811 Disha Challenger Chem
811 Disha Challenger Chem
811 Disha Challenger Chem
1. 2. 3. 4. 5.
MARK YOUR
6. 7. 8. 9. 10.
RESPONSE
11. 12. 13.
808 IIT-JEE CHEMISTRY Challenger
14. A scarlet compound (A) Pb3O4 gives a chocolate brown 25. In concentrated sodium thiosulfate solution, silver nitrate
ppt. (B) and a colourless solution C with HNO3. The brown gives
ppt (B) is of (a) white ppt. of Ag2S2O3
(a) PbO2 (b) 2Pb(NO3)2 (b) soluble complex of Na3[Ag(S2O3)2]
(c) PbO (d) none
(c) black ppt. of Ag2S
15. Black residue of NiS gives a green compound (A) in
(d) black ppt of Ag
aquaregia, A is
26. Which of the following anions is not easily removed from
(a) Ni(NO3)2 (b) SO2
aqueous solution by precipitation?
(c) NiCl2 (d) none of these
16. NiCl2 solution on treatment with KCN produces (a) Cl (b) SO 24
(a) K2[Ni(CN)4] (b) Ni(CN)2
(c) K2[Ni(CN)3] (d) none of these (c) NO 3 (d) CO 32
17. K2[Ni(CN)4] solution on treatment with sodium hydroxide 27. A salt on treatment with dil HCl gives a pungent smelling
and bromine water followed by heating gives a black
gas and a yellow ppt. The salt gives green flame when
residue (A). The compound A is
burnt. The salt solution gives a yellow ppt. with potassium
(a) NiO (b) NaCN
chromate. The salt is
(c) Ni2O3 (d) none of these
(a) BaS2O3 (b) PbS2O3
18. Addition of NaOH to Pb(NO3)2 gives a white precipitate
of (c) CuSO4 (d) NiSO4
(a) NaPbO2 (b) Na2PbO2 28. Which compound does not dissolve in hot dilute HNO3 ?
(c) PbO (d) Pb(OH)2 (a) CuS (b) CdS
19. (A) on heating with concentrated H2SO4 and MnO2 yields (c) HgS (d) PbS
brown fumes. Then A contains 29. A black sulphide is formed by the action of H2S on
(a) Br (b) Cl (a) CdCl2 (b) CuCl2
(c) I (d) none of these (c) NaCl (d) ZnCl2
20. AgBr dissolves in Na2S2O3 solution & produces 30. When a copper (II) sulphate solution is treated with excess
(a) Ag 2 S (b) Ag2 S2 O3 of ammonia, it forms
(c) Ag2 SO4 (d) none of these
(a) a red ppt.
21. AgBr dissolves in Na2S2O3 solution and forms (A). On (b) a white ppt. turning black
boiling an aquous solution of (A), a ppt. (B) is obtained.
The colour of B is (c) a deep blue solution
(d) a black ppt.
(a) Red (b) White
(c) Black (d) Colourless 31. A colourless solid on heating evolved carbon dioxide and
22. When Sb2O3 is added to a solution of KIO3 acidified with also gave a white residue. The residue was soluble in water
HCl, one of the products formed is and evolved carbon dioxide when treated with dilute acid.
(a) SbCl3 (b) SbCl5 The solid compound is
(c) Sb(OH)3 (d) HSb(OH)6 (a) calcium bicarbonate (b) sodium carbonate
23. One of the product formed, when Bi2O3 is added to an (c) sodium bicarbonate (d) calcium carbonate
alkaline solution of sodium hypochlorite, is 32. Starch iodide paper is used to test the presence of
