Sol 10

1
AITS-FT-II-(Paper-1) PCM(Sol)-JEE(Advanced)/15
FIITJEE JEE(Advanced)-2015
FIITJEE Students From All Programs have bagged 34 in Top 100, 66 in Top 200 and 174 in Top 500 All India Ranks. FIITJEE Performance in JEE (Advanced), 2014:
2521 FIITJEE Students from Classroom / Integrated School Programs & 3579 FIITJEE Students from All Programs have qualified in JEE (Advanced), 2014.
ANSWERS, HINTS & SOLUTIONS

FULL TESTII
(PAPER-1)
Q. No. PHYSICS CHEMISTRY MATHEMATICS

1. C B D
ALL INDIA TEST SERIES
2. B C B
3. D D D
4. A A A
5. A A A
6. A A D
7. C C B
B, C, D B, C, D A, B, C, D
8.
A, B, C, D A, C A, C
9.
A, C, D A, B, C, D A, B
10.
A, B, C
11. A, D A, B, C, D
12. A B C
13. B B C
14. A B D
15. C C C
16. D C B
(A) (r), (B) (q), (A q) (B s) (A) (s) (B) (p)
1. (C r) (D p)
(C) (p), (D) (p) (C) (r) (D) (t)
(A) (p, s, t), (A) (q), (B) (s), (A) (p) (B) (r)
1. (B) (q, r), (C) (C) (r), (D) (p) (C) (p) (D) (r)
(q, r), (D) (p, s, t)
1. 5 4 9
2 7 1
2.
2 n=3 5
3.
5 9 8
4.
2 8 1
5.
4 3 2
6.
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
2
Physics PART I
SECTION A

1. Electric field is tangential direction at all points (E.r 0) and decreasing with increase in r. (r =
magnitude of radius vector of a point)
2. Since, Electrostatic potential is zero at all points on axis,

v
So, along axis 0 Er = 0
r
3. Va Vb Vc because electric field inside conductor is zero.

rb rb

Vb (E E ' E ind E ind ).dr ' ).dr , because E ' E ind
(E ' E ind ' 0 for all points inside

conductor or outside the conductor.
4. An infinite wire can be taken as half of closed loop.

0i
Hence B d
2

5. Let us consider a strip of thickness dx at a distance x
. x
dR
adx
ra
1 1 a dx
Reff

dR
r
x
Reff
a
aln 1
r
q K qind
6. VA Vind 0 K . 0
(d a sin t) R
R.q dqind Rqa cos t
qind
(d a sin t) dt (d a sin t)2
8. Force applied by hinge on rod may be towards P, away from P or zero depending upon distance
from point O. Accordingly linear momentum of rod + bullet system may decrease increase or
remains constant respectively. Similarly angular momentum of system about Q may decrease,
increase or remain constant respectively.
9. =1m
vmax = A = 4
y / t 4 10 2
v 10m / s
y / x 4 103
3 v
A = 2 10 m also 10Hz and amax A2 80 cm / s2

3
10. From centre of mass of system ball and centre of tube moves in circular path.
MR
Radius of curvature of ball at the time of projection of ball is
mM
Normal force between tube and ball if M = 2m, at the time of projection of ball is
mV0
Vcm =
mM
V V 2
N m 0 cm
r1

11. Equivalent circuit is D

R 2R
A 2R C
2R R
B
1 1 1 M
14. L
k k L L
K K
k . k
L 5.60 K
k k
hc hc 6.626 10 34 3 10 8
15. eV V 31103 V
cut off e cut off 1.6 10 19 0.4 10 10
SECTION - B
1. Using Kirchofs first law at point P
SECTION C
1. VO = VP
KQ KQ 2Kq
Vshell
R 3R 5R
KQ 1 2
Vshell 1
R 3 5
KQ 4 2

