Research Article: Treated Coconut Coir Pith As Component of Cementitious Materials
Research Article: Treated Coconut Coir Pith As Component of Cementitious Materials
Research Article
Treated Coconut Coir Pith as Component of
Cementitious Materials
Copyright 2015 Dana Konakova et al. This is an open access article distributed under the Creative Commons Attribution License,
which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
The presented paper deals with utilization of raw and treated coir pith as potential component of cementitious composites. The
studied material is coir pith originating from a coconut production. Its applicability as cement mixture component was assessed
in terms of the physical properties of concrete containing different amount of coir pith. Basic physical properties, compressive and
bending strength, and hygric transport characteristics as well as thermal properties belong among the studied characteristics. It
was proved that the concrete with 5% (by mass of cement) of this waste material shows appropriate physical properties and it gives
rise to an applicable material for building structures. Generally, the coir pith can be regarded as lightening additive. When 10% of
coir pith was added, it has led to higher deterioration of properties than what is acceptable since such dosing is greatly increasing
the total porosity. The influence of chemical treatment of coir pith was evaluated as well; both tested treatment methods improved
the performance of cementitious composites while the acetylation was somewhat more effective the treatment by NaOH.
waste gains on importance. An agroindustrial economy of [20] investigated 12-year-old mortar blocks reinforced by
many countries is frequently based on a production of coir fibers; they found them unaffected by the cementitious
agricultural materials and their further treatments. A huge environment. Abdullah et al. [21] studied mechanical prop-
problem, significantly affecting a sustainability of the process, erties and fracture behaviour of coconut fibre-based green
becomes a disposal of biomass. Although technologies for composites. They proved that the highest strength of modulus
its treatment (e.g., transformation into the energy) have of rupture and compressive strength were achieved in the
been already developed, a biomass is still not commonly case of 9% of coconut fibres reinforcement. Utilization of coir
utilized. Unfortunately, it is mainly being disposal, left on fibres as well as of a coir pith as cement replacement was
fields, or burned up. This usually happens in underdeveloped the matter of the study performed by Sonia and Dasan [22].
countries, which have almost no regulatory possibilities for They focused on mechanical properties, water imbibing, and
changing these heavily polluting methods, spoiling environ- microbial growth.
ment. Agricultural biomass can be found, for example, in The utilization of a coir pith as concrete additive is the
form of stems, leaves, residual straw, roots, hulls, and shells, matter of this study. Coir piths with three different chemical
and it originates from crop plants as sugar cane, wheat, treatments were used as additive in dosing of 5 and 10% of
maize, coconut palm, oil palm, rice, cotton, bamboo, and Portland cement content in concrete mixtures. Its applica-
so forth. Recycling of this waste and its further application bility was investigated by means of physical characteristics
in civil engineering could solve pollution problems, and it determination. Among studied properties belong the basic
could also lead to a conservation of natural resources. The physical characteristic, mechanical strength, hygric transport
most common agricultural waste, utilized as SCM, is a rice parameters, and thermal properties. Achieved results were
husk ash. Its application as Portland cement replacement compared with the reference material, concrete with no coir
up to 30% was studied by Muthadhi and Kothandara- pith added.
man [11]. They proved that a rice husk ash is a reactive
pozzolana, which improves mechanical strength as well as 2. Material and Samples
other properties. Gastaldini et al. [12] also dealt with this
alternative pozzolana; they proved positive effect of a rice Compositions of studied concrete mixtures are presented in
husk ash on concrete shrinkage as well as its resistance against Table 1. Portland cement CEM I 52.5 R was used as the main
chlorides. A corn cob ash can be used in form of cement binder component. Its chemical composition (obtained by
replacement also. According to the study of Adesanya and XRF methods) is presented in Table 2, while its mineralogical
Raheem [13], improvement of chemical resistance of concrete composition according to Bogue is in Table 3. The utilized
was observed in all studied mixtures with a corn cob ash coconut coir pith was obtained from the Gudiyattam con-
up to 15%. Zhang et al. [14] studied the effect of a wheat sortium of the state Tamil Nadu (India). As a secondary
husk ash, and they reported improvement of workability and product of coir fibres extraction from outer protective peel of
compressive strength of concrete mixtures. Possibilities of a coconut, the coir pith was separated mechanically, cleaned,
utilization of a bagasse ash as SCM were studied by Chi and dried. The coir pith has a lignocellulose nature and it
[15] and also by Ganesan et al. [16]. According to Ganesan is composed of 2-3% short fibres and cork. It contains high
et al., the best solution was found in 20% replacement, amount of lignin (31%) and cellulose (27%) and a ratio of
while Chi reported 10% as the best ratio of cement replace- carbon-nitrogen is around 100 : 1. Thanks to the high content
ment. of lignin, the coir pith is resistant to a biological degradation.