(a) NaBiO3 (b)Na2BiO2 (a) iodine (b) oxidising agent
(c) BiCl3 (d) none (c) iodide ion (d)reducing agent
24. When bismuth chloride is poured into large volume of 33. A white powder soluble in NH4OH, but insoluble in water
water the white precipitate formed is of is
(a) Bi(OH)3 (b) Bi2O3
(a) BaSO4 (b) CuSO4
(c) BiOCl (d) Bi2Cl3
(c) PbSO4 (d) AgCl
34. Which one of the following does not give borax bead 44. [X] + H2SO4 [Y], a colourless gas with irritating smell
test? [Y] + K2Cr2O7 + H2SO4 green solution. [X] and [Y] are
(a) Pb++ (b) Mn++ (a) SO3 , SO (b) Cl, HCl
2
(c) Cr+++ (d) Cu++ (c) S , H2S (d) CO3 , CO2
35. Precipitate(s) soluble in aqua regia is
45. Which of the following hydroxides dissolves in NaOH?
(a) CoS (b) HgS
(a) Fe(OH)3 (b) Cu(OH)2
(c) NiS (d) all of these
(c) Al(OH)3 (d) None of these
36. Purple of cassius is
46. Which of the following substances dissolves in aqua-regia
(a) gold sol (b) silver sol and ammonium hydroxide respectively?
(c) [Ag2S3]S (d) platinum sol
(a) PbSO4 & HgS (b) PbSO4 & AgCl
37. Mercury (II) forms a complex with
(c) HgS & AgCl (d) HgS & PbSO4
(a) KI (b) H2S
47. Which of the following acidic radicals can not be detected
(c) SnCl2 (d) NaOH
by dilute or concentrated H2SO4?
38. Ion present in Nesslers reagent is
(a) Sulphide (b) Fluoride
(a) Hg++ (b) HgI 4 (c) Nitrate (d) Iodide
(c) HgI2 (d) Hg2++ 48.. A laboratory reagent imparts green colour to the flame. On
39. Silver chloride dissolves in hypo solution to form a heating with solid K2Cr2O7 and conc. H2SO4 it evolves a
complex. red gas. Identify the reagent
66. A metal salt solution gives a yellow precipitate with 74. A colourless salt, colours a Bunsen flame violet and also
AgNO3(aq). The yellow precipitate dissolves in dil HNO3. turns moistened litmus paper blue. The salt is
The yellow precipitate also dissolves in NH4OH. The anion (a) Na2CO3 (b) KNO3
present in metal salt solution is (c) K2CO3 (d) Cu(OH)2
(a) I (b) CrO42 75. To clear solution X of a compound a solution of BaCl2 is
(c) PO4 3 (d) Br added when a heavy white precipitate is formed which does
67. The use of H2S as a reagent for qualitation analysis of cations not dissolve in dil HCl. The compound in solution contains
is based on the fact that which anion ?
(a) H2S form coloured sulphides (a) SO42 (b) NO3
(b) H2S is a weak acid and we can control the degree of (c) Br (d) CO32
ionisation of H2S by adding HCl or NH4OH 3
76. BO3 can be identified using
(c) H2S is a weak acid (a) alcohol
(d) The colour of the metal sulphide precipitated depends (b) conc. H2SO4
upon the pH of the solution
(c) alcohol and conc. H2SO4
68. The most reliable confirmatory test for chloride ion is chromyl
(d) none of these
chloride test. Which of the following salts fails to respond
to this test ? 77. On addition of aqueous NaOH to a salt solution, a white
gelatinous precipitate is formed, which dissolves in excess
(a) ZnCl2 (b) MgCl2
of alkali. The salt solution contains
(c) CuCl2 (d) HgCl2
(a) Cr3+ (b) Al3+
69. Select the pair that sublimes on heating.
(c) Ba2+ (d) Fe3+
(a) NH4OH and NH4Cl (b) HgCl2 and Ag2C
78. When excess of NH4OH is added to CuSO4 solution which
(c) HgCl2 and NH4Cl (d) none of these
of the following is formed ?
