SAFETY DATASHEET

(Following Regulations (EC) No 1907/2006 & (EC) No 1272/2008)

SDS Number: 609 Date of first issue: 01 February 2000 Date of last revision: 21 October 2013

1 - Identification of product
1.1 - Identification of Product
Firemaster FireBarrier 110, Firemaster FireBarrier 135,
The above-mentioned products are cements.
1.2 - Use of Product

These products are used for fire protection to concrete tunnel linings, structural steel and vessels.

1.3 - Identification of Company

U.K. THERMAL CERAMICS LIMITED
Tebay Road, Bromborough
Wirral, Merseyside CH62 3PH
Tel. : +44 (0) 151 334 4030
Fax : +44 (0) 151 334 1684
www.morganthermalceramics.com
[email protected]
EMERGENCY INFORMATION
Tel: + 44 (0) 7931 963 973
Language: English
Opening hours: Only available during office hours

1/8 609
2 - Hazard Identification
2.1 - Classification of the substance/ mixture
2.1.1 CLASSIFICATION ACCORDING TO REGULATION (EC) NO 1272/2008
Classified as category 1 damaging to eyes, category 2 skin irritant, category 3 respiratory irritant and category 1 skin sensitizer

2.1.2 CLASSIFICATION ACCORDING TO DIRECTIVE 1999/45/EEC

Classified as causing serious damage to eyes and a skin sensitizer
2.2 - Labelling Elements
2.2.1 LABELLING ELEMENTS ACCORDING TO REGULATION (EC) NO 1272/2008

Hazard pictogram: GHS05

Signal Word: Danger
Hazard statements:
H315: Causes skin irritation
H318: Causes serious eye damage
H317: May cause an allergic skin reaction
H335: May cause respiratory irritation

2.2.2 LABELLING ELEMENTS ACCORDING TO DIRECTIVE 1999/45/EEC

Irritant Xi
R41 Risk of serious damage to eyes.
R43 May cause sensitisation by skin contact
2.3 - OTHER HAZARDS WHICH DO NOT RESULT IN CLASSIFICATION
CHRONIC EFFECTS FOR CRYSTALLINE SILICA
These products may contain minimal amounts of crystalline silica. Prolonged/repeated inhalation of respirable crystalline silica dust may cause
delayed lung injury (silicosis).
IARC (International Agency for Research on Cancer) states that there is "sufficient evidence in humans for the carcinogenicity of inhaled
crystalline silica in the form of quartz or cristobalite from occupational sources to classify crystalline silica as carcinogenic to humans (Group 1)".
(Monograph V 68)
In making the overall evaluation the Working Group noted however that carcinogenicity in humans was not detected in all industrial
circumstances studied.

3 - Composition / Information On Ingredients

DESCRIPTION
These products are cements for fire protection.
Composition
COMPONENT % CAS Number Index number REACH Registration Number
Cement <20 EINECS No. 266-043-4 Not Applicable Not yet available
Clay 20-60 Not Applicable Not Applicable Not yet available
Alumina <30 EINECS No. 215-691-6 Not Applicable Not yet available
Alumino silicate <20 Not Applicable Not Applicable Not yet available
Calcium sulfate <30 Not Applicable Not Applicable Not yet available
Saw dust <10 Not Applicable Not Applicable Not yet available
Other inert mineral material <40 Not Applicable Not Applicable Not yet available

None of the components are radioactive under the terms of European Directive Euratom 96/29.

2/8 609
4 - First-Aid measures
4.1 - Skin

In case of skin irritation rinse affected areas with water and wash gently. Do not rub or scratch exposed skin.
4.2 - Eyes

In case of eye contact flush abundantly with water; have eye bath available. Do not rub eyes. Seek medical attention is irritation persists.
4.3 - Nose and Throat

If these become irritated move to a dust free area, drink water and blow nose. Seek medical attention if irritation persists.
If symptoms persist, seek medical advice.

5 - Fire-fighting measures

Non combustible products. However, virgin product binder may burn and produce gases and/or fumes.
Packaging and surrounding materials may be combustible. Use extinguishing agent suitable for surrounding combustible materials.

6 - Accidental Release Measures

6.1 - PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES

Provide the workers with appropriate protective equipment until the situation is restored to normal (see section 8).
6.2 - ENVIRONMENTAL PRECAUTIONS

Prevent further dust dispersion for example by damping the materials.