R 3 5
KQ 20 9 11 KQ
=
R 15 15 R
2. Using Bernoullis theorem
1 2 v2
v p gh or h .. (1)
2 2gh
Put : V = r = r (2) in (1)
1 1 1
5.
v u f
4
1 1 2

v (3R / 2) R
1 2 2 4

v R 3R 3R
3R
v=
4
3R
v 2 1
4
m
u 3R 4 2

2
1
amplitude of image = 4 2
2
5
Chemistry PART II
SECTION A
1. Ag | Ag2CO3 s | Na2CO3 aq. || KBr aq. | AgBr s | Ag s

Anode : 2Ag s CO32
Ag2CO3 s 2e
Cathode : AgBr s e
Ag s Br aq.
CO32 aq. 2AgBr s
2Br aq. Ag2CO3 s
2
o 0.059 Br
Ecell E cell log
2 CO32
At eqm.
2
0.059 Br
0 E o
cell log 2
2 CO3
o
Br
0 E cell 0.059 log
2
CO3
Br
0.059log EoC EoA
2
CO3
EoAg/ AgCl/ Cl E oAg / Ag 0.059 log K spAgBr
K sp Ag2CO3
EoAg/Ag CO 2 EoAg 0.059 log
3 /CO3
2
K sp AgBr
Br K AgBr
log log sp
CO23 K sp Ag2CO3
Br 4 10 13
2 10 7
CO32 8 10 12
2. 1N 2N N
ln 2 ln 2
1 2
24 6
No 6
No e t 3
et 2
t ln 2
ln2 ln2
24 6 t ln 2

t = 4.8 hours
6
3. R R
R CH2
O
R R
R + CH2
O
R R
R R
CH2 R O

H2C CH CH2
R O
r
4. 0.414 for octahedral void fitted with our red spherical balloon.
r
r
0.414

r 0.414
Initial r radius = 0.6
Final r radius = 0.414
Initial r 6
14.5
Finalr 0.414
5. The number of maxima in the radial charge density curve is (n l)

For 3d electron, n = 3 and d = 2
Hence, n l = 3 2 = 1
There will be only one maximum in the curve for 3 d electron.
6. In Perkin reaction, the carbanion attacks the carbonyl carbon of aromatic aldehyde to produce
finally the unsaturated acid
The electron withdrawing groups increase reactivity of aldehydes in this reaction by increasing
the electron deficiency of carbonyl atom. Thus NO2 increases the reactivity and the groups like
N(CH3)2 and CH3 decreases the reactivity.

7. The order of ligand strength in the spectrochemical series F H2O NH3 NO2 . A strong ligand
causes a larger degree of splitting resulting in high value of E (energy). Therefore corresponding
hc
low value of E

Protonation occurs on the OH which can produce more stable carbocation and while
rearrangement phenyl has higher migratory aptitude over o-substituted phenyl.
7
Solutions for Q. No. 12 to 13

Let the no. of moles of H2, O2 and He are x, y and z respectively
x + y + z = 2.0
Pressure exerted by 2 moles of gaseous mixture is 50 atm.
After the first electric spark decrease in pressure = 50 12.5 = 37.5 atm
decrease in no. of moles of gaseous mixture is 1.5
But from the given information limiting reagent in first step is O2
1
from H2 g O 2 g H2O
2
H2 and O2 reacted are in the ratio of 2 : 1
0.5 mole of O2 should be reacted with 1.0 mole of H2
No. of mole of O2 in the mixture (y) = 0.5
When again O2 is passed, pressure increased from 12.5 to 25.0 atm
Change in pressure = 12.5 atm
12.5 2
No. of moles of O2 added = 0.5 mole
50
Now H2 will be completely reacted
No. of moles H2 actually left after first electric spark = x 1
1
H2 O2 H2O
2
x 1
x 1
2
Now change in pressure in 25 10 = 15 atm
15 2
change in no. of moles is 0.6
50
x 1
x 1 0.6
2
x 1.4
no. of moles of H2 = 1.4
no. of moles of He = 2.0 (1.4 + 0.5) = 0.1
1.4
mole fraction of H2 = = 0.7
2.0
14. Possible structure after test (a) would be that of a 1 or a 2 alcohol and not that of 3 alcohol.
15. Only non-resolvable compound is a 1 alcohol out of the given choices.
16. Oxidation of compound with CrO3 in pyridine gives a compound, that gives Tollens test. This
implies that it is a primary alcohol.
SECTION-B