70. A white solid A when heated gives off a colourless gas
(a) [Cu(NH3)4]SO4 (b) [Cu(NH4)4]SO4
that turns lime water milky. The residue left behind is yellow
when hot and white when cold. The solid A is (c) [Cu(NH4)3]SO4 (d) [Cu(NH3)3]SO4
(a) K2CO3 (b) ZnCO3 79. White deposit often observed on laboratory window panes
is
(c) CuCO3 (d) CdCO3
(a) AgNH2Cl (b) NH4Cl
71. The composition of the soluble complex formed when Cd2+
ion react with excess of KCN is (c) CaCN2 (d) KNO3
(a) K4[Cd(CN)6] (b) K3[Cd(CN)6] 80. When HgS+ (black ppt in group II of cation) is dissolved in
(c) K[Cd(CN)2] (d) K2[Cd(CN)4] aqua regia, the function of HCl in the mixture (aqua regia is
a mixture of HNO3 and HCl) is to
72. For precipitating out group II cations, H2S gas is passed
through O.S. acidified with HCl, group II cations are (a) oxidise the sulphur (b) oxidise the mercury
completely removed before proceeding to analysis of group (c) complex the sulphur (d) complex the mercury
III cations. However sometimes a yellow precipitate is 81. When SO2 is passed through K2Cr2O7 solution
persistently formed even after repeatedly passing H2S gas. (a) the solution is turned black
This is due to (b) the solution is decolourised
(a) CdS (b) As 2 S 3 (c) SO2 is reduced
(c) AsO 4 3 (d) S (d) green Cr2(SO4)3 is formed
73. Fill in the blank. 82. Yellow ammonium sulphide is
Na 2 B4 O7 .10H 2 O
acid
?
heat
B2 O 3
Mg or Na
B (a) an oxidising agent
(b) a solvent for metal sulphides
(a) H3BO4 (b) H3BO3
(c) acidic in nature
(c) H2B3O4 (d) None of these
(d) a solution of H2S in aqueous NH4Cl solution
MARK YOUR 1. 2. 3. 4. 5.
RESPONSE 6.
ANALYTICAL CHEMISTRY 813
MARK YOUR
17. 18. 19. 20.
RESPONSE
1. Statement-1 : A very dilute acidic solution of Cd2+ and 5. Statement-1 : Boiling a solution containing Cl, Br and
Ni2+ gives yellow precipitate of CdS on I with potassium persulphate, violet and
passing hydrogen sulphide. brown vapours appear.
Statement-2 : Solubility product of CdS is more than that Statement-2 : Br and I are oxidised to Br2 and I2 but
of NiS. Cl is not oxidised.
2. Statement-1 : Sulphate is estimated as BaSO4 and not as 6. Statement-1 : First group basic radicals are precipitated
MgSO4. as their chlorides.
Statement-2 : Ionic radius of Mg2+ is smaller than that Statement-2 : The solubility product of these chlorides
of Ba2+. are more than the solubility product of
3. Statement-1 : Borax bead test is applicable only to other basic radical chlorides.
coloured salts.
7. Statement-1 : Acidified K 2 Cr 2 O 7 solution is turned
Statement-2 : In borax bead test, coloured salts are green when SO2 is passed through it.
decomposed to give coloured metal
Statement-2 : SO2 acts as an oxidising agent in this
metaborates.
reaction.
4. Statement-1 : Cu2+ and Cd2+ are separated from each
other by first adding KCN solution and 8. Statement-1 : V group basic radicals are precipitated as
then passing H2S gas. their carbonates in presence of NH4OH.
Statement-2 : KCN reduces Cu2+ to Cu+ and forms a Statement-2 : NH4OH maintains the pH of the solution
complex with it. basic.
MARK YOUR 1. 2. 3. 4. 5.
RESPONSE 6. 7. 8.
ANALYTICAL CHEMISTRY 815
9. Statement-1 : NH4Cl is added in III group basic radicals Statement-2 : NO2 is acidic in nature and is a mixed
to suppress the ionisation of NH4OH. anhydride of HNO3 and HNO2.
Statement-2 : In the presence of high concentration of 13. Statement-1 : Magnesium does not impart any
OH ions, basic radicals of other groups characteristic colour to the flame.
will also get precipitated in III group. Statement-2 : Due to its small size and a high effective
10. Statement-1 : Oxalate is removed as an interfering acid nuclear charge, magnesium requires a large
radical by boiling the filtrate obtained after amount of energy for excitation of
group II with conc. HNO3 to dryness. electrons.
Statement-2 : Oxalate is decomposed to CO2 gas. 14. Statement-1 : Coloured salts form coloured metaborates
11. Statement-1 : Nesslers reagent gives a brown precipitate in borax bead test.
with NH3. Statement-2 : When heated borax gives a glassy
Statement-2 : NH4OH gives a brown precipitate with transparent bead consisting of sodium
Fe3+. metaborate only.
