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Credits: 6 Semester:: CWS: PRS: Mte: Ete: Pre

This document provides information about the Metallurgical Thermodynamics and Kinetics course offered by the Department of Metallurgical and Materials Engineering at Indian Institute of Technology Roorkee. The course is worth 4 credits and is offered in the 6th semester. It introduces the laws of thermodynamics and their applications to chemical equilibrium conditions. The course covers topics like the three laws of thermodynamics, theory and models of metallic solutions, relation between chemical and electrical driving forces, and metallurgical kinetics over 42 contact hours. Suggested textbooks on thermodynamics, kinetics, and materials are also listed.

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53 views2 pages

Credits: 6 Semester:: CWS: PRS: Mte: Ete: Pre

This document provides information about the Metallurgical Thermodynamics and Kinetics course offered by the Department of Metallurgical and Materials Engineering at Indian Institute of Technology Roorkee. The course is worth 4 credits and is offered in the 6th semester. It introduces the laws of thermodynamics and their applications to chemical equilibrium conditions. The course covers topics like the three laws of thermodynamics, theory and models of metallic solutions, relation between chemical and electrical driving forces, and metallurgical kinetics over 42 contact hours. Suggested textbooks on thermodynamics, kinetics, and materials are also listed.

Uploaded by

Amey Vidvans
Copyright
© © All Rights Reserved
Available Formats
Download as PDF, TXT or read online on Scribd
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Download as pdf or txt
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INDIAN INSTITUTE OF TECHNOLOGY ROORKEE

NAME OF DEPARTMENT: Department of Metallurgical and Materials Engineering

1. Subject Code: MT102 Course Title: Metallurgical Thermodynamics and Kinetics


2. Contact Hours: L: 3; T: 1; P: 0

3. Examination Duration (Hrs): Theory: 0 3 Practical: 0 0

4. Relative Weightage: CWS: 2 5 PRS: 0 0 MTE: 2 5 ETE: 5 0 PRE: 0 0

5. Credits: 0 4 6 Semester: Autumn

7. Pre-requisite: Nil 8. Subject Area: DCC


9. Objective
To introduce the laws of thermodynamics and their applications to chemical equilibrium
conditions.

10. Details of the Course:

Sl. Contents Contact


No. Hours
1 Introduction to Thermodynamics: Basic concept and definitions- 2
concept of state, reversible and irreversible processes, path and state
functions, extensive and intensive properties, thermodynamic
equilibrium, zeroth law of thermodynamics
2 First Law of Thermodynamics: Internal energy, Enthalpy, Constant 5
volume and pressure process; Isothermal and adiabatic process.
3 Second Law of Thermodynamics: Criterion for equilibrium, Entropy 7
and disorder, Most probable microstate, Configutational entropy and
thermal entropy; Auxiliary functions, Maxwells relations, Gibbs-
Helmholtz equation.
4 Third Law of Thermodynamics: Variation of Gibbs energy with 8
temperature and pressure, Clausius-Clapeyron equation;
Thermodynamic properties of mixtures of ideal and imperfect gasses;
reaction in gas mixtures, reaction of pure condensed phases with gas
mixture, Standard Gibbs energy of reactions, Ellingham diagrams.
5 Theory and Models of Metallic Solutions: Raoults and Henrys law, 8
activity of a component, Gibbs-Duhem equation, non-ideal solutions,
regular solutions, quasi-chemical model of solutions, activity and
alternative standard state; Reaction equilibrium in condensed systems,
Gibbs phase rule; Derivation of binary phase diagrams, ternary phase
diagrams
6 Relation Between Chemical and Electrical Driving Forces: Nernst 6
equation, concentration and formation cells, Pourbaix diagram,
Thermodynamics of point defects, Thermodynamics of surfaces.
7 Metallurgical Kinetics: Heterogeneous reaction; Gas-solid, solid- 6

1
liquid, liquid-liquid and solid-solid systems. Empirical and Semi-
empirical Kinetics, Concept of Johnson-Mehl equation, Thermal
analysis.
Total 42

11. Suggested Books

Sl. No. Authors/Name of Books/ Publisher Year of


Publications/
Reprint
nd
1 Dehoff R.T., Thermodynamics in Materials Science, 2 Ed., CRC 2006
Press.

2 Gaskell D.R., Introduction to Metallurgical Thermodynamics 3rd 1995


Ed., McGraw-Hill.

3 Ghosh A., Textbook of Materials and Metallurgical 2003


Thermodynamics, Prentice Hall of India.

4 Upadyaya G.S. and Dube R.K., Problems in Metallurgical 1985


Thermodynamics and Kinetics, Pergamon Press.

5 Balluffi R.W., Allen S.M. and Carter W.C., Kinetics of Materials, 2005
John Wiley and Sons.

6 Poirier D.R. and Geiger G.H., Transport Phenomena in Materials 1994


Processing Minerals, Metals and Materials Society.

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