In this paper, the studied material is agricultural waste The coir pith was treated in order to increase its durability in
originating in a coconut production. Very little attention was cementitious matrix and also to reduce its negative effect on
paid to this topic and only few papers dealing with this topic the cement hydration course. Two different treatments were
were found in common sources. Olanipekun et al. [17] per- tested and compared with untreated coir pith: acetylation by
formed the comparative study of concrete properties using help of acetic anhydride and alkaline treatment by sodium
coconut shells and palm kernel shell as coarse aggregates. hydroxide. The dosing of coir pith in composite was set as
They concluded that, by utilization of the coconut shells, costs 5% and 10% of cement mass. Summary of the utilized coir
of a concrete production are reduced by 30%. Gunasekaran pith is shown in Table 4 and their granulometry is presented
et al. [18] did research dealing with coconuts shells also. They in Figure 1. The granulometry of treated coir pith was some-
tried to replace a part of a coarse aggregate by these shells and what coarser since the fine particles were lost during the
they studied its influence on plastic shrinkage and deflection treatment. Other components of designed concrete mixtures
characteristic of a concrete slab. They reported decrease of were four gradings of silica sand with 98.5% amount of SiO2
plastic shrinkage thanks to the utilized coconut shells. In and plasticizer SIKA 1035 (based on polycarboxylate ether).
their other study [19], they focused on a lightweight concrete Water/cement ratio was set as 0.52 in all cases of studied
with coconut shells as a coarse aggregate and Gunasekaran mixtures.
et al. studied its flexural properties. Mechanical strengths The measurements of material parameters of hardened
showed similar values as in the case of other lightweight concrete specimens were performed after 28 days of standard
concretes. Concrete with coconut fibres reinforcement was curing (100% RH). It took place in a conditioned laboratory at
the matter of the study performed by Ramli et al. [20]. They the temperature of 22 1 C and 2530% of relative humidity.
studied influence of three types of aggressive environments List of utilized specimens for particular measurement is
on strength and durability of the concrete. Ramli et al. presented in Table 5.
Advances in Materials Science and Engineering 3
Table 2: Chemical composition of cement CEM I 52.5 R. Figure 1: Granulometry curves of three types of coir pith.
Component Amount [% by mass]
CaO 64.9 Table 5: List of specimens.
SiO2 18.1
Dimension [mm] Number of
Al2 O3 6.4 Measurement
samples
Fe2 O3 2.4 Water vacuum 50 50 50 3
MgO 1 saturation method
Na2 O 0.3 Cups methods 115 3
K2 O 1.2 Absorption 50 50 50 3
SO3 4.9 experiment
P2 O5 0.2 Thermal properties 70 70 70 3
Porosimetry 50 50 50 2
Table 3: Mineralogical composition of cement CEM I 52.5 R. Mechanical 40 40 160 3
properties
Component Amount [% by mass]
C3 S 66.1
C2 S 2.3 on the determination of the external pressure needed to
C3 A 12.9 force the mercury into a pore against the opposing force of
C4 AF 7.3 the liquids surface tension. The pore size is then calculated
from the measured pressure using Washburns equation. The
experiments were carried out using instruments PASCAL 140
Table 4: Chemical treatment of coir piths. and 440 (Thermo Scientific). The range of an applied pressure
Treatment of coir pith Matrix density [kg m3 ] corresponds to the pore radius from 10 nm to 100 m.