12. Statement-1 : NO2 is a reddish brown gas which is 15. Statement-1 : A white precipitate of silver chloride gets
produced by action of NO3 with acid dissolved in NH4OH solution.
when this gas is passed through alkalies it Statement-2 : NH3 reacts with AgCl and forms a soluble
gives nitrites only. complex having the formula [Ag(NH3)2]Cl.
1. Which of the following will give the ring test? 5. Among the ions Zn++, Ni++, and Cr+++, which are coloured
(a) PbNO3 (b) NaNO3 (a) Zn++ (b) Ni++
(c) Bi(NO3)3 (d) Ba(NO3)2 (c) Cr +++ (d) None of these
2. When borax is heated on the loop of Pt wire, it swells up due 6. A gas X is passed through water to form a saturated
to loss of water of crystallisation. When it is further heated solution. The aqueous solution on treatment with silver
and, it melts to a liquid which solidifies to a transparant nitrate gives a white ppt. The saturated aqueous solution
glassy mass. The glassy mass is of also dissolves magnesium ribbon with evolution of a
(a) Na2BO2 (b) NaBO2 colourless gas Y. Identify X and Y.
(c) BO (d) B2O3 (a) X = CO2 (b) Y = CO2
3. An aq. solution contains following ions (c) X= Cl2 (d) Y =H2
7. Which of the following are true?
Hg 2 , Hg , Pb , Cd . The addtion of dil HCl
(a) Lime water is used for the test of carbonate radical
precipitates
(b) In Vth group, K2Cr2O7 is used for the test of Barium
(a) Hg2Cl2 (b) PbCl2 ion
(c) HgCl2 (d) CdCl2
(c) Ammonium Thiocyanate is used in the detection of
4. The ion that can be precipitated by HCl as well as H2S is CO2+ and Fe3+ ions
(a) Fe+++ (b) Zn++ (d) Ammonium sulphate can be used in place of
(c) Pb ++ (d) Cu++ ammonium chloride in third group
MARK YOUR 1. 2. 3. 4. 5.
RESPONSE 6. 7.
816 IIT-JEE CHEMISTRY Challenger
8. Which of the following is true? (a) Fe3+ gives brown colour with potassium ferricyanide.
(a) Cobalt can be tested with dimethyl glyoxime (b) Fe 2+ gives blue precipitate with potassium
(b) Sb2S3 is yellow in colour ferricyanide.
(c) I2 is liberated when an iodide is heated with conc. (c) Fe3+ gives red colour with potassium thiocyanate.
H2SO4 (d) Fe2+ gives brown colour with ammonium thiocyanate.
(d) HNO3 need not be used in the 3rd group, if ferric 15. Carbon dioxide (CO2) when passed through lime water, it
compound is given in a mixture first turns milky and then becomes clear. The turbidity
reappears if
H 2SO 4 HNO3
9. A(Black) B(gas) Colloidal Sulphur ; (a) the clear solution is boiled
( White turbid)
(b) more CO2 gas is bubbled through it
B D
HCl
E H 2SO 4 ; Identify A & E (c) fresh lime water is added to it
( ppt.) (d) none of the above is correct
(a) A = FeS (b) A = CuS 16. A salt on heating with conc. HNO3 and on addition of excess
(c) E = CuS (d) E = HgS of ammonium molybdate forms a yellow precipitate. The
acid radical(s) present in salt is/are
HCl
10. X H 2S Y ; Y (NH 4 ) 2 S2 Soluble ; (a) AsO 4 3 (b) PO43
ppt. ( yellow )
(c) AsO 3 3 (d) BO33
X may contain
17. A mixture of inorganic salts when treated with dil HCl gives
(a) As 3+ (b) Sb3+ out a colourless gas which turns lime water milky. It indicates
(c) Sn2+ (d) Cd2+ the presence of the radical
11. During salt analysis, the third group filtrate is treated with (a) CO32 (b) HCO3
H 2 S when the sulphides of the fourth group are
(c) SO32 (d) SO42
precipitated. The sulphide which is black and insoluble in
conc. HCl is 18. Nitric acid used in the laboratory often acquires yellow
colour. This yellow colour can be removed by
(a) NiS (b) CoS
(c) MnS (d) ZnS (a) adding little magnesium powder
12. The reagents, NH4Cl and aqueous NH3 will precipitate (b) bubbling air through warm acid
1. 2. 3.