1. Silver Ore is dissolved by complex formation using CN in presence of air followed by
precipitation with zinc.
Lead Involves roasting of PbS followed by self reduction.
Iron Involves calcination followed by carbonmonoxide reduction.
Magnesium Involves calcination (of MgCl2.6H2O in presence of dry HCl gas) followed by fused
salt electrolysis.
SECTION C
8
2. COCH3
H3C
P=
Br
Br
1.92
3. nMn mol = 0.016 mol.
2 60
nhydrazinehydrate = 0.9 5.332 mol = 0.096 mol.
50
1
neqKIO3 = 4 N 0.48L = 0.192 neqhydrazine reacted with KIO3
10
0.192
nhydrazine left after reaction with Mn+ = mol = 0.048 mol
4
n+
nhydrazine reacted with M = (0.096 0.048) mol = 0.048 mol
nM 1 0.016 1

nhydrazine n 0.048 3
4. FTTTTFFFTTFTTT
(IX) A is a buffer solution; pH of A = pKa = 2
1
B is an aqueous solution of SacNa; pH of B = pK w pK a logc = 8
2
5. Total work done = Area of circle A (anticlockwise) Area of circle B (clockwise)

= 40 36 = 4 unit
heat flows into the system along the path ADB, = 5 3+2 = 4 unit
6. CCl3CH(OH)2 + NaOH CHCl3 + HCOONa+ + H2O

Chloral hydrate (A)
1 h
CHCl3 + O2 COCl2 + HCl
2
(A) (phosgene)
(B)
Cl OC2H5
O=C + 2HOC2H5 O=C + 2HCl
Cl OC2H5
(diethyl carbonate)
(C)
O O O
OC2H5
H5C2OCOC2H5 + CH3MgBr H5C2OCOC2H5 H5C2OCCH3
CH3 CH3MgCl
OH O
CH3MgCl
CH3CCH3 CH3CCH3
H3O+
CH3
9
Mathematics PART III

SECTION A
1. Possibilities:
6!
(i) three digit occur twice = 5 C3 900 ways
2!2!2!
(ii) two digit occur three times = 200 ways
(iii) one digit occur four times and other twice = 300 ways
(iv) all digits are same = 5
Total possibilities = 1405
2. |z 2i| = 2 represent a circle with centre (0, 2), radius 2 unit and |z 1 3i| + |z + 1 3i| = 2 2
represent an ellipse they touch each other at (0, 4)
n
3. Let f n n1Cr 1 2n1 1
r 0
f(9) = 1023 = 3.11.31
Total divisors are = 8
100
4.
2 1 x3
a0 a1x a 2 x 2 ..... a100 x100 cos x cos x ..... cos x 100
2 2 2 2 2
Replacing x by x and adding
100 100 50 x
1 x3
1 x3
a0 a2 x2 ..... a100 x100 cos
2
cos
2
50
Put x = 1 2100 a2i k = 100
i 0
5. The desired condition is to have the circle N inside the convex region of the parabola y = x 2
clearly a 1, otherwise circle will cross x-axis also for circle to be inside the parabola the number
of points of intersection must be less than or equal to 2
Equation y + (y a)2 = 1, has one or less than one solution
D0
5
a
4

3 3
6. IN = x loge sin x dx x loge sin x dx
0 0

3 2 3 2 3
= x loge 2 dx x loge sin x dx = ID
2 0 2 0 2
IN 3

ID 2
7. OT2 = OA OB
T
O A B
10
8. Let ABCDPQRS be a cube, the numbers a, b, c, d, e, f be written on the faces

ade + abe + abf + adf + cde + bce + bcf + cdf = 2004
2
(e + f)(a + c)(b + d) = 2 3 167
Possible combination are 4 3 167, 2 6 167, 2 3 334, 2 2 501
T = a + b + c + d + e + f = 174, 175, 339, or 505
2
9. If x 0, x + (a 5)x + 1 = 0
2
x < 0, x + (a + 1)x + 1 = 0
Equation has exactly three distinct solution if (1)
Either (a 5)2 > 4 and (a + 1)2 = 4
Or (a 5)2 = 4 and (a + 1)2 > 4
10. ODC = HEA = GFB