Coir pith A Untreated 1535
Coir pith B Sodium hydroxide treated 1403 3.2. Mechanical Properties. Mechanical properties as com-
Coir pith C Acetylation treated 1341 pressive strength and bending strength were measured
according to standards [24]. A measurement of bending
strength was performed using the loading device MTS 100.
An arrangement of the experiment was the classical three-
3. Experimental Methods point bending with 100 mm span length. For determination
3.1. Basic Physical Properties. Bulk density, matrix density, of compressive strength, special loading device EU40 was
and open porosity were measured using the water vacuum employed. The samples from the measurement of bending
saturation method [23]. Each sample was dried in a drier to strengths were used. In the actual experiment, samples were
remove majority of the physically bound water. After that, put between two steel pressure plates with dimensions of 40
the samples were placed into a desiccator with deaired water. 40 mm. Great emphasis was given to the centring of the
During three hours, air was evacuated with a vacuum pump arrangement, since only simple compression should act.
from the desiccator. The samples were then kept under water
for not less than 24 hours. 3.3. Hygric Properties. Measurement of water vapour trans-
Characterization of a pore structure was determined by port parameters was performed applying the cup methods
the mercury intrusion porosimetry. This method is based (dry-cup and wet-cup) [25]. The aim of this measurement is
4 Advances in Materials Science and Engineering
to make two environments with different water vapour partial Table 6: Basic physical properties.
pressure. In dry-cup arrangement, cup contains silica gel,
which simulates 5% relative humidity. Specimens were water Bulk density Matrix density Open porosity
Material
and vapour proof insulated on four lateral sides. The aim of [kg m3 ] [kg m3 ] [%]
the insulating was to reach one dimension transport. Then, Ref. 2072 2526 18.0
they were put on the cups with silica gel and there they were A-5 1857 2307 19.5
air-sealed fixed. Cups were then placed into a climatic cham- A-10 1602 2214 27.6
ber which keeps temperature of 25 C and relative humidity B-5 1846 2287 19.3
of 50%. For two weeks, cups were periodically weighted. The B-10 1564 2178 29.0
steady state values of mass gain or mass loss determined C-5 1874 2303 18.6
by linear regression for the last five readings were used for C-10 1588 2208 28.1
the determination of water vapour diffusion resistance factor.
After two weeks, measurement cups were remade to the wet-
cup arrangement; it means that silica gel is exchanged for Table 7: Mechanical properties.
water, which simulates relative humidity of 95%. Otherwise,
experimental process of wet-cup measurement is the same as Compressive strength Bending strength
Material
in the case of dry-cup. [MPa] [MPa]
The water liquid transport was characterized by the water Ref. 63.1 9.8
absorption coefficient. Specimens were insulated, as in the A-5 40.1 9.3
case of water vapour transport, on four lateral sides. Then, A-10 15.2 4.3
the face side of specimens was immersed 1-2 mm in the B-5 47.6 8.5
water. Constant water level in the tank was achieved by a B-10 12.8 4.1
Mariotte bottle with two capillary tubes. One of them, inside C-5 48.3 9.5
diameter of 2 mm, was ducked under the water level. The
C-10 14.5 4.5
second one, inside diameter of 5 mm, was above water level.
The automatic balance allowed for recording the increase of
mass. The water absorption coefficient was calculated from
the sorptivity plot [26] which was set up from measured growing amount of coir pith. In the case of 5% coir pith,
data. Apparent moisture diffusivity was calculated from water the matrix density decreases by 9% and in the case of 10%
absorption coefficient by Kumaran equation [27], but this it goes down by 13%. Changes of open porosities, calculated
is just for an approximation of the real values of apparent from the above discussed values, are negligible when coir
moisture diffusivity. This value depends on moisture content, pith dosing is just 5% of cement. Higher difference can be
which is disregarded in Kumaran relation. observed in the higher amount of utilized coir pith. Changes
in pore structure of concrete material containing coir pith are
3.4. Thermal Properties. Using the device ISOMET 2104 more obvious from measured pore size distribution curves
[28], thermal conductivity and specific heat capacity were (Figure 2). The presence of coir pith caused increase of wide
determined. This commercial device applies a dynamic mea- range of capillary pores (diameter of 0.1 to 100 m) volume.