MARK YOUR
RESPONSE
4. 5. 6.
818 IIT-JEE CHEMISTRY Challenger
1. d 2. c 3. c 4. c 5. d 6. c 7. a 8. a 9. c 10. d
11. c 12. a 13. b 14. a 15. c 16. a 17. c 18. d 19. a 20. b
21 c 22 d 23 a 24 c 25 b 26 c 27 a 28 c 29 b 30 c
31 c 32 b 33 d 34 a 35 d 36 a 37 a 38 b 39 c 40 b
41 b 42 d 43 a 44 a 45 c 46 c 47 b 48 b 49 a 50 c
51 d 52 a 53 c 54 a 55 c 56 d 57 c 58. d 59. a 60. b
61. d 62. d 63. b 64. b 65. a 66. a 67. b 68. d 69. c 70. b
71. d 72. c 73. b 74. c 75. a 76. c 77. b 78. a 79. b 80. d
81. d 82. a
1 a 5 d 9 a 13 b 17 b
2 c 6 a 10 b 14 b 18 a
3 d 7 a 11 b 15 d 19 a
4 b 8 d 12 c 16 d 20 c
1 b 4 b 7 c 10 a 13 d
2 b 5 a 8 b 11 b 14 c
3 a 6 c 9 a 12 d 15 a
1. c 2. b, d 3. a, b 4. c 5. b, c 6. c, d 7. a, b, c 8. c 9. a, c 10. a, b, c, d
11. a, b 12. a, b 13. a, b, d 14. b, c 15. a, c 16. a, b 17. a, b, c 18. b 19. b, d 20. c
heat 25. (b) With a conc. solution of Na2 S2O3, silver forms a
12. (a) PbO2 Mn HNO3 HMnO 4 Pb
soluble complex
pink
2Ag S2 O 32 Ag 2S 2 O 3 ;
14. (a) Pb3O 4 4HNO3
Scarlet compound Ag 2S 2 O 3 3Na 2S2 O 3 2 Na 3 [ Ag (S 2 O 3 ) 2 ]
(A)
Na 2 CO 3 HCl NaCl H 2 O CO 2
820 IIT-JEE CHEMISTRY Challenger
32. (b) An oxidising agent (OA) will accept e from I ion and 46. (c) AgCl is soluble in ammonium hydroxide.
converts it into I2 which gives blue colour with starch
AgCl 2 NH 4 OH Ag ( NH 3 ) 2 Cl 2H 2 O
Starch KI OA Starch I 2 HgS is dissolved in aqua-regia.
blue colour
33. (d) AgCl is soluble in NH4OH due to the formation of 3HgS 2HNO 3 6HCl 3HgCl 2
soluble complex [Ag(NH3)2]Cl and AgCl is insoluble 2NO 3S 4H 2 O
in water.
47. (b) Dilute H2 SO4 is used to detect group I radicals
34. (a) Pb is p-block element. It does not form coloured
whereas conc. H2SO4 is used to detect the group II
metaborate.
radicals. Among the options given fluoride radicals
36. (a) On reducing auric chloride by stannous chloride, the
are group III radicals hence cannot be detected by
colloidal solution of gold is obtained, which is called
dilute or concentrated H2SO4.
purple of cassius.
48. (b) The reagent is BaCl2 which imparts green colour to
flame. BaCl2 forms chromyl chloride (which is red in
37. (a) HgI 2 2KI K 2 [HgI 4 ]
Complex salt colour), when treated with K2Cr2O7 and conc. H2SO4.
(Potassium mercuric iodide)
2BaCl2 K 2 Cr2 O 7 3H 2SO 4
38. (b) Ammonia gas turns Nesslers reagent (K 2HgI4 +
NaOH) into yellow brown colour K 2SO4 2BaSO 4 2CrO2 Cl2 3H 2 O
Brown ppt.