1 1
R2 sin A cos A 2R 2 sinC cosC cos2 A R 2 sin A sinB sinC
2 3
First two equality gives, tan A = 4 sin C cos C
From first and last, 3 cos A = 2 sin2 C (1 + 4 cos2 C) cos A
3 = 2 sin2 C (1 + 4 cos2 C)
3 1
sinC or
2 2
11. Score of 5 can be obtained as 5 or (1, 4) or (1, 1, 3) or (1, 1, 1, 2)

1 1 1 1
P (scoring 5) = 2 3 4 similarly
6 6 6 6
1 1 1 1 1
P (scoring 6) = 2 3 4 5
6 6 6 6 6
1 1 1 1 1
P (scoring 7) = 2 3 4 5 6
6 6 6 6 6
P (scoring 1) is impossible event
12.-13. Let OM = d D L C
MDC ~ AMB x x
AK2 + OK2 = AO2 = DO2 = DL2 + OL2
M
k2x2 sin2 + (kx cos d)2 = x2 sin2 + (x cos + d)2 O
(k2 1)x2 = 2xd (k + 1) cos as k + 1 > 0 kx kx
(k 1)x = 2d cos
Now, AB CD = 2(AK LD) = 2(k 1)x sin = 2d sin 2 A K B
If AMB = 60, = 30
3
If AMD = 60, = 60 in either case sin2
2
AB CD = 2 3
14.-16. a, c, b are in H.P.

2 1 1

c a b
x y 1 1 1
Line 0 passes through a fixed point
a b c
2, 2

1 1
So centre of ellipse is ,
2 2
Which is also centre of auxiliary circle
1 1
p , q radius of auxiliary circle = 2
2 2
11
Length of major axis = 4 also it segment of focal chord are 1, 2

1 1 4 8
2 b2
1 2 b 3
2 2
1 1 8
Director circle x y 4
2 2 3
SECTION B
1. (A) 20, b, c are in H.P.

1 1 2

20 c b
This can be written as (40 b)( c + 20) = 800 we must have 20 < b < 40 or 0 < 40 b < 20,
consider factorisation of 800 in which one term is less that 20
(40 b)(c + 20) = 800 = 1 800 = 2 400 = 4 200 = 5 160 = 8 100 = 10 80 = 16 50
Thus pair (b, c) = (39, 780), (38, 380), (36, 180), (35, 140), (32, 80), (30, 60), (24, 30) but b
divides c
Only 5 triples satisfy required requirement
(B) Solutions of m + n + p = 10, are 3 10 1C3 1
(C) ab + b a + 1 = 0
(a + 1)(b 1) = 2
(a + 1, b 1) {(1, 2), (1, 2), (2, 1), (2, 1)}
(a, b) {(0, 1), (2, 3), (1, 0), (3, 2)
(D) Let z = x + iy then (x + iy)20 = x iy
|z|20 = |z| |z|(|z|19 1) = 0
|z| = 1 or 0
|z| = 0
Ordered pair (0, 0)
Let z 0 then (x + iy)20 (x + iy) = x2 + y2
z21 = |z|2 = 1 z21 1 = 0, which are 21 roots
2. (A) f(x) = x4 + ax3 + bx2 + cx + d

, , , are real roots of equation f(x) = 0
f(x) = (x )(x )(x )(x )
|f(i)| = 1 (1 + 2)(1 + 2)(1 + 2)(1 + 2) = 1 this is possible if = = = = 0
a=b=c=d=0
(B) x5 1 = 0
4 3 2
(x 1)(x + x + x + x + 1) = 0
2
x x x3 x4 x x2 x3 x4

