PTG14 Oh4
PTG14 Oh4
PTG14 Oh4
4. Heat exchangers;
Steam, steam processes
Ron Zevenhoven
bo Akademi University
Thermal and flow engineering / Vrme- och strmningsteknik
tel. 3223 ; [email protected]
bo Akademi University | Thermal and Flow Engineering | 20500 Turku | Finland 1/74
bo Akademi University | Thermal and Flow Engineering | 20500 Turku | Finland 2/74
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picture: http://www.secshellandtube.com/model-info.html
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Schematics for
(a) counterflow,
(b) parallel flow,
(c) crossflow,
(d) 1 shell and 2
tube passes, and
(e) 2 shell and 4
tube passes.
pictures: KJ05
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Q
TH TC T T( x ) T " " T
T
Q
With
Q
U T T dA
Q
Q A
U T T
H C
C H
this integrates to
U A T2 T1 U A T
Q lm
T2 with lm short for
ln logarithmic mean
T1
pictures: T06
Heat exchanger analysis /4
The LMTD method:
F correction factor
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Condensers
Condensors are used to liquify vapors; the condensation heat
(or latent heat) is absorbed by a coolant (often water)
Evaporators
Evaporators are used to concentrate a solution of
a non-volatile solute and a volatile solvent (in
most cases the solvent is water).
One application is to produce a slurry of crystals
in a saturated mother liquid.
Another very important application is as reboiler
for partial evaporation of distillation column
bottom liquid
bo Akademi University | Thermal and Flow Engineering | 20500 Turku | Finland 18/74
Heat exchanger efficiency vS91
A simple steady-state Thermodynamic analysis
heat transfer process; Energy balance
heat is transported from Q
Q
medium 1 to medium 2
Entropy balance
by conduction through a
Q
Q
material that separates
S gen
them. T T
Temperature T1 > T2 Q
.T T
S gen Q
T T TT
This shows that Sgen is
.
Q1
.
Q2
large for large temperature
differences (T1-T2) and low
T = T1 T = T2
temperatures T1 and T2
bo Akademi University | Thermal and Flow Engineering | 20500 Turku | Finland 19/74
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Heat exchanger effective performance /2
Picture: http://www.learnthermo.com/T1-tutorial/ch05/lesson-C/pg10.php
Ideally, the flows aquire each others temperature: the
exergy losses will then be zero. For this, the heat capacity
rates cp for the hot (H) and cold (C) streams should be
equal: CcpC = HcpH.
bo Akademi University | Thermal and Flow Engineering | 20500 Turku | Finland 21/74
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Cmin min{m
C c pC , m
H c pH } and Cmax max{m
C c pC , m
H c pH }
picture: T06
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Heat
exchanger
effective-
ness /4
Top: parallel flow
left) and counter
flow (right) single
tube HEs
Bottom: one (left)
and many (right)
(2,4,6,...) shell-
passes and multiple
of 2 tube passes
pictures: T06
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table: KJ05
table: KJ05
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picture: KJO5
Heat exchanger selection
The heat effects of phase transitions (boiling/condensing)
can be quite large and for a pure substance take place at a
constant temperature
bo Akademi University | Thermal and Flow Engineering | 20500 Turku | Finland 30/74
Power (+ heat) production /1
Combustion of fuel (or Nuclear reaction in nuclear
waste) in a furnace reactor steam production
production of steam in a production of electricity in a
boiler production of steam turbine + generator
electricity in a steam turbine + Combustion (oxidation) of
generator fuel in a fuel cell direct
Combustion of fuel in an conversion of chemical energy
engine production of into electricity
electricity in a steam turbine +
generator OR motion of a
vehicle
Combustion of fuel in a gas
turbine production of
electricity in generator
bo Akademi University | Thermal and Flow Engineering | 20500 Turku | Finland 31/74
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Heat exchangers in a condensing
power plant
Steam Flue gas
sv: nga sv: rkgas
Ambient air
Fuel Boiler water sv: uteluft
sv: brnsle sv: pannvatten
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Picture: SEHB06
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Water:
critical point
+374.15C, 22.12 MPa
Triple point
+0.01C, 0.6112 kPa
pictures: KJ05
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p = constant
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saturation
temperature
for this pressure
superheated
vapour
subcooled
(compressed) liquid
picture: KJ05
Connecting, for different pressures, the saturation points for the gas (C,
C, C,....) gives the saturated vapour line; similarly the saturation
points for the liquid (E, E, E, ...) gives the saturated liquid line.