Chromyl chloride
2K 2 [HgI4 ] NaOH NH 3 (red gas)
NH 2 Hg 2 I3 4KI NaI H 2 O 49. (a) The reagent is FeSO4 which give SO2 and SO3 on
heating
39. (c) AgCl 2Na 2S2 O 3 Na 3 [Ag(S 2 O 3 ) 2 ] NaCl
H ypo Sod. argentothi osulphate
2FeSO4 Fe 2 O3 SO 2 SO3
(colourles s solution) Ferrous sulphate
43. (a) Stable oxidation state of Mn in alkaline medium is +6. CH3 C N N C CH3
So, MnO2 is oxidised to K2MnO4 by atmospheric Ni + 2 NH4Cl + 2H2O
oxygen in KOH medium. CH3 C N N C CH3
52. (a) This is a typical Group I test of basic radicals 61. (d) It is the correct answer.
62. (d) Due to higher concentration of CO32 the Ksp of
Pb ( NO 3 ) 2 2HCl PbCl 2 2HNO 3 ;
MgCO3 will be exceeded and it will get precipitated in
group V.
PbCl 2 2KI PbI 2 2KCl
63. (b) (NH4)2SO4 can be used in place of NH4Cl.
( Yellow ppt.)
64. (b) BaCO3 forms a yellow ppt of Barium chromate. BaCO3
53. (c) Test for II A group forms a white precipitate of BaSO4. BaCl2 is soluble in
water.
3CuS 8HNO 3 3Cu ( NO 3 ) 2 2 NO 3S 4H 2 O
65. (a) The brown ring formed involves Fe2+ and NO (nitric
Cu ( NO 3 ) 2 4 NH 4 OH [Cu ( NH 3 ) 4 ]( NO 3 ) 2 4H 2 O oxide).
Tetram min e cupric nitrate
( deep blue solution ) The brown ring formed is [Fe(H2O)5NO]SO4.
66. (a) The precipitate of silver phosphate is yellow. It is
54. (a) This is test for IIB groups for radicals arsenic,
soluble in dil HNO3 as also in NH4OH. The yellow
antmony and tin.
precipitate of AgI is insoluble in NH4OH.
As2S5 10HNO3 2H3AsO4 67. (b) It is the correct answer.
Arsenic acid Addition of HCl suppresses the degree of ionisation
of H2S due to common ion effect (H+ is common ion)
10NO 2 2H 2 O 5S
and only group II sulphides get precipitated.
68. (d) HgCl2 fails to respond to chromyl chloride test.
H 3 AsO 4 12(NH 4 ) 2 MoO 4 21HNO 3
69. (c) Both HgCl2 and NH4Cl are sublime substances.
(NH 4 )3 AsO 4 .12MoO3 21NH 4 NO3 12H 2 O 70. (b) ZnCO3 on heating leaves a residue that is yellow when
Yellow ppt.
hot and white when cold.
55. (c) This is a test for Al3+ (Group III), hence X is AlCl3
ZnCO3 ZnO CO 2
AlCl3 3NH 4 OH Al(OH)3 3NH 4 Cl ; 71. (d) The composition of soluble complex formed is
Gelatinous
K2[Cd(CN)4].
Al(OH)3 NaOH NaAlO2 2H 2 O 72. (c) This is due to presence of AsO43.
(ppt) Soluble 73. (b) It is the correct answer.
56. (d) This is a Group V test 74. (c) K2CO3 gives violet flame due to K+ ions. It turns
moistened litmus paper blue as its solution is basic
CaCO3 2CH 3COOH (solution of KNO3 is neutral).
1. (a) The stoichiometry of the salt often affects the or [OH] = approximately = 5 104
solubility of the salt, so the least soluble salt is not
Using pOH = log[OH]
necessarily the one with the smallest solubility
constant. Simply for interest (!), lets derive the general pOH = log(5 104 ) = log(5) + [log(104)]
formula : = log(5) + 4
For the equation : AxBy = xAy+ + yBx; p = solubility pOH = 3.5 approximately
10 97 4. (b) ZnS Zn 2 S2
Therefore, solubility of Bi2S3= 5 = 1020 approx.
