How Does The Fenton's Reaction Work ?

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What are examples of organic materials?

Examples of organic materials include wood, paper, textiles and animal parts. Organic materials
are any type of materials that are found in nature or are made out of items that are found in
nature. Organic materials are composed solely of organic compounds. These compounds contain
the element carbon, which is widely found in nature in plants and animals. Organic materials
naturally deteriorate over time, according to Preservation 101.

Fenton's reagent is a solution of hydrogen peroxide with ferrous iron as a catalyst that is used
to oxidize contaminants or waste waters. Fenton's reagent can be used to destroy organic
compounds such as trichloroethylene (TCE) and tetrachloroethylene (perchloroethylene, PCE). It
was developed in the 1890s by Henry John Horstman Fenton as an analytical reagent.

How does the Fenton's reaction work ?


After addition of the iron and the hydrogen peroxide, they are going to react together to generate
some hydroxyl radicals as it shows in the following equations:
Fe2+ + H2O2 ----> Fe3+ + .OH + OH-
Fe3+ + H2O2 ----> Fe2+ + .OOH + H+
The typical range for the iron dose is 1 part of Fe per 5-25 parts of H2O2.

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