These lines come together at the critical point, on what is called the
liquid-vapour dome (sv: kupol)
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pictures: KJ05
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mixture: m
picture:
gas mV KJ05
x
mgas mliquid m V mL
mg
(with " f" from german " flssig" )
mg m f
Note that x is a thermodynamic property, like p,T,v, u, h, s
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mgas mV
x
http://www2.cemr.wvu.edu/~smirnov/mae320/figs/F3-8.jpg
mgas mliquid m V mL
mg
x (with " f" from german " flssig" )
mg m f
With specific volume v = V/m (m3/kg)
(= 1/density !) this gives for x:
Vtotal V V
v ; v L L ; v V V and Vtotal VL VV
m total mL mV
mL mV
v m total v L mL v V m V v vL vV
m total m total
v vL v vL
v ( x ) v L x v V or x
v V vL v LV
v vf v vf
or with other notation v ( x ) v f x v g or x
vg vf v fg
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22 MPa
Source: http://energy.sdsu.edu/testcenter/testhome/Test/solve/basics/tables/tablesPC/pSatH2O.html
see also: http://users.abo.fi/rzevenho/ThermodynamicPropertyTableforsaturatedwater-pressure.pdf
bo Akademi University | Thermal and Flow Engineering | 20500 Turku | Finland 48/74
Steam tables: saturation temperature
374C
Source: http://energy.sdsu.edu/testcenter/testhome/Test/solve/basics/tables/tablesPC/TSatH2O.html
see also: http://users.abo.fi/rzevenho/ThermodynamicPropertyTableforsaturatedwater-temperature.pdf
bo Akademi University | Thermal and Flow Engineering | 20500 Turku | Finland 49/74
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Steam tables: data superheated
60 MPa
Source: http://energy.sdsu.edu/testcenter/testhome/Test/solve/basics/tables/tablesPC/superH2O.html
see also: http://users.abo.fi/rzevenho/ThermodynamicPropertyTableforsuperheatedvaporofwater.pdf
bo Akademi University | Thermal and Flow Engineering | 20500 Turku | Finland 51/74
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Example: Isothermal compression of steam
Thirty-one (31) kg of (superheated)
steam in a piston-cylinder assembly are
compressed slowly (i.e. reversibly) and
isothermally at 500C from 100 kPa to
300 kPa. Making use of entropy data,
calculate the heat transfer Q. picture: KJ05
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critical
point
Source: http://www.ent.ohiou.edu/~thermo/property_tables/H2O/ph_water.html
bo Akademi University | Thermal and Flow Engineering | 20500 Turku | Finland 57/74
critical
point
Source: http://www.ent.ohiou.edu/~thermo/property_tables/H2O/hs_water.html
bo Akademi University | Thermal and Flow Engineering | 20500 Turku | Finland 58/74
Example: h,p diagrams
If 1 kg/s steam at
330C, 50 bar is
led through a
throttling valve
(sv: strypventil) in
which pressure is
reduced to 5 bar,
what will be the
final temperature ?
(S96-3.5a)
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Example: h,p diagrams
How much
turbine power can
be obtained if 50
kg/s steam at
530C and 90 bar
expands against
7.2 bar. Compare
this with the heat
release from this
steam if it would
condense at 7.2
bar.
(S96-3.10)
bo Akademi University | Thermal and Flow Engineering | 20500 Turku | Finland 61/74
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Example: h,s diagrams
How much turbine
power can be
obtained if 50 kg/s
steam at 530C
and 90 bar
expands against 7.2
bar. Compare this
with the heat
release from this
steam if it would
condense at 7.2
bar.