108
Using Ksp = [Zn2+][S2]
49
1.0 1021 = (5.00 103)[S2]
2 10
Solubility of Ag2S = 3 = 1016 approx.
4 [S2] = (1.0 1021)/(5.00 103) = 1/5 1018
Pb(NO3)2(aq) + Na2SO4(aq)
Hence, [OH]2 = Kb [CN] = 1.39 105 0.02
PbSO4(s) + 2 NaNO3(aq)
= 1.39 105 2 102 = 2.78 107
ANALYTICAL CHEMISTRY 823
Compound A, the white solid, is PbSO4(s). Neither (ii) Na2ZnO2 + 2HCl 2NaCl + Zn(OH)2
the reactant Pb(NO3)2 nor the product NaNO3 can
Zn(OH)2 + 2HCl ZnCl2 + 2H2O
precipitate because all nitrates and sodium salts are
water soluble. PbI2 cannot precipitate because io- Soluble
dide is not present. 13. (b) The mixture will contain BaCl2 as it will only give a
9. (a) The dissolution of Pb(OH)2(s) is represented by the white precipitate with K2SO4.
following equation.
BaCl 2 K 2SO 4 BaSO 4 2KCl
Pb(OH)2(s) Pb2(aq) + 2 OH-(aq) ( white ppt .)
At pH 9, the concentration of OH-(aq) is greater than 14. (b) The mixture contains AgNO3
the concentration of OH(aq) at pH 7. According to AgNO3 reacts with brine (NaCl) to give the precipitate
Le Chteliers principle, the additional common ion, of AgCl (A), which is soluble in NH4OH.
OH(aq), will shift the position of equilibrium to the
left, and less Pb(OH)2 will dissolve.
AgCl 2 NH 4 OH [Ag( NH 3 ) 2 ] Cl 2H 2 O
(soluble )
10. (b) The reactions described in the passage show that
lead(II) is successively precipitated as PbSO4, PbI2,
15. (d) It is chromyl chloride test.
and PbCO3. This sequence shows (assuming equal
anion concentrations, as must be done here) that 16. (d) The yellow precipitate F is due to PbCrO4.
PbCO3 is less soluble than PbI2, and PbI2 is less 17. (b) B is lead chromate
soluble than PbSO4. The order in which the anions
D is lead chromate
precipitate Pb2+ is: CO32 then I then SO42. When
this sequence is applied to the question, answer F is lead chromate
choice (b) is in the correct order, and answers (a), (c),
and (d) are all in the opposite order. 18. (a) 2MnO2 (s) 4KOH O 2 2K 2 MnO4 2H 2 O
(Black) (Green)
11. (b) The initial Na2SO4(aq) solution in Reaction 1 is 15 'X' 'Y'
mL of 0.300 MNa2SO4(aq).
= 0.00900 mol
(i) 2KMnO 4 H 2 O KI 2KOH 2MnO 2 KIO3
12. (c) (i) Since the mixture is soluble in water to give strong 'D'
alkaline solution, it must contain NaOH as one of the
(ii) 2KMnO 4 8H 2 SO 4 10FeSO 4
constituents.
(ii) Since the aqueous solution gives precipitate with 2MnSO 4 5Fe 2 (SO 4 )3 K 2 SO 4 8H 2 O
dil. HCl, which dissolves in excess of dil. HCl, it must
(iii)
contain zinc salt.
cold
Thus the mixture consists of ZnSO4 and NaOH which 2KMnO4 H 2SO4 Mn 2 O7 K 2SO4 H 2O
'E '
explains all the given reactions.
Reactions : 3
Mn 2 O7 2MnO 2 O2
'E' 'F ' 2
(i) ZnSO4 + 4NaOH Na 2 ZnO 2 + Na 2 SO 4 +
2H2O
19. (a) The compound E is Mn2O7. It is acidic.