1 x 2 1 x 4 1 x 1 x3 1 x2 1 x 4 x5 x x5 x3
=
x

x2

x2

x
= 2
x

x2
=

2 x x 5 x2 x 4
2

2
1 x 2 1 x 4 1 x 4 1 x2 1 x 1 x4 1 x2 x4 x6
1 1 1 1 3
(C) cos x 0 cos x 1 and cos x
2 2 2 2 2
x2
1
cos x 1 f(x) = 0
2 f x 0
x1
12
(D) Let AD = x, BAD = D

BD C
In ABD, 2R
sin x 2 3
2 3
sin = 60
4 A 1
x 2 1 BD 2 B
Using cosine rule cos 60
2x
1 3 5
BD
2
1 3
a , b
2 2
SECTION C
1. f(9) = f(4 + 5) = f(4.5) = f(20)
= f(16 + 4) = f(16.4) = f(64)
= f(8.8) = f(8 + 8) = f(16)
= f(4.4) = f(4 + 4) = f(8)
2. g(x) = f(x) f(x) .. (1)
g(x) = f(x) 2f(x) .. (2)
F(x) = (2f(x)f(x) + 2g(x)g(x))(f2 (x) + g2(x)) + (f 2(x) + g2(x))(2f(x)f(x) 2g(x)g(x)) .. (3)
Using (1) and (2) in equation (3), we get F(x) = 0
F(x) is constant function F(0) = 1 = F(1)
3. f(x) = tan1 (tan x)
5
f r f 1 f 2 f 3 f 4 f 5 = 1 + 2 + 3 + 4 + 5 2 = 15 5
r 1
a = 15, b = 5
4. Minimum area will be in case of square with vertices
2, 2 , 2, 2 ,
2, 2 and 2, 2
Minimum area = 8s
200 200
r
5. r x r r 1 x
r 0 r 0
200
0 1x ..... 200 x 200 0 1 1 x ..... 200 1 x
201 100
= 0 1 1 x ..... 99 1 x
99 1 x 1 x

x
100200 101
Equating coefficient of x , x , .., x respectively we get
201 201 201
100 = C101, 101 = C102, .., 200 = C201
200
A r 100 101 ..... 200 2200
r 100
200
When 2 is divided by 15 we get remainder 1
6. Take B as the origin, BC and BA as x and y axis y
and z axis perpendicular to the plane of ABC 3 3
3
0, 6, 0 A D ,
2 2
, 3

3
BA 6j , CD 6 i j 3k
2 2

n BA CD = 3k 3 2i 3 2i k

n 2 x
The minimum distance d = BC 3 2 B(0) C
n 3 6, 0, 0

Sol 10

Uploaded by

Copyright:

Available Formats

Sol 10

Uploaded by

Document Information

Original Description:

Original Title

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

Sol 10

Uploaded by

Copyright:

Available Formats

1

ANSWERS, HINTS & SOLUTIONS

Q. No. PHYSICS CHEMISTRY MATHEMATICS

2. Since, Electrostatic potential is zero at all points on axis,

3. Va Vb Vc because electric field inside conductor is zero.

4. An infinite wire can be taken as half of closed loop.

5. Let us consider a strip of thickness dx at a distance x

11. Equivalent circuit is D

1. Ag | Ag2CO3 s | Na2CO3 aq. || KBr aq. | AgBr s | Ag s

5. The number of maxima in the radial charge density curve is (n l)

Solutions for Q. No. 12 to 13

15. Only non-resolvable compound is a 1 alcohol out of the given choices.

5. Total work done = Area of circle A (anticlockwise) Area of circle B (clockwise)

6. CCl3CH(OH)2 + NaOH CHCl3 + HCOONa+ + H2O

Mathematics PART III

8. Let ABCDPQRS be a cube, the numbers a, b, c, d, e, f be written on the faces

10. ODC = HEA = GFB

11. Score of 5 can be obtained as 5 or (1, 4) or (1, 1, 3) or (1, 1, 1, 2)

14.-16. a, c, b are in H.P.

Length of major axis = 4 also it segment of focal chord are 1, 2

1. (A) 20, b, c are in H.P.

2. (A) f(x) = x4 + ax3 + bx2 + cx + d

(D) Let AD = x, BAD = D

You might also like