Msds - PHP Asetat
Msds - PHP Asetat
Msds - PHP Asetat
2 2
Fire
3 0
Re a c t iv it y 0
P e rs o n a l H
P ro t e c t io n
Toxicological Data on Ingredients: Acetic acid: ORAL (LD50): Acute: 3310 mg/kg [Rat]. 4960 mg/kg [Mouse]. 3530 mg/kg
[Rat]. DERMAL (LD50): Acute: 1060 mg/kg [Rabbit]. VAPOR (LC50): Acute: 5620 ppm 1 hours [Mouse].
p. 1
Acetic acid vapors may form explosive mixtures with air. Reactions between acetic acid and the following materials
are potentially explosive: 5-azidotetrazole, bromine pentafluoride, chromium trioxide, hydrogen peroxide, potassium
permanganate, sodium peroxide, and phorphorus trichloride. Dilute acetic acid and dilute hydrogen can undergo an
exothermic reaction if heated, forming peracetic acid which is explosive at 110 degrees C. Reaction between chlorine
trifluoride and acetic acid is very violent, sometimes explosive.
Small Spill:
Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. If
necessary: Neutralize the residue with a dilute solution of sodium carbonate.
Large Spill:
Flammable liquid. Corrosive liquid. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. If the
product is in its solid form: Use a shovel to put the material into a convenient waste disposal container. If the product is in
its liquid form: Absorb with DRY earth, sand or other non-combustible material. Do not get water inside container. Absorb
with an inert material and put the spilled material in an appropriate waste disposal. Do not touch spilled material. Use water
spray curtain to divert vapor drift. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance
on disposal. Neutralize the residue with a dilute solution of sodium carbonate. Be careful that the product is not present at a
concentration level above TLV. Check TLV on the MSDS and with local authorities.
Precautions:
\Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not ingest. Do not
breathe gas/fumes/ vapor/spray. Never add water to this product. In case of insufficient ventilation, wear suitable respiratory
equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and
eyes. Keep away from incompatibles such as oxidizing agents, reducing agents, metals, acids, alkalis.
Storage:
Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep container tightly closed and
sealed until ready for use. Avoid all possible sources of ignition (spark or flame).
Engineering Controls:
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective
threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location.
Personal Protection:
Splash goggles. Synthetic apron. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves
(impervious).
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits:
TWA: 10 STEL: 15 (ppm) [Australia] TWA: 25 STEL: 27 (mg/m3) [Australia] TWA: 10 STEL: 15 (ppm) from NIOSH TWA: 25
STEL: 37 (mg/m3) from NIOSH TWA: 10 STEL: 15 (ppm) [Canada] TWA: 26 STEL: 39 (mg/m3) [Canada] TWA: 25 STEL: 37
(mg/m3) TWA: 10 STEL: 15 (ppm) from ACGIH (TLV) [United States] [1999] TWA: 10 (ppm) from OSHA (PEL) [United States]
TWA: 25 (mg/m3) from OSHA (PEL) [United States]Consult local authorities for acceptable exposure limits.
p. 3
Physical state and appearance: Liquid.
Odor: Pungent, vinegar-like, sour (Strong.)
Taste: Vinegar, sour (Strong.)
Molecular Weight: 60.05 g/mole
Color: Colorless. Clear (Light.)
pH (1% soln/water): 2 [Acidic.]
Boiling Point: 118.1°C (244.6°F)
Melting Point: 16.6°C (61.9°F)
Critical Temperature: 321.67°C (611°F)
Specific Gravity: 1.049 (Water = 1)
Vapor Pressure: 1.5 kPa (@ 20°C)
Vapor Density: 2.07 (Air = 1)
Volatility: Not available.
Odor Threshold: 0.48 ppm
Water/Oil Dist. Coeff.: The product is more soluble in water; log(oil/water) = -0.2
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water, diethyl ether, acetone.
Solubility:
Easily soluble in cold water, hot water. Soluble in diethyl ether, acetone. Miscible with Glycerol, alcohol, Benzene, Carbon
Tetrachloride. Practically insoluble in Carbon Disulfide.
Routes of Entry: Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion.
p. 4