surement method so that time of a measurement reduces to No distinct influence of chemical treatment of individual
dozens of minutes. The measurement process is based on an types of coir pith can be observed, because achieved values
analysis of a temperature response of an analysed material of basic physical properties of concrete with different treated
to heat flow impulses. The heat flow is induced in a resistor coir pith are almost equal.
of a probe by a distributed electric power. The temperature
is recorded and evaluated from the polynomial regression. 4.2. Mechanical Properties. Compressive strength and bend-
Both thermal properties were determined in dependence on ing strength of composites are presented in Table 7. The
moisture content. utilization of coir pith always leads to the compressive
strength fall and the reference material shows the highest
4. Results and Discussion value. Generally, it can be deduced that by replacing 10%
of cement by coir pith (regardless of chemical treatment)
4.1. Basic Physical Properties. Results obtained from the water compressive strength decreases by about almost 78%. How-
vacuum saturation method are summarized in Table 6 while ever, in the case of 5% replacement, achieved results differ
the pore size distribution is shown in Figure 2. The highest and the influence of chemical treatment can be observed.
value of bulk density and also matrix density was obtained Concrete containing coir pith with no chemical treatment
by the reference material with no coir pith. Dosage of 5% achieved compressive strength by 36% lower; the chemical
of the coir pith leads to the bulk density decrease by about treated coir pith (both sodium hydroxide and acetic acid
10% and dosage of 10% causes the fall by about 24% what treatment) reduced the compressive strength just by about
is obviously caused by low bulk density of coir pith. The 24%. Bending strengths achieve almost similar values in the
matrix density of pure coir pith (Table 4) is lower than case of the reference material and the concretes with 5% of
what is typical for silicates (about 2500 kg m3 ); thus, the coir pith. When material contains 10% of studied coir pith, it
values of matrix density of composites also go down with leads to the bending strength decrease by 56%. In the case of
Advances in Materials Science and Engineering 5
1400
(ii) Mechanical properties were also decreased by utiliza-
tion of coir pith. Compressive strength of concrete
1300 containing 10% of coir pith went down by almost 78%;
therefore, utilization of such amount of waste material
1200
is not useful. However, utilization of 5% of SCM leads
1100 to quite appropriate results. In this case, positive effect
of chemical treatment was proved. When chemical
1000
treated coir pith was used, values of compressive
900 strength fell down by about 24%. Regarding bending
strength, 5% of coir pith led to comparable values
800
0 5 10 15 20 25 30
like in the case of reference material. When higher
Volumetric moisture content (%m3 m3 ) percentage of the waste material was used, bending
strength decreased by about 56%.
Ref. B-10
A-5 C-5 (iii) Measured hygric properties can be divided into two
A-10 C-10 parts according to physical state of water. Water liquid
B-5 transport characteristic and water vapour transport
characteristic were measured. It was proved that by
Figure 4: Influence of moisture and coir pith additive on specific utilization of 5% of coir pith ability of water transport
heat capacity. was comparable with reference concrete. However,
when 10% of cement was replaced, water transport
ability increases considerably.
capacity. When coir pith is used, it always leads to specific heat (iv) Thermal properties show high dependency on mois-
capacity increase. In the case of 5% cement replacement, the ture content. However, regarding the influence of coir
growth is by about 9%. Concretes containing 10% of coir pith pith utilized as cement replacement, it was proved
reach values by about 13% higher than the reference material. that this waste material improved thermal insulating
From achieved results of thermal characteristic, it can be abilities of final concrete. The higher amount of coir
deduced that utilization of coir pith leads to improvement pith material contains the better thermal insulator
of thermal insulating capabilities of concrete due to the concrete is.
lightening of concrete; the specific heat capacity, that is, ability
of material to accumulate heat, is also improved by coir pith The experimental results summarized above show that
admixing. although utilization of coir pith would be positive from
the economic as well as environmental point of view, its
5. Conclusions applicability is limited by final physical properties of concrete.
In our study, 5% of coir pith dosage leads to appropriate
The matter of this paper was to determine possibilities of building material. When 10% of this waste material is used,
utilization of coir pith as component of cementitious mate- physical properties are deteriorated more than what is accept-
rials. Coir pith is agricultural waste originating in coconut able.
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