Do not flush spillage to drain and prevent from entering natural watercourses.
Check for local regulations, which may apply
6.3 - METHODS AND MATERIALS FOR CONTAINMENT AND CLEAN UP

Pick up large pieces and use a vacuum cleaner.

If brushes are used, ensure that the area is wetted down first.
Do not use compressed air for clean up.
Do not allow to become windblown.

7 - Handling and storage

7.1 - PRECAUTIONS FOR SAFE HANDLING

Handling can be a source of dust emission and therefore the processes should be designed to limit the amount of handling. Whenever possible,
handling should be carried out under controlled conditions (i.e., using dust exhaust system).
Regular good housekeeping will minimise secondary dust dispersal.
7.2 - CONDITIONS FOR SAFE STORAGE

Store in original packaging in dry area whilst awaiting use

Avoid damaging packaging.
Recyclable cardboard and/or plastic films are recommended for packaging.
7.3 - SPECIFIC END USE

Please refer to your local Morgan Thermal Ceramics’ supplier.

3/8 609
8 - Risk Management Measures / Exposures Controls / Personal Protection

Industrial hygiene standards and occupational exposure limits vary between countries and local jurisdictions. Check which exposure levels apply to your facility. If
no regulatory dust or otherstandards apply, a qualified industrial hygienist can assist with a specific workplace evaluation including recommendations for
respiratory protection. Examples of exposure limits for respirable dust (in January 2002) are given below:
EXPOSURE LIMIT*
COUNTRY Respirable Crystalline SOURCE
Quartz Cristobalite
Dust silica
3 mg/m3 or
Germany 0.15 mg/m3 0.15 mg/m3 TRGS 900,
6 mg/m3
France 5 mg/m3 0.10 mg/m3 0.05 mg/m3 Décret 97-331 du 10 avril 1997
U.K. 4 mg/m3 0.30 mg/m3 HSE - EH40
* Gravimetric concentrations of respirable dust – 8-hour time weighted average.
8.2 - EXPOSURE CONTROLS
8.2.1 APPROPRIATE ENGINEERING CONTROLS
Review your applications in order to identify potential sources of dust exposure.
Local exhaust ventilation, which collects dust at source, can be used. For example down draft tables, emission controlling tools and materials
handling equipment.
Keep the workplace clean. Use a vacuum cleaner fitted with a HEPA filter. Avoid brushing and compressed air.

If necessary, consult an industrial hygienist to design workplace controls and practices.

The use of products specially tailored to your application(s) will help to control dust. Some products can be delivered ready for use to avoid
further cutting or machining. Some could be pre-treated or packaged to minimise or avoid dust release during handling.
Consult your supplier for further details
8.2.2 - Personal Protective Equipment

Skin Protection
Use of gloves and work clothes is recommended.

Eye Protection
Wear safety glasses

Respiratory Protection
Use appropriate respiratory protective equipment (RPE) if necessary.

Information and Training of workers

Workers should be informed on:
• The requirements for the use of protective equipment and clothing.
Workers should be trained on:
• The proper use of protective equipment
8.2.3 - Environmental Exposure Controls

Refer to local, national or European applicable environmental standards for release to air water and soil.
For waste, refer to section13

4/8 609
9 - Physical and chemical properties

APPEARANCE
Grey Powder

BOILING POINT
Not applicable

FLASH POINT
Not applicable

AUTOFLAMMABILITY
Not applicable

OXIDISING PROPERTIES
Not applicable

RELATIVE DENSITY
1.5 - 3 g/cm³

SOLUBILITY
Not applicable

PARTITION COEFFICIENT
Not applicable

ODOUR
None

MELTING POINT
> 1000°C

FLAMMABILITY
Not applicable

EXPLOSIVE PROPERTIES
Not applicable

VAPOUR PRESSURE
Not applicable

pH
Not applicable

LENGTH WEIGHTED GEOMETRIC MEAN DIAMETER

5/8 609
LENGTH WEIGHTED GEOMETRIC MEAN DIAMETER
Not applicable

10 - Stability and Reactivity

10.1 - Reactivity

The material is stable and non reactive.

