words, at pressures only slightly above the
atmospheric, the marginal pressure rise is sufficient to obtain the target yield, and since the
operating pressure requirement is not abnormally high, cost of equipment are lower than what
could have been expected. For energy consumption, contact process therefore consumes less
energy amount in terms of gas and liquid circulation utilities of the plant. In the selection of
catalyst for the catalytic converter, vanadium pentoxide is more preferred than platinum since it
is susceptible to reacting with arsenic impurities in the sulphur feedstock. Vanadium pentoxide is
selected as the catalytic medium for the proposed process because it has relatively low tendency
to poisoning from contamination, lower cost of acquisition and operation and lastly a better
option to be used in large scale production plants. Likewise, double contact double absorption
system was used since it can achieve higher conversion than the single contact single absorption
process (SCCA). If the SO2 and SO3 gases are passed through the DCDA towers, higher yield of
sulfuric acid will be obtained because of further absorption and conversion of the product stream
with SO3 and SO2; thus reducing the unconverted SO2 of the product stream from the converter.
In the cooling tower, there is a large amount of heat generated. Instead of discarding the
heat, it is used in raising the temperature of the steam through a heat exchanger which will then
be the input for a turbine to produce electricity. In terms of generating electricity from the steam
turbine, the problem identified is in the quantity of power produced. Since our template is
designed for small-scale industries, the generated electricity is lesser compared to other plants
since the flow rate of the entering steam is small in value.