(S96-3.10)
bo Akademi University | Thermal and Flow Engineering | 20500 Turku | Finland 63/74
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Pictures: SEHB06
T,s diagram
and h,s
(Mollier)
diagrams
for water/steam
4.7 Combustion; Fuels
bo Akademi University | Thermal and Flow Engineering | 20500 Turku | Finland 65/74
Combustion processes
Combustion or burning is a Two types of combustion
complex sequence of chemical cases can be distinguished:
reactions between a fuel and an Constant pressure
oxidant accompanied by the combustion, in furnaces and
production of heat or both heat boilers
and light in the form of either a Constant volume
glow or flames. combustion, in internal
Since not every oxidation combustion engines
process results in the
production of heat (for example,
corrosion), the term
combustion can only be applied
to exothermic processes that
occur at a rate fast enough to
produce heat. (Source:
wikipedia)
Picture: T06
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Enthalpy of combustion
Methane oxidation in air: CH4 + 2(O2 +3.76 N2) CO2 + 2H2O + 23.76 N2
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Fuels /1
Important properties of
fuels are:
calorific heating value
air demand (kg air / kg fuel)
moisture and ash-forming matter
content
combustible volatiles and char
content and the ratio of these
(fuel ratio)
availability and costs, and
stability of these
pollution-producing species
content
CO2 / kWh power or CO2 / km
for vehicles
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Petroleum coke 89 3.1 1.7 1.2 4.0 0 2 10 88 <1 33.7 35.0 11.1
Solid recovered fuel 48 7.0 0.84 24 0.12 1.0 20 60 8 12 19.1 22.2 8.6
(from waste)
Sewage sludge 25 4.1 3.4 19 1.2 0.06 68 10 7 15 10.0 11.8 6.5
Meat & bone meal 42 5.8 7.5 16 0.38 0.2 7 61 6 26 16.2 18.8 7.4
*%-wt dry; ** %-wt as received; *** MJ/kg; **** kg dry air / kg dry fuel
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T T
bo Akademi University | Thermal and Flow Engineering | 20500 Turku | Finland 71/74
Sources
A94: P.W. Atkins The 2nd Law, Scientific American Books (1994)
BR98: G.L. Borman, K.W. Ragland Combustion Engineering McGraw-Hill (1998)
CB98: Y.A. engel, M.A. Boles Thermodynamics. An Engineering Approach, McGraw-Hill (1998)
KJ05: D. Kaminski, M. Jensen Introduction to Thermal and Fluids Engineering, Wiley
(2005)
L96: Lervik, P. Vrmetekniska tabeller, 3rd ed, bo Akademi University (1996)
http://web.abo.fi/fak/ktf/vt/Common/Docs/tabeller.pdf
SEHB06: P.S. Schmidt, O. Ezekoye, J. R. Howell D. Baker Thermodynamics: An Integrated Learning
System (Text plus Web) Wiley (2006)
T06: S.R. Turns Thermal Fluid Sciences, Cambridge Univ. Press (2006)
TUD86: Apparaten voor de procesindustrie / Apparaten voor warmteoverdracht, (ST42/i20) Delft
University of Technology (1986) (in Dutch)
S96: G. hman, H. Saxn Vrmeteknikens grunder, bo Akademi University (1996) (in Swedish)
Steam tables: pressure table
for example: http://users.abo.fi/rzevenho/ThermodynamicPropertyTableforsaturatedwater-pressure.pdf
Steam tables: temperature table
for example: http://users.abo.fi/rzevenho/ThermodynamicPropertyTableforsaturatedwater-temperature.pdf
Steam tables: superheated vapour table
for example: http://users.abo.fi/rzevenho/ThermodynamicPropertyTableforsuperheatedvaporofwater.pdf
bo Akademi University | Thermal and Flow Engineering | 20500 Turku | Finland 72/74
Appendix: case slide 51 h,p diagram
s
-0.5
kJ/kgK
mTs
31773-0.5
= 12 MJ
bo Akademi University | Thermal and Flow Engineering | 20500 Turku | Finland 73/74
s
-0.5
kJ/kgK
mTs
31773-0.5
= 12 MJ
bo Akademi University | Thermal and Flow Engineering | 20500 Turku | Finland 74/74