1. (b) Cd2+ is a 2nd group radical and Ni2+ is a 4th group 8. (b) Correct explanation : NH4OH converts NH4HCO3
radical. So solubility product of NiS has to be more present, if any into (NH4)2CO3.
than CdS. Further Cd2+ gives yellow colour of CdS
9. (a) R is the correct explanation of A.
with H2S, but Ni2+ gives black colour of NiS with
H2S. So both assertion and statement are wrong. (d) 10. (a) R is the correct explanation of A.
is correct choice. 11. (b) Correct explanation : Alkaline solution of K2[HgI4]
2. (b) Sulphate is estimated as BaSO 4 because of its (Nesslers reagent) gives a brown precipitate of
insolubility in water. BaSO4 forms a white ppt. Reason Millons base H2N.HgO.HgI with NH3.
is correct but do not explain the assertion. 12. (d) Assertion is false because NO2 when passed through
3. (a) R is the correct explanation of A. alkalies produces nitrates and nitrites.
4. (c) Because PbCl2 & PbS are insoluble 9. (a, c) FeS H 2SO4 FeSO4 H 2S ;
A (Black) B
5. (b, c) Because Zn++ is not having unpaired d-electron,
while Ni++ & Cr+++ are having unpaired d e . H 2S 2HNO3 2NO2 2H 2 O S
(B) (Colloidal
sulphur)
ANALYTICAL CHEMISTRY 825
12. (a, b) Al3+ (third group radical) and Ca2+ (fifth group
(NH 4 )3 [PMo12 O 40 ] 2NaNO3 12NH 4 NO3 12H 2 O
radical) precipitate out as their hydroxide with (yellow ppt)
NH4Cl and aq. NH3 (NH4OH) which are the group
reagents. 17. (a,b ,c) All these (i.e., CO32, HCO3 and SO32) are
indicated.
13. (a, b & d) The reactions are
18. (b) It is the most commonly used method.
4NaCl + K2Cr2O7 + 6H2SO4
2CrO2Cl2 + 4NaHSO4 + 2KHSO4 + 3H2O 19. (b,d) NaH 2 PO 4 NaOH Na 3 PO 4 H 2O
(Red vapours)
NaHCO3 NaOH Na 2 CO3 H2O
CrO2Cl2 + 4NaOH Na2CrO4 + 2NaCl + 2H2O
Chromyl chloride yellow solution 20. (c) At this concentration of HCl, the chlorides of basic
radicals of group I will get precipitated.
826 IIT-JEE CHEMISTRY Challenger
1. A -s; B-r; C-q ; D-p Thus excess of sulphide ions will be available and hence
the ionic product of IV group sulphides exceeds their
The reagents provided in the left side are the group
solubility product and precipitate will be obtained.
reagents for group II, III, IV and VI respectively and hence
have been matched with their basic radicals. 5.. A-p, r; B-r, s; C-q, s
Alkali and alkaline earth metals give characteristic colour FeCl3 3KCNS Fe(CNS)3 3KCl
when introduced in Bunsen flame- Ferric thiocyanate
(blood red colour)
Na - Golden yellow; Ca - Brick Red; Ba - Apple Green; K -
Violet. (ii) 4FeCl3 3K 4 [Fe(CN)6 ] Fe4 [Fe(CN) 6 ]3 12KCl
Ferric ferrocyanide
3. A-p, q, s; B-p; C-q, s; D-q, r, s (prussian blue)
dil. HCl is the reagent for first group which contains Ag+,
(C) Complex of copper decomposes by acetic acid to form
Pb2+ and Hg22+ (ous).
copper sulphate which gives red brown ppt. of cupric
The second group reagent is H2S in presence of HCl and ferrocyanide with potassium ferrocyanide.
Pb2+, Hg2+ and As3+ are the second group radicals. Again
Sn4+ is a second group radical, so the solubility product of [Cu(NH 3 ) 4 ]SO 4 4CH 3COOH CuSO 4 4CH 3COONH 4
(a) CoCl2 2KCN Co(CN) 2 2KCl (a) 2NaOH Br2 NaBr NaOBr H 2O
(buff coloured)
NaOBr NaBr O
Co(CN) 2 4KCN K 4 [Co(CN)6 ]
2K 4 [Co(CN) 6 ] O H 2O 2K 3 [Co(CN) 6 ] 2KOH
Pot. cobaltocyanide