Agilent Presentation On DGA - Gas Chromatography For The Energy Industry PDF
Agilent Presentation On DGA - Gas Chromatography For The Energy Industry PDF
Agilent Presentation On DGA - Gas Chromatography For The Energy Industry PDF
Facilitates Configuration
Optimized Performance
Common
w/o Analyzer Factory Configured with Chemical Testing
Components
Field Verification
Customer
CD
Analyzers measure:
• H2, N2, O2, CO, and CO2
• C2 (ethane, ethylene, acetylene)
• C3 (propane, propylene),
• C4 (1-butene)
ASTM D3612-A Minimum Detection Limits for ASTM D3612-C Detection Limits, ppm
Component Gases Dissolved in Oil, ppm Compound (signal/noise = 3)
H2 5 H2 0.6
Hydrocarbons 1 O2 11.0*
CO2 25 N2 11.2
Atmospheric gases 50 CH4 0.06
CO 0.09
CO2 0.1
C2H2 0.05
C2H4 0.04
C2H6 0.04
C3H8 0.2
*Estimated from the H2 response.
Resource Allocation
Industry Regulation
• EPA and CEN have initiated programs to inventory GHG
emissions through continuous measurement.
• Continuous measurement provides meaningful information to
track trends and help in the fight against climate change.
Typical Chromatogram
7.143
700
N2O
600
ECD
CH4 20.18ppm v
500 CO2 376.4ppm v N2: carry gas
N2O 3.27ppm v
400 ArCH4, 2mL/min, make up
300
200
2 4 6 8 10 12 min
FID1 A, FID1A, Front Signal (GREEN_N2OE_JULY283\GREEN_JULY22_GC 2009-07-28 16-03-16\D000011.D)
pA
5.709
250
200
CO2
FID/ methanizer
150
N2: carry gas
100 CH4
3.314
50
0
2 4 6 8 10 12 min
N 2O , EC D 2 B
A r e a = 2 5 0 7 .4 0 3 0 4 * A m t + 6 6 .9 3 3 5 0 4
Standards sample information A re a R e l. R e s % ( 1 ) : - 2 3 .1 7 4
Greenhouse gases standards are diluted for multi-level
8000
calibration by dynamic blending N2O: 3.27 - 0.0327 ppm V 4
7000
5000
Original 10 X diluting 20 X diluting 100X diluting 4000
3000
CH4 20.18 2.018 1.009 0.2018
2000
CO2 376.4 37.64 18.82 3.764 3
1000 2
N2O 3.27 0.327 0.1635 0.0327 1
0 C o r r e la tio n : 0 .9 9 9 8 8
0 1 2 A m o u n t[p p m ]
C O 2 , F ID 1 A C H 4 , F ID 1 A
A r e a = 7 .4 0 3 9 9 6 8 4 * A m t - 5 .8 9 5 4 5 4 6 A r e a = 7 .4 0 4 9 5 0 9 8 * A m t - 0 .2 4 3 6 2 8 9
A re a R e l. R e s % ( 1 ) : 2 7 .3 5 8 A re a R e l. R e s % ( 1 ) : 2 3 .0 8 2
4 140 4
2500 CO2 : 376.4 - 3.764 ppm V CH4 : 20.18 - 0.2018 ppm V
120
2000
100
1500 80
60
1000
40
500 3
3 20
2 2
1 1
0 C o r r e la tio n : 0 .9 9 9 9 6 0 C o r r e la tio n : 0 .9 9 9 9 6
Hz ECD
146 N2O: 32.7ppb N2: carrier gas
144
Ar/CH4, 2mL/min, make up
142
140
138
136
134
pA 2 4 6 8 10 12 min
FID/ methanizer
10 CH4: 0.2 ppm CO2: 3.76 ppm
N2: carrier gas
9
2 4 6 8 10 min
… Excellent Sensitivity
7.143
220 ECD
N2O, 473ppb (calculated)
200
N2: carrier gas
Ar/CH4, 2mL/min, make up
180
160
SF6
8
26
.9
37
A9.658
a:
140
re
2 4 6 8 10 12 min
FID1 A, FID1A, Front Signal (AIR _JULY30\GREEN_JUN26_GC 2009-07-30 21-21-32\D000007.D)
pA
5.712
27.5
25
FID/ methanizer
22.5
CH4,2.7ppm N2: carrier gas
20 CO2, 380ppm
17.5
(calculated) (calculated)
3.315
15
12.5
10
2 4 6 8 10 12 min
Typical Chromatogram
N2O
5.140 - N2O
700
600
CH4 20.18ppm v
ECD channel
500
CO2 376.4ppm v N2: carry gas
400
300
N2O 3.27ppm v
200 ArCH4, 2ml/min, make up
1 2 3 4 5 6 7 min
FID1 A, FID1A, Front Signal (GREEN_WHOL...26_ARCH4_1M_JUN26\GREEN_JUN26_GC 2009-06-26 15-48-39\D000285.D)
pA
CO2
5.464 - CO2
200
175
150
125
100
25
0
1 2 3 4 5 6 7 min
TCD3 C, TCD3C, Aux Signal (GREEN_WHOL...UN26_ARCH4_1M_JUN26\GREEN_JUN26_GC 2009-06-26 15-48-39\D000285.D)
25 µV
1.801
160
140
TCD : channel
5.441 - CO2
120
100
40
20
1 2 3 4 5 6 7 min
dynamic blending 6 0 0 0
Concentration, ppm V 5 0 0 0
4 0 0 0
Original 10 X diluting 20 X diluting 100X diluting
3 0 0 0
0 1 2 A m o u n t[ p p m ]
C O 2 , F ID 1 A C H 4 , F ID 1 A
A re a = 7 .3 8 6 7 6 2 8 9 * A m t -0 .1 4 2 7 8 3 4 A re a = 7 .4 7 5 5 3 2 2 4 * A m t + 0 .2 7 0 2 8 3 9
A re a A re a
R e l. R e s % ( 1 ) : - 4 .6 3 9 R e l. R e s % ( 1 ) : - 2 3 .1 1 1
1 6 0
1 2 0
2 0 0 0
1 0 0
1 5 0 0 8 0
6 0
1 0 0 0
4 0
5 0 0 3
3 2 0
2
2
1 1
0 C o r r e la tio n : 1 .0 0 0 0 0 0 C o r r e la tio n : 0 .9 9 9 9 6
0 1 0 0 2 0 0 3 0 0 A m o u n t[ p p m ] 0 1 0 A m o u n t[ p p m ]
Typical Chromatogram
Typical Chromatogram
Typical Chromatogram
Publication Title
5990-5129EN Simultaneous Analysis of Greenhouse Gases by Gas
Chromatography