10.2 - Chemical Stability

The product is inorganic, stable and inert

10.3 - Possibility of Hazardous Reactions

During first heating, oxidation products from the organic binder might be emitted in a temperature range from 180°C to 600°C. It is
recommended to ventilate the room until gases and fumes have disappeared. Avoid exposure to high concentrations of gas or fumes.
10.4 - Conditions to Avoid

Please refer to handling and storage advice in Section 7

10.5 - Incompatible Materials

None
10.6 - Hazardous decomposition products

Upon heating above 900°C for sustained periods, this amorphous material begins to transform to mixtures of crystalline phases. For further
information please refer to Section 16.

11 - Toxicological information
11.1 - TOXICOKINETICS, METABOLISM AND DISTRIBUTION

11.1.1 BASIC TOXICOKINETICS

As manufactured, these products may contain a minimal amount of crystalline silica.
Exposure is predominantly by inhalation or ingestion, available toxicological information is as follows:

11.1.2 Human Toxicological data

Epidemiology for crystalline silica
Prolonged/repeated inhalation of respirable crystalline silica dust may cause delayed lung injury (silicosis).
In evaluating crystalline silica as a cancer risk, the International Agency for Research on Cancer (IARC) reviewed several studies from different
industries and concluded that crystalline silica from occupational sources inhaled in the form of quartz or cristobalite is carcinogenic to humans
(Group 1) [IARC Monograph; vol.68; June 1997]. However, in reaching its conclusion, IARC stated that the carcinogenicity in humans could not
be found in all industries reviewed and that carcinogenicity might be dependent on inherent characteristics of crystalline silica or on external
factors affecting biological activity (e.g., cigarette smoking) or distribution of its polymorphs.

11.2 - INFORMATION ON TOXICOLOGICAL EFFECTS

Experimental studies for crystalline silica

Animals exposed to very high concentrations of crystalline silica, artificially or by inhalation, have reported fibrosis and tumours (IARC
Monographs 42 and 68).
Inhalation and intratracheal installation of crystalline silica in rats caused lung cancer. However, studies in other species such as mice and
hamsters caused no lung cancer. Crystalline silica also caused fibrosis in rats and hamsters in several inhalation and intratracheal installation
studies.

ACUTE TOXICITY
Lethal dose 50 % (LD50) / lethal concentration 50% (LC50): N.A.

12 - Ecological information

These products are inert materials that remain stable overtime.

No adverse effects of this material on the environment are anticipated.

6/8 609
13 - Disposal Considerations
WASTE TREATMENT
Waste from these materials may be generally disposed off at a landfill, which has been licensed for this purpose. Please refer to the European
list (Decision N° 2000/532/CE as modified) to identify your appropriate waste number, and insure national and/or regional regulations are
complied with.

Unless wetted, such a waste is normally dusty and so should be properly sealed in containers for disposal. At some authorised disposal sites,
dusty waste may be treated differently in order to ensure they are dealt with promptly to avoid them being windblown. Check for any national
and/or regional regulations, which may apply.
Additional information

When disposing of waste and assigning European Waste Code (EWC) any possible contamination during use will need to be considered and
expert guidance sought as necessary.

14 - Transport information

Not classified as dangerous goods under relevant international transport regulations (ADR, RID, IATA, IMDG).
Ensure that dust is not windblown during transportation.

Definitions:

ADR Transport by road, council directive 94/55/EC

IMDG Regulations relating to transport by sea
RID Transport by rail, Council Directive 96/49/EC
ICAO/IATA Regulations relating to transport by air
ADN European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways

15 - Regulatory information
SAFETY HEALTH AND ENVIRONMENT REGULATIONS/LEGISLATION SPECIFIC FOR THE SUBSTANCES OR MIXTURES
EU regulations:

- Council Directive 67/548/EEC "on the approximation of the laws, regulations and administrative provisions relating to the classification,
packaging and labelling of dangerous substances as modified and adapted to the technical progress" (OJEC L 196 of 16 August 1967, p.1
and its modifications and adaptations to technical progress).
- Council Directive 1999/45/EC of 31 May 1999 concerning the approximation of the laws, regulations and administrative provisions of the
Member States relating to the classification, packaging and labelling of dangerous preparations (OJ L 200 of 30.7.1999)
- Regulation (EC) No 1907/2006 dated 18th December 2006 on Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH)
- Regulation (EC) No 1272/2008 dated 20th January 2009 on classification, labelling and packaging of substances and mixtures (OJ L 353)
- Commission Directive 97/69/EC of 5 December 1997 adapting to technical progress for the 23rd time Council Directive 67/548/EEC (OJEC
of 13 December 1997, L 343).
- Commission regulation (EC) No 790/2009 of 10 August 2009 amending, for the purposes of its adaptation to technical and scientific
progress, Regulation (EC) No 1272/2008 of the European Parliament and of the Council on classification, labelling and packaging of
substances and mixtures.
- The 1st Adaptation to Technical Progress (ATP) to Regulation (EC) No 1272/2008 enters into force on 25 September 2009. It transfers the
30th and 31st ATPs of Directive 67/548/EEC to the Regulation (EC) No 1272/2008.
PROTECTION OF WORKERS
Shall be in accordance with several European Directives as amended and their implementations by the Member States:
a) Council Directive 89/391/EEC dated 12 June 1989 "on the introduction of measures to encourage improvements in the safety and health
of workers at work" (OJEC (Official Journal of the European Community) L 183 of 29 June 1989, p.1).
b) Council Directive 98/24/EC dated 7 April 1998 "on the protection of workers from the risks related to chemical agents at work" (OJEC L
131 of 5 May 1998, p.11).

OTHER POSSIBLE REGULATIONS

Member States are in charge of implementing European Directives into their own national regulation within a period of time normally given
in the Directive. Member States may impose more stringent requirements. Please always refer to any national regulation.
Chemical Safety Reports have been requested from suppliers, as soon as this information is available it will be shared with downstream users.

7/8 609
16 - Other Information
useful references

(the directives which are cited must be considered in their amended version)
- Council Directive 89/391/EEC dated 12 June 1989 "on the introduction of measures to encourage improvements in the safety and health of
workers at work" (OJEC L 183 of 29 June 1989, p.1).
- Regulation (EC) No 1907/2006 dated 18th December 2006 on registration, Evaluation, Authorisation and Restriction of Chemicals (REACH)
- Regulation (EC) No 1272/2008 dated 20th January 2009 on classification, labelling and packaging of substances and mixtures (OJ L 353)
- Commission Directive 97/69/EC of 5 December 1997 adapting to technical progress for the 23rd time Council Directive 67/548/EEC (OJEC
of 13 December 1997, L 343).
- Council Directive 98/24/EC of 7 April 1998 "on the protection of the health and safety of workers from the risks related to chemical agents at
work" (OJEC L 131 of 5 May 1998, p11).
precautionary measures
Additional information and precautions to be considered upon removal of after service material

Continuous use of these products at temperatures above 900°C may, as with many other refractories, lead to the formation of cristobalite (a
type of crystalline silica).
Please refer to sections 2, 11 and to national regulation on crystalline silica.

High concentrations of dusts may be generated when after-service products are mechanically disturbed during operations such as wrecking.
Therefore Morgan Thermal Ceramics recommends:
a) control measures are taken to reduce dust emissions;
b) all personnel directly involved wear an appropriate respirator to minimise exposure; and
c) Compliance with local regulatory limits.
website
For more information connect to:
The Morgan Thermal Ceramics’ website: (http://www.morganthermalceramics.com/)
Or the ECFIA’s website: (http://www.ecfia.eu)
Or Deutsche KeramikFaser-Gesellschaft e.V’ website: (http://www.dkfg.de/)
Revision Summary
General Update of SDS to comply with REACH Regulation, changes to sections 1-16
technical data sheets

For more information on individual products please see the relevant technical data sheet listed below:
Product Datasheet Code
Other Information
NOTICE:
The information presented herein is based on data considered to be accurate as of the date of preparation of this Material Safety Data Sheet.
However safe as provided by law, no warranty or representation, express or implied, is made as to the accuracy or completeness of the
foregoing data and safety information, nor is any authorisation given or implied to practice any patented invention without a licence. In addition,
no responsibility can be assumed by the vendor for any damage or injury resulting from abnormal use, from any failure to adhere to
recommended practices, or from any hazards inherent in the nature of the product (however, this shall not act to restrict the vendor’s potential
liability for negligence or under statute